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11.
In this study, the adsorption of 2-, 3-, 4-anisidines on metal (Co)-supported pumice has been performed. The amount of cobalt on pumice was measured by ICP-OES analysis. Scanning electron microscopy indicated the formation of metal modification on the pumice surface. The samples were examined by Fourier transform infrared spectroscopic analysis of the adsorption process. The data show that after cobalt cation was supported on pumice, the adsorption of 2-, 3-, 4-anisidines was characterized by the bands at 2,958, 1,633, 1,450, 760, and 734 cm?1. Adsorption of anisidines was observed only on Co-supported pumice, not on bulk pumice. The results show that the main adsorption process can only occur on the metal cation and metal oxide surface of pumice. Geometrical effects of isomers were monitored after adsorption.  相似文献   
12.
Fuzzy process capability indices for quality control of irrigation water   总被引:1,自引:0,他引:1  
Water covers over 70% of the Earth surface and is a very important resource to people and the environment. Water pollution affects drinking water, rivers, lakes and oceans all over the world. This consequently harms human health and the natural environment. Water pollution can also affect the crops. So, water pollution is an important issue for humanity. Therefore, the control of irrigation water is a necessity. In this paper, a methodology based on process capability indices (PCIs) has been presented to control the levels of pH, dissolved oxygen (DO) and temperature (T) in dam’s water for irrigation. Fuzzy PCIs have been proposed for this aim. The fuzzy estimates of $ \hat C_p Water covers over 70% of the Earth surface and is a very important resource to people and the environment. Water pollution affects drinking water, rivers, lakes and oceans all over the world. This consequently harms human health and the natural environment. Water pollution can also affect the crops. So, water pollution is an important issue for humanity. Therefore, the control of irrigation water is a necessity. In this paper, a methodology based on process capability indices (PCIs) has been presented to control the levels of pH, dissolved oxygen (DO) and temperature (T) in dam’s water for irrigation. Fuzzy PCIs have been proposed for this aim. The fuzzy estimates of and are obtained for pH, DO, and T based on Buckley’s interval estimation approach and based on fuzzy specification limits. An application has been made for Kesikk?prü Dam in Ankara, Turkey. In this paper, Buckley’s approach is re-arranged to obtain a triangular fuzzy membership function because it cannot be obtained from Buckley’s approach in some situation.  相似文献   
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Two-month flow-through exposure experiments of tributyltin (TBT) and triphenyltin (TPhT) were conducted with abalone, Haliotis gigantea. Nominal concentrations of 100 ng TBT/l and 100 ng TPhT/l caused significant spermatogenesis in ovaries of exposed females. There were also significantly more contracted primary oocytes observed in females exposed to either TBT or TPhT than controls. The incidence of two types of unknown cells was also significant in females exposed to TPhT. No significant histological changes were observed in testis of exposed males. This ovarian spermatogenesis caused by TBT and/or TPhT resembles gastropod imposex. Remarkably high concentrations of TBT and TPhT were observed in the head (including central nervous system ganglia), compared to muscles concentrations. Accumulation of TBT and TPhT in the head may disturb reproductive hormonal regulators through neuropeptides released from ganglia. This, as well as possible aromatase inhibition, may be one of the inducers for spermatogenesis in the abalone ovaries.  相似文献   
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An artificial neural networks (ANN) model is developed to study the observed pattern of local scour at bridge piers using an FHWA (Federal Highway Administration) data set composed of 380 measurements at 56 bridges in 13 states. Various ANN estimates of observed pier scour depth on different choices of input variables are examined. Reducing the number of variables from 14 to 9 has negligible effect on the coefficient of determination, R2, (0.73 vs. 0.72). Further sensitivity analysis indicates that pier scour depth can be estimated using only four variables: pier shape and skew, flow depth and velocity with a coefficient of determination of 0.81, suggesting that inclusion of some variables actually diminishes the quality of ANN predictions of short term observed pattern of scour. The ANN estimates indicate that flow depth and flow velocity make up 66% of the coefficient of determination.  相似文献   
17.
Istanbul is the largest city in Turkey with an area of around 5750 km2 and a population of around 10.8 M (2000). In 1980, the population was only around 4.7 M and so has more than doubled in only 2 decades. In 2000, around 65% of the population were living on the European side of the city with its large industrial/commercial and trade centres. The population is increasing as a result of both births exceeding deaths and mass immigration. Consequently, planned and unplanned housing are increasing while green areas are decreasing in area. Monitoring urban growth will enable the Municipality of Istanbul to better manage this complex urban area.  相似文献   
18.
Histological examination of gonads as well as chemical analysis of organotin compounds in tissues of the giant abalone, Haliotis madaka, was conducted to evaluate continuing endocrine disruption in abalone populations in Japan. Abalone specimens were collected from two different areas, Tsushima as a reference site and Jogashima as a site representative of declining abalone populations where serious organotin contamination had been observed, each month from January 1998 to March 1999. Scores were given to the development stages of reproductive cells in the ovary and testis. The degree of sexual maturation was evaluated by calculating the mean value of a histogram of these scores for the reproductive cells of each abalone. The temporal variations in degree of sexual maturation showed that female and male abalone from Tsushima matured synchronously, while those from Jogashima did not, which were similar to results of the previous study during September 1995–November 1996. Approximately 19% of the female abalone from Jogashima were masculinized with an ovo-testis, which was also similar to the result of the previous study. The masculinization of female abalone is reported to be induced by tributyltin (TBT) and triphenyltin (TPhT) from antifouling paints. Concentrations of the sum of butyltins (TBT, dibutyltin (DBT) and monobutyltin (MBT): ΣBTs) and the sum of phenyltins (TPhT, diphenyltin (DPhT) and monophenyltin (MPhT): ΣPhTs) in the muscle of abalone from Jogashima (n = 73) of 7.8 ± 9.0 ng/g wet wt. and 4.5 ± 6.8 ng/g wet wt., respectively, were significantly higher than those from Tsushima (n = 87) of 4.7 ± 4.9 ng/g wet wt. and 0.8 ± 1.7 ng/g wet wt., respectively (p < 0.05 for ΣBTs; p < 0.001 for ΣPhTs), although concentrations of TBT and TPhT in the muscle of abalone from Jogashima (n = 73) of 2.2 ± 2.5 ng/g wet wt. and 5.8 ± 5.1 ng/g wet wt., respectively, were insignificantly and significantly higher than those from Tsushima (n = 87) of 0.4 ± 0.6 ng/g wet wt. and 0.5 ± 0.9 ng/g wet wt., respectively, (p > 0.05 for TBT; p < 0.001 for TPhT). Thus, endocrine disruption as well as contamination by organotins in the giant abalone from Jogashima is still persisting.  相似文献   
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20.
Knowledge of the tectonic history of the Pamir contributes to our understanding of both the evolution of collisional orogenic belts as well as factors controlling Central Asian aridification. It is, however, not easy to decipher the Mesozoic–Cenozoic tectonics of the Pamir due to extensive Neogene deformation in an orogen that remains largely understudied. This study reports detrital apatite and zircon fission-track (FT) ages from both the eastern Tajik Basin sedimentary rocks and Pamir modern river sands. These FT data, supported by vitrinite reflectance and zircon and apatite U–Pb double dating, suggest that the majority of the FT ages are unreset and record exhumation stages of the Pamir, which has served as the source terrane of the Tajik Basin since the Cretaceous. Furthermore, we combine the new data with a compilation of published detrital apatite and zircon FT data from both the Tajik Basin sedimentary rocks and Pamir modern river sands, to explore the Mesozoic–Cenozoic tectonic history of Pamir. Deconvolved FT Peak Ages document two major Mesozoic exhumation events associated with the Late Triassic–Early Jurassic Cimmerian orogeny that reflects accretion of the Pamir terranes, as well as the Early–early Late Cretaceous deformation associated with the northward subduction of the Neo-Tethys Ocean beneath Pamir. The compiled data also show significant Late Eocene–Neogene exhumation associated with the ongoing formation of the Pamir, which peaks at ca. 36, 25, 14 and 7 Ma.  相似文献   
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