Cenozoic “radiobarite” occurrences in the Ohře (Eger) Rift, Bohemian Massif: Mineralogical and geochemical revision     

J. Ulrych  J. Adamovic   K. k  J. Frna  Z. &#x;anda  A. Langrov  R. Skla  M. Chvtal 《Chemie der Erde / Geochemistry》2007,67(4):301-312

Barite occurrences related to the Cenozoic (Late Alpine) low-temperature hydrothermal activity are present in the continental Ohře (Eger) Rift area. A specific, Ra-bearing type of barite has been known under the name “radiobarite” from this area since 1904. Revision of 12 localities revealed the presence of alleged radiobarite only in the Teplice (Lahošť–Jen&#xed;kov) and Karlovy Vary areas. Barite from other localities is radium-poor. Barite crystals showing concentric oscillation colour zoning totally prevail. Isomorphous substitution of Sr (X×10⁻¹ to X×wt%), Ca (X×10⁻² wt%) and Fe (X×10⁻¹ wt%) for Ba was proved. Average SrO contents of 0.4 wt% are markedly exceeded in some samples from Lahošť–Jen&#xed;kov (max. 3.2 wt%) and Karlovy Vary (max. 4.9 wt%). Besides inclusions of stoichiometric iron disulphide, the same samples also contain iron disulphides with unusual high contents of Co (max. 12.2 wt%) and Ni (max. to 8.4 wt%). Specific activity of ²³⁸U in the studied barites is very low while that of ²²⁶Ra reaches 8 Bq/g in several samples. Therefore, ²²⁶Ra is not in equilibrium with its parent uranium. These “radiobarites” or their parts must be therefore relatively young, not older than 10–15 ka. Very low uranium contents (<0.4 ppm) were also confirmed by neutron activation analyses of barite samples.

Unit-cell dimensions refined from X-ray powder diffraction data do not show any systematic variation with the measured chemical composition. Their values agree with the data given in the literature. Reflection half-widths, however, seem to correlate with chemistry. Peaks are wider in samples from Lahošť–Jen&#xed;kov and Karlovy Vary.

Sulphur and oxygen stable isotope compositions of the Cenozoic barite mineralization of Teplice area are very uniform (δ³⁴S values between 3.9‰ and 7.1‰ CDT, and δ¹⁸O values between 6.1‰ and 7.7‰ SMOW), while the barites of Děc˘&#xed;n area show more variable sulphur sources. Sulphate derived from sediments of the Tertiary Most Basin seems to dominate for the Teplice area, while Cretaceous sediments are a more probable sulphur source in the Děc˘&#xed;n area. Calculation of oxygen isotope composition of hydrothermal fluids based on fluid inclusion homogenization temperatures and barite δ¹⁸O data shows δ¹⁸O_fluid values in the range of meteoric waters or δ¹⁸O – shifted deep circulating meteoric or basinal waters.  相似文献   

Lacustrine transgressions in the late Cenozoic Ussuri-Khanka depression (Primor’e)     

A. M. Korotkii  T. A. Grebennikova  L. P. Karaulova  N. I. Belyanina 《Russian Journal of Pacific Geology》2007,1(4):352-365

In the Ussuri-Khanka depression of Primorye, the Quaternary alluvial-lacustrine and lacustrine sedimentogenesis progressed under conditions of transgressive accumulation in response to the depression tectonic subsidence and recurrent climatic fluctuations. The alluvial dams and irregular accumulation are proved to have been the leading factors of lakes’ formation within the depression. As is shown, fluctuations of the water level in limnic reservoirs depended on the climatic changes. New data considered in this work confirm the lacustrine genesis of a greater part of the Middle Pleistocene-Holocene sedimentary succession in the Khanka depression. Two transgressive phases, when the water level in the lakes rose by 1.5–2.0 m above the present one, are established for the Subboreal. The general conclusion is that the mesorhythmic structure of the sedimentary succession in the Ussuri-Khanka depression reflects the influence of climatic fluctuations in the Late Cenozoic.  相似文献   

Testing the accuracy of quartz OSL dating using a known-age Eemian site on the river Sula, northern Russia   总被引：1，自引：0，他引：1  

A.S. Murray  J.I. Svendsen  J. Mangerud  V.I. Astakhov 《Quaternary Geochronology》2007,2(1-4):102-109

Quartz optically stimulated luminescence (OSL) forms the basis for the chronology of Weichselian ice advances in Arctic Eurasia developed over the last few years. There is almost no age control on this chronology before 40 ka, except for some marine sediments correlated with marine isotope stage (MIS) 5e on the basis of their palaeofauna. Results from more southern latitudes have shown that dose estimates based on quartz OSL and the single aliquot regenerative (SAR) dose procedure may underestimate the age of MIS 5e deposits. Here we use the same method to date well-described marine sediments, thought to have been deposited during the very beginning of the Eemian interglacial at 130 ka, and exposed in two sections on the river Sula in northern Russia. Various quality-control checks are used to show that the OSL behaviour is satisfactory; the mean of 16 ages is 112±2 ka (σ=9 ka). This represents an underestimate of 14% compared to the expected age, a discrepancy similar to that reported elsewhere. In contrast to SAR, the single aliquot regeneration and added (SARA) dose procedure corrects for any change in sensitivity during the first OSL measurement. The SARA results are shown to be 10% older than those from SAR, confirming the geological age estimate and suggesting that SAR ages may underestimate older ages (larger doses), despite their good performance in the younger age range.  相似文献   

La descente et la montée étendues: the spatially <Emphasis Type="Bold">d</Emphasis>-anisotropic and the spatio-temporal case     

E. Porcu  P. Gregori  J. Mateu 《Stochastic Environmental Research and Risk Assessment (SERRA)》2007,21(6):683-693

There is a great demand for statistical modeling of phenomena that evolve in both space and time, and thus, there is a growing literature on correlation function models for spatio-temporal processes. In particular, various properties of these correlation functions have been studied only for the merely spatial or temporal case, fact that constitutes a strong motivation for our work. The goal of this paper is to inspect some properties, obtained with respect to partial differentiation and integration, of stationary spatio-temporal correlation functions for which anisotropy is obtained through isotropy between components as in Fernández-Casal et al. (Stat Comput 13(2):127–136, e>2003e>). We show that through partial differentiation and integration it is possible to obtain permissible spatio-temporal correlation functions in the space–time domain. Other new results regard specific classes of space–time correlations introduced in recent literature. A curious result arises by differentiating scale mixtures of Euclid’s hat. Work partially funded by grant MTM2004-06231 from the Spanish Ministery of Science and Education.  相似文献   

Trimble GPS 5700在航测高程控制中的应用     

邹志平  张小勇  李鸿 《地理空间信息》2007,5(5):30-32

简要介绍了Trimble GPS 5700接收机的功能特点及新的RTK增强技术(eRTK),并结合贵阳市1∶2000航空摄影测量工程,介绍了运用Trimble GPS 5700接收机进行的GPS水准拟合高程试验和高程拟合精度,简单阐述了影响GPS高程测量精度的因素及GPS水准拟合高程代替几何水准应注意的几个问题。  相似文献   

Finite-difference Euler Deconvolution Algorithm Applied to the Interpretation of Magnetic Data from Northern Bulgaria     

Daniela?GerovskaEmail author  Petar?Stavrev  Marcos J.?Araúzo-Bravo 《Pure and Applied Geophysics》2005,162(3):591-608

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Contribution of stable isotopes to the understanding of the unsaturated zone of a carbonate aquifer (Nerja Cave, southern Spain)     

Francisco Carrasco  Bartolom Andreo  Cristina Lin  Jacques Mudry 《Comptes Rendus Geoscience》2006,338(16):1203-1212

We analysed the stable isotopes (¹⁸O and ²H) of rainwater and drip water within a cave (Nerja Cave) located in the unsaturated zone of a carbonate aquifer. Rainfall is more abundant and presents lower isotopic content in winter, while the volume of drip water is greater and its isotopic content is lower in summer. The flow analysis of ¹⁸O through the unsaturated zone confirms the seasonal lag between rainfall and the appearance of drip water in the cave and reveals that the unsaturated zone of the aquifer, in the sector of the cave, behaves like an inertial system with a strong capability to modulate the input signal. To cite this article: F. Carrasco et al., C. R. Geoscience 338 (2006).  相似文献   

THE PALEOCURRENT PATTERN OF EARLY TERTIARY REDBEDS IN THE HOH XIL BASIN,NORTHERN TIBET PLATEAU:IMPLICATIONS FOR AN EARLY UPLIFT AND UNROOFING     

Yi Haisheng  Wang Chengshan  Lin Jinhui  Zhu Lidong  Liu Dengzhong  Huang JijunWT  ”BX 《地学前缘》2000,(Z1)

THE PALEOCURRENT PATTERN OF EARLY TERTIARY REDBEDS IN THE HOH XIL BASIN,NORTHERN TIBET PLATEAU:IMPLICATIONS FOR AN EARLY UPLIFT AND UNROOFING  相似文献   

应用与透射电子显微术相结合的电子能量损失谱(EELS)测定矿物中Ce和Fe的氧化态     

徐惠芳 《高校地质学报》2000,6(2):137-144

在透射电子显微镜(TEM)中,与样品发生弹性散射的高能电子可被用于成像和产生选区电子衍射(SAED),它们能提供关于样品结构的重要信息。高分辨透射电子显微镜(HRTEM )由于它具有高的空间分辨率,因而可以在原子的尺度上来研究样品的结构和微结构(或织构 )。此外,TEM中入射的高能电子还经历了与样品的非弹性相互作用,它可以提供关于样品的 化学和电子结构的进一步信息。据此,以TEM中的X射线能量色散谱学(EDS)和电子能量损失 谱学(EELS)为基础,产生了分析电子显微术(AEM)。其中EELS能够提供有关样品的诸如定量 化学分析(包括除氢以外的所有元素)、氧化态、配位、结晶度以及化学键合类型等有价值的 信息。HRTEM与EELS结合的研究则能从纳米尺度上提供关于矿物反应的微结构和微化学信息 。应用以M4和M5边的电子能量 损失近边结构(ELNES)为基础的EELS,研究了被建议作为放射性废料寄主相的烧绿石中Ce的 氧化态。与Ce3＋相比,Ce4＋的M4和M5边具有较高的能量损失。M4与M5边之间以及它们之后的弱峰之间的 强度比可用于Ce3＋与Ce4＋的定量分析。在内蒙所产烧绿石矿物的颗粒,其未蚀变区的EELS数据指示出有Ce3＋及其他稀士元素。然而由相邻蚀变区得出的EELS光谱则显示为Ce4＋、Ba及其他稀土元素。这表明在烧绿石蚀变期间,Ce的氧化导致了稀土元素、U及α衰变产物Pb的损失。基于Fe-L3边之ELNES的特征,EELS也能提供关于含Fe的闪石、辉石及其他硅酸盐矿物中Fe的氧化态的定量信息。应用这一方法直接测定了相互连生的一对闪石和辉石中Fe氧化态的定量值。其中闪石的Fe3＋/∑Fe原子数之比=0.65,而按间接计算方法得出的该闪石之相应的比值为0.5,两 者间有明显的差异。  相似文献   

Usable Values of Nickel Ore and Nickel Concentrate Certified Reference Materials          下载免费PDF全文

Zhizhong Cheng  Mei Liu  Hongku Huang  Tiexin Gu  Weidong Yan  Hongli Wen 《Geostandards and Geoanalytical Research》2015,39(2):221-232

The preparation and characterisation of three nickel ores and two nickel concentrate certified reference materials are described in this paper. The samples of nickel ore and nickel concentrate were collected from the Hongqiling nickel deposit in Jilin province. The raw materials were crushed and passed through a 2.0‐mm sieve. The rough samples were then ground for 48 hr in a high‐alumina ball mill to a final size of < 0.074 mm. Homogeneity of the samples was tested by X‐ray fluorescence spectrometry (WD‐XRF) and inductively coupled plasma‐atomic emission spectrometry (ICP‐AES). The relative standard deviations (RSD) of results on mass fraction measurements by WD‐XRF were < 1.0% m/m for eighteen components. F‐tests showed that all five samples were homogeneous. Nineteen laboratories contributed with measurement results (2127 in total) for the certification of mass fractions for twenty‐three elements and compounds. Twenty‐three components in the nickel ores and twenty components in the nickel concentrates were characterised as certified values, while the Ni mass fractions ranges from 0.1 to 9.02% m/m in these certified reference materials. These five samples were approved as national certified reference materials by the National Organisation of Reference Materials of China in 2012.  相似文献