多元素衬值累加地球化学方法在找矿中的应用——以青海省夏日哈-什多龙远景区为例     

赵志飞 《地质与勘探》2020,56(2):328-336

青海省夏日哈-什多龙成矿远景区位于青藏高原东昆仑东段,西起都兰县夏日哈镇,东至兴海县什多龙一带,跨祁漫塔格北坡-夏日哈岩浆弧和北昆仑岩浆弧,是青海省重要的成矿区。为了在该区寻找新的成矿有利地段,本文在对该区区域地质背景、矿产特征及区内典型矿床地质特征系统研究的基础上,利用多元素衬值累加地球化学找矿方法,在区域上优选出一批找矿靶区。多元素衬值累加地球化学找矿方法首先收集远景区1∶5万水系沉积物测量成果,经过数据处理,绘制远景区衬值累计地球化学图,进而建立典型矿床找矿模式,最终通过对比分析,选出新的找矿靶区。对圈定的找矿靶区进行野外踏勘检查,均发现不同程度的矿化线索,为今后在该区进一步找矿起到了很好的指导作用。通过本次工作,发现了该方法在靶区圈定方面的优势:(1)可快速圈定异常,提高工作效率;(2)编制的地球化学图浓集中心更显著;(3)圈定的找矿靶区找矿成果显著,尤其针对陆相火山岩型多金属矿、斑岩型铜钼矿、矽卡岩型多金属矿找矿成果突出;(4)能直观反映背景变化趋势,有助于评价异常。  相似文献   

黄陵断穹核部鳞片石墨矿地球化学特征与成因研究     

程林 《地质与勘探》2020,56(4):745-758

黄陵断穹核部石墨矿是我国鳞片(晶质)石墨矿的主要产区,对该区石墨矿的研究具有重要理论和实际意义。该区已有石墨矿研究成果多侧重于矿床地质方面,对矿床成因分析缺乏地球化学支撑。为此,本文从地球化学层面查明石墨矿原岩类型,碳质富集岩相、变质作用和晶质石墨的形成,为矿床成因和成矿作用提供地球化学依据。通过系统采集区内主要石墨矿样品,进行主量元素、微量元素、稀土元素和同位素分析,根据矿床地球化学原理和分析方法,阐明石墨矿的物质来源,成矿元素集散行为和矿床形成机制。根据主量元素含量和组合,推断石墨的原岩为碳质粉砂质泥岩。微量元素的双重性指示石墨矿的物质有两个来源:中太古代野马洞岩组和中太古代东冲河片麻杂岩。独特的稀土元素配分型式说明物源转化为原岩时存在着强烈的地球化学反应。石墨矿的碳同位素组成支持碳质来自有机物的观点。  相似文献   

榍石LA-ICP-MS U-Pb定年中元素分馏的影响及校正研究     

靳梦琪  李艳广  王鹏  汪双双  黎卫亮 《岩矿测试》2020,39(2):274-284

同位素地质年代学是探索地质体时空演化及地球动力学等问题的基础学科,应用最为广泛的当属含铀副矿物的U-Pb定年技术。榍石具有相对较低的U-Pb体系封闭温度,并广泛发育于岩浆岩、各类变质岩、热液成因岩石以及少量沉积岩中,是一种理想的中高温地质事件定年矿物。利用电感耦合等离子体质谱法(ICP-MS)测定榍石U-Pb年龄时,不可避免地要解决高普通铅以及元素分馏效应对测试的影响。本文对榍石LA-ICP-MS实验过程中的元素分馏行为进行研究,采用相同基体的标准样品与未知样品对比,发现了榍石不同颗粒之间元素分馏行为不一致的现象;同时采用不同的元素分馏校正方法,分别应用于锆石、独居石和榍石进行对比研究,认为分馏行为一致的副矿物定年可以采用"指数法"和"均值法"对数据进行校正,但是对于榍石这种分馏行为不一致的副矿物,定年时只有采用"截距法"对数据进行校正才可以获得正确的年龄。进而将此结论应用于秦岭造山带老牛山地区岩浆成因榍石样品,得到的结果与锆石年龄一致,表明"截距法"可以避免分馏行为不一致导致的校正不准确的问题。本研究成果为榍石LA-ICP-MS U-Pb定年方法的完善提供了一种思路。  相似文献   

GBW10010a大米标准物质复(研)制及数据特征     

杨榕  顾铁新  潘含江  刘妹  周国华 《岩矿测试》2020,39(6):866-877

随着我国对生态文明建设的重视,自然资源综合调查势在必行,对生物标准物质亦提出了新的需求。当前相关调研工作已经大面积开展,自然资源综合调查、农产品与食品安全评价都需要对生物样品元素组成进行准确测试,需要以生物标准物质作为生物成分测试量值比对和溯源的基础,因此对生物基体标准物质的需求量大幅增加。大米作为主要粮食之一,其食品安全日益受到重视,对大米中的化学成分进行准确的分析测试具有重要的现实意义,因而对大米标准物质的需求量尤为突出,但目前大米成分分析标准物质已供不应求。本文严格按照《标准物质定值的通用原则及统计学原理》（JJF 1343—2012）和《地质分析标准物质的研制》（JJF 1646—2017）等相关规范要求,开展了GBW10010a大米成分分析标准物质的复（研）制工作,包括样品采集、加工制备、均匀性检验、稳定性检验、多家实验室协作定值测试及不确定度评定等关键环节。结果表明：本次复（研）制的大米标准物质定值成分多样、量值准确可靠,符合国家一级标准物质的要求。GBW10010a共定值54项主微量元素,包括Ag、Al、As、B、Ba、Be、Bi、Ca、Cd、Ce、Co、Cr、Cs、Cu、Dy、Er、Eu、Fe、Gd、Ge、Hg、Ho、K、La、Li、Ho、Mg、Mn、Mo、N、Na、Nb、Nd、Ni、P、Pb、Pr、Rb、S、Sb、Sc、Se、Si、Sm、Sr、Tb、Th、Tl、Tm、U、V、Y、Yb、Zn,其中的39项元素给出了标准值及不确定度,包括Ag、Al、As、B、Ba、Ca、Cd、Ce、Co、Cs、Cu、Dy、Er、Fe、Hg、K、Li、Mg、Mn、Mo、N、Na、Nd、Ni、P、Pb、Pr、Rb、S、Sb、Se、Si、Sm、Sr、Tb、Tl、Y、Yb、Zn;15项元素提供参考值,包括Be、Bi、Cr、Eu、Gd、Ge、Ho、Ho、La、Nb、Sc、Th、Tm、U、V。与原有GBW10010大米标准物质相比较,GBW10010a中As、Cd、Co、Cr、Cu、Hg、Mn、Mo、Ni、Zn等重金属元素含量显著下降,其中Cd、Cu、Zn降幅较大,分别下降约39%、43%、38.7%,一定程度上反映了农田生态环境的改善。本批标准物质定值元素总数量增加了6项,新增定值元素Ag、Nb（Nb给出参考值）,并且各项元素不确定度范围整体上有所缩小,如Al、Cd、Cu、Fe、K、Mg、Mo、Na、P、Pb、Se、Zn等对生物易有影响的重要元素,表明了地质分析测试方法技术的进步及定值水平的提高。本批标准物质定值元素涵盖了具有生物效应的大部分主微量元素,适用于农业生态环境地球化学调查与评价、生物样品测试、农产品质量与食品安全评价样品测试时的分析仪器校正、分析方法评价和分析质量监控等多个领域。  相似文献   

The complex one-sided integrals of Cauchy and Hadamard and application to boundary element method     

S. G. Mogilevskaya 《国际地质力学数值与分析法杂志》1998,22(12):947-968

The definitions of complex integrals of Cauchy and Hadamard with the singular point coinciding with the end point of the integration curve are proposed. It is shown that the new integrals satisfy most of the properties of the regular ones, including the change of variables. It is also shown that the Cauchy principal value (CPV) and Hadamard finite-part (HFP) integrals can be considered as a sum of the new type integrals. The application to numerical solution by the boundary element method (BEM) and the complex hypersingular integral equation (CHSIE) for the multiregions of interacting elastic bodies and bodies with cracks and holes is discussed. The different ways to place the collocation points are considered. The numerical results for the problems of circular hole and circular elastic inclusion in infinite plate indicated that the appropriate choice of the approximating functions leads to a high accuracy of the calculation. Applications of the new technique to geomechanics problems are discussed. © 1998 John Wiley & Sons, Ltd.  相似文献   

A continuum model of layered rock masses with non-associative joint plasticity     

D. P. Adhikary  A. V. Dyskin 《国际地质力学数值与分析法杂志》1998,22(4):245-261

Layered rock masses can be modelled either as standard, orthotropic continua if the layer bending can be neglected or as Cosserat continua if the influence of layer bending is essential. This paper presents a finite element smeared joint model based on the Cosserat theory. The layers are assumed to be elastic with equal thickness and equal mechanical properties. All the cosserat parameters are expressed through the elastic properties of layers, layer thickness and joint stiffness. Plastic-slip as well as tensile-opening of layer interface (joint) are accounted for in a manner similar to the conventional non-associative plasticity theory. As an application, the behaviour of an excavation in a layered rock mass is examined. The displacement and stress fields given by smeared joint models based on the Cosserat continuum and the conventional anisotropic continuum approaches are compared with those obtained from the discrete joint model. The conventional anisotropic continuum model is found to break-down completely when the effective shear modulus in the direction parallel to layering is low in comparison to the shear modulus of the intact layer, whereas the Cosserat model is found to be capable of accurately reproducing complex load–deflection patterns irrespective of the differences in shear moduli. © 1998 John Wiley & Sons, Ltd.  相似文献   

四川盆地西南缘龙马溪组泥岩地球化学特征及物源区和构造背景分析   总被引：1，自引：0，他引：1  

张茜  肖渊甫  王晓飞  余谦  王剑  赵安坤  门玉澎  周业鑫 《地质论评》2020,66(5):1393-1410

本文对川西南荥经地区龙马溪组泥岩的岩石学、矿物学及元素地球化学开展了研究,探讨了龙马溪组沉积环境、物源区属性及构造背景。结果表明,研究区龙马溪组泥岩砂质、钙质含量较高,指示其沉积水体较浅。稀土元素特征及及A—CN—K图解说明龙马溪组泥岩组成较少受成岩及交代作用影响,样品较完整地保存了物源和风化作用信息。K2O、Rb、Al2O3 /TiO2含量较高及Eu负异常指示其母岩为偏酸性的长英质岩、花岗岩类,推测主要来自康滇古陆新元古代早期地台盖层。ICV值大于1,CIA平均值为66,Th/U与地壳UCC值相近,Rb/Sr值明显低于PAAS,指示其物源为近源初次旋回的快速沉积产物,受化学风化作用较小,沉积环境为干燥、寒冷环境。La/Yb、LREE/HREE及Sc/Cr等值均与被动大陆边缘值相近,结合Sc/Cr—La/Y等判别图解,说明研究区沉积构造背景主要为被动大陆边缘。  相似文献   

不透水地基上均质土坝渗流自由面的有限元计算     

牛文杰  叶为民 《岩土力学》2007,28(Z1):375-378

为了保证土坝安全,水利工程中需要对土坝进行渗流计算,首先需要确定自由面。根据达西定律和渗流连续方程,以及水头和流量边界条件,建立了不透水地基上的均质土坝渗流的计算模型。利用Geoslope软件,采用有限元离散的方法计算了土坝的渗流自由面,并分析了土坝在不同的渗透系数情况下的自由面位置的差异。最后,解析解计算的自由面结果验证了有限元计算自由面方法是正确的。  相似文献   

CALCULATING THE DYNAMIC STIFFNESS MATRIX OF 2-D FOUNDATIONS BY DISCRETE WAVE NUMBER INDIRECT BOUNDARY ELEMENT METHODS     

J. X. ZHAO  A. J. CARR  P. J. MOSS 《地震工程与结构动力学》1997,26(1):115-133

Apart from some special cases, calculating the dynamic stiffness matrix of foundations on a layered half-space, especially for embedded foundations, is computationally expensive. An efficient method for two-dimensional foundations in a horizontally layered soil media is presented in this paper. This method is based on indirect boundary element methods and uses discrete wave number solution methods for calculating Green's functions for displacements and analytical methods for the integrations over the boundary. For surface foundations, the present method applies at all frequencies. For embedded foundations or for constructing energy transmitting boundaries, because the free-field part is modelled by boundary elements and the excavated part is modelled by finite elements, the present method applies only at low frequencies for the spring coefficients (the real parts of the dynamic stiffness matrix) but applies at all frequencies for the damping coefficients (the imaginary part of the dynamic stiffness matrix) for undamped sites. The novelty of the method can be used for three-dimensional foundations. © 1997 by John Wiley & Sons, Ltd.  相似文献   

Elastoplastic deformation around underground openings under biaxial initial stress field     

Yuzo Obara  Katsuhiko Sugawara 《国际地质力学数值与分析法杂志》1997,21(10):721-737

Estimation of elastoplastic deformation around an underground opening induced by the excavation of it, especially displacement and strain field in plastic region, is presented in this paper, as well as the formulation for calculating the displacement and strain in the plastic region around the underground opening by the coupled Boundary Element Method - Characteristics Method (BEM-CM). In this method, the non-associated flow rule is adopted to calculate the displacement and strain field in the plastic region, which is determined by the integration of the displacement along characteristics lines under the boundary condition of the elastic displacement on an elastoplastic interface analysed. It is shown that this method is one of the accurate and effective methods for estimating not only the shape and extent of the plastic region but also the state of the displacement and strain in the plastic region around the underground opening, comparing the theoretical solution with numerical results by this method for a circular opening under hydrostatic initial stress condition. Furthermore, this method is applied to rectangular and horse-shoe shaped openings and the characteristics of the strain field in the plastic region are discussed. © 1997 by John Wiley & Sons, Ltd.  相似文献