氢氧化钠预处理对提高泡塑富集金能力的探讨   总被引：3，自引：1，他引：3  

李琴美 《黄金地质》1997,3(4):72-75

用氢氧化钠处理的泡塑对金的回收率高，富集能力强，并根据金的分布情况对影响泡塑富集能力的原因进行了探讨，为泡塑分离富集金的分析提供了一种新的泡塑予处理方法。  相似文献   

Improved Platinum-Group Element Extraction by NiS Fire Assay from Chromitite Ore Samples Using a Flux Containing Sodium Metaphosphate   总被引：1，自引：0，他引：1  

L. Paul Bédard  Sarah-Jane Barnes 《Geostandards and Geoanalytical Research》2004,28(2):311-316

Many chromite-rich rocks contain relatively high concentrations of the platinum-group elements (PGE). In many cases, the phases carrying PGE occur as either platinum-group minerals (PGM) or as base metal sulfides in solid solution in sulfides. In some cases, such as the UG-2 unit of the Bushveld Complex, the PGM are occluded inside chromite grains. Chromites are notably difficult to dissolve in most fluxes and if the chromite contains some PGM the possibility exists that not all the PGE will be recovered during fusion. In this work, shortcomings in published methods of analysis based on the nickel sulfide fire assay procedure were investigated and a new procedure developed based on the addition of sodium metaphosphate to the fusion mixture. Optimum composition of the fusion mixture was found to be 10 g sodium metaphosphate and 9 g silica to 10 g sample, 15 g sodium carbonate, 30 g lithium tetraborate, 7.5 g nickel and 4.5 g sulfur to achieve complete dissolution of chromite grains. The new flux mixture was evaluated by the analysis of reference material CHR-Pt+ (which is known to contain PGM inside chromite grains) and no undissolved chromite grains were found in the glassy slag. Analysis of the nickel sulfide beads from this fire assay using neutron activation analysis showed similar results for Rh and Ru when compared with published conventional true (or accepted) values, while Au, Ir, Os, Pd and Pt values determined here were 10 to 30% higher than the corresponding published conventional true values. It was concluded that the addition of sodium metaphosphate improved chromite dissolution in the flux and appears to improve PGE recovery.  相似文献   

High-pressure experimental growth of diamond using C–K₂CO₃–KCl as an analogue for Cl-bearing carbonate fluid     

Emma Tomlinson  Adrian Jones  Judith Milledge 《Lithos》2004,77(1-4):287-294

High-pressure, high-temperature diamond growth experiments have been conducted in the system C–K₂CO₃–KCl at 1050–1420 °C, 7.0–7.7 GPa. KCl is of interest because of the strong effect of halogens on the phase relations of carbonate-rich systems [Geophys. Res. Lett. 30 (2003) 1022] and because of the occurrence of KCl coexisting with alkali silicate–carbonate fluids in natural-coated diamond [Geochim. Cosmochim. Acta 64 (2000) 717]. We have used system C–K₂CO₃–KCl as an analogue for these mantle fluids in diamond growth experiments. The presence of KCl reduces the potassium carbonate liquidus to ≤1000 °C at 7.7 GPa, allowing it to act as a solvent catalyst for diamond growth at temperatures below the continental geotherm. This is a reduction on the minimum diamond growth temperature reported in the alkali-carbonate–C–O–H system [Lithos 60 (2002) 145]. Diamond growth using carbonate solvent catalysts is characterised by a relatively long induction period. However, the addition of KCl also reduced the period for diamond growth in carbonate to 5 min; no such induction period appears to be necessary. It is suggested that KCl destabilises carbonate, allowing greater solubility and diffusion of carbon.  相似文献   

The groundwater recharge regime of some slightly metamorphosed neoproterozoic sedimentary rocks: an application of natural environmental tracers          下载免费PDF全文

Sandow Mark Yidana  Eric Koffie 《水文研究》2014,28(7):3104-3117

Isotope data of precipitation and groundwater in parts of the Voltaian Basin in Northern Ghana were used to explain the groundwater recharge regime in the area. Groundwater recharge is an important parameter in the development of a decision support system for the management and efficient utilization of groundwater resources in the area. It is therefore important to establish the processes and sources of groundwater recharge. δ¹⁸O and δ²H data for local precipitation suggest enrichment relative to the Global Meteoric Water Line (GMWL) and indicate that precipitation takes place at a relative humidity less than 100%. The groundwater data plot on an evaporation line with a slope of 5, suggesting a high degree of evaporative enrichment of the precipitation in the process of vertical infiltration and percolation through the unsaturated zone into the saturated zone. This finding is consistent with the observation of high evapotranspiration rates in the area and ties in with the fact that significant clay fraction in the unsaturated zone limits vertical percolation and thus exposes the percolating rainwater to the effects of high temperatures and low humidities resulting in high evapotranspiration rates. Groundwater recharge estimates from the chloride mass balance, CMB, method suggest recharge in the range of 1.8–32% of the annual average precipitation in the form of rainfall. The highest rates are associated with areas where open wells encourage significant amount of groundwater recharge from precipitation in the area. In the northern parts of the study area, groundwater recharge is lower than 12%. The recharge so computed through the application of the CMB methodology takes on a spatial distribution akin to the converse of the spatial pattern of both δ¹⁸O and δ²H in the area. As such, the locations of the highest recharge are associated with the most depleted values of the two isotopes. This observation is consistent with the assertion that low vertical hydraulic conductivities slow down vertical percolation of precipitation down to the groundwater water. The percolating precipitation water thus gets enriched in the heavier isotopes through high evapotranspiration rates. At the same time, the amount of water that finally reaches the water table is considerably reduced. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Groundwater recharge in an arid grassland as indicated by soil chloride profile and multiple tracers          下载免费PDF全文

Tianming Huang  Zhonghe Pang  Jilai Liu  Lihe Yin  W. Mike Edmunds 《水文研究》2017,31(5):1047-1057

Previous studies have shown that shallow groundwater in arid regions is often not in equilibrium with near‐surface boundary conditions due to human activities and climate change. This is especially the case where the unsaturated zone is thick and recharge rate is limited. Under this nonequilibrium condition, the unsaturated zone solute profile plays an important role in estimating recent diffuse recharge in arid environments. This paper combines evaluation of the thick unsaturated zone with the saturated zone to investigate the groundwater recharge of a grassland in the arid western Ordos Basin, NW China, using the soil chloride profiles and multiple tracers (²H, ¹⁸O, ¹³C, ¹⁴C, and water chemistry) of groundwater. Whereas conventional water balance and Darcy flux measurements usually involve large errors in recharge estimations for arid areas, chloride mass balance has been widely and generally successfully used. The results show that the present diffuse recharge beneath the grassland is 0.11–0.32 mm/year, based on the chloride mass balance of seven soil profiles. The chloride accumulation age is approximately 2,500 years at a depth of 13 m in the unsaturated zone. The average Cl content in soil moisture in the upper 13 m of the unsaturated zone ranges from 2,842 to 7,856 mg/L, whereas the shallow groundwater Cl content ranges from 95 to 351 mg/L. The corrected ¹⁴C age of shallow groundwater ranges from 4,327 to 29,708 years. Stable isotopes show that the shallow groundwater is unrelated to modern precipitation. The shallow groundwater was recharged during the cold and wet phases of the Late Pleistocene and Holocene humid phase based on palaeoclimate, and consequently, the groundwater resources are nonrenewable. Due to the limited recharge rate and thick unsaturated zone, the present shallow groundwater has not been in hydraulic equilibrium with near‐surface boundary conditions in the past 2,500 years.  相似文献   

高效液相色谱-电感耦合等离子体质谱联用检测土壤中的无机硒形态   总被引：3，自引：3，他引：0  

秦冲  施畅  万秋月  王磊  刘爱琴  安彩秀 《岩矿测试》2018,37(6):664-670

土壤样品中亚硒酸盐Se(Ⅳ)和硒酸盐Se(Ⅵ)的形态分析中,提取剂的选择和检测方法是技术的关键。以往的提取剂容易导致硒形态发生转变或无法同时提取Se(Ⅳ)和Se(Ⅵ),常用的氢化物发生原子荧光光谱法无法直接测定Se(Ⅵ),而是通过差减法得出Se(Ⅵ)含量。本文对比了不同提取剂的提取能力,确定使用0. 1 mol/L氢氧化钠溶液作为提取剂,在55℃超声萃取土壤样品30 min,提取液经高效液相色谱分离,电感耦合等离子体质谱检测,建立了土壤中Se(Ⅳ)和Se(Ⅵ)的形态分析方法。采用Hamilton PRP X-100色谱柱,以6 mmol/L柠檬酸为流动相,pH=5. 5,在8 min内可完全分离Se(Ⅳ)和Se(Ⅵ),两者的检出限分别为0. 15μg/L、0. 16μg/L,线性相关系数(r~2)均大于0. 999。以土壤为基体进行加标回收试验,Se(Ⅳ)和Se(Ⅵ)的回收率在84. 2%～95. 8%之间,相对标准偏差为1. 4%～5. 3%(n=6)。该方法简单快速,具有良好的精密度和准确度,适用于土壤中无机硒的形态分析。  相似文献   

上海洋山建港后港域夏季水文泥沙状况分析   总被引：1，自引：0，他引：1  

李鹏  杨世伦  龚文浩  徐小弟 《海洋工程》2009,27(2):81-88

对2007年9月17-26日在上海洋山港海域固定观测点(平均水深13 m)观测得到的水文泥沙要素,以及悬沙和底质样品分析.分析结果为:1)港域有效波高0.21-1.37 m(风速0.6～14.0 m/s),平均0.61 m(平均风速5.5 m/s).平静天气(平均风速小于5.0 m/s)下,波高随水深变化,两者的相关系数为0.899;而在强风天气下,波高受风况控制.2)最大表层流速超过2.00 m/s.大潮涨潮流占优势,小潮时落潮流占优势;与北岛链汉道封堵前相比,大潮涨、落潮平均流速分别减小15%和30%,小潮涨、落潮平均流速均减小30%～40%.各层余流均为西北方向,与涨潮流方向一致;垂向平均余流速0.11 cm/s,表层达0.25 m/s.3)离底高程1.35 m层和0.35m层最大悬沙浓度均大于3 kg/m3,两层平均悬沙浓度分别为0.89和0.95 kg/m3.无论大潮还是小潮涨潮悬沙浓度均大于落潮,这种现象在大潮时更为显著,潮周期中最大悬沙浓度出现在涨急.与工程前相比悬沙浓度明显降低,大、小潮降低均达20%.4)港区底质平均粒径9.0μm,工程后有变细的趋势.  相似文献   

钢筋混凝土结构电渗阻锈技术研究   总被引：5，自引：0，他引：5  

唐军务  李森林  蔡伟成  胡明  朱雅仙 《海洋工程》2008,26(3)

通过测量电渗阻锈过程中阻锈剂渗入量、脱盐率以及钢筋极化电阻,研究了混凝土技术参数和电渗电量对电渗阻锈效果的影响.试验结果表明,电渗阻锈技术能在脱除盐污染混凝土中氯离子的同时,将有效阻锈基团快速迁移到钢筋表面,使已腐蚀的钢筋快速恢复钝化而达到防腐的目的.  相似文献   

Effect of Fly Ash on Frost-Resistance and Chloride Ions Diffusion Properties of Marine Concrete     

杨文武  钱觉时  章一颖 《中国海洋工程》2009,23(2):367-377

It is necessary to pay more attention to the durability of concrete undergoing freeze-thaw cycles and seawater attack simultaneously.Investigated are the effects of water-binder ratio,fly ash (FA) contents and air-entraining agent on resistance to frost and chloride diffusion of marine concrete blended with FA in natural seawater.The results show that fly ash does not improve the frost resistance of concrete but can improve its resistance to chloride diffusion by addition of less than 30%.The resistance to frost and chloride diffusion of FA concrete can be improved with the decrease of water-binder ratio,and FA may improve both of them simultaneously only being mixed with air-entraining agent.A ratio (named as R) of the frost-resisting durability factor to chloride diffusion coefficient can be used to evaluate the durability of marine concrete.Scanning electron microscope (SEM) analyses are consistent with the evaluations by the value of R.  相似文献   

氯化物型盐碱地池塘底泥中水溶性盐的分布特征     

张美昭  张兆琪  郑伟刚  董双林 《海洋湖沼通报》2001,(4):50-55

1997－1999年夏天，对位于黄河下游的氯化物型盐碱地池塘底泥中的水溶性盐进行了分析。结果表明：底泥中的含盐量，SO^2-4,Ca^2 ,Mg^2 含量是随着塘龄的增加而升高，而其余离子基本不随塘龄的增加而变化。各离子的垂直分布为“泥－土”混合层的含量较低，“水－泥”交界层含量较高。  相似文献