加水热模拟中深湖与煤系泥岩地化特征比较   总被引：2，自引：0，他引：2  

梁春秀  魏志平等 《沉积学报》2002,20(1):165-168

通过深湖泥岩和煤系泥岩的加水热模拟研究认为,在热模拟实验过程中,深湖泥岩和煤系泥岩显示不同特征,并且其演化有差别。深湖泥岩利于液态原油的生成,并且转化率高于煤系泥岩。深湖泥岩残余可溶有机质饱和烃含量高于煤系泥岩,非烃含量则低于煤系泥岩。深湖泥岩胶质 /沥青质和饱芳比均随温度升高而降低,而煤系泥岩的胶质 /沥青质随温度升高有增加趋势,其饱芳比的变化则不大或有降低趋势。深湖泥岩的T_max难以指示演化阶段,其干酪根碳同位素值明显轻于煤系泥岩,它们的值均随温度的升高而变重。  相似文献   

碳酸盐岩与泥质烃源岩生气规律对比研究   总被引：10，自引：1，他引：10  

黄志龙  钟宁宁  张四海 《地球化学》2003,32(1):29-34

配制了两套成熟度相近的碳酸盐岩和泥质岩丰度系列样品。采用半封闭外加温加压式热压模拟装置对碳酸盐岩的生烃情况进行了热模拟实验，研究了碳酸盐岩生气量随成熟度和温度变化的趋势，探讨了碳酸盐岩生气的变化规律。碳酸盐岩与泥质岩的生烃潜力是有机质质量和有机质丰度的函数，与岩性无关；碳酸盐岩的产气规律与泥质岩相似，而且两者产烃的量级也相当，并不存在碳酸盐岩生排烃效率高的现象；碳酸盐岩和泥质岩总有机碳(TOC)含量在热模拟过程中基本上不发生变化；不同岩性的有机质的产烃效率主要受温度和有机质类型决定。  相似文献   

伊通地堑下第三系原油和生油岩中芳构化五环三萜及其地球化学意义     

兰文波  张英歧 《地球化学》1997,26(6):33-46

详细研究了吉林伊通地堑下第三系生油岩和原油中的芳烃生物标志物，包括常规的多环芳烃，以及丰富的来源于高等植物的芳香二萜和芳构化的五环三萜。目前，原油中芳构化五环三萜类生物类生物标志物国内外均尚报道极少。还详细讨论了利用原油中最新发现的芳构化五环三萜在解决本区生物输入，油源对比以及石油成因等方面的重要意义。  相似文献   

Thermal evolution of an extensional detachment as constrained by organic metamorphic data and thermal modeling: Graz Paleozoic Nappe Complex (Eastern Alps)   总被引：1，自引：0，他引：1  

Gerd Rantitsch  Reinhard F. Sachsenhofer  Christian Hasenhüttl  Barbara Russegger  Thomas Rainer 《Tectonophysics》2005,411(1-4):57-72

Following Early Cretaceous nappe stacking, the Eastern Alps were affected by late-orogenic extension during the Late Cretaceous. In the eastern segment of this range, a Late Cretaceous detachment separates a very low- to low-grade metamorphic cover (Graz Paleozoic Nappe Complex, GPNC) above a low- to high-grade metamorphic basement. Synchronously, the Kainach Gosau Basin (KGB) collapsed and subsided on top of the section.Metamorphism of organic material within this section has been investigated using vitrinite reflectance data and Raman spectra of extracted carbonaceous material. In the southern part of the GPNC, vitrinite reflectance indicates a decrease in organic maturity towards the stratigraphic youngest unit. The remaining part of the GPNC is characterized by an aureole of elevated vitrinite reflectance values and Raman R2 ratios that parallels the margins of the GPNC. Vitrinite reflectance in the KGB shows a steep coalification gradient and increases significantly towards the western basin margin. The observed stratigraphic trend in the southern GPNC is a result of deep Paleozoic to Early Cretaceous burial. This maturity pattern was overprinted along the margins by advective heat and convective fluids during Late Cretaceous to Paleogene exhumation of basement rocks.During shearing, the fault zone was heated up to ca. 500 °C. This overprint is explained by a two-dimensional thermal model with a ramp-flat fault geometry and a slip rate of 1 to 1.5 cm/year during 5 Ma fault movement. The collapse basin above the detachment subsided in a thermal regime which was characterized by relaxing isotherms.  相似文献   

Is maturity index an efficient tool to assess the effects of the physical disturbance on the marine nematode assemblages?—A critical interpretation of disturbance-induced maturity successions in some study cases in Maldives     

SEMPRUCCI F.  COLANTONI P.  BALSAMO M. 《海洋学报(英文版)》2016,35(4):89-98

Maturity index(MI), based on nematode life strategies, has been proposed in 1990 to assess the possible variations of the terrestrial and freshwater nematode assemblages induced by anthropogenic activities. It was subsequently applied also to marine ecosystems and, even if comparatively not yet very popular, it offers a good method to assess the ecological quality in relation to a wide range of anthropogenic drivers. However, few data are available on its response to physical stress, a key factor especially in the coastal areas. In this study, marine nematode genera from two study cases carried out in Maldives are used to test both MI and life strategy traits(i.e., c-p classes) for detecting the effects of physical disturbance. The results confirm that nematodes are well adapted to physical stress showing a general high rate of recovery. C-p scaling and MI did not seem to be appropriate for revealing this disturbance type probably because there are no empirical evidences on the life strategy of several genera, and a possible differential response to various disturbance types may be hypothesized.  相似文献   

活动断裂带岩石的变形机制和摩擦性质—以圣·安德列斯断层为例     

金田龙  王勤 《江苏地质》2021,45(4):375-383

岩石的变形机制和力学性质对认识活动断裂带的孕震机制和发震过程都具有重要意义。圣·安德列斯（San Andreas）转换断层是太平洋板块与北美板块的构造边界,也是重要的地震活动带,总结了美国南加州地震中心对圣·安德列斯断层钻孔断层岩的研究进展。对断层泥的高速摩擦实验发现：动力弱化现象只在高速滑移时才发生,伴随着摩擦生热,岩石的摩擦系数显著降低。断层泥中富镁黏土矿物的富集可以显著降低断层的摩擦系数,促进蠕滑,黏土矿物的不均一分布可导致断裂带变形行为和地震分布的突变。与断层泥和碎裂岩不同,粉碎岩形成于快速传播地震的断裂端部,具高孔隙率和高渗透率,流体活动性强。此外,断层岩的有机质成熟度可用来追溯古地震造成的热异常。在川滇中国地震科学实验场开展科学钻探项目,研究断层岩样品的显微结构、物理性质和变形历史,以期为理解大陆汇聚与转换挤压过程中复杂的地震活动提供重要信息。  相似文献   

Relationship between rank and distribution of methylaromatic hydrocarbons for condensates of different origins     

P. Garrigues  J. Connan  E. Parlanti  J. Bellocq  M. Ewald 《Organic Geochemistry》1988,13(4-6)

Aromatic hydrocarbon fractions from thirty gas condensates have been analysed by capillary GC and high resolution Shpol'skii spectroscopy for the determination of the relative distribution in methylphenanthrene (MP), dimethylphenanthrene (DMP) and methylpyrene (MPy) series. The measured maturity indices, MPI, DMPI and MPyI which appeared previously suitable for rocks, coals and crude oils have been tested for the recognition of rank levels of condensates. MPI and DMPI exhibit a remarkedly similar evolution which allows the differentiation of the samples analysed in these works. Such studies extend the applicability of alkylaromatic hydrocarbon ratios to the characterization of maturity level of condensates which range from immature-marginally mature to overmature samples, partially biodegraded or not.  相似文献   

The control of maturity and kerogen type on quantitative analytical pyrolysis data     

Kjell ygard  Steve Larter  Joe Senftle 《Organic Geochemistry》1988,13(4-6)

Quantitative pyrolysis-gas chromatography has been performed on 96 kerogen samples isolated from 17 wells on the Norwegian Continental shelf. Petrographic and bulk geochemical measurements were also performed on the samples, and a combined data set of 117 variables for each sample was analysed using principal components analysis (PCA). This approach provides an objective and reproducible means of kerogen characterisation, which can be easily automated. In addition to objective kerogen characterisation and facile visualisation of facies and maturity related chemical trends, the method has the potential to allow objective prediction of key geochemical parameters such as maturity level from pyrogram data.  相似文献   

Effect of maturity on carbon isotope ratios of oils and condensates     

C.J. Clayton 《Organic Geochemistry》1991,17(6)

For modelling isotopic variations in oils it is convenient to differentiate the effects of oil generation ( 100–150°C) from the effects of oil to gas cracking ( 150–180°C). During generation, δ¹³C of kerogen may increase by up to 1% due to release of isotopically light oil and gas, although most kerogens show little or no chan δ¹³C of the generated oil increases by between 0 and 1% (av. 0.5%) due to mixing of isotopically heavy oil with an initial isotopically light unbound fraction, possibly of bacterial origin. The change occurs mostly over the first 20% of generation. During oil to gas cracking, kinetic isotope effects become important and the effect on δ¹³C of the remaining oil can be modelled as a Rayleigh process. δ¹³C increases by 1.5% by 50% cracking. Insufficient data are available to calibrate the effects at higher levels of cracking, and modelling these variations is hindered by a lack of understanding of the mechanism of pyrobitumen formation. However, increases greater than about 4% are unlikely to be observed. With increasing maturity, the low molecular weight fractions become isotopically heavy faster than the high molecular weight fractions. As a result, any separation of the low molecular weight fraction into a gas phase (“condensate formation”) will produce an isotopic difference between oil and condensate that depends on maturity. In the early stages of generation the condensate may be up to 1% lighter than the remaining oil. With increasing maturity, this difference at first decreases and then increases in the opposite sense. By half way through oil to gas cracking the condensate may be 1.5% heavier than the residual liquid. More subtle rearrangement reactions may result in small, but significant, changes to the shape of the isotope “type-curves” when different oil fractions are compared.  相似文献   

Quantitative chemical characterization of vitrinite concentrates using pyrolysis-gas chromatography. Rank variation of pyrolysis products     

J.T. Senftle  S.R. Larter  B.W. Bromley  J.H. Brown 《Organic Geochemistry》1986,9(6)

A series of hand-picked vitrinite samples from the Lower Kittanning Seam, Pennsylvania have been examined using quantitative pyrolysis-gas chromatography. These vitrinites ranged in rank from 0.59 to 1.71% reflectance, a rank range from high volatile C bituminous to low volatile bituminous. High molecular weight pyrolysis products included alkyl aromatic and phenolic compounds. Attempts have been made to correlate the pyrolysis product composition to rank parameters including vitrinite reflectance, volatile matter yield, carbon content, atomic H/C ratio and Rock-Eval determined T_max. Total yield of phenols was found to be strongly and inversely rank related. A clear relationship between C₈ alkyl-benzene yield and rank was not found for the sample set.  相似文献