原油族组分成气的化学动力学模型及其标定   总被引：27，自引：2，他引：27       下载免费PDF全文

卢双舫  付晓泰 《地质学报》1997,71(4):367-373

利用等温密封热解实验技术及恒速升温热解实验与PY—GC分析技术的结合,本文分别建立并标定了原油中各族组分,即饱和烃、芳烃、非烃和沥青质成气的化学动力学模型。结果表明,原油中不同族组分成气的过程均可用平行一级反应描述,但不同组分在平均活化能及活化能分布上有明显的差异。各族组分在地史过程中成气的过程可由各自的化学动力学模型来描述。这将使原油成气过程的定量、动态描述成为可能。  相似文献   

Pall型摩擦阻尼支撑内力计算方法   总被引：3，自引：0，他引：3  

吴斌  张纪刚  欧进萍 《世界地震工程》2004,20(2):6-11

从Pall摩擦阻尼器四连杆机构的几何非线性变形特征出发，分析框架位移、支撑刚度、阻尼器摩擦力、阻尼器大小、支撑倾角、支撑屈曲力等对一种改进的Pall摩擦阻尼器-T形芯板摩擦阻尼器支撑的受力特点，拟合出可供设计人员使用的实用计算公式。  相似文献   

利用前兆事件对云南地区地震进行中短期预测研究   总被引：1，自引：0，他引：1       下载免费PDF全文

秦嘉政  钱晓东 《地震学报》2004,26(2):140-150

对某些类型的主震事件, 进行中短期预测也许是可能的. 利用Varnes, Bufe和Varnes提出的破裂时间法模拟前兆地震能量加速释放模型,通过实际观测资料与理论公式的拟合, 可以建立主地震事件的中短期预测技术, 用以确定表示主震的地点、时间和震级大小. 本文使用的是云南区域台网的地震目录资料，覆盖的时间段为1965~2002年. 统计分析表明，在此37年时间内，等于或大于2.5级地震资料是相当完整的. 本文对云南地区的30次主震事件进行了模拟，其中25次主震事件由前兆序列模拟得到的预测时间和震级与实际值相当接近，主震震级预测精度约0.57个震级单位，假定已知前兆序列中最后一次事件，则预测主震发生时间误差约0.64年.对另外的5次主震事件，由于没有足够的前兆事件来充分确定前兆能量加速曲线或是存在对能量加速释放曲线的干扰事件，而不能进行破裂时间法模拟.本文的研究结果还表明，由于云南是破坏性地震和中小地震活跃的地区，因此，主地震与前兆事件最佳搜索半径不存在明显的线性关系.主震矩与系数k，m之间存在强烈的相关性，利用主震地震矩与系数的关系和限制指数m的取值范围，可进一步缩小预测时间和预测震级的最佳拟合区范围，提高了模拟主震事件的预测精度. 本文采用破裂时间法对30次主震事件进行拟合，80％以上获得了较好的结果. 显示出该方法在预测已知主震事件序列的能力方面大有希望，因此，利用前兆事件对未来主震事件进行中短期预测的前景是令人鼓舞的.   相似文献   

Radiative Exchange in an Urban Street Canyon   总被引：1，自引：4，他引：1  

Ian N. Harman  Martin J. Best  Stephen E. Belcher 《Boundary-Layer Meteorology》2004,110(2):301-316

The influence of building geometry on the radiation terms ofthe surface energy balance is a principal reason for surfacetemperature differences between rural and urban areas.Methods exist to calculate the radiation balance in an urban area,but their validity across the range of urban geometries andmaterials has not been carefully considered.Here the exchange of diffuse radiation in an urban street canyon isinvestigated using a method incorporating all reflections of radiation.This exact solution is compared to two commonly used approximationsthat retain either no reflections, or just one reflection of radiation.The area-averaged net radiative flux density from the facets of the canyondecreases in magnitude monotonically as the canyon aspect ratio increases.The two approximate solutions possess unphysical differences from thismonotonic decrease for high canyon aspect ratios or low materialemissivities/high material albedos.The errors of the two approximate solutions are small for near blackbodymaterials and small canyon aspect ratios but can be an order ofmagnitude for intermediate material properties and deep street canyons.Urban street canyon models need to consider at least one reflectionof radiation and multiple reflections are desirable for full applicability.  相似文献   

Change of crustal gravitational potential energy in the Taiwan orogen by the Chi-Chi earthquake sequence     

Shu-Kun Hsu  Chung-Liang Lo 《Earth and Planetary Science Letters》2004,222(2):573-581

The active convergence between the northwest corner of the Philippine Sea Plate and the southeast margin of the Eurasian Plate has given rise to the Taiwan mountain-building and produced numerous earthquakes. Among the earthquakes, the 1999 Chi-Chi earthquake is the largest one recorded in the century. In this study, we examine the crustal gravitational potential energy (GPE) change in the Taiwan orogen caused by the Chi-Chi earthquake sequence, which was catalogued by the regional broadband seismometer array for a whole year. As a result, we find that the crust was going up and down randomly during the earthquake sequence, but an overall cumulative gain of the crustal GPE, +1.82×10¹⁶ J, was rapidly achieved in 1 month after the main shock. The crustal GPE was nearly still afterwards and reached +1.90×10¹⁶ J in 1 year. Spatially, although the main surface faulting has occurred in western Taiwan, the crustal GPE gain is mainly distributed in central Taiwan at the area where the existing crustal GPE is high and the existing lithospheric GPE is relatively low. The crustal GPE loss by the Chi-Chi earthquake sequence can also be observed and is generally distributed at both sides of the crustal GPE gain area. The crustal GPE gain mainly found in central Taiwan corroborates that the uplift of the Taiwan orogen is principally taking place in central Taiwan, rather than in the more hazardous western Taiwan.  相似文献   

A new method for testing pile by sin- gle-impact energy and P-S curve     

许昭永  段永康  王彬  胡毅力  杨润海  许峻  赵晋明 《地震学报(英文版)》2004,17(Z1)

Introduction Through many year's practices by vast numbers of scientific and technological workers andefforts from all aspects, the dynamic testing method of high-low strain has formally entered intothe technical code of foundation pile test of construction at last (The Industry Standards of thePeople's Republic of China, 2003). The striking mode of the dynamic testing method of high strainis stipulated as hammer in the code, the striking of rocket can also be used. The latter is widely…  相似文献   

Frequency domain modal analysis of earthquake input energy to highly damped passive control structures     

Izuru Takewaki 《地震工程与结构动力学》2004,33(5):575-590

A new complex modal analysis‐based method is developed in the frequency domain for efficient computation of the earthquake input energy to a highly damped linear elastic passive control structure. The input energy to the structure during an earthquake is an important measure of seismic demand. Because of generality and applicability to non‐linear structures, the earthquake input energy has usually been computed in the time domain. It is shown here that the formulation of the earthquake input energy in the frequency domain is essential for deriving a bound on the earthquake input energy for a class of ground motions and for understanding the robustness of passively controlled structures to disturbances with various frequency contents. From the viewpoint of computational efficiency, a modal analysis‐based method is developed. The importance of overdamped modes in the energy computation of specific non‐proportionally damped models is demonstrated by comparing the energy transfer functions and the displacement transfer functions. Through numerical examinations for four recorded ground motions, it is shown that the modal analysis‐based method in the frequency domain is very efficient in the computation of the earthquake input energy. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

Seismic tests on reinforced concrete and steel frames retrofitted with dissipative braces     

F. J. Molina  S. Sorace  G. Terenzi  G. Magonette  B. Viaccoz 《地震工程与结构动力学》2004,33(15):1373-1394

Seismic tests have been conducted on two 3‐storey structures protected with pressurized fluid‐viscous spring damper devices. One of the structures was a reinforced concrete frame with clay elements in the slabs, while the other one was a steel frame with steel/concrete composite slabs. The spring dampers were installed through K bracing in between the floors. The tests were performed by means of the pseudodynamic method, which allowed the use of large and full‐size specimens, and by implementing a specific compensation strategy for the strain‐rate effect at the devices. The test results allowed the verification of the adequacy of the attachment system as well as the comparison of the behaviour of the unprotected buildings with several protected configurations, showing the benefits of the application of the devices and the characteristics of their performance. The response of the protected structures was always safer than that of the unprotected ones mainly due to a significant increase of equivalent damping. The increase in the damping ratio depends on the level of deformation. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

1998年南海夏季风爆发前后区域动能收支研究     

魏贵洲  钟中卢伟 《气象科技》2004,32(3):155-162

利用1998年南海季风试验(SCSMEX)资料和区域动能收支方程，对南海南部和北部两个区域该年夏季风爆发前后的区域总动能和区域扰动动能收支进行了诊断分析。结果表明，南海北区夏季风爆发前后动能主要在高层制造，大部分动能被摩擦消耗，南区夏季风爆发前后动能主要在高层被破坏，摩擦项充当动能源。扰动动能主要在高层和部分在低层制造。在此期间，南海地区一直向邻近区域输出动能。  相似文献   

大气边界层湍流能量交换特征研究进展     

李富余张宏升  陈家宜 《气象科技》2004,32(5):305-310

从一维湍流能量平衡方程出发,回顾了近几十年湍流能量平衡方程中的各项以及Karman常数k的研究成果,总结了大气边界层湍流能量交换特征的研究概况和热点问题,并对今后发展趋势做了展望。实验研究表明,湍流能量平衡方程中的各项在不同条件下有不同的形式;传统的能量产生和耗散的局地平衡假设存在不足,特别是在不稳定条件下,垂直的湍流输运和压力脉动对湍流能量收支起了非常重要的作用。Karman常数与Rossby数和Reynolds数无关,在比较光滑的下垫面上k近似等于040±001。  相似文献