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1.
Compositional variation in Hg-bearing sphalerite from the polymetallic Eskay Creek deposit, British Columbia, Canada 总被引:1,自引:0,他引:1
Tassos A. Grammatikopoulos Oleg Valeyev Tina Roth 《Chemie der Erde / Geochemistry》2006,66(4):307-314
The Eskay Creek, British Columbia, Canada, is a polymetallic, gold- and silver-rich, volcanic-hosted, massive sulfide deposit. The ore in the deposit is divided into subzones distinguished by mineralogy, texture, grade and metallurgical characteristics. This study presents the results of a mineralogical examination of three composite field samples, with emphasis on the chemistry of sphalerite. Sphalerite is associated with variable amounts of Hg-tetrahedrite and cinnabar, and an array of sulfides, sulphosalts and non-opaque minerals. Electron micro probe analyses of sphalerite in the three composite samples reveal wide variations in compositions. The Hg content in sphalerite in the three samples varies between 0.08 and 16.35 wt%, whereas the Fe content ranges from 0.33 to 2.29 wt%. The chemical formula of the sphalerite shows the compositional range (Zn0.89–0.98Hg0.01–0.09.Fe0.005–0.02)S. Sphalerite exhibits an almost perfect substitution of Hg and Zn, as shown by the negative covariance between them. Sphalerite with the highest Hg contents tends to have the lowest Fe concentrations. The highest Hg contents in sphalerite are recorded in the samples with the highest bulk Hg concentrations and with the highest cinnabar contents.
The compositional variations of sphalerite are important because they can be used in mapping ore forming fluids and indicate possible temporal variations. Second, determination of the compositional variation of the sphalerite in the mine has metallurgical implications because the mineral is an important Zn source. The mineralogical data indicate that non-physical processes (e.g. pyrometallurgy) must be used to separate Hg from Zn concentrates, with direct environmental implications, that is, release of metals, such as Hg, into the environment during mining and processing. 相似文献
2.
3.
DING Tiping ZHANG Chengxin WAN Defang LIU Zhijian ZHANG Guilan Institute of Mineral Resources Chinese Academy of Geological Sciences Baiwanzhuang Rd. Beijing 《《地质学报》英文版》2003,77(4):519-521
A new experimental calibration was undertaken in this study to get a more reliable sphalerite-galena sulfur isotope geothermometer. The experimental conditions selected in study were very similar to those of natural hydrothermal solution. The high-precision SF6 method was used in sulfur isotope analyses. The obtained calibration curve for sulfur isotope fractionation between sphalerite and galena can be expressed with the equation 10001nαSp-Gn= 0.74×106T-2+0.08. 相似文献
4.
Abstract. Near-infrared (NIR) and visible light microthermometry was applied to the fluid inclusions in sphalerite from a possible southeast extension of the Toyoha polymetallic deposit. Sphalerite occurs as euhedral-subhedral crystals or collo-form aggregates with a variety of color, which contain a well-developed growth banding. Combined with morphological observations, fluid inclusions in dark-colored sphalerite were examined using a near-infrared light microscopic technique, whereas those in light-colored sphalerite and quartz were examined by a conventional visible light microscopy.
Salinities of fluid inclusions in dark-colored sphalerite have a wide variation (1.0–10.3 wt % NaCl equiv.) compared to that in light-colored sphalerite and quartz (0.0–3.4 wt % NaCl equiv.). These variations suggest that the conventional microthermometric data from light-colored sphalerite and quartz were inadequate to interpret the ore formation process. Dark-colored colloform sphalerite and a dark core of subhedral sphalerite formed from high-salinity fluids (6.5–10.3 wt % NaCl equiv.) under highly supersaturated conditions with respect to sphalerite.
The NIR and visible light microthermometry of fluid inclusions in sphalerite combined with its morphological observations is an invaluable method to infer the formation conditions of sphalerite. The NIR and visible light microthermometry is useful to reveal how the nature of ore fluids changed with time. 相似文献
Salinities of fluid inclusions in dark-colored sphalerite have a wide variation (1.0–10.3 wt % NaCl equiv.) compared to that in light-colored sphalerite and quartz (0.0–3.4 wt % NaCl equiv.). These variations suggest that the conventional microthermometric data from light-colored sphalerite and quartz were inadequate to interpret the ore formation process. Dark-colored colloform sphalerite and a dark core of subhedral sphalerite formed from high-salinity fluids (6.5–10.3 wt % NaCl equiv.) under highly supersaturated conditions with respect to sphalerite.
The NIR and visible light microthermometry of fluid inclusions in sphalerite combined with its morphological observations is an invaluable method to infer the formation conditions of sphalerite. The NIR and visible light microthermometry is useful to reveal how the nature of ore fluids changed with time. 相似文献
5.
Abstract. Skeletal sphalerite with stellar, cruciform and snowflake-like (or cauliflower-like) shapes included in pyrite is widely found in the Dajing tin-polymetallic deposit. It occurs only in chalcopyrite-pyrite mineralization stage. The compositions of all sphalerites in the chalcopyrite-pyrite stage are characterized by high Cu content (3.9 - 7.0 wt% with a mean of 5.4 wt%), while the skeletal crystal sphalerite has higher zinc and cadmium contents, and lower copper and iron contents, compared with other sphalerites of the same stage. The skeletal crystal sphalerite in pyrite is possibly generated by exsolution. 相似文献
6.
广东大降坪硫(铅锌)矿床岩浆热液叠加作用——来自闪锌矿Rb-Sr年龄及硫同位素的证据 总被引:2,自引:2,他引:0
广东大降坪硫(铅锌)矿床位于与岩浆作用有关的大绀山多金属矿田的中部,主矿体为赋存在震旦纪变质岩中的层状、透镜状黄铁矿矿体,最近在两个不同产状的黄铁矿矿体下部又新发现了脉状及层状铅锌矿体。文章通过对铅锌矿体的年龄及硫同位素研究,探讨其与主矿体的成因关系,获得了脉状铅锌矿体中闪锌矿的Rb-Sr等时线年龄为(88.5±3.9)Ma,即晚白垩世,与上部黄铁矿矿体的年龄(约630 Ma)相差较大,而与整个大绀山多金属矿田的成矿作用时限一致。三种不同产状的矿体硫同位素组成差异明显:层状黄铁矿矿体富集硫的轻同位素(δ34S=-10.90‰~-25.55‰),且与围岩的硫同位素范围一致,说明硫来自生物的细菌还原硫;透镜状黄铁矿矿体δ34S组成范围较宽(-9.38‰~22.69‰),具多源性硫的特征;铅锌矿体的δ34S在-7.1‰~6.4‰之间变化,硫可能来自深源岩浆,并受围岩成分混染。多方面的证据表明,大降坪黄铁矿矿体下部的铅锌矿体形成于晚白垩世的岩浆热液成矿作用,透镜状黄铁矿矿体受到岩浆热液的叠加。 相似文献
7.
凤梨山铅锌矿产于中酸性岩浆岩与三叠系海相碳酸盐地层的热接触变质晕内。闪锌矿为主要的矿石矿物。其成矿作用可分为沉积成岩同生成矿期(I)、渗流热水成矿溶液改造富集成矿期(Ⅱ)和热接触变质成矿期(Ⅲ)。本文根据闪锌矿的地质产状、矿物共生组合及成矿作用的特点,对它进行了物理化和化学性质、矿物包裹体特征、硫与铅同位素地球化学的研究,并探讨了它的成因问题。 相似文献
8.
(InstItute of Rock Mineral Analysis Ministry of Geology Mineral Resources Beijing ) 《岩矿测试》1995,(2):81-113
研制的黄铁矿、黄铜矿、方铅矿和闪锌矿4个标准物质是国内首次成功研制的硫化物矿物成分分析标准物质。样品采用重选、磁选和电磁选等选矿技术提纯矿物,获得纯度大于95%的单矿物样品。黄铁矿和闪锌矿用棒磨机少量多级粉碎至0.147mm,方铅矿和黄铜矿用小型玛瑙球磨机粉碎至0.097mm。经单因素方差分析检验,均匀性符合要求。采用小包装在干燥、充氩气气氛中保存样品,使样品稳定性有足够保证。连续4年定期监测了样品中全硫含量,证明稳定性良好。样品由国内经计量认证的5家实验室采用多种分离富集手段、不同原理方法协同分析。标准值的确定依据数据分布特征而定,对于服从正态分布的元素,用算术平均值作为定值,对不服从正态分布的元素用多参数模式定值。共确定了56个标准值,16个参考值,6个信息值。该批标准物质于1994年12月通过了国家标准物质研究中心组织的专家复审,并于1995年4月被国家技术监督局批准为国家一级标准物质,标准号分别为GBW07267(GSM-1)、GBW07268(GSM-2)、GBW07269(GSM-3)、GBW07270(GSM-4)。 相似文献
9.
天然闪锌矿可见光催化还原甲基橙的实验研究 总被引:4,自引:0,他引:4
本文研究了可见光下天然闪锌矿的光催化还原能力,通过可见光下天然闪锌矿对甲基橙的光催化降解实验讨论了天然闪锌矿晶格中的杂质缺陷、导带能级位置、光生空穴捕获剂和溶液pH值对可见光催化降解效率的影响。结果表明,在抗坏血酸做空穴捕获剂的条件下,经2 h的可见光催化实验,甲基橙能被天然闪锌矿完全还原降解。天然闪锌矿晶格中丰富的杂质缺陷在禁带中形成杂质能级,可将闪锌矿对光的响应拓展到可见光的波长范围。与天然金红石相比,闪锌矿对甲基橙的较强光催化还原降解效果与其导带电子更负的氧化还原电势有关。此外,空穴捕获剂和pH值的选择都是影响催化效果的关键因素。天然闪锌矿在可见光催化降解污染物领域颇有应用前景。 相似文献
10.
通过对闪锌矿的矿物共生组合,成分、形态及物理性质标型特征的研究,讨论了台江龙井街铅锌矿的成矿物质来源、成矿温度及成因类型。 相似文献