Modeling the Permeability Loss of Metallic Iron Water Filtration Systems     

Sabine Caré  Richard Crane  Paolo S. Calabrò  Antoine Ghauch  Emile Temgoua  Chicgoua Noubactep 《洁净——土壤、空气、水》2013,41(3):275-282

Over the past 30 years the literature has burgeoned with in situ approaches for groundwater remediation. Of the methods currently available, the use of metallic iron (Fe⁰) in permeable reactive barrier (PRB) systems is one of the most commonly applied. Despite such interest, an increasing amount of experimental and field observations have reported inconsistent Fe⁰ barrier operation compared to contemporary theory. In the current work, a critical review of the physical chemistry of aqueous Fe⁰ corrosion in porous media is presented. Subsequent implications for the design of Fe⁰ filtration systems are modeled. The results suggest that: (i) for the pH range of natural waters (>4.5), the high volumetric expansion of Fe⁰ during oxidation and precipitation dictates that Fe⁰ should be mixed with a non‐expansive material; (ii) naturally occurring solute precipitates have a negligible impact on permeability loss compared to Fe⁰ expansive corrosion; and (iii) the proliferation of H₂ metabolizing bacteria may contribute to alleviate permeability loss. As a consequence, it is suggested that more emphasis must be placed on future work with regard to considering the Fe⁰ PRB system as a physical (size‐exclusion) water filter device.  相似文献   

Dynamic,Mechanistic, and Thermodynamic Modeling of Zn(II) Ion Biosorption onto Zinc Sequestering Bacterium VMSDCM     

Vishal Mishra  Chandrajit Balomajumder  Vijay K. Agarwal 《洁净——土壤、空气、水》2013,41(9):883-889

The surface of the bacterial cells before the biosorption of Zn(II) ion has been found rough, heterogeneous, and non‐crystalline together with tremendous protrusions and negatively charged functional groups. The bacterium was characterized as rod shaped with Gram‐negative type of cell wall structure. In reaction dynamics, pseudo‐second‐order kinetics with higher linear correlation coefficient (R²) ranging between 0.97 and 0.99, lower sum of square errors (SSE) (0.035–0.081) and chi (χ²) (0.0013–0.009) provided a better explanation of sorption of Zn(II) ion on bacterium surface as compared to pseudo‐first‐order model. The removal of Zn(II) was governed by both film and intra‐particle diffusion at onset and later stage of sorption of metal ion on the surface of bacterial cells. The R² (0.92–0.94) for intra‐particle diffusion model was quite higher with lower values of SSE (9.56–16.33) and chi (χ²) (11.26–19.65) against the Bangham's model. The positive value of ΔH (16.628 × 10^?6 kJ/mol) and ΔS (5320.90 kJ/mol/K) showed that the biosorption of Zn(II) ion across liquid phase on bacterial surface was endothermic with increased randomness at solid–liquid interface. The negative values of ΔG demarcated the whole process as spontaneous in nature. In the present work, the distribution coefficient was found to be > 0.5 at various temperature ranges. At the attainment of equilibrium, the residual concentration of Zn(II) ion in liquid phase was around 0.6 mg/L, which was much below the limit described by United States Environmental Protection Agency (USEPA), i.e. 5 mg/L.  相似文献   

专题地图色彩的智能设计   总被引：1，自引：0，他引：1  

苏志军  李嘉星  刑光成 《地理空间信息》2013,11(1):144-146,15

为提高专题地图色彩设计的智能化水平,结合专题地图制图的实际需求,给出了一种专题地图色彩智能设计算法;其基本思路为以设计者的配色期望、色彩情感数据库和色彩协调理论为基础,采用粒子群算法进行配色方案的选取,借助孟.斯宾瑟的美度公式对配色方案进行进一步优化,进而得出专题地图智能设色的最优方案。  相似文献   

竣工前后房产面积测绘差异原因分析     

宋军 《测绘与空间地理信息》2013,(8):210-211,213

以竣工前后的房产面积差异分析为研究对象,从计算规则改变、设计变更、施工变更等五个方面分析了其中原因,全文是笔者长期工作实践基础上的理论升华,相信对从事相关工作的同行能有所裨益。  相似文献   

菲律宾海西北部岩芯记录的125 ka以来的地磁场强度及其影响因素          下载免费PDF全文

葛淑兰  L 《地球物理学报》2013,56(2):542-557

沉积物记录的地磁场强度首先提供了模拟地磁场演化的数据约束,其次提供了沉积物的年龄信息. 本文报道了菲律宾海西北部岩芯记录的地磁场相对强度,并结合岩石磁学和沉积学性质探讨了影响强度的各个因素. 除底部红粘土层的局部磁偏角偏转可能揭示了沉积后改造以外,磁化率各向异性和地磁场方向特征表明沉积物为原状沉积. 岩石磁学性质表明沉积物符合磁性均一性,可以记录可靠的地磁场强度. 由于红粘土层及其下部的磁偏角异常,本文讨论其上部约125 ka的结果. 常规归一方法获得的两个地磁场强度参数NRM/ARM(特征剩磁和非磁滞剩磁比值)和NRM/κ(特征剩磁和磁化率比值)与其它记录对比得到时间-深度对比点,对比点之间的年龄为线性内推或者外推. 地磁场强度时间模型上的岩芯氧同位素与全球氧同位素综合曲线一致证明强度结果的有效性和对比的正确性. 磁化率为归一参数的强度大多低于以非磁滞剩磁为归一参数的强度,频谱和相关分析证明NRM/ARM不与ARM和磁性矿物粒度(ARM/κ)相关,也没有轨道周期性,而NRM/κ却与κ和ARM/κ相关,而且有13~12 ka的周期. 由此我们认为NRM/ARM记录的地磁场强度比NRM/κ更好地消除了气候印记. 进一步探讨了超顺磁含量、碳酸钙含量、磁性矿物组成以及磁性矿物粒度变化与地磁场强度差值的关系,发现末次间冰期较高的超顺磁含量和磁性矿物粒度的较大范围变化造成了地磁场强度差值,后者至少造成了90%差异. 中等含量的碳酸钙和较小的磁性矿物组成变化不是磁场强度差值产生的原因. 如何校正磁性矿物粒度变化的影响将是下一步工作的重点.  相似文献   

PEDOGENESIS IN LATE PREHISTORIC INDIAN MOUNDS,UPPER MISSISSIPPI VALLEY     

Arthur E. Bettis III 《自然地理学》2013,34(3):263-279

Inceptisols are developed on silt loam, loam, and sandy loam Indian mounds at the Keller Mound Group and Bluff Top Mound in northeastern Iowa. The mounds date to the Allamakee Phase of the Late Woodland Period (ca. 1650–1250 B.P.) and are built with fill obtained from the A, E, and upper B horizons of pre-existing soils (Alfisols). Differences in the morphologic and chemical characteristics of soils on different mounds are attributed to textural differences of the mounds' fill. Coarse-textured mound fill is pedogenically altered at a faster rate than fine-textured fill, but total carbon percentage of the A horizon attains a steady state faster in fine-textured mound fill. Total phosphorus content is used to determine from which horizons of pre-existing soils the specific layers of mound fill originated. Rates and pathways of pedogenesis in mound fill may not provide good analogues for the early stages of soil development in materials that have not undergone previous weathering and subsequent modification by humans. Nevertheless, mound soils are useful benchmarks for some pedologic studies since they provide time lines for evaluating minimum rates for development of argillic and albic horizons, as well as attainment of the Alfisol order.  相似文献   

From data to decision-making – experiences in Integrated Earth Observation (IEO)     

Györk Fülöp  Péter Hargitai  Ildikó Szikszainé Szigeti  Katalin Takács 《国际地球制图》2013,28(1):46-62

Within the confines of Earth Observation Scientific Knowledge and Technology Transfer in Hungary (EKAT) titled ESA PECS project we gained forum for utilization of our earth observation (EO) knowledge and possibility for further development of experiences. The project aims the horizontal preparation of Hungary for ESA membership – for a dynamically developing sphere in the common part of science, technology and business. For the efficient transfer and dissemination, we preconceived target groups and principles to reach main take-up points and to open new forums of information exchange. Nowadays, user-friendly service, complex supply and real-validation process all have great importance. Joining units of suitable data choice, entire ingestion–processing chains and ergonomic interfaces can only offer a timely and professional solution for the challenges of industry and business sectors. It has to be clearly seen, that information and communication technologies (ICT) and information control becomes a more and more significant part of EO services.  相似文献   

明渠非恒定流流速分布及推移质运动研究进展          下载免费PDF全文

马爱兴  陆彦  陆永军  曹民雄 《水科学进展》2012,23(1):134-142

明渠非恒定流流速分布及非恒定流作用下推移质运动分别是水力学和泥沙运动力学研究中的重要问题之一。近几十年来,国内外许多学者在这些领域做过很多探索,取得了一定进展,也存在较多问题。在总结相关研究成果的基础上,简述了明渠非恒定流试验方法、流速分布、床面切应力、非恒定流输沙与水流运动不同步现象、产生原因、以及非恒定流推移质输沙公式等方面的成果,指出了现有研究中存在的不足,提出了需要进一步研究的关键问题:应用先进的量测仪器,研究非恒定流作用下非均匀沙运动输移规律。  相似文献   

震后茂县牟托村堆积物特征与植被分布关系     

闵维康  吴勇  刘海  姜丽丽  陈东 《地下水》2012,(4):147-149

"5·12"大地震后,茂县牟托地区的地形地貌和生态系统受到很大的破坏。本文对茂县牟托地区典型斜坡的植物生长状况、土壤颗粒组成、土壤含水率进行了调查分析,获得了土壤颗粒大小、渗透性、含水率与植物生长之间的关系;研究表明,土壤颗粒组成中,细颗粒所占比例越高,其渗透系数越小,土壤含水率越大,植物的生长状况愈佳;土壤细颗粒所占比例相近的情况下,含水率高的地区植物生长好。根据研究成果,结合生态恢复的技术和方案实施的安全性以及可行性,提出水泥喷灌、修筑挡水阶梯和排水沟、种植植物等生态恢复的方案以及保持斜坡稳定的措施。  相似文献   

板桥学校液化带工程地质条件及液化土层特性          下载免费PDF全文

侯龙清  陈松  陈革  徐红梅  程丽红 《水文地质工程地质》2012,39(1):102-106

砂土液化是地震主要次生地质灾害之一。在512汶川地震中,德阳等地发生较大面积砂土液化现象。为详细了解液化带工程地质基本特征,选择板桥学校液化带进行详细液化震害调查、钻探和现场试验。结果表明:（1）液化震害典型,主要包括喷水冒砂、地表裂缝、侧移和基础下沉等;（2）砾石层是唯一的无粘性土层,砾石层分为性质不同的全新世沉积和更新世沉积两部分,未见砂层分布;（3）液化土层是全新统砾石层,该砾石的颗粒大小分布特征表现为级配不良,并有粒组缺失现象;（4）非液化盖层对喷出物有过滤作用,砂粒等细颗粒容易沿裂缝喷出地表,卵砾石等粗颗粒受阻留在土层中,导致喷出物为砂土。  相似文献