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11.
Surface water/groundwater interaction in the Piora Aquifer,Switzerland: evidence from dye tracing tests 总被引：5，自引：2，他引：3
Martin?H.?OtzEmail author Heinz?K.?Otz Ines?Otz Donald?I.?Siegel 《Hydrogeology Journal》2003,11(2):228-239
Results of seven dye tracing tests done from 1993–1997 to investigate the extent to which lakes and surface water interact
with the underlying Triassic Piora Aquifer, Switzerland, are reported here. Two of the dye tracing tests showed that groundwater
flows in the Piora Aquifer from the Piora Valley to springs in the adjacent Santa Maria Valley, and even further east to the
di Campo Valley considerably outside of the Piora Valley surface water divide.
Lake Ritom located in the Piora Valley loses water only to the Canaria Valley outside of the lake's surface-water watershed
at the lake's western margin when lake levels are above 1,835 m above sea level. Dye tracing tests show that a major sinkhole
in the Piora Valley, Calderoni Sinkhole, is located precisely on the water divide where subsurface flow in the Piora Valley
and surface water diverge and move in opposite directions. The dye tracing results also showed no hydraulic connection between
surface water in the Piora Valley and the famous Pertusio Spring, located in the upper Santa Maria Valley. Only a small amount
of dye from the two dye tracing tests done in 1993 and 1997 entered an exploratory gallery built to test the viability of
the AlpTransit tunnel, being built in competent rock under the Triassic Piora Aquifer, effectively perched above.
Electronic Publication 相似文献
12.
Mohammad Ali Zanjanchi Hassan Sajjadi Majid Arvand Ali Mohammad‐Khah Bahram Ghalami‐Choobar 《洁净——土壤、空气、水》2011,39(11):1007-1013
The potential of MCM‐41 for the removal of cationic dyes from water solution was evaluated using sodium dodecyl sulfate (SDS) for the surface modification of this mesoporous material. Admicelle structures formed on the surface of the calcined MCM‐41 are capable of removing organic pollutants and cationic species from water environment. The structural, textural, and surface chemical characteristics of the prepared SDS‐modified MCM‐41 (SDS‐MCM‐41) were studied. The adsorption capacity of SDS‐MCM‐41 was evaluated for methylene blue (MB) as a target cationic dye. Equilibrium adsorption isotherm data were manipulated employing nonlinear regression analysis. The Langmuir, Freundlich, and Sips isotherm models were examined. The adsorption data were well fitted to both Langmuir and Sips isotherm models. The maximum adsorption capacity of SDS‐MCM‐41 for MB, based on Langmuir and Sips models, were 290.8 and 297.3 mg g?1, respectively. Ethanol was found to be an effective solvent for partial regeneration of the adsorbent. 相似文献
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In the present study, activated carbons were prepared from sisal fiber (Agave sisalana sp.) and pomegranate peel (Punica granatum sp.) using phosphoric acid as the activating agent. Both sisal fiber activated carbon (SFAC) and pomegranate peel activated carbon (PPAC) were characterized using methylene blue number, iodine number, BET surface area, SEM, and FTIR. The BET surface area of the SFAC and PPAC were 885 and 686 m2/g, respectively. The adsorption studies using C.I. Reactive Orange 4 dye on the SFAC and PPAC were carried out. The effects of time, initial adsorbate concentration, pH, and temperature on the adsorption were studied. The isotherm studies were carried and it was found that the Langmuir and Freundlich isotherms fit well for the adsorption of RO 4 on SFAC, while adsorption of RO 4 on PPAC is better represented by the Langmuir and Temkin isotherms. Adsorption kinetics of adsorption was determined using pseudo first order, pseudo second order, Elovich and intraparticle diffusion models and it was found that the adsorption process follows pseudo second order model. Thermodynamics parameters such as changes in free energy (ΔG), enthalpy (ΔH), and entropy (ΔS) were determined by using van't Hoff equation. The positive ΔH value indicates that RO 4 dye adsorption on SFAC and PPAC is endothermic in nature. 相似文献
14.
Nasser Modirshahla Mohammad A. Behnajady Rajab Rahbarfam Aydin Hassani 《洁净——土壤、空气、水》2012,40(3):298-302
In the present study, effects of operational parameters on the electrical energy consumption for photooxidative process (UV/H2O2) for the decolorization of C. I. Acid Red 88 (AR88) have been investigated. In a series of experiments, 20 mg L?1 of AR88 solution were irradiated in the presence of different concentrations of H2O2 (to find out optimum amount of H2O2) by UV light intensity of 30 W m?2 for certain irradiation times. The decolorization of the dye followed pseudo first‐order kinetics, and hence, the figure‐of‐merit electrical energy per order (EEO) is appropriate for estimating the electrical energy efficiency. The electrical energy consumption was determined during the variation of some parameters such as initial H2O2 concentration, initial dye concentration, UV light intensity, pH, and the gap size of solution. Results showed that electrical energy could be reduced by optimizing operational parameters. 相似文献
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This study examined the UV/H2O2 decolorization efficiency under high UV photon flux (intensity normalized by photon energy) irradiation; the incident UV was ranging from 3.13 × 10?8 to 3.13 × 10?6 einstein cm?2 s?1. The experimental results showed that complete decolorization of 20 mg L?1 methylene blue (MB) can be achieved within 5 s and 99% decolorization of 1000 mg L?1 MB can be achieved in 180 s under the best condition of high UV intensity UV/H2O2 process. To the best of our knowledge, UV/H2O2 decolorization process in such a short time has not been reported. The electrical energy per order of the process was 16.21 kWh m?3 order?1 and it is relatively economical compared with other advanced oxidation processes. The kinetics of decolorization follows pseudo‐first order. There is a linear relationship between rate constant and UV intensity, which indicates that increasing UV intensity does not cause decline in light utilization efficiency. The experiment related to initial substrate concentration shows decolorization rate of different substrate concentration (20–1000 mg L?1) are closed to each other. Besides, optimal H2O2 concentration, comparative study with low photon flux light, decolorization of other types of dyes and TOC removal were also studied. 相似文献
17.
This study characterized sludge from an anoxic baffled reactor (ABR) used to treat textile dyeing wastewater. The process was run over 150 days. On day 152, five sludge samples were collected from compartments 1–5 of the ABR and a set of captive tests was conducted to investigate their particle size distributions (PSDs), dye biosorption and biodegradation properties, and dehydrogenase activity (DHA). The results indicated that the PSD of the five sludge samples from the ABR were similar. Methylene blue biosorption to the sludge samples followed the pseudo‐second‐order kinetic model and the actual biosorption process was controlled by external and intraparticle diffusion, simultaneously. After the sludge samples were cultivated for 24 h, the acid red GR dye removal efficiencies were 59.5, 68.3, 76.4, 61.5, and 65.4%, respectively. Eliminating dye biosorption, the dye biodegradation efficiencies were only 38.8, 46.3, 52.6, 48.3, and 46.0%, respectively. Furthermore, the DHA values were 28.2, 45.3, 56.5, 41.0, and 35.0 µg TF mL?1 h?1, respectively, and the DHA variation was in accordance with the dye biodegradation efficiency variation. 相似文献
18.
Ali Olad Ali Reza Amani‐Ghadim Mir Saeed Seyed Dorraji Mohammad Hosein Rasoulifard 《洁净——土壤、空气、水》2010,38(4):401-408
The removal of Alphazurine FG (AF) dye from water by an electrocoagulation process has been studied. The effect of some operational parameters, such as anode material, current density, initial dye concentration, pH of solution, conductivity, and inter‐electrode distance, on the removal efficiency was investigated. Iron and aluminum were used as anodes in the electrocoagulation cell. It was found that the efficiency of the iron anode was better than that of the aluminum anode for AF removal. The factors that affected the removal efficiency were the current density and the initial dye concentration. The removal efficiency increased from about 35% at 25 A m–2 to about 97% at 100 A m–2, during 4 min of electrocoagulation. The results exhibited pseudo‐first‐order kinetics for AF removal by electrocoagulation. In addition, a mathematical model was successfully established for predicting the removal efficiency. A comparison between the model results and experimental data gave a high correlation coefficient (R2 = 0.9925), which indicates that the model is able to predict the removal efficiency of AF. 相似文献
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Degradation of an anthraquinone dye, disperse blue E‐4R, by zero‐valent iron (ZVI)/ozone (O3) was carried out in a series of laboratory‐scale experiments. The obtained results indicated that this method was much more effective than single ZVI or single O3 at removal of color, chemical oxygen demand, total organic carbon, and adsorbable organic halogen. The effect of several related operational parameters, including O3 dosage, zero valent iron dosage, temperature, pH value, and ZVI particle size were also discussed. Finally, we tried to decontaminate some actual samples with this method, which showed high treatment efficiency to the sample pretreated by conventional activated sludge. 相似文献