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A simple, low cost, highly effective, and useful Fenton oxidation treatment of synthetic dye bath waste with pickling liquor as a source of iron (Fe2+ catalyst) is reported. Optimizations of contact time, Fe2+ and H2O2 doses are carried out. Oxidative de‐colorization and degradation of Reactive Blue 4 and Reactive Orange 16 was measured in terms of decrease in absorbance at their wavelength of maximum absorption (RB4, 599 nm; and RO16, 493 nm) and also as reduction in chemical oxygen demand (COD). Approximately, 62% COD was removed in 2 h at optimized doses of Fe2+ (8.95 mM) and H2O2 (61.8 mM) by using pickling waste as a source of Fe2+ catalyst. Similar performance efficiency was observed when neat FeSO4 was used as a source of Fe2+, indicating that pickling liquor can be a low cost source of Fe2+ to treat synthetic dye bath waste by Fenton method. 相似文献
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Martin Sharp Keith Richards Ian Willis Neil Arnold Peter Nienow Wendy Lawson Jean-Louis Tison 《地球表面变化过程与地形》1993,18(6):557-571
As part of an integrated study of the hydrology, meltwater quality and dynamics of the Haut Glacier d'Arolla, Switzerland, the glacier's drainage network structure was determined from patterns of dye recovery in 342 injection experiments conducted from 47 moulins distributed widely across the glacier. This structure was compared with theoretical predictions based upon reconstructed patterns of water flow governed by (a) the subglacial hydraulic potential surface, and (b) the subglacial bedrock surface. These reconstructions were based on measurements of ice surface and bedrock topography obtained by a combination of ground survey and radio-echo sounding techniques. The two reconstructions simulate the drainage system structures expected for (a) closed channels, in which water is pressurized by the overlying ice, and (b) gravity-driven, open-channel flow. The closed-channel model provides the best fit to the observed structure, even though theoretical calculations suggest that, under summer discharge conditions, open-channel flow may be widespread beneath the glacier. Possible reasons for this apparent discrepancy are discussed. 相似文献
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R. E. Wallace III 《Environmental Geology》1993,22(4):362-366
This paper summarizes over four years of studies and testing of a sinkhole/spring system in north Tampa. Sulphur Springs Pool delivers an average of 95 million l/d to the Hillsborough River, which is tributary to Tampa Bay. In 1986, owing to increasingly erratic bacterial levels at the natural bathing area adjacent to Sulphur Springs, the Hillsborough County Health Department closed the pool for swimming. The City of Tampa, Southwest Florida Water Management District (SWFWMD), Hillsborough County Environmental Protection Commission, and the United States Geological Survey have gathered data in an attempt to better understand the system and possible sources of contamination. The Sulphur Springs Action League is a civic group in the area, which has an objective of reopening the pool for recreational purposes. Environmental Engineering Consultants, Inc. provided pro bono technical assistance and expertise in assisting the Action League with its goal. The Action League obtained a grant from SWFWMD to outfit underwater divers for sinkhole exploration as well as water quality and dye trace analysis. The main suspects for bacterial contamination of the pool were two significant sinkholes located 1950 and 2300 m north of the spring. A series of dye tests and water-quality tests were performed. It was estimated that the underground velocity of water was between 90–100 m/h. Using a dye trace, bacteria testing, and travel time estimating, a new source of contamination was found in a Department of Transportation (DOT) stormwater retention basin in which a sinkhole had opened up and was receiving stormwater. The two significant sinkholes received stormwater from commercial and residential areas, and this stormwater brings a large amount of bacteria into the sinkhole, which funnels into the underground system and induces a bacteria spike at Sulphur Springs pool that exceeds the bathing water standards. The City of Tampa has constructed an experimental initial flush capture basin that will sand-filter stormwater to see if this will favorably affect bacteria levels. A mayor's task force in Tampa has recommended ultraviolet disinfection as an interim solution to the contamination problem. 相似文献
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Purification of Wastewaters Containing Azo Dyes This study describes the degradability of the azo dye C.I. Reactive Violet 5 by a continuous flow biological treatment system consisting of three rotating disc reactors. The azo dye was first decolorized in an anaerobic reactor. Decolorization was improved by adding an auxiliary substrate (yeast extract and acetic acid). Although severe operating conditions were experienced due to failures in the temperature and pH-controllers, the reactor recovered quickly and continued to decolorize reliably. The removal of the auxiliary substrate in the anaerobic reactor was not satisfactory, probably due to the copper in the azo dye. Batch experiments showed that copper was removed from the dye molecule and precipitated during the decolorization. In the continuous flow reactor, the copper precipitate on the disc can redissolve due to a pH-gradient in the fixed biomass becoming toxic again for the bacteria. In the following two aerobic reactors, the auxiliary substrate was degraded, but mineralization of the dye metabolites was insufficient. The aromatic amines produced by the anaerobic decolorization are more toxic in the bacterial luminescence test than the azo dye. Therefore, decolorization alone cannot be used to treat colored wastewater. Since the amines can also be produced in anaerobic parts of rivers, the dyes have to be removed in a more efficient way. That is the reason why in further experiments ozonation is being tested to increase the biological degradability of the azo dye for a following aerobic stage. Either ozonation can be used after the two stage treatment of the dye in anaerobic/aerobic reactors or the dye can be oxidized directly, making the addition of auxiliary substrate unnecessary. These configurations are being tested with the goal to degrade the dye with the least ozone consumption. 相似文献
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收集十几块和田玉仔料和数十块仿和田玉仔料样品,进行肉眼与镜下观察。简要总结和田玉仔料与仿和田玉仔料以及染色和田玉仔料的肉眼鉴别要领。 相似文献
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Zeynep Eren 《洁净——土壤、空气、水》2012,40(11):1284-1289
This study illustrates the degradation of an azo dye, Reactive Yellow 81 (RY81), by the combined irradiation of UV‐C and ultrasound in the presence of homogeneous (Fe2+) and heterogeneous (TiO2, ZnO) catalysts. The efficiency of homogeneous and heterogeneous oxidation systems was evaluated in regard of the decolorization and mineralization of RY81. Decolorization followed pseudo‐first‐order kinetics with homogeneous and heterogeneous catalysts. Complete color removal was accomplished by homogeneous sonocatalytic and sonophotocatalytic oxidation processes with apparent rate constants of 0.96 × 10?3 and 46.77 × 10?3 s?1, respectively, in the presence of Fe2+. However, partial color removal was obtained by heterogeneous sonocatalytic, photocatalytic, and sonophotocatalytic oxidation processes with apparent rate constants of 2.32 × 10?3, 3.60 × 10?3, and 3.67 × 10?3 s?1, respectively, in the presence of ZnO. TiO2 had the worst catalytic effect of all of the oxidation processes. The addition of hydrogen peroxide increased the rate constants of the heterogeneous oxidation processes and decreased the rate constants of the homogeneous oxidation processes. RY81 mineralization was 62.8% for the US/UV/Fe2+ homogeneous oxidation process, which was the best oxidation process, whereas it was 43.5% for the US/UV/ZnO/H2O2 heterogeneous oxidation process within 2 h reaction time. 相似文献
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Characterizing heterogeneous soil water flow and solute transport using information measures 总被引：1，自引：0，他引：1
Heterogeneous water flow and solute transport in soils are an important phenomenon and difficult to be characterized. The objectives of this study were to investigate the heterogeneity of solute transport related to heterogeneous soil water flow using dye infiltration experiments, and to characterize heterogeneous water flow and solute transport in soils using the information theory. Field experiments of dye infiltration were performed in four plots. Various information measures were applied to characterize information content and complexity of water flow and solute transport in soils. Information contents and complexities of the maximum and apparent infiltration depths, and the mean and standard deviation of concentrations in the vertical direction of the plots were calculated. More heterogeneous processes of soil water flow and transport result in higher information/complexity values. The probability distributions of mean concentration were similar to those of the corresponding apparent infiltration depths for the plots, indicating that heterogeneity of dye concentrations was closely related to that of soil water flow. However, the range of information entropy and complexity of the water flow sequences was much narrower than that of the sequences of the concentrations. The results suggested that the transport processes were more heterogeneous than the water flow processes. Compared with the probability distributions of flow parameters, the information measures appeared to be a more versatile tool to describe flow and transport heterogeneities in soils. 相似文献