北祁连拉硐超基性岩体铬尖晶石特征研究及找矿意义          下载免费PDF全文

徐均强  徐伟祥  杜韦  崔灿 《山东国土资源》2014,30(4):49-54

拉硐超基性岩体位于青海省祁连县城东北约15km处,面积约7.6km2,岩性主要由蛇纹石化橄榄岩、蛇纹石化辉榄岩、蛇纹岩及纯橄岩组成,共发现157个铬铁矿小矿体,铬铁矿体成群出现,依据野外铬铁矿体分布范围,自西向东划分为10个矿带,通过对其中铬尖晶石取样分析研究,并与区内其他含矿岩体中铬尖晶石样品化验分析结果对比,确定该类岩体不同岩性组合带的找矿方向。  相似文献   

探讨变质作用对铬铁矿床的改造——古老岩层中铬铁矿找矿方向研究          下载免费PDF全文

陈世忠  朱筱婷 《中国地质》2013,40(6):1912-1924

提要：岗上超镁铁质岩主要由纯橄岩和石榴橄榄岩组成,主要组成矿物橄榄石、铬铁矿、石榴子石、单斜辉石和斜方辉石等。铬铁矿的Cr^#[Cr/(Cr+Mg)×100]从51到89变化,铬铁矿矿物表现为4期次演化的特点,反映了从岩浆期向榴辉岩相、角闪岩相和绿片岩相演化特征。随着超镁铁质岩的演化,铬铁矿中Cr^#不断增大,而铬铁矿Mg^#〔Mg×100/(Mg+Fe²⁺)〕不断减少,氧逸度不断增加。在绿片岩相－绿片角闪岩相退变质过程中,铬铁矿中Cr、Mg和Al减少,Fe相对增加,产生富Cr尖晶石变质作用样式。晚期剪切变形等次生变化有利于富铬铬铁矿矿物的形成和铬铁矿的富集。同时,绿片岩相变质作用降低了铬铁矿与其他硅酸盐矿物的结合强度,降低了开采强度和成本,使原本不易于开采的铬铁矿体变得可以开采。这些意味着该地区铬铁矿矿体展布要结合区域构造特征和变质作用进行研究、尤其是结合中晚期脆韧性构造进行分析。  相似文献   

西藏雅鲁藏布江缝合带普兰地幔橄榄岩铬尖晶石成因研究     

赵斌  龚小晗  黄启帅  史仁灯 《岩石学报》2020,36(2):455-468

普兰蛇绿岩位于雅鲁藏布江缝合带西段,其中地幔橄榄岩由方辉橄榄岩、含单斜辉石方辉橄榄岩以及少量二辉橄榄岩及纯橄岩组成。尖晶石是地幔橄榄岩中常见的副矿物,可以作为重要的岩石学成因指示剂。在野外地质调查基础上,通过岩相观察、电子探针、尖晶石成分面分析、电子背反射衍射分析,可将普兰地幔橄榄岩铬尖晶石分为三类:第一类铬尖晶石呈自形,粒径较小(<100μm),或包裹于斜方辉石中,或杂乱分布于橄榄石和辉石之间,具有高Cr^#(>0.6)、低Mg^#(0.43~0.57)的特征,为部分熔融+玻安质熔体交代成因;第二类铬尖晶石呈半自形-他形,粒径较大(>100μm),常含有橄榄石、辉石包裹体,具有中Cr^#(0.17~0.42)、高Mg^#(0.63~0.77)的特点,主要受部分熔融作用影响;第三类铬尖晶石呈他形蠕虫状与辉石交生在一起构成后成合晶结构,粒径变化较大,具有低Cr#(0.17~0.28)、高Mg^#(0.67~0.77)的特点。EBSD分析结果显示尖晶石、辉石的结晶学优选方位(CPO)较为相似,表明为同一矿物分解而来,单斜辉石与大陆岩石圈地幔捕掳体中石榴子石的稀土元素对比表明构成后成合晶结构的辉石和铬尖晶石为具有大陆岩石圈地幔属性的高压石榴子石退变分解而成。综合分析表明:普兰蛇绿岩的地幔橄榄岩体在从石榴子石相深度上升过程中发生了石榴子石退变、岩石部分熔融及熔体渗透作用,岩体经历了威尔逊旋回初期的大陆裂谷阶段,主体经历了中-低程度的部分熔融,类似大洋中脊环境,局部受到了富硅、富镁玻安质熔体的影响。  相似文献   

Petrological investigation of the Ganyu peridotite in the Sulu ultrahigh-pressure terrane, eastern China   总被引：1，自引：0，他引：1  

Shizhong Chen  Jingsui Yang 《Tectonophysics》2009,475(2):383-203

The ultramafic body sampled in the Chinese Continental Scientific Drilling (CCSD) Hole PP3 is located in the eastern part of the Dabie-Sulu UHP metamorphic belt near Donghai County. It is about 480 m thick, and consists chiefly of garnet peridotite, dunite and serpentinite. The principal minerals include olivine, chromium spinel, diopside, enstatite, garnet with minor secondary augite, phlogopite and amphibole. Both the olivine and orthopyroxene are highly magnesian, and the garnet is pyropic with 5.4-6.4% CaO and 0.3-3.3% Cr₂O₃. Two generations of clinopyroxene are present; an early diopside followed by augite. Chromium spinels are highly variable with Cr#s (100Cr / (Cr + Al)) between 51 and 89, and their compositions reflect different processes of formation, namely partial melting and eclogite, amphibole and greenschist facies metamorphism. The Mg#s (100 Mg / (Mg + Fe²⁺))of the spinels correlate positively with the Cr#s but negatively with oxygen fugacity. Based on the spinel compositions the ultramafic rocks originated in the shallow mantle, then subducted to depths of more than 100 km and finally exhumed to the surface. They underwent partial melting at shallow depths, mostly in the spinel facies, and were later transformed into garnet peridotites during deep subduction. All of the rocks were weakly metasomatized during exhumation and were subjected to retrograde metamorphism.  相似文献   

雅鲁藏布江缝合带白朗县白岗尖晶石—石榴子石相二辉橄榄岩的相界反应及其意义   总被引：3，自引：0，他引：3  

夏斌  周国庆  李建峰  陈根文  刘维亮  王冉  董冰华 《地质论评》2012,58(3):453-470

西藏白朗县白岗村蛇绿混杂岩中有一罕见的尖晶石石榴子石二辉橄榄岩小岩块,被松软的蛇纹岩化尖晶石二辉橄榄岩包裹其中。岩块中发育有碎基单斜辉石、斜方辉石中出溶单斜辉石、切过出溶单斜辉石的贯入单斜辉石和外来碎粒单斜辉石及钙质辉石+铬尖晶石→钙铁石榴子石相界反应。同时,在岩块和包壳岩石的橄榄石中出现针状硅镁石出溶物。计算这些矿物的温度压力表明,它们的温度压力都处于>800℃,>1.8GPa以上的地幔石榴子石域超高压环境,而且,经历过一个上升→俯冲→上升的"N"字形历程。  相似文献   

新疆东准噶尔扎河坝橄榄岩单斜辉石、铬尖晶石地球化学特征及铬铁矿成矿作用          下载免费PDF全文

王召林  孟贵祥  汤贺军  袁璐璐  杨竹森  肖艳东 《中国地质》2021,48(2):477-494

扎河坝蛇绿岩是东准噶尔地区一条重要的蛇绿岩带,主要由橄榄岩、层状辉长岩、玄武岩、斜长花岗岩、硅质岩等组成。其中橄榄岩主要由方辉辉橄岩(方辉橄榄岩)、二辉橄榄岩和少量纯橄岩组成。二辉橄榄岩中的单斜辉石Cr_2O_3平均1.11%,Al_2O_3平均4.77%,MgO平均16.99%,CaO平均21.84%,SiO_2平均50.00%;铬尖晶石副矿物具有较低的Cr_2O_3(平均40.35%)、Cr~#(平均0.53)和更高的Al_2O_3(平均24.10%), MgO(平均13.23%)和Mg~#(0.62)含量,属高Al型,橄榄岩形成于扎河坝洋扩张时期(MOR环境);块状铬铁矿铬尖晶石各元素含量变化较小:Cr_2O_3平均55.45%,Al_2O_3平均10.88%, MgO平均11.98%和Mg~#为0.60,属SSZ背景高Cr型铬铁矿。二辉橄榄岩单斜辉石具有典型的熔融残余结构和熔-岩反应结构,斜方辉石保留绢石化假晶和部分未蚀变的辉石残余体(主要是顽火辉石),铬尖晶石副矿物具有熔蚀特征。单斜辉石的熔融残余结构是含铬矿物熔融、释放铬的一种表现,是橄榄岩部分熔融程度升高,向更富镁方向演化的结构标志,但可能对富Cr型铬铁矿的形成贡献有限。橄榄岩存在熔-岩反应新生的单斜辉石、橄榄石及结构标志。熔-岩反应过程中流体、挥发分的作用不可忽视。文章还探讨了铬铁矿Cr~#、Mg~#和Al_2O_3含量差异与蛇绿岩形成的构造背景关系及影响因素。卡拉麦里洋壳俯冲和地幔对流循环使扎河坝早期形成于MOR环境的富Al铬尖晶石富集,形成高Cr块状铬铁矿。  相似文献   

与金刚石原生矿有关的铬尖晶石形态特征     

张学初  陈明珊 《矿产与地质》2008,22(3):270-272

铬尖晶石是寻找金刚石原生矿的重要指示矿物之一,重砂测量中往往发现大量的铬尖晶石。单纯利用矿物化学成分判别它们是否与金刚石原生矿有关,电子探针测试工作量大、耗资高。如果根据显微镜下矿物形态特征鉴定与选择性的电子探针分析相互验证,将是一种既经济又简单、而且更可靠的判别方法。本文主要介绍与金刚石原生矿有关的铬尖晶石在显微镜下的形态特征。  相似文献   

矿物微量元素组成用于火成岩构造背景判别   总被引：1，自引：0，他引：1  

赵振华 《大地构造与成矿学》2016,(5):986-995

火成岩中的矿物,特别是稳定副矿物的微量元素组成可用于火成岩构造–岩浆背景的判别。产于不同构造背景火成岩中单颗粒锆石原位微量元素含量的准确测定,积累了大量资料。本文介绍了用锆石微量元素含量的二维核密度分布投影,构建了U/Yb-Nb/Yb、Sc/Yb-Nb/Yb和U/Yb-Sc/Yb构造背景判别图解,可以区分洋中脊、地幔柱影响的洋岛及俯冲有关的弧(大陆弧)等不同构造背景形成的火成岩。单斜辉石、尖晶石、黑云母和角闪石的微量元素或主量元素组成同样可用于构造背景识别。  相似文献   

Supra-subduction affinity in the Neoproterozoic serpentinites in the Eastern Desert, Egypt: Evidence from mineral composition     

A.E.S. Khalil  M.K. Azer   《Journal of African Earth Sciences》2007,49(4-5):136-152

Serpentinites in the Eastern Desert (ED) of Egypt represent integral components of the ophiolites. Metamorphic textures of the serpentinites preserve the complex mineralogical evolution from primary peridotite through metamorphism, and late-stage hydrothermal alteration. Two textural types are distinguished in the olivines of the present serpentinized peridotites, namely (a) highly-strained olivine grains with kink bands, as in the deformed mantle tectonites from ophiolites, and (b) non-strained grains. The latter may represent recrystallized crystals during later thermal metamorphic events due to the intrusion of granite. On the basis of X-ray diffraction analysis, antigorite is the main serpentine minerals with lesser chrysotile and lizardite which indicates that serpentinites were formed under prograde metamorphism. Relict primary minerals of the serpentinites are Cr-spinel, olivine and pyroxene. Chrome spinel relicts have high Cr# (0.60–0.80), whereas primary olivines are Mg-rich nature (Fo = 89–96). Geochemical compositions of serpentinites indicate that they formed not at mid-ocean ridges but at spreading centers associated with subduction zones and this could have happened in a supra-subduction zone either in the fore-arc or back-arc environments. Mineral compositions of primary chrome spinels and olivines are similar to those of modern fore-arcs. High Cr# in the relict chrome spinels and Fo in the primary olivines of serpentinites indicate that they are residual after extensive partial melting and originated by sea-floor spreading during subduction initiation.  相似文献   

Point defects and cation tracer diffusion in (Ti _x Fe _1?x ) _3?δ O₄ 1. Non-stoichiometry and point defects     

S. Aggarwal  R. Dieckmann 《Physics and Chemistry of Minerals》2002,29(10):695-706

 The deviation from stoichiometry, δ, in spinel solid solutions of the type (Ti _x Fe _1−x )_3−δ O₄ with x=0.1, 0.2 and 0.25 was studied thermogravimetrically as a function of oxygen activity, a _O2, at 1100, 1200 and 1300 ^∘C. The experimental results, S-shaped curves for δ vs. log a_O2, are presented and discussed with regard to the type of point defects prevailing under different conditions in the deviation from stoichiometry. It is concluded that cation vacancies are the predominant point defects at high oxygen activities, while cation interstitials prevail at low oxygen activities. The temperature and composition dependencies of point defect concentrations are also discussed. Received: 1 October 1996 / Accepted: 15 September 2002 Acknowledgements The authors thank the US Department of Energy for support of this work under Grant no. DE-FGO2–88ER45357. This work made use of the Cornell Center of Materials Shared Experimental Facilities, supported through the National Science Foundation Materials Research Science and Engineering Centers program (DMR-0079992).  相似文献