25～75℃酸性NaCl溶液中方铅矿的溶解动力学   总被引：4，自引：0，他引：4  

张生  李建平  王玉荣  胡光黔 《地球化学》2002,31(6):587-592

在25～75℃、pH=0.43～2.45的1mol/LNaCl溶液中进行了方铅矿的溶解动力学实验。发现在远平衡条件下,方铅矿的溶解速率r与氢离子活度犤H+犦呈线性关系,溶解速率方程(速率定律)为:r=k犤H+犦,即对H+而言,溶解反应为一级。其中速率常数k为2.344×10-7mol/m2·s(25℃)、1.380×10-6mol/m2·s(50℃)、7.079×10-6mol/m2·s(75℃)。溶解反应的活化能为43.54kJ/mol,方铅矿的溶解机理为表面化学反应,速率决定步骤为表面配合物的离解。  相似文献   

Analyzing CO2 emissions mitigation by technology improvement in Central and Eastern Europe     

Diana Ürge-Vorsatz  Adam Szeszler 《GeoJournal》2002,57(3):211-226

As a legacy of the centrally planned economy, the economies in transition of Central and Eastern Europe (CEE) have a unique potential to reduce their greenhouse gas emissions through the improvement in their high energy intensities. Since much of this `low-hanging fruit' in energy-efficiency improvements can be highly cost-effective, many developed countries facing difficulties in meeting their greenhouse gas (GHG) emission targets domestically are eager to find such opportunities in the CEE region. Therefore, studies analysing the potentials and costs of carbon dioxide reduction through technology improvement in the region have come into the limelight. While there are a few excellent studies in the region aimed at analysing climate change abatement potentials, they all embark on different assumptions, methodologies and boundary conditions. It is hence difficult, if not impossible, to compare and analyse the results of these studies across different authors, countries or time horizons. Consequently, the purpose of this paper is to place four leading studies on GHG mitigation through technology improvement from the CEE region into an internationally comparable framework. Four studies were selected from three countries, Poland, Hungary and Estonia, which are all the results of major national and international efforts to assess costs and potentials of GHG reduction. The paper places their assumptions, methods and final results into a framework which enables policy-makers and project designers to compare these across geographical and technological boundaries. Since other studies from around the globe have been analysed in this framework in the literature, this paper provides a vehicle for the findings of these four studies to be compared to others worldwide. In addition, the paper highlights a few areas where similar studies to be completed in the future in the region may be enhanced by incorporating features used in GHG mitigation research in other parts of the world. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

油压夯管锤蓄能器与活塞振动耦合性的数学解析          下载免费PDF全文

李国民 《探矿工程》2002,(1):52-54

蓄能器容积的变化与夯管锤的工作过程是紧密联系在一起的，由于活塞的前后运动以及在运动过程中的每一时刻所需要的油量不同的，理想状态就要通过蓄能器的容积变化来调节，就是说蓄能器的容积变化要与夯管锤的冲击振动相耦合。简要介绍了油压夯管锤结构原理，分别解释了油压夯管锤蓄能器与夯管锤的容积压力耦合。  相似文献   

A methodology for the evaluation of long-term volcanic risk from pyroclastic flows in Campi Flegrei (Italy)     

I. Alberico  L. Lirer  P. Petrosino  R. Scandone 《Journal of Volcanology and Geothermal Research》2002,116(1-2)

The volcanological history of Campi Flegrei suggests that the most frequent eruptions are characterized by the emplacement of pyroclastic flow and surge deposits erupted from different vents scattered over a 150-km² caldera. The evaluation of volcanic risk in volcanic fields is complex because of the lack of a central vent. To approach this problem, we subdivided the entire area of Campi Flegrei into a regular grid and evaluated the relative spatial probability of opening of vents based on geological, geophysical and geochemical data. We evaluated the volcanic risk caused by pyroclastic flows based on the formula proposed by UNESCO (1972), R=H×V×Va, where H is the hazard, V is the vulnerability and Va is the value of the elements at risk. The product H×V was obtained by performing simulations of type eruptions centered in each cell of the grid. The simulation is based on the energy cone scheme proposed by Sheridan and Malin [J. Volcanol. Geotherm. Res. 17 (1983) 187–202], hypothesizing a column collapse height of 100 m for eruptions of VEI=3 and 300 m for eruptions of VEI=4 with a slope angle of 6°. Each simulation has been given the relative probability value associated with the corresponding cell. We made use of the GIS software ArcView 3.2 to evaluate the intersection between the energy cone and the topography. The superposition of the areas invaded by pyroclastic flows (124 simulations for VEI=3 and 37 for VEI=4) was used to obtain the relative hazard map of the area. The relative volcanic risk map is obtained by superimposing the urbanization maps.  相似文献   

Nonlinear earthquake response analysis and energy calculation for seismic slit shear wall structures     

蒋欢军  吕西林 《地震工程与工程振动(英文版)》2002,1(2):227-237

Based on the concept of structural passive control, a new type of slit shear wall, with improved seismic performance when compared to an ordinary solid shear wall, was proposed by the authors in 1996. The idea has been verified by a series of pseudo-static and dynamic tests. In this paper a macro numerical model is developed for the wall element and the energy dissipation device. Then, nonlinear time history analysis is carried out for a 10-story slit shear wall model tested on a shaking table. Furthermore, the seismic input energy and the individual energy dissipated by the components are calculated by a method based on Newmark-β assumptions for this shear wall model, and the advantages of this shear wall are further demonstrated by the calculation results from the viewpoint of energy. Finally, according to the seismic damage criterion on the basis of plastic accumulative energy and maximum response, the optimal analysis is carried out to select design parameters for the energy dissipation device.  相似文献   

钢筋砼摩擦耗能支撑框架结构的单元刚度和力学模型分析     

李慧峰  张玉蓉 《地震研究》2002,25(1)

为研究钢筋砼摩擦耗能支撑框架结构的动力反应性能 ,对其中的摩擦耗能器单元和框架杆单元的单元刚度和力学模型做了分析。钢筋砼摩擦耗能支撑单元由支撑杆单元和钢板—橡胶摩擦耗能器单元组成 ,支撑单元可取空间杆单元 ,摩擦耗能器单元为平面应力矩形单元。摩擦耗能器单元的剪切恢复力曲线为理想的弹塑性曲线 ,根据耗能器单元的力学模型 ,可确定其在每一时刻的刚度 ;框架结构空间杆单元的恢复力模型采用双线型模型 ,根据杆单元的力学模型 ,可确定其在每一时刻的刚度。并利用所编制的程序对十层单榀两跨空间普通框架和摩擦耗能支撑框架在地震作用下进行了弹塑性反应时程分析 ,结果表明耗能支撑框架的顶层最大位移明显小于普通框架  相似文献   

中国城市与城市发展理论的历史   总被引：7，自引：1，他引：7  

薛凤旋 《地理学报》2002,57(6):723-730

论述中国自周期以来的城市概念和理论，指出中国城市性质和城市结构的自有特点及其与西方发展经验为基础的城市概念和理论不同，将中国漫长的演变历史分为封建时代，中华人民共和国建立至1978年和1978年以后的改革开放3个时期。3个时期所形成的城市概念和理论，都有中国特色，是中国城市及城市化向前发展的重要的理解和指导基础。  相似文献   

新时期我国区域经济地理学发展问题初探   总被引：4，自引：0，他引：4  

刘曙光 《地域研究与开发》2002,21(2):1-4

我国新时期的区域经济地理学在取得全面发展的同时，在理论体系，研究方法和实践领域等方面还需要进一步的发展，文章根据学习和实践区域经济地理学的体会，初步提出基础理论和应用理论，思维方法和技术方法等方面发展见解，并指出区域创新系统和国际经济技术合作等学科应注意拓展的重要实践领域，最后提出我国区域经济地理学科发展的建议。  相似文献   

帕隆藏布河流纵剖面演化的最小功模式   总被引：3，自引：0，他引：3  

蒋忠信 《山地学报》2002,20(1):26-31

河流地貌最小功原理表明河流纵误时面形态将向力示使流速增大的方向演化，据此推导出矩形流域全程流速的平均值（u^-）与河流纵误时面形态指数（N）的关系式：u^∝-f(N)={1/2-1/[(N 1)(N 2)]}^1/2，f(N)被称为流速函数。这一最小功模式表明河流纵剖面演化方向是N由小变大。以西藏帕隆藏布中上游流域系统、干流全程及Ⅰ级阶地为例，由最小功模式计算的全程流速均值与实测值相吻合，从而检验了上述最小功原理和数学模式。  相似文献   

青藏高原土壤水热分布特征及冻融过程在季节转换中的作用   总被引：21，自引：0，他引：21  

杨梅学  姚檀栋  何元庆 《山地学报》2002,20(5):553-558

利用GAME-Tibet期间所取得的高分辩率土壤温度和含水量资料，对青藏高原（主要是藏北高原）土壤水热分布特征及冻融过程在季节转换中的作用进行了分析。指出藏北高原4cm学深处土壤在10月份开始冻结，次年4-5月份开始消融，冻结持续时间长达5-7个月。冻结过程有利于土壤维持其水分，因此，在刚刚开始消融时土壤含水量仍然很高。从而为夏季风爆发前土壤通过蒸发向大气提供水分打下了基础。指出土壤冻融过程可能在高原季节转换中起着重要作用。  相似文献