Sulfides in petroleum     

J.D. Payzant  D.S. Montgomery  O.P. Strausz   《Organic Geochemistry》1986,9(6)

The homologous series of terpenoid sulfides previously reported to be present in Athabasca bitumen have been detected in a variety of petroleums from the Western Hemisphere. All 22 samples examined, ranging in age from Devonoan to Cretaceous, contained the terpenoid sulfides. A method is described for the isolation of sulfides from petroleums based on the selective oxidation of sulfides to more polar sulfoxides which are easily removed from the mixture and their subsequent reduction to sulfides. The sulfide content in the petroleum maltenes examined ranged from 0.3 to 16.1% w/w. In addition to the bicyclic and tetracyclic terpenoid sulfides a new series of tricyclic terpenoid sulfides has been identified, and the details of the isoprenoid side chain have been elucidated for all three homologous series. The distributions by carbon number of the bicyclic and tetracyclic homologous series of terpenoid sulfides show pronounced variations which are attributed to thermal maturity and degree of water washing of the petroleum, thus the ability to identify terpenoid sulfides should provide a useful tool for oil-oil and oil-source rock correlation studies. The bicyclic and tricyclic terpenoid sulfides have the same carbon framework as the carotenoids which suggest that these sulfides were accessory pigments in photosynthesis.  相似文献   

沥青质傅里叶变换红外光谱 (FT IR)分析及其在有机地球化学研究中的应用   总被引：5，自引：0，他引：5  

廖泽文  耿安松 《地球化学》2001,30(5):433-438

沥青质傅里叶变换红外光谱（FT－IR）分析可以反映出其分子结构上的特征，红外吸收因子Z[I(1380cm^-1)/I(720cm^-1）]能指示不同来源沥青质的母质类型；吸收因子Y[I(1600cm^-1)/I(1450cm^-1)]可以较好地讨论沥青质的成熟度演化状况；沥青质的红外研究认为，所有的沥青质都具有较好的再生烃潜力，其中Ⅲ型母质来源的沥青质具有较好的再生气潜力。而Ⅰ和Ⅱ型母质来源的沥青质具有高的再生油潜力。  相似文献   

藏北高原双湖地区中侏罗统海相油页岩生物标志化合物分布特征及其意义   总被引：4，自引：2，他引：4  

林金辉  伊海生等 《沉积学报》2001,19(2):287-292

重点报道了藏北双湖地区中侏罗统海相油页岩的生物标志化合物特征,首次在该层位油页岩中检出丰富的正烷烃、类异戊二烯烷烃、萜类化合物及甾类化合物。正烷烃图谱呈单峰形,nC₁₅、nC₁₆或nC₁₇为主峰碳,轻烃组份占有绝对优势,OEP值 0.93～ 1.0 1,无明显的奇偶碳数优势分布;Pr/Ph值为 0.77～ 1.5 9,在剖面序列中呈波动分布,显示弱植烷优势或姥鲛烷优势;藿烷以C₃₀ 占优势,萜烷相对丰度五环三萜烷 >三环萜烷 >四环萜烷;规则甾烷∑ (C₂₇+C₂₈) >∑C₂₉,∑C₂₇/∑C₂₉值为 0.79～ 1.2 0,在剖面序列中下部C₂₇甾烷略占优势,上部C₂₉甾烷略占优势,重排甾烷C₂₇/规则甾烷C₂₇值为 0.5 1～ 3.6 3,在剖面序列中具有显著的波动性,同时检出了少量孕甾烷和 4-甲基甾烷。有机质母质构成中,既有丰富的藻类等低等水生生物,可能还有一定比例陆生高等植物输入混合的特点。油页岩处于成熟阶段,整个油页岩剖面序列具有一致的热演化程度。剖面中部油页岩具有极高的原始生产力,氧化-还原条件也是控制油页岩TOC和沥青“A”含量在剖面垂向变化的重要因素.  相似文献   

从有机包体特征探讨油气运移时间—以东海盆地西湖坳陷花港组储层为例     

叶素娟  姜亮 《矿物岩石》2001,21(2):38-41

通过对西湖坳陷花港组砂岩成岩作用过程中捕获的有机包裹体研究，表明不同成岩阶段形成的自生矿物中有机包裹体的类型，产状和组分特征各不相同。本研究采用激光拉曼光谱技术测定包裹体有机组分以及α石英ESR测年技术，通过包裹体有机组分的成熟度特征，结合区域埋藏史和烃源岩有机质成熟史，确定了砂岩成岩史与有机质成熟史，并探讨了油气运移时间的关系。本区存在两期油气运移；一期与砂岩晚成岩A阶段的石英加大发育期一致，年龄约为24Ma以后，另一期则与N1末期的龙井运动引起的挤压所造成的裂隙有关。  相似文献   

塔里木盆地库鲁克塔格奥陶系牙形石色变指标与有机质成熟度的关系     

李金龙  王璞珺  孙少波  贾军涛  张艳 《新疆地质》2006,24(4):373-376,I0013

应用牙形石色变指标(CAI)对塔里木盆地孔雀河斜坡东北段南雅尔当山剖面奥陶系有机质成熟度进行了研究,得出的结果是南雅尔当山却尔却克组产出的牙形石色变指标CAI值为2~2.5,有机质处于成熟阶段.综合研究认为,本区奥陶系烃源岩在中奥陶世逐渐进入生烃门限并快速成熟;在奥陶纪末达到经历的最大古地温,顶部为80℃,底部为180℃,之后遭受抬升剥蚀,区域剥蚀量在2 300 m左右.本区奥陶系烃源岩存在3种生烃类型:第Ⅰ种为南雅尔当山型,为非有效烃源岩;第Ⅱ种为群克1井部分生烃型,奥陶纪末抬升剥蚀后埋深在2 500 m以上的烃源岩(Ⅱ-1型)停止生烃,埋深在2 500 m以下的烃源岩(Ⅱ-2型)持续生烃;第Ⅲ种为二次生烃型,当中新生代的快速沉积使Ⅱ-1型烃源岩顶部埋深达到3 200 m时,相同层位的烃源岩达到经历的最大古地温,开始二次生烃,生烃潜力最大.  相似文献   

原油生成温度计算的理论与实践     

唐友军  王铁冠 《矿物岩石地球化学通报》2007,26(3):218-220

定量求取原油的成熟度是目前尚未有效解决的问题。Mango发现4个C7的异构化合物相对组成有显著的不变性,提出了稳态催化轻烃成因模式。据该模式的2,4-/2,3-二甲基戊烷比值是一项纯温度参数,Bement和Mango等建立了该轻烃温度参数与埋深温度的函数关系式用于原油生成温度计算,为定量研究原油成熟度提供了新思路。本文以塔中地区为例,计算了原油的Mango参数,得到原油K1平均为1.06,在Mango给出的相对稳定范围。应用原油生成温度公式计算的原油生成温度为120~129℃,折算镜质组反射率R。=0.88%~0.90%,与新藿烷成熟度参数反映的成熟度特征相一致,说明该方法是可靠的。  相似文献   

Hydrocarbon Generating Potential of Mineral—Bituminous Matrix in Source Rocks     

陈建平  黄第藩 《中国地球化学学报》1998,17(3):234-240

Mineral-bituminous matrix(MBM) makes up a major part of source rocks,but its potential in hydrocarbon generation is uncertain,Mineral and organic (Maceral and kerogen) compositions,organic maturity and fluorescence of MBM are studied based on source rock samples from eastern Jiuquan(Jiudong)Basin.The results show that MBM is dominated by inorganic minerals and among the small percentage of organic components those of secondary origins are predominant over the primary species.This strongly indicates that the significance of MBM in hydrocarbon generation is limited.  相似文献   

Distribution Patterns of Pentacyclic TriterpenoidHydrocarbons in Low-Mature Source Rocksfrom Eastern China     

HOU Dujie  ZHANG Linye  WANG Tieguan Research Centre for Organic Geochemistry  Jianghan Petroleum Institute  Jingzhou  Hubei Applied Geochemistry Section  Dept. ofGeosciences  China University of Petroleum  Changping  Beijing Geochemistry Research Section  Shengli Petroleum Geological Sciences Institute  Shengli Petroleum Administration Bureau  Dongying  Shandong 《《地质学报》英文版》1998,72(4):399-408

Four typical distribution patterns of pentacyclic triterpenoid hydrocarbons (types A-D) are distinguished in the low-mature source rocks from eastern China. Type A has a relatively high content of pentacyclic triterpenes. It exists in immature sediments and the distribution and abundance of triterpenes vary with the maturity of the sediments. An unknown C30 triterpene (UCT2) has also been detected in very shallow sediments. This compound is very unstable and disappears rapidly with the increase of depth. Type B is characterized by a relatively high amount of 17α(H), 21β(H)-30-homohopane. This kind of distribution pattern is common in coals and terrestrial sediments of low maturity. Type C has a relatively high content of diahopane and neohopane series. The analysis shows that this distribution pattern may have an indirect relationship with the input of higher plants despite its microbial source. There are C30-unconfirmed triterpane (UCT2) and a relatively high content of C35 hopane in type D. The dist  相似文献   

Digital quantification of the miospore coloration to assess the thermal maturity: Novel RGB-based measuring technique     

《Marine and Petroleum Geology》2015

The post depositional thermal maturity and its related chemical changes induce the sporomorphs color alteration, which is a common useful tool in the optical microscopy of the organic matters (OM) and their pre-geochemical studies. The present contribution uses the modern available opportunity of digital technology to achieve a quantifying system technique, which includes color measurements and their possible graphic presentation. The normal digital images of sporomorphs from several ages and geological settings are used to obtain color measurements in the form of digital Red, Green and Blue triple color system (RGB). These measurements were accomplished using some software programs such as Photoshop™^© or ImageJ with employing average microscope setup. The triple RGB color readings are plotted on a ternary diagram, which is divided into three fields. These fields express the maturity levels. The presented new RGB-based quantifying technique is economic and provides a simple examination for maturity, which is linked to the hydrocarbon generation. This can partially replace or walk side by side with the vitrinite reflectance microscopy.  相似文献   

基于傅里叶变换质谱的烃源岩成熟度评价方法及地质意义     

韩双彪  谢林丰  唐致远  李剑  王成善  Brian HORSFIELD 《地质学报》2023,97(5):1717-1721

<正>伴随非常规油气资源的勘探开发,油气资源开采的广度和深度进一步扩大,一定程度上缓解了我国油气供需矛盾、保障了我国能源安全,同时有力推动了能源结构战略转型。但同时也对能源地质研究工作提出了新的挑战。有机质成熟度是油气评价的重要参数之一,不同成熟阶段的有机质会对应产出不同成因、不同性质、不同质量的油气,如何准确评价沉积有机质成熟度是当前油气资源勘探开发工作的关键问题之一。前人在科研实践工作中从光学、化学、谱学等角度提出了适用条件各异的成熟度评价方法,在部分地质环境中获得了良好的应用效果,但已有的成熟度指标多受测定方法原理的制约导致其适用性不同程度受限(肖贤明等,2020),制约了油气资源的高质量勘探开发。  相似文献