东海近海水质无机氮类测定中的不确定度探讨     

任松  张丽旭  卜建平  陈东 《海洋通报》2006,25(1):30-37

分析探讨了东海近海水质无机氮类测定中不确定度的影响因素。其中,考虑到海洋环境监测的一些特殊性,在建立评定不确定度分量的数学模型时,引入了重复性实验校正因子f,并选取2004年东海区海洋环境监测中不同海域的试样进行原始平行性测定资料,以A类方式评定量化重复性实验校正因子f的不确定度分量;同时,以A类或B类的方式对近海水质无机氮类测定中的其它各个不确定度分量进行了评定。结果表明,NH_4~ 测定的相对合成标准不确定度分量最大,重复性实验校正因子f是近海水质无机氮类测定不确定度的主要来源。在此基础上,计算了东海近海水质无机氮类(NO_2~-、NO_3~-、NH_4~ )测定中的相对合成标准不确定度分别约为0.080,0.034,0.10。  相似文献   

胶州湾围隔浮游生态系统氮、磷营养盐迁移-转化模型研究   总被引：2，自引：1，他引：2       下载免费PDF全文

李克强  王修林  石晓勇  祝陈坚  李瑞香 《海洋学报》2007,29(3):76-83

通过对目前生态动力学模型的总结和综合,以生态系统中氮、磷营养盐循环为主线,建立了适用于海洋围隔浮游生态系统的多变量的营养盐迁移-转化动力学模型.该模型包括浮游植物、浮游动物、溶解无机态营养盐、溶解有机态营养盐和生物碎屑5个模块,涉及溶解无机氮、磷酸盐、溶解有机氮、溶解有机磷、浮游植物、浮游动物和生物碎屑7个状态变量.分别利用1999年秋季和2000年夏季胶州湾围隔生态实验数据进行了模型和验证工作,成功地模拟了富加营养盐条件下围隔浮游生态系统中氮、磷营养盐生物化学迁移-转化过程,并确定了20余个参数的量值.  相似文献   

南海深海盆表层沉积物氮的地球化学特征与生态学功能   总被引：4，自引：1，他引：4  

郑国侠  宋金明  孙云明  戴纪翠 《海洋学报》2006,28(6):44-52

研究了南海深海盆区域(南沙海槽西南部)表层沉积物中氮的形态、分布及其在生物地球化学循环中的功能.研究表明,表层沉积物中不同形态氮的含量不同.其中,氧化还原转化态的氮(SOEF-N)含量最高,平均为68.3μg/g,占总氮(TN)的7.08%;弱酸转化态氮(WAEF-N)含量最小,仅占总氮(TN)的1.09%.离子交换态(IEF-N),WAEF-N,S OEF-N及TN的地球化学分布特征存在一定相似性:均由海槽东西两侧向中央递增,并在槽底呈高含量分布;SAEF-N(强碱转化态)分布则与该趋势相反.IEF-N,SAEF-N和SOEF-N的分布主要受沉积物中有机碳含量(OC)控制;而WAEF-N则与碳酸盐(CaCO₃)存在显著的负相关关系;TN与OC不具有显著意义的相关,间接说明二者来源的不同.同时,各形态氮的分布还与沉积物粒度类型密切联系.此外,研究区域内由沉积物提供的氮源很大程度上补偿了浮游植物对水体中营养盐的消耗,对维持该海域的初级生产力水平起到一定作用.其中,IEF-N和SOEF-N的释放对浮游植物生长及初级生产力的贡献较为显著.  相似文献   

Nutrient Limitation in Macroalgae (Ulva and Enteromorpha) from the Rías Baixas (NW Spain)     

Ruben Villares  & Alejo Carballeira 《Marine Ecology》2004,25(3):225-243

Abstract.  Photosynthesis and growth rates in samples of two green seaweeds ( Ulva and Enteromorpha ) were monitored in the laboratory. The macroalgae were collected every 15 days from four coastal embayments in Galicia (NW Spain). Ulva samples were found to be nutritionally limited, particularly in summer. The physiological activity of Enteromorpha did not appear to be as affected by nutrient scarcity, although it may have suffered from phosphorus limitation. The subsistence quotas, critical concentrations and storage capacity for N and P in Ulva were comparable to those obtained by other investigators in similar studies. The trace metals analysed apparently did not negatively affect the macroalgae at the measured concentrations; one explanation is that many of these metals function as essential micronutrients. The complex physiological interactions between metals and nutrients, however, may complicate interpretation of the results.  相似文献   

呼伦湖的近期扩张及其与全球气候变化的关系   总被引：10，自引：0，他引：10  

秦伯强  王苏民 《海洋与湖沼》1994,25(3):280-287

通过近２０多年湖泊水量平衡分析发现，湖泊水位变化主要由湖盆内径流补给量的丰枯决定。进一步分析揭示，呼伦湖地区乃至整个东北地区，本世纪以来随气温升高，随水有增加的趋势。降水增加导致入湖径流量，湖水位上升，呼伦湖本世纪以来的扩张与内蒙古东部地区其他内陆湖泊的变化一致，但这在我国乃至整个亚洲内陆干旱或半干旱区是独一无二的，为此成为这一地区气候变化的指示器。  相似文献   

Processes Causing the Temporal Changes in Si/N Ratios of Nutrient Consumptions and Export Flux during the Spring Diatom Bloom     

Naoki?YoshieEmail author  Yasuhiro?Yamanaka 《Journal of Oceanography》2005,61(6):1059-1073

Two processes are generally explained as causes of temporal changes in the stoichiometric silicon/nitrogen (Si/N) ratios of sinking particles and of nutrient consumption in the surface water during the spring diatom bloom: (1) physiological changes of diatom under the stress of photosynthesis of diatom and (2) differences of regeneration between silicon and nitrogen. We investigated which process plays an important role in these changes using a one-dimensional ecosystem model that explicitly represents diatom and the other non-silicious phytoplankton. The model was applied to station A7 (41°30′ N, 145°30′ E) in the western North Pacific, where diatom regularly blooms in spring. Model simulations show that the Si/N ratios of the flux exported by the sinking particles at 100 m depth and of nutrient consumptions in the upper 100 m surface water have their maxima at the end of the spring diatom bloom, the values and timings of which are significantly different from each other. Analyses of the model results show that the differences of regeneration between silicon and nitrogen mainly cause the temporal changes of the Si/N ratios. On the other hand, the physiological changes of diatoms under stress can hardly cause these temporal changes, because the effect of the change in the diatom's uptake ratio of silicon to nitrogen is cancelled by that in its sinking rate.  相似文献   

The fate of dumped sediments monitored by a high-resolution multibeam echosounder system,Weser Estuary,German Bight     

Claudia?WienbergEmail author  Jens?Dannenberg  Dierk?Hebbeln 《Geo-Marine Letters》2004,24(1):22-31

With the development of high-resolution multibeam echosounder systems (MBES) for surveying shallow-water areas a new tool is available to monitor rapid changes in seabed morphology as, e.g., caused by the dumping of dredge spoil in coastal waters. In this study, four data sets of repeated bathymetric surveys with a MBES were processed and analyzed. The data were collected in a 1.94-km² dumping site in the outer Weser Estuary (German Bight). Between June and December 1998, 2.6 million m³ of dredged sediment were deposited there. The bathymetric maps generated in the course of this study reveal features such as subaqueous dunes, scour holes, and mounds of dumped dredge spoil. The mean water depth decreased by about 1 m during the dumping period. Furthermore, difference grids showing changes in sediment volume allowed a calculation of the sediment budget for the monitored area. After a time period of only 5 months, 0.5 million m³ of the originally dumped 2.6 million m³ of dredge spoil had already been removed from the dumping site.  相似文献   

Monitoring the Kuroshio Extension with Dynamically Constrained Synthesis of the Acoustic Tomography, Satellite Altimeter and in situ Data     

Konstantin V. Lebedev  Max Yaremchuk  Humio Mitsudera  Iwao Nakano  Gang Yuan 《Journal of Oceanography》2003,59(6):751-763

A finite-difference quasigeostrophic (QG) model of an open ocean region has been employed to produce a dynamically constrained synthesis of acoustic tomography and satellite altimetry data with in situ observations. The assimilation algorithm is based upon the 4D variational data interpolation scheme controlled by the model's initial and boundary conditions. The data sets analyzed include direct and differential travel times measured at the array of five acoustic transceivers deployed by JAMSTEC in the region of the Kuroshio Extension in 1997, Topex/Poseidon altimetry, CTD soundings, and ADCP velocity profiles. The region monitored is located within the area 27.5°–36.5°N, 143°–155°. The results of assimilation show that mesoscale variability can be effectively reconstructed by five transceivers measuring direct and reciprocal travel times supported by relatively sparse in situ measurements. The misfits between model and data lie within the observational error bars for all the data types used in assimilation. We have compared the results of assimilation with the statistical inversion of travel time data and analyzed energy balances of the optimized model solution. Energy exchange between the depth-averaged and shear components of the observed currents reveals a weak decay of the barotropic mode at the rate of 0.2 ± 0.7⋅10⁻⁵ cm²/s³ due to topographic interaction. Mean currents in the region are unstable with an estimate of the available potential energy flux from the mean current to the eddies of 4.7 ± 2.3⋅10⁻⁵ cm²/s³. Kinetic energy transition has the same sign and is estimated as 2.8 ± 2.5⋅10⁻⁵ cm²/s³. Potential enstrophy is transferred to the mesoscale at a rate of 5.5 ± 2.7⋅10⁻¹⁸ s⁻³. These figures provide observational evidence of the properties of free geostrophic turbulence which were predicted by theory and observed in numerical experiments. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Differences in ratios of stable isotopes of nitrogen in long-finned pilot whales (Globicephala melas) in the western and eastern North Atlantic   总被引：1，自引：0，他引：1  

Abend  Alan G.; Smith  Tim D. 《ICES Journal of Marine Science》1995,52(5):837-841

  相似文献   

Annual Variation of Benthic Nutrient Fluxes in Shallow Coastal Waters (Gulf of Trieste, Northern Adriatic Sea)   总被引：5，自引：0，他引：5  

Alessandra  Bertuzzi  Jadran  Faganeli Antonio  Bflmbati 《Marine Ecology》1996,17(1-3):261-278

Abstract. Benthic fluxes of dissolved N. Si and P nutrients, alkalinity, dissolved inorganic C (DIC), and O₂ from sediments in the Gulf of Trieste (northern Adriatic, Italy) were measured monthly for 16 months, using laboratory incubated flux chambers at in siru temperatures in the dark. The annual average fluxes were: 02 = -19.3 ± 8.2, DIC = 13.7 ± 9.6, NO3 = -0.04 ± 0.16, NH4 = 0.3 ± 0.4. PO₄= 4.001 ± 0.01, Si = 0.9 ± 0.1 mmol m-² d^-1, with strong temporal fluctuations. The highest effluxes of all nutrients and DIC were observed in the summer. Small effluxes of DIC and NH4 and influxes of Si and PO4 were observed in late winter. Only NH₄ (ca. 50%) and Si (ca. 70%) fluxes were significantly correlated with temperature. This correlation suggests that the rate of downward input and the quality of sedimented organic matter (autochthonous and allochthonous) were superimposed on the temperature fluctuations. High DIC, NH₄ and Si effluxes observed in May 1993 during low temperature were due to the degradation of sedimentary organic matter produced by an early spring bloom of benthic microalgae which occurred about 6 weeks earlies while the autumn phytoplankton bloom was simultaneously reflected in enhanced benthic fluxes due to higher temperature. The role of benthic biological advection in this transport across the sediment-water interface, evaluated by comparison between measured benthic and calculated diffusive fluxes from nutrient pore water concentrations, was of minor importance. This is probably due to low infaunal activity throughout the year it was localized mostly in the narrow surficial layer. The annual average diffusive fluxes of NH4 and PO4 were higher than those measured, probably due to the presence of nitrificationdenitrifi-cation processes and redox-dependent chemical reactions at the oxic sediment-water interface, respectively. Only during bottom-water hypoxia in September 1993 did strong PO₄ effluxes prevail. Calculations based on the Redfield stoichiometry of oxic decomposition of organic N to NH4 and NO3, and differences between diffusive and measured NH₄ fluxes showed that denitrifkation averaged 0.8 mmol m^-2 d^-1. Significant correlations between NH₄ and PO₄ DIC and Si, and NH4 and Si fluxes suggested their parallel regeneration and utilization at the sediment-water interface. The nutrient fluxes observed were not significantly linked to O₂ consumption, suggesting also that anaerobic oxidation processes were important at the sediment-water interface in the gulf. The N, P and Si nutriqnts released from sediment pore waters are probably utilized in benthic microalgal and bottorn-hater primary production. This indicates that pelagic and benthic communities in the central part of the Gulf of Trieste function relatively independently of each other.  相似文献