Transport of dissolved methoxy-nonafluorobutane through a saturated column     

Kenneth Y. Lee  Jeong-Yub Lee  James J. Mellett 《Environmental Geology》2004,46(6-7):883-889

Solute transport experiments were conducted in a one-dimensional saturated column using dissolved methoxy-nonafluorobutane (HFE-7100), a Novec engineered fluid developed by the 3M Corporation, as the solute. Novec engineered fluids are considered dense non-aqueous phase liquids (DNAPLs) because they are immiscible with water and have a specific gravity greater than one. The HFE-7100 fluid is safer and environmentally friendlier than common DNAPL contaminants such as tetrachloroethylene (PCE) or trichloroethylene (TCE); thus, it is an ideal substitute DNAPL for laboratory groundwater contamination research. Three sets of solute transport experiments were conducted. The first set of experiments was conducted in a glass-bead-packed column using dissolved HFE-7100 as the solute. The second set of experiments was conducted in a sand-packed column using dissolved HFE-7100 as the solute. The third set of experiments was conducted in a sand-packed column using dissolved PCE as the solute. The dissolved HFE-7100 column breakthrough concentrations were compared with dissolved PCE breakthrough concentrations. Results show that the one-dimensional solute transport equation was successful in describing the transport behavior of dissolved HFE-7100. This study demonstrates that the HFE-7100 fluid can be used as a safer substitute DNAPL for groundwater contaminant dissolution and transport research.  相似文献   

Effects of temperature and humidity upon the transport of sedimentary particles by wind   总被引：3，自引：0，他引：3  

Cheryl McKenna Neuman 《Sedimentology》2004,51(1):1-17

Wind tunnel simulations of aeolian transport carried out over a range in mean temperature between 32 °C and ?9 °C suggest that cold airflows support higher mass transport rates (Q) than very warm air. The magnitude of this increase is larger than expected, so that analytical and semi‐empirical models underestimate Q. Extrapolation of the results suggests that, at ?40 °C, as for example in the dry valleys of Antarctica in winter, Q may be as much as 70% higher than for the equivalent wind speed in hot deserts at air temperatures of 40 °C. Temperature‐dependent changes in air density and turbulence contribute to this result. The decreased tension of water adsorbed onto particle surfaces at low temperatures is postulated to reduce interparticle cohesion and, thus, to increase the elasticity of particle impacts on cold beds. Definition of the roles that temperature and humidity play in aeolian transport is relevant to studies of palaeoenvironmental reconstruction and extraterrestrial (or planetary) geology. Investigation of present‐day, cold climate features and of climate change effects also requires knowledge of these fundamental relations.  相似文献   

Nuclear Waste Disposal Simulations: Couplex Test Cases     

H. Hoteit  Ph. Ackerer  R. Mosé 《Computational Geosciences》2004,8(2):99-124

We give some results obtained for the Couplex test cases proposed by the ANDRA. In this paper our aim is twofold. Firstly, to compute the release of nuclides out of the repository by concentrating on the 3D near field (Couplex 2). The simulation of the transport phenomena takes into account the dissolution of the glass containers and congruent emissions of the radio-nuclides including filiation chains and some simplified chemistry. Secondly, it is to use the near field computations in order to simulate the nuclide migrations in a 2D far field (Couplex 3). Coupling in between the two simulations takes into consideration the periodicity of the disposal modules and the geometry of the repository described in Couplex 1. The mixed finite element and discontinuous Galerkin methods are used to solve the convection–diffusion equations. In order to handle the nonlinear precipitation/dissolution term, we developed a new iterative technique that combines Picard and Newton–Raphson methods.  相似文献   

Modélisation du transport réactif en milieux poreux non saturés avec une méthode ELLAM en maillage variable     

Anis Younes 《Comptes Rendus Geoscience》2004,336(6):547-552

Modelling contaminant transfer with biological/chemical/radioactive processes needs appropriate numerical methods able to reproduce sharp concentration fronts. In this work, we develop a new Eulerian–Lagrangian Localized Adjoint Method (ELLAM) for solving the reactive transport equation with non-constant coefficients. To avoid interpolation (leading to errors), we use a moving grid to define the solution and test functions. The method is used to simulate first the infiltration of solute into a column of unsaturated porous medium and second the multispecies transport. The developed ELLAM gives accurate results without non-physical oscillations or numerical diffusion, even when using large time steps. To cite this article: A. Younes, C. R. Geoscience 336 (2004).  相似文献   

Long-term bed load transport rate based on aerial-photo and ground penetrating radar surveys of fan-delta growth, Coast Mountains, British Columbia     

Channa P. Pelpola  Edward J. Hickin   《Geomorphology》2004,57(3-4):169-181

Sequential aerial photography, sonar bathymetry, ground-penetrating radar (GPR), and sediment sampling and analysis provide the basis for calculating the volumetric and mass rate of progradation of the delta of Fitzsimmons Creek, a steep, high-energy, debris-flow-dominated channel draining about 100 km² of the southern Coast Mountains of British Columbia. Fitzsimmons Creek is typical of small mountain rivers in the region. GPR imaging is used to define the pre-depositional morphology of the receiving basin, a technique that improves the accuracy of the volumetric survey. The 52-year record (1947–1999) of progradation yielded an average annual volumetric transport rate of 1.00±0.16×10⁴ m³ year⁻¹ for bed load, corresponding to a mass transport rate of 1.60±0.28×10⁴ Mg year⁻¹. Bed load yields are consistent with those obtained in hydrogeomorphically similar basins in the region and elsewhere. Decade-based annual rates, which vary from 0.64±0.11×10⁴ to 2.85±0.38×10⁴ Mg year⁻¹, provide poor estimates of the 52-year average. Indeed, the 52-year record may also not be long enough to fully integrate the significant fluctuations in the sediment efflux from Fitzsimmons Creek. The methodology proposed in this paper can be transferred to other comparable mountain environments worldwide.  相似文献   

A parameterisation for the threshold shear velocity to initiate deflation of dry and wet sediment   总被引：1，自引：0，他引：1  

Wim M. Cornelis  Donald Gabriels  Roger Hartmann 《Geomorphology》2004,59(1-4):43

A new parameterisation for the threshold shear velocity to initiate deflation of dry and wet particles is presented. It is based on the balance of moments acting on particles at the instant of particle motion. The model hence includes a term for the aerodynamic forces, including the drag force, the lift force and the aerodynamic-moment force, and a term for the interparticle forces. The effect of gravitation is incorporated in both terms. Rather than using an implicit function for the effect of the aerodynamic forces as reported earlier in literature, a constant aerodynamic coefficient was introduced. From consideration of the van der Waals force between two particles, it was further shown that the effect of the interparticle cohesion force between two dry particles on the deflation threshold should be inversely proportional to the particle diameter squared. The interparticle force was further extended to include wet bonding forces. The latter were considered as the sum of capillary forces and adhesive forces. A model that expresses the capillary force as a function of particle diameter squared and the inverse of capillary potential was deduced from consideration of the well-known model of Fisher and the Young–Laplace equation. The adhesive force was assumed to be equal to tensile strength, and a function which is proportional to particle diameter squared and the inverse of the potential due to adhesive forces was derived. By combining the capillary-force model and the adhesive force model, the interparticle force due to wet bonding was simplified and written as a function of particle diameter squared and the inverse of matric potential. The latter was loglinearly related to the gravimetric moisture content, a relationship that is valid in the low-moisture content range that is important in the light of deflation of sediment by wind. By introducing a correction to force the relationship to converge to zero moisture content at oven dryness, the matric potential–moisture content relationship contained only one unknown model parameter, viz. moisture content at −1.5 MPa. Working out the model led to a rather simple parameterisation containing only three coefficients. Two parameters were incorporated in the term that applies to dry sediment and were determined by using experimental data as reported by Iversen and White [Sedimentology 29 (1982) 111]. The third parameter for the wet-sediment part of the model was determined from wind-tunnel experiments on prewetted sand and sandy loam aggregates. The model was validated using data from wind-tunnel experiments on the same but dry sediment, and on data obtained from simulations with the model of Chepil [Soil Sci. Soc. Am. Proc. 20 (1956) 288]. The experiments showed that soil aggregates should be treated as individual particles with a density equal to their bulk density. Furthermore, it was shown that the surface had to dry to a moisture content of about 75% of the moisture content at −1.5 MPa before deflation became sustained. The threshold shear velocities simulated with our model were found to be in good agreement with own observations and with simulations using Chepil's model.  相似文献   

黄河三门峡水库—小浪底水库间夏季降水量年际变化及水汽形势分析     

张胜军  陈怀亮  翁永辉 《气象科技》2005,(Z1)

利用1960~1999年全国600个站月平均降水资料,对黄河三门峡水库—小浪底水库间的夏季降水总量年际变化进行了统计分析,并应用功率谱诊断方法提取了夏季各月降水的振荡周期。在此基础上,选取了黄河三门峡水库—小浪底水库间降水量多与少的年份,利用NCEP再分析资料研究了其上空的水汽变化以及水汽输送量变化。结果表明,黄河三门峡水库—小浪底水库间降水量多的年份,其上空为较为明显的水汽辐合;降水量比较少的年份,其上空为明显的水汽辐散。选取多雨年(1982年)及少雨年(1997年),结合NCEP再分析资料以及TBB资料,进一步验证了上述结论。  相似文献   

Basal sediment evacuation by subglacial meltwater: suspended sediment transport from Haut Glacier d'Arolla,Switzerland     

Darrel A. Swift  Peter W. Nienow  Trevor B. Hoey 《地球表面变化过程与地形》2005,30(7):867-883

Proglacial suspended sediment transport was monitored at Haut Glacier d'Arolla, Switzerland, during the 1998 melt season to investigate the mechanisms of basal sediment evacuation by subglacial meltwater. Sub‐seasonal changes in relationships between suspended sediment transport and discharge demonstrate that the structure and hydraulics of the subglacial drainage system critically influenced how basal sediment was accessed and entrained. Under hydraulically inefficient subglacial drainage at the start of the melt season, sediment availability was generally high but sediment transport increased relatively slowly with discharge. Later in the melt season, sediment transport increased more rapidly with discharge as subglacial meltwater became confined to a spatially limited network of channels following removal of the seasonal snowpack from the ablation area. Flow capacity is inferred to have increased more rapidly with discharge within subglacial channels because rapid changes in discharge during highly peaked diurnal runoff cycles are likely to have been accommodated largely by changes in flow velocity. Basal sediment availability declined during channelization but increased throughout the remainder of the monitored period, resulting in very efficient basal sediment evacuation over the peak of the melt season. Increased basal sediment availability during the summer appears to have been linked to high diurnal water pressure variation within subglacial channels inferred from the strong increase in flow velocity with discharge. Basal sediment availability therefore appears likely to have been increased by (1) enhanced local ice‐bed separation leading to extra‐channel flow excursions and[sol ]or (2) the deformation of basal sediment towards low‐pressure channels due to a strong diurnally reversing hydraulic gradient between channels and areas of hydraulically less‐efficient drainage. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

The effect of bed mobility on resistance to overland flow     

Shixiong Hu  Athol D. Abrahams 《地球表面变化过程与地形》2005,30(11):1461-1470

When sediment grains are transported as bed load in overland flow, there is a net transfer of momentum from the flow to the grains. When these grains collide with other grains, whether on the bed or in the flow, streamwise flow velocity decreases and resistance to flow increases. Resistance to flow generated in this manner is termed bed‐load transport resistance. Resistance to flow f over a plane bed may be partitioned into grain resistance f_g and bed‐load transport resistance f_bt. We use the symbols f_btf and f_btm to denote f_bt for flows over fixed beds and over mobile beds, respectively, and we compute the effect of bed mobility on flow resistance f_mob by subtracting f_btf from f_btm. The data for this study come from 54 flume experiments with fixed beds and 38 with mobile beds. On average f_mob is approximately equal to half of f_btm, which is about one‐quarter of f. Hence, f_mob is about one‐tenth of f. Predictive equations are developed for f_btf, f_btm and f_mob using dimensional analysis to identify the relevant independent variables and regression analysis to evaluate the coefficients associated with these variables. Values of f_mob are always positive which implies that mobile beds offer greater resistance to flow than do fixed beds. Evidently bed‐load grains colliding with mobile beds lose more momentum to the bed than do grains colliding with fixed beds. In other words, grain collisions with mobile beds are less elastic than those with fixed beds. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

Suspended sediment transport along an idealised tidal embayment: settling lag, residual transport and the interpretation of tidal signals     

David Pritchard 《Ocean Dynamics》2005,55(2):124-136

We present semi-analytical solutions for suspended sediment concentration (SSC) and residual sediment transport in a simple mathematical model of a short tidal embayment. These solutions allow us to investigate in some detail the characteristic tidal and semi-tidal variation of SSC and the processes leading to residual sediment transport, including settling and scour lags, the roles of ‘local’ and ‘advective’ contributions, and the presence of internally or externally generated overtides. By interpreting the transport mechanisms in terms of the classic conceptual models of settling lag we clarify how these models may be expressed in mathematical terms. Our results suggest that settling lag is usually a more important process than scour lag, and that a local model which neglects advection may predict the direction of net sediment transport incorrectly. Finally, we discuss our results in the context of other transport processes and morphodynamic feedback.  相似文献