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应用偏光显微镜和电子探针技术研究安徽铜官山矽卡岩型铜铁矿床伴生元素金银铂钯铀的赋存状态 总被引：4，自引：2，他引：2
安徽铜官山矽卡岩型铜铁矿床富含多种稀有贵金属金银铂钯和铀,本文应用偏光显微镜与电子探针技术对该地区贵金属和铀矿物的含量、矿物种类、赋存状态及其嵌布特征进行研究,并利用电子探针Th-U-Pb定年技术推测铀矿物的形成时期。研究表明:金主要以银金矿独立矿物存在,成色均值约为638,与铜的硫化物密切依存,金矿物形成于成矿中晚期的中低温环境;银的独立矿物有银金矿、碲银矿、辉银矿,还与铜铋铅等以类质同象形式结合形成不同种类的矿物组合,且含量在74.15%~0.12%不等;铂钯矿物以含铂碲钯矿为主;铀以晶质铀矿独立矿物存在且与磁铁矿密切依存,晶质铀矿的形成年龄约为124±14 Ma,晚于岩体形成年龄(约139 Ma),早于黄铜矿和含金银铂钯等矿物,而与磁铁矿同在燕山中晚期形成。结合镜下观察,认为铜官山矽卡岩型铜铁矿床主要矿物生成顺序依次是:石榴子石-磁铁矿、晶质铀矿,含金银铂钯矿物,黄铜矿。本研究为贵金属选矿提供了线索,同时利用晶质铀矿的年龄数据界定了伴生贵金属的形成年代。 相似文献
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S. J. Mills W. D. Birch R. Maas D. Phillips I. R. Plimer 《Australian Journal of Earth Sciences》2013,60(3):281-299
The Devonian Lake Boga Granite in northern Victoria, while almost entirely under thin Murray Basin cover, is one of the largest plutons in the western Lachlan Fold Belt. Its only exposure is a quarry penetrating the Cenozoic sediments. In the quarry, prominent pod pegmatites and miarolitic cavities suggest a high level of emplacement. The granite, a non-magnetic, fractionated S-type, contains a large range of accessory minerals, including primary uranium- and REE-bearing phosphates and oxides, and primary copper sulfides. Monazite-series minerals show an exceptionally wide range of compositions, from normal monazite-(Ce) through cheralite (Ca – Th-rich) to rare huttonitic monazite (Th-rich) and brabantite; U contents in monazite also vary widely (0 – 7.9 wt%). Primary low-Ca uraninites are well preserved and are unusual in having low Th/U and LREE. Late-stage cavity fluorapatite crystals up to several centimetres across show intricate elemental zoning patterns with extreme U gradients (<10 – 6900 ppm) in some crystals. New 40Ar – 39Ar ages for magmatic biotite, muscovite and K-rich feldspar average 365 ± 3 Ma, which approximates the emplacement age of the granite. This is supported by a 377 ± 12 Ma U – Th – Pb (CHIME) age for primary uraninite. New whole-rock geochemical data support earlier observations: the granite is strongly fractionated (SiO2 70.7 – 76.0 wt%; 4.2 – 0.6 wt% FeOt) and peraluminous (ASI = 1.23 – 1.45), and has slightly elevated Na2O and P2O5 (0.30 wt%) contents compared with other fractionated S-type granites from the Lachlan Fold Belt. Trace-element abundances are typical of fractionated granites, although U and Cu concentrations vary strongly and reach >60 and ≈1400 ppm, respectively. REE patterns also vary strongly, from LREE-enriched with moderate Eu depletion, to flat with strong Eu depletion. The flattest of the REE patterns, in samples with FeOtotal < 1%, are characterised by M-type tetrad effects. These and other samples also show low (subcrustal average) and variable Zr/Hf (35 – 16) and Nb/Ta (8 – 4) ratios; these and other unusual elemental fractionations are related to changes in elemental partitioning during the late magmatic stage, when felsic peraluminous magma and high-temperature magmatic fluid coexisted. 相似文献
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本文对纳米比亚欢乐谷地区与铀成矿关系密切的白岗岩进行了系统的主量元素、微量元素及Sr-Nd同位素研究。结果表明,矿化白岗岩具有较高的SiO_2(68.81%~76.02%,平均值73.11%),富钾,A/CNK为0.96~1.07,平均值1.01,为亚碱性系列的准铝质-弱过铝质岩石。岩石富集轻稀土[LREE/HREE=2.53~7.71;(La/Yb)_N=2.14~10.40],Eu亏损中等,高Rb/Sr比值(2.03~5.50,平均值4.36),岩石同时富集Rb、Th、U、K及Pb等大离子亲石元素,亏损Ba、Nb、Ta及Sr等元素。岩石的初始~(87)Sr/~(86)Sr比值为0.73035~0.79345,ε_(Nd)(t)值为-13.5~-17.4,晶质铀矿的ε_(Nd)(t)值为-14.8~-16.5,两阶段Nd模式年龄为2.43~2.56Ga。元素和Sr-Nd同位素地球化学特征表明矿化白岗岩是在碰撞后的伸展构造环境中形成的,主成矿期的成矿物质来源于富铀的前达马拉基底;热液叠加改造期的铀可能来源于原生铀矿物本身。 相似文献
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目前我国发现的天然铀氧化物为UO_(2.03)-UO_(2.85)的连续演化系列,均属UO_2(UO_(1.75)-UO_(2.30))的萤石型立方结构,即铀氧化物氧铀比的变化未产生相应的结构相的变化,但其物理特性却随着化学成分的变化(特别是矿物中氧铀比值)而变化,导致化学成分与结构相之间的矛盾。笔者认为天然铀氧化物中的六价铀(U~(6+))并不加入矿物晶格,而是以无定形铀酰离子团(UO_2)~(2+)或以三氧化铀的水化物(UO_3·nH_2O)形式存在于UO_2晶格的缺陷中。天然铀氧化物中这些非晶质的(UO_2)~(2+)或(UO_3·nH_2O)的混入量与生成的地质环境,特别是沉淀时体系的氧逸度、硫逸度有重要关系,它不只决定了形成铀氧化物的性质,同时也决定了矿物中氧铀比的变化。沥青铀矿是UO_2结晶体与呈凝胶的(UO_2)~(2+)基团及(UO_3·nH_2O)的混合物,因此,矿物中氧铀比的变化并不引起矿物相的转换。 相似文献
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赣南6722铀矿床钛铀矿—晶质铀矿—铀石—沥青铀矿显微共生组合的厘定及成因意义 总被引：1，自引：0，他引：1
通过235U诱发裂变径迹及电子探针测试综合研究,在6722铀矿床的含矿隐爆角砾岩胶结物中首次发现钛铀矿—晶质铀矿—铀石—沥青铀矿显微共生组合。这样一种在1 cm2(光薄片)范围内分布,而且不存在任何脉状相互穿插现象的钛铀矿—晶质铀矿—铀石—沥青铀矿显微共生组合表明其形成于同一成矿物理化学体系中。根据UO2—TiO 2—H2O体系稳定场,确定6722铀矿床中钛铀矿—晶质铀矿—铀石—沥青铀矿显微共生组合形成温度范围为250~350℃,属中—高温热液成因。 相似文献
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A method for U–Pb isotopic dating using secondary ion mass spectrometer (SIMS) was developed for uraninite. Correlation between 251(UO)+/235U+ and 206Pb+/235U+ obtained by a sensitive high‐resolution ion microprobe (SHRIMP) was adopted for a calibration from secondary ion ratios (Pb+/U+) to the atomic abundance ratios (Pb/U). In this study, a uraninite sample (206Pb/238U = 0.1647) collected from Faraday mine, Bancroft, Canada, is used as a reference material for the U–Pb calibration. The established method was applied to three uraninite samples collected from the Chardon, Ecarpière, and Mistamisk mines. The calibrated 206Pb*/238U ratios of the three uraninites show correlation with Pb/U elemental ratios obtained using an electron probe microanalyzer (EPMA) (correlation coefficients: 0.98, 0.99, and 0.97, respectively), which indicates the reliability of the SHRIMP calibration method used in this study. The analysis of Ecarpière uraninite provides concordant U–Pb data, and a weighted average of the 206Pb*/238U age is 287 Ma ±8 Ma (95 % conf.) which is consistent with the previous chronological results by SIMS. Mistamisk uraninite provides discordant U–Pb data with the upper and lower intercept ages of 1 729 and 421 Ma, which correspond to uraninite formation in association with the Hudsonian orogeny and the remobilization of uranium as pitchblende, respectively. The U–Pb age of Chardon uraninite (315 Ma) is consistent with the igneous activity of Mortagne granite, but is older than the previously reported age (264 Ma). Marcasite in the Chardon uraninite altered to goethite under the oxidizing condition, which indicates that U–Pb system in the uraninite crystallized at 315 Ma was disturbed under the oxidizing condition. The established calibration method using Faraday uraninite is useful for U–Pb isotopic dating on the scale of a few micrometers to tens of micrometers, which make it possible to obtain the accurate age of uraninite. 相似文献
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陕西华阳川铀-多金属矿床晶质铀矿电子探针U-Th-Pb化学定年及其地质意义 总被引：1，自引：0，他引：1
华阳川铀-多金属矿床位于小秦岭陆内造山带内,以铀铌铅为主,并伴生稀有、稀土元素矿化,含矿脉岩主要有伟晶岩和碳酸岩。文章利用电子探针U-Th-Pb化学定年技术对华阳川铀-多金属矿床中晶质铀矿开展了定年工作,并获得了2组U-Th-Pb年龄。第一组晶质铀矿加权平均年龄为(221.9±5.1)Ma(MSWD=0.36,n=18),该区印支期老牛山岩体及邻近的黄龙铺钼矿床、黄水庵钼矿床年龄均集中在220 Ma左右,说明晚三叠世是东秦岭地区一个重要的成岩成矿时代,华阳川铀-多金属矿床在220 Ma左右也发育一期铀-铌成矿作用。第二组晶质铀矿加权平均年龄为(137.1±2.0)Ma (MSWD=1.06,n=47),指示了华阳川铀-多金属矿床存在白垩纪的一期铀-铌活化-沉淀事件。测定的2组晶质铀矿化学年龄可能分别记录了该区自晚三叠世开始的后碰撞伸展环境和早白垩世的造山后伸展环境。 相似文献
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U6+-phases are common alteration products, under oxidizing conditions, of uraninite and the UO2 in spent nuclear fuel. These U6+-phases are subjected to a radiation field caused by the α-decay of U, or in the case of spent nuclear fuel, incorporated actinides, such as 239Pu and 237Np. In order to evaluate the effects of α-decay events on the stability of the U6+-phases, we report, for the first time, the results of ion beam irradiations (1.0 MeV Kr2+) of U6+-phases. The heavy-particle irradiations are used to simulate the ballistic interactions of the recoil-nucleus of an α-decay event with the surrounding structure. The Kr2+-irradiation decomposed the U6+-phases to UO2 nanocrystals at doses as low as 0.006 displacements per atom (dpa). U6+-phases accumulate substantial radiation doses (∼1.0 displacement per atom) within 100,000 yr if the concentration of incorporated 239Pu is as high as 1 wt.%. Similar nanocrystals of UO2 were observed in samples from the natural fission reactors at Oklo, Gabon. Multiple cycles of radiation-induced decomposition to UO2 followed by alteration to U6+-phases provide a mechanism for the remobilization of incorporated radionuclides. 相似文献
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竹山下铀矿床成矿过程探讨 总被引：3，自引：0，他引：3
对竹山下铀矿床中蚀变糜棱岩的矿物成分进行了研究,发现了一种新型Ｕ－Ｗ共生的蚀变糜棱岩型铀矿床,铀矿物主要是晶质铀矿;指出相应的成矿作用为燕山早期（１６５×１０６ａ±）气热高温热液铀成矿作用。 相似文献