Kinetic study of the dehydroxylation of chrysotile asbestos with temperature by in situ XRPD   总被引：6，自引：0，他引：6  

A. Cattaneo  A. F. Gualtieri  G. Artioli 《Physics and Chemistry of Minerals》2003,30(3):177-183

 The kinetics of the dehydroxylation of chrysotile was followed in situ at high temperature using real-time conventional and synchrotron powder diffraction (XRPD). This is the first time kinetics parameters have been calculated for the dehydroxylation of chrysotile. The value of the order of the reaction mechanism calculated using the Avrami model indicates that the rate-limiting step of the reaction is a one-dimensional diffusion with an instantaneous nucleation or a deceleratory rate of nucleation of the reaction product. Hence, the rate-limiting step is the one-dimensional diffusion of the water molecules formed in the interlayer region by direct condensation of two hydrogen atoms and an oxygen atom. The calculated apparent activation energy of the reaction in the temperature range 620–750 °C is 184 kJ mol⁻¹. The diffusion path is along the axis of the fibrils forming the fibers. The amorphous or short-range ordered dehydroxylate of chrysotile is extremely unstable because forsterite readily nucleates in the Mg-rich regions. Moreover, it is less stable than the dehydroxylate of kaolinite, the so-called metakaolinite, which forms mullite at about 950 °C. This difference is interpreted in terms of the different nature of the two ions Mg²⁺ and Al³⁺ and their function as glass modifier and glass-forming ion, respectively. Received: 10 April 2002 / Accepted: 7 January 2003 Acknowledgements This work is part of a COFIN project (04 Scienze della Terra, NR 17, 2000) supported by MURST. Dr Dapiaggi is kindly acknowledged for help during the data collection at the Dipartimento di Scienze della Terra, University of Milan.  相似文献   

Kinetics of Disproportionation of Inorganic Polysulfides in Undersaturated Aqueous Solutions at Environmentally Relevant Conditions     

A. Kamyshny  A. Goifman  D. Rizkov  O. Lev 《Aquatic Geochemistry》2003,9(4):291-304

The rate of the reversible homogeneous disproportionation of polysulfides was studied by following the optical absorbance of polysulfide solutions in a continuous plug flow reactor equipped with an on-line photometric detector. In order to avoid heterogeneous slow reactions involving sulfur colloids or precipitate, the reaction was initiated by an abrupt pH change from an undersaturated solution containing predominantly tetrasulfide species to a pH where pentasulfide is the dominant species. The disproportionation was found to follow first order reversible reaction dynamics. At environmentally relevant conditions the characteristic time of the disproportionation reaction is of the order of 10 s. This characteristic time implies that necessary conditions for speciation of the different polysulfide species by chromatography or another separation and subsequent quantification scheme should be of the order of 1 s.  相似文献   

我国能源消费结构变化与气候特征   总被引：9，自引：1，他引：9       下载免费PDF全文

袁顺全  千怀遂 《气象科技》2003,31(1):29-32

文章利用多项式法将气候耗能量从能源消费总量中分离出来，用统计分析的方法探讨了气候耗能量与气候因子之间的关系及其变化。研究表明：从20世纪50年代到80年代初期，旱涝灾害是影响我国气候耗能量的主要气候因子，它们之间存在显著的线性相关关系，随着经济的发展和人民生活水平的提高，旱涝灾害对气候耗能量的影响逐渐减弱，气温对气候耗能量的影响日趋显著，目前正处于过渡时期。  相似文献   

一次区域性大暴雨环境特征分析     

柳林  李娜  常平  张国胜 《山东气象》2003,23(4):12-14

通过对冀东南、鲁西北一次区域性大暴雨的分析表明：除有利的大尺度环流背景以外，超低空急流是大暴雨不稳定能量和水汽的主要输送者，高能区不稳定能量释放，产生大暴雨所需的强烈上升运动。暴雨落区与超低空急流前部最大风速切变区的位置密切相关。  相似文献   

青藏高原上中尺度对流系统(MCSs)的个例分析及其比较   总被引：3，自引：0，他引：3  

ZHU Guofu  CHEN Shoujun 《大气科学进展》2003,20(3):311-322

对1995年7月25—28日高原上连续数日出现MCSs的现象进行了红外云图特征及其演变、大尺度环境背景场和对流有效位能的分析。可以发现，所有这些MCSs有着相似的日变化演变过程；它们的初始对流在中午由于日射加热开始活跃，之后迅速发展，这些MCSs在后下午形成，在傍晚达到最强，之后逐渐减弱。其中26日MCS最为强大，它是在单一的强大的近于圆形的高原反气旋高压背景下受强的低层热力强迫和条件不稳定的驱动而发生的。这些发生条件都与高原本身的热力作用紧密相关，所以它的发生发展主要与高原特有的较为纯粹的热力因子相联系。28日MCS是另一个很强的MCS，它明显地受到中纬度西风槽的斜压区的影响，这二个很强的MCS有着不同的发展机制和显著不同的表现特征。  相似文献   

地震动输入能量衰减规律的研究   总被引：6，自引：1，他引：6  

公茂盛  谢礼立  章文波 《地震工程与工程振动》2003,23(3):15-24

对所收集到的266条强震记录，将其按场地条件分类，计算了不同场地条件、不同延性系数下的“绝对”和“相对”输入能量反应谱，然后利用两步回归法，得出了不同场地条件下地震动“绝对”和“相对”两种输入能量的衰减规律，分析了场地条件、延性系数、震级及距离等参数对地震动能量谱的影响，并对两种输入能量衰减规律进行了比较。  相似文献   

地震勘探中的炸药震源药量理论与实验分析   总被引：5，自引：1，他引：5  

张智  刘财  邵志刚 《地球物理学进展》2003,18(4):724-728

炸药由于具有良好的脉冲特性及高能量的特点而作为地震勘探中的主要震源，就炸药本身来说，在地震勘探中药量、井深等参数的选取对激发能量和激发频率有很大的影响。为此，本文运用炸药爆炸理论，从炸药作功角度来加以论述，并通过理论和实验分析得出选取一个最佳的药量和井深激发，既能提高炸药作功能力，又能增强激发能量，从而激发强能量的高频震源子波，达到指导野外地震采集和节约经济成本的目的。  相似文献   

The climatic impacts of land surface change and carbon management, and the implications for climate-change mitigation policy   总被引：4，自引：0，他引：4  

Gregg Marland  Roger A. Pielke Sr. 《Climate Policy》2003,3(2):149-157

Strategies to mitigate anthropogenic climate change recognize that carbon sequestration in the terrestrial biosphere can reduce the build-up of carbon dioxide in the Earth’s atmosphere. However, climate mitigation policies do not generally incorporate the effects of these changes in the land surface on the surface albedo, the fluxes of sensible and latent heat to the atmosphere, and the distribution of energy within the climate system. Changes in these components of the surface energy budget can affect the local, regional, and global climate. Given the goal of mitigating climate change, it is important to consider all of the effects of changes in terrestrial vegetation and to work toward a better understanding of the full climate system. Acknowledging the importance of land surface change as a component of climate change makes it more challenging to create a system of credits and debits wherein emission or sequestration of carbon in the biosphere is equated with emission of carbon from fossil fuels. Recognition of the complexity of human-caused changes in climate does not, however, weaken the importance of actions that would seek to minimize our disturbance of the Earth’s environmental system and that would reduce societal and ecological vulnerability to environmental change and variability.  相似文献   

广东“5.24”暴雨的湿有效能量分析          下载免费PDF全文

周海光  刘延英  石定朴 《大气科学学报》2003,26(6):859-864

利用海峡两岸及邻近地区暴雨试验期间的时间加密观测资料,分析了1998年5月24日发生在广东省的一次暴雨过程。发现湿有效能量与此次暴雨降水的关系比较清楚。降水开始前,暴雨区的能量显著增加,强降水开始于能量显著减少时;强降水时,暴雨区的能量出现小幅反弹;当暴雨区能量再次显著减少后暴雨降水结束;这是一次能量锋暴雨,暴雨开始前有能量锋生现象发生,暴雨强降水时段与强能量锋同步,暴雨区位于高能舌北侧能量锋附近。  相似文献   

HLAFS和T63数值预报产品在暴雨分析中的应用     

陈威  姜荣 《黑龙江气象》1997,(3):10-12

首次使用ＨＬＡＦＳ数值预报产品对黑龙江省暴雨进行分析，结合Ｔ６３数值预报产品，利用两者提供的物理一０８时和２０时的实况场和预报场格点资料，对黑龙江省一次暴雨过程进行分析，找出了暴雨发生的物理机制，指出深厚的水汽条件以及水汽的辐合，强烈的上升运动和不稳定能量的存贮和释放是产生暴雨的关键因素。  相似文献