A helium stratified and ingassed lower mantle: resolving the helium paradoxes     

Honggang Zhu  Xuefang Li  Yingkui Xu 《Acta Geochimica》2020,(1):4-10

It is generally believed a variation of 3He/4He isotopic ratios in the mantle is due to only the decay of U and Th,which produces4 He as well as heat.Here we show that not only3He/4He isotopic ratios but also helium contents can be fractionated by thermal diffusion in the lower mantle.The driving force for that fractionation is the adiabatic or convective temperature gradient,which always produces elemental and isotopic fractionation along temperature gradient by thermal diffusion with higher light/heavy isotopic ratio in the hot end.Our theoretical model and calculations indicate that the lower mantle is helium stratified,caused by thermal diffusion due to*400℃temperature contrast across the lower mantle.The highest3He/4He isotopic ratios and lowest He contents are in the lowermost mantle,which is a consequence of thermaldiffusion fractionation rather than the lower mantle is a primordial and undegassed reservoir.Therefore,oceanicisland basalts derived from the deepest lower mantle with high3He/4He isotopic ratios and less He contents—the long-standing helium paradox,is solved by our model.Because vigorous convection in the upper mantle had resulted in disordered or disorganized thermal-diffusion effects in He,Mid-ocean ridge basalts unaffected by mantle plume have a relatively homogenous and lower!3He/4He isotopic compositions.Our model also predicts that 3He/4He isotopic ratios in the deepest lower mantle of early Earth could be even higher than that of Jupiter,the initial He isotopic ratio in our solar system,because the temperature contrast across the lower mantle in the early Earth is the largest and less4 He had been produced by the decay of U and Th.Moreover,the early helium-stratified lower mantle owned the lowest He contents due to over-degassing caused by the largest temperature contrast.Consequently,succeeding evolution of the lower mantle is a He ingassed process due to secular cooling of the deepest mantle.This explains why significant amount of He produced by the decay of U and Th in the lower mantle were not released,another long-standing heat–helium paradox.  相似文献   

Degassing of primordial major energy source for hydrogen and helium as the internal terrestrial processes     

Arie Lev Gilat  Alexander Vol 《地学前缘(英文版)》2012,3(6):911-921

Examples of the mightiest energy releases by great earthquakes and volcanic eruptions and hypotheses providing explanations for them are analyzed along with the results of some recently published researches and visualizations.The emerging conclusions are that the mechanism of the strong earthquake is a chemical explosion;that volcanic eruption is a special type of earthquake wherein the hypocenter rises to the earth-surface;and that there is an association between the seismic-volcanic processes and mantle "fluids" and the lack of energy for mantle plumes.A conceptual system of hypotheses is put forward to explain the conservation of energy during Earth’s accretion,its quasi-stable release by primordial H- and He-degassing and of the crucial role of the energy of degassing-comprisingreactions in endogenic processes.Specific mechanisms and chemical processes are proposed for the gas-liquid mantle plumes melting through the solid mantle using heat-energy released in reactions of their metamorphic and chemical transformation under gradual decrease of pressure and temperature;volcanic gases are put forward as energy carriers.He performance as a unique measuring transformer correlative to the internal heat flow was used for calculation of energy release by degassing;it equals to 5.12×10²⁰ J/yr.an amount of energy five-fold greater than the entire energy loss involved in earthquake and volcanic activity.The hypotheses proposed are objectively testable.  相似文献   

Processes controlling 234U and 238U isotope fractionation and helium in the groundwater of the St. Lawrence Lowlands,Quebec: The potential role of natural rock fracturing     

《Applied Geochemistry》2016

The goal of this study is to explain the origin of ²³⁴U–²³⁸U fractionation in groundwater from sedimentary aquifers of the St. Lawrence Lowlands (Quebec, Canada), and its relationship with ³He/⁴He ratios, to gain insight regarding the evolution of groundwater in the region. (²³⁴U/²³⁸U) activity ratios, or (²³⁴U/²³⁸U)_act, were measured in 23 groundwater samples from shallow Quaternary unconsolidated sediments and from the deeper fractured regional aquifer of the Becancour River watershed. The lowest (²³⁴U/²³⁸U)_act, 1.14 ± 0.01, was measured in Ca–HCO₃-type freshwater from the Quaternary Shallower Aquifer, where bulk dissolution of the carbonate allows U to migrate into water with little ²³⁴U–²³⁸U isotopic fractionation. The (²³⁴U/²³⁸U)_act increases to 6.07 ± 0.14 in Na–HCO₃–Cl-type groundwater. Preferential migration of ²³⁴U into water by α-recoil is the underlying process responsible for this isotopic fractionation. An inverse relationship between (²³⁴U/²³⁸U)_act and ³He/⁴He ratios has been observed. This relationship reflects the mixing of newly recharged water, with (²³⁴U/²³⁸U)_act close to the secular equilibrium and containing atmospheric/tritiogenic helium, and mildly-mineralized older water (¹⁴C ages of 6.6 kyrs), with (²³⁴U/²³⁸U)_act of ≥6.07 and large amounts of radiogenic ⁴He, in excess of the steady-state amount produced in situ. The simultaneous fractionation of (²³⁴U/²³⁸U)_act and the addition of excess ⁴He could be locally controlled by stress-induced rock fracturing. This process increases the surface area of the aquifer matrix exposed to pore water, from which produced ⁴He and ²³⁴U can be released by α-recoil and diffusion. This process would also facilitate the release of radiogenic helium at rates greater than those supported by steady-state U–Th production in the rock. Consequently, sources internal to the aquifers could cause the radiogenic ⁴He excesses measured in groundwater.  相似文献   

Dissolved helium and TDS in groundwater from Bhavnagar in Gujarat: Unrelated to seismic events between August 2000 and January 2001     

S. K. Gupta  R. D. Deshpande 《Journal of Earth System Science》2003,112(1):51-60

Temporal variations have been observed in both dissolved helium and TDS in the form of increase in basaltic and decrease in alluvial aquifers. The increase in basaltic aquifers has been explained by enhanced pumping of old groundwater with relatively higher concentration of dissolved helium and salt, whereas the decrease in alluvial aquifers has been explained by dilution from the post monsoon groundwater recharge. Therefore, the observed temporal variations cannot be ascribed to the contemporary enhanced seismic activity in this region since August–September 2000.  相似文献   

Geographical Distribution of 3He/4He Ratios in the Chugoku District, Southwestern Japan     

Yuji Sano  Naoto Takahata  Tetsuzo Seno 《Pure and Applied Geophysics》2006,163(4):745-757

We have collected 34 hot spring and mineral spring gases and waters in the Chugoku and Kansai districts, Southwestern Japan and measured the ³He/⁴He and ⁴He/²⁰Ne ratios by using a noble gas mass spectrometer. Observed ³He/⁴He and ⁴He/²⁰Ne ratios range from 0.054 R_atm to 5.04 R_atm (where R_atm is the atmospheric ³He/⁴He ratio of 1.39 × 10⁻⁶) and from 0.25 to 36.8, respectively. They are well explained by a mixing of three components, mantle-derived, radiogenic, and atmospheric helium dissolved in water. The ³He/⁴He ratios corrected for air contamination are low in the frontal arc and high in the volcanic arc regions, which are consistent with data of subduction zones in the literature. The geographical contrast may provide a constraint on the position of the volcanic front in the Chugoku district where it was not well defined by previous works. Taking into account the magma aging effect, we cannot explain the high ³He/⁴He ratios of the volcanic arc region by the slab melting of the subducting Philippine Sea plate. The other source with pristine mantle material may be required. More precisely, the highest and average ³He/⁴He ratios of 5.88 R_atm and 3.8±1.6 R_atm, respectively, in the narrow regions near the volcanic front of the Chugoku district are lower than those in Kyushu and Kinki Spot in Southwestern Japan, but close to those in NE Japan. This suggests that the magma source of the former may be related to the subduction of the Pacific plate, in addition to a slight component of melting of the Philippine Sea slab.  相似文献   

He diffusion and (U–Th)/He thermochronometry of zircon: initial results from Fish Canyon Tuff and Gold Butte     

Peter W. Reiners  Kenneth A. Farley  Hunter J. Hickes 《Tectonophysics》2002,349(1-4)

To evaluate the potential of (U–Th)/He geochronometry and thermochronometry of zircon, we measured He diffusion characteristics in zircons from a range of quickly and slowly cooled samples, (U–Th)/He ages of zircons from the quickly cooled Fish Canyon Tuff, and age-paleodepth relationships for samples from 15 to 18 km thick crustal section of the Gold Butte block, Nevada. (U–Th)/He ages of zircons from the Fish Canyon Tuff are consistent with accepted ages for this tuff, indicating that the method can provide accurate ages for quickly cooled samples. Temperature-dependent He release from zircon is not consistent with thermally activated volume diffusion from a single domain. Instead, in most samples apparent He diffusivity decreases and activation energy (E_a) increases as cycled step-heating experiments proceed. This pattern may indicate a range of diffusion domains with distinct sizes and possibly other characteristics. Alternatively, it may be the result of ongoing annealing of radiation damage during the experiment. From these data, we tentatively suggest that the minimum E_a for He diffusion in zircon is about 44 kcal/mol, and the minimum closure temperature (T_c, for a cooling rate of 10 °C/myr) is about 190 °C. Age–paleodepth relationships from the Gold Butte block suggest that the base of the zircon He partial retention zone is at pre-exhumation depths of about 9.5–11 km. Together with constraints from other thermochronometers and a geothermal gradient derived from them in this location, the age–depth profile suggests a He T_c of about 200 °C for zircon, in reasonable agreement with our interpretation of the laboratory measurements. A major unresolved question is how and when radiation damage effects become significant for He loss from this mineral.  相似文献   

Performance of CRONUS-P – A pyroxene reference material for helium isotope analysis     

《Quaternary Geochronology》2016

Helium isotope analyses are central to modern earth science and measured by many noble gas laboratories around the globe (Burnard, 2013; Wieler et al., 2002), spanning a wide spectrum of fundamental research – from identifying primordial reservoirs in the Earth mantle to paleoclimate reconstructions. The CRONUS-Earth initiative included the manufacturing, distribution and analysis of a pyroxene reference material (CRONUS-P) that was designed to be useful for internal reliability control of ³He measurements within a few percent and potentially for ⁴He on a higher level of uncertainty.This short paper describes the CRONUS-P material and its performance as ³He and ⁴He reference sample for noble gas laboratories. The companion paper by Blard et al. 2015 describes in depth the inter-laboratory helium isotope experiment within CRONUS-Earth.We show normalized helium isotope data of CRONUS-P measured at three different noble gas laboratories. Data from all three laboratories show no relation between helium isotope concentrations and sample mass, implying that the material is homogeneous. The data show that CRONUS-P is useful as an internal standard for ³He within better 2% (1σ) and for ⁴He within better 10%.  相似文献   

天津王3井逸出氦气浓度变化特征分析     

龚永俭  陈嵩  程立康  李旭东 《震灾防御技术》2015,10(S1):750-759

对天津王3井逸出氦气浓度日变化和年变化特征进行了分析,结果表明：①王3井逸出氦气浓度日变幅背景值在0.0012%—0.0036%之间,日变幅在冬季偏高;②在大多数观测日的10—18时左右,王3井逸出氦气浓度日变化曲线有“波谷”,但没有明显的“波峰”,但在部分观测日逸出氦气浓度日变化曲线的“波谷”却不明显,王3井逸出氦气浓度日变化形态不属于“固体潮”型;③王3井逸出氦气浓度年变化曲线呈上升的“双峰双谷”似“潮汐”形态,一般在6月、12月左右出现“波峰”,3月、9月左右出现“波谷”,相比较而言,“波峰”更显著。通过对井孔所在地的地质构造、大气温度、降水、同井孔水位、周边地热资源开采等因素的分析,笔者认为王3井逸出氦气浓度的变化基本不受大气温度、降水和同井孔水位变化的影响,主要与井孔所在地的断层活动性和周边地热资源的开采有关。  相似文献   

Noble gas data from Goldfield and Tonopah epithermal Au-Ag deposits,ancestral Cascades Arc,USA: Evidence for a primitive mantle volatile source     

《Ore Geology Reviews》2017

The He, Ne, and Ar isotopic composition of fluid inclusions in ore and gangue minerals were analyzed to determine the source of volatiles in the high-grade Goldfield and Tonopah epithermal Au-Ag deposits in southwestern Nevada, USA. Ar and Ne are mainly atmospheric, whereas He has only a minor atmospheric component. Corrected ³He/⁴He ratios (with atmospheric He removed) range widely from 0.05 to 35.8 times the air ³He/⁴He ratio (R_A), with a median of 1.43 R_A. Forty-one percent of measured ³He/⁴He ratios are ≥4 R_A, corresponding to ≥50% mantle He assuming a mantle ratio of 8 R_A. These results suggest that mafic magmas were part of the magmatic-hydrothermal system underlying Goldfield and Tonopah, and that associated mantle-sourced volatiles may have played a role in ore formation. The three highest corrected ³He/⁴He ratios of 17.0, 23.7, and 35.8 R_A indicate a primitive mantle He source and are the highest yet reported for any epithermal-porphyry system and for the Cascades arc region. Compiled ³He/⁴He measurements from epithermal-porphyry systems in subduction-related magmatic arcs around the world (n = 209) display a statistically significant correlation between ³He/⁴He and Au-Ag grade. The correlation suggests that conditions which promote higher fluid inclusion ³He/⁴He ratios (abundance of mantle volatiles and focused upward volatile transport) have some relation to conditions that promote higher Au-Ag grades (focused flow of metal-bearing fluids and efficient chemical traps). Results of this and previous investigations of He isotopes in epithermal-porphyry systems are consistent with the hypothesis posed in recent studies that mafic magmas serve an important function in the formation of these deposits.  相似文献   

北京地区大灰厂井与五里营井氦气观测资料的对比分析   总被引：1，自引：0，他引：1  

武晓东  王志惠  朱石军 《山西地震》2012,(1):28-30

对比分析了北京市地震局丰台大灰厂井和延庆五里营井的氦气观测资料,发现由于井水深度、井水类型和水温的不同,丰台大灰厂井氦气含量明显低于延庆五里营井的氦气含量;两口井氦气年变都是冬高夏低;日变形态基本一致,都表现为一峰一谷的形态;两口井氦气含量与观测环境温度负相关。  相似文献