尿素络合法分离-气相色谱/同位素质谱法分析土壤和植物中低含量(ppm级)正构烷烃的碳同位素   总被引：1，自引：1，他引：0  

王宁  朱庆增  谢曼曼  宋智甲  王道聪  贾秋唤  岑况  储国强  孙青 《岩矿测试》2015,34(4):471-479

尿素络合法和5A分子筛法是常用的分离富集环境样品中正构烷烃的方法,但由于复杂的处理流程对于低含量正构烷烃的回收率普遍较低。本文通过优化尿素络合法分离富集正构烷烃的实验条件,建立了尿素络合法分离-气相色谱/同位素质谱分析土壤和植物中低含量正构烷烃单体碳同位素的方法。即采用正己烷-丙酮溶解样品,在4℃冰箱中与2 m L尿素-甲醇饱和溶液反应48 h;用去离子水溶解尿素络合物,加入正己烷后分离出有机相和水相,分别用正己烷、丙酮-正己烷萃取有机相和水相中的正构烷烃。中长链正构烷烃的回收率达79%~104%,高于5A分子筛法和已有尿素络合法的富集效果;单体碳同位素的分析精度为0.09‰~0.63‰(1σ)。利用改进的方法分析实际样品,大幅降低了未分峰和共流出物的干扰,提高了实际样品中ppm级中长链正构烷烃的回收率。  相似文献   

Research on Strong Earthquake Tendency on Active Tectonic Block Boundaries in the Chinese Mainland     

Zhang Langping  Li Zhixiong  Shao Zhigang  Yin Xiangchu 《中国地震研究》2011,25(2):189-200

Previous studies have shown that the active tectonic block boundaries in the Chinese mainland are the main belts and concentration areas of strong earthquakes occurring in the Chinese mainland.It is essential to carry out follow-up analysis of strong earthquake risk of active tectonic block boundaries.In this paper,we carry out the analysis on the tendency of strong earthquakes along each active tectonic block boundary from three aspects respectively,including the evolutionary characteristics of the Load/Un...  相似文献   

基于原地应力测量数据的中国大陆地壳上部应力状态研究   总被引：9，自引：2，他引：7       下载免费PDF全文

王艳华  崔效锋  胡幸平  谢富仁 《地球物理学报》2012,55(9):3016-3027

在两个水平主应力随深度呈线性增加的前提下,通过数学推导,建立了侧压系数、水平最大与水平最小主应力之比(σ_H/σ_h)以及剪应力相对大小μ_m等应力参数随深度变化的关系式.在此基础上,依据中国大陆1780条二维水压致裂和应力解除的原地应力测量数据,对多个应力参数随深度的变化进行了回归分析.结果显示,中国大陆地壳浅部的侧压系数随深度的变化呈完整的双曲线形态,通过稳定性检验说明,即使缺少较深的原地应力实测数据,只要有一定数量的测试深度超过1500 m的数据,仍然可以得到比较可信的侧压系数回归分析结果,在整个脆性上地壳的物性参数没有本质变化的前提下,可以利用地壳浅部的侧压系数回归分析结果推断脆性上地壳的2个水平主应力的取值范围;相对于侧压系数,在中国大陆地表以下几千米深度范围内,σ_HH/σ和μ_m的变化不大,更接近线性分布,σ_H/σ_h的拟合值在1.5左右,μ_m的拟合值在0.2左右,并且μ_m的线性集中程度更好.利用μ_m的大小来判断活动断裂的地震危险性具有一定合理性.  相似文献   

多方法联合分析未来地震发生趋势          下载免费PDF全文

余怀忠  程佳  张小涛  刘杰  李纲  张永仙 《地震工程学报》2012,34(1):1-9

综合多种前兆方法分析地震活动规律,研究目标地区未来地震发生的趋势。首先采用图像信息法(PI)进行扫描,从长期尺度上找出研究区域内地震活动异常的地区,并结合相关的活动断裂分布及区域地震活动确定未来地震的发震危险区;然后采用加卸载响应比(LURR)、态矢量(SV)、矩张量加速释放(AMR)等中短期前兆方法分析这些区域的地震发生可能,并对地震发生的相关信息做进一步估算;在空间上实现向地震危险区域的逐渐逼近,时间上实现从长期预测到中短期预测的自然过渡。作为回顾性震例研究,我们对近3年来发生在中国西部的强震(ML6.5)进行了检验,结果表明,相对于单一算法而言,将不同前兆方法适当组合结合能够更为明确地为未来地震危险性评估提供信息和约束。  相似文献   

中国集装箱多门户港口区域空间结构的形成与机理     

潘坤友  曹有挥  梁双波  魏鸿雁 《地理科学进展》2013,32(2):214-222

运用港口首位度和修正的赫希曼-赫芬达尔指数, 从箱流的角度对1998-2010 年中国集装箱港口体系的空间结构转型进行了定量测度。结果表明:① 集装箱港口体系的重心由珠三角地区向长三角地区缓慢转移;② 集装箱港口体系总体进入“边缘挑战阶段”, 箱流的分散化成为中国集装箱港口体系空间变化的主流倾向, 但7 大港区首位港的极辐作用存在显著差异;③ 中国集装箱港口体系空间结构呈现低级均衡、单门户、多门户并存的多样化特征, 其中, 长三角、珠三角地区形成集装箱多门户港口区域的空间结构已成事实。政府宏观调控与政策引导, 枢纽港资源瓶颈约束, 边缘港口的设施、服务趋同, 港航企业网络扩展和腹地交通网络拓展与完善等因素是多门户空间结构形成的主要动力。  相似文献   

美国西部地区加卸载响应比的时空演化及地震活动性分析     

张浪平  尹祥础  梁乃刚 《地震》2008,28(4):29-38

美国西部地区位于环太平洋地震带, 该地震带是地球上地震活动最为强烈的地带, 为了研究该地区的地震活动性, 对该地区进行了加卸载响应比的时空扫描, 考察了该地区加卸载响应比异常区域的时空演化; 并用2001—2006年的扫描结果与次年实际发生的5级以上地震进行对比, 发现绝大部分的强震都发生在前一年的预测区域内。 根据加卸载响应比的时空演化和该地区的最新扫描结果, 对未来地震活动性进行了分析。  相似文献   

Absolute parameters of four W UMa stars with extreme low mass ratios     

《New Astronomy》2022

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The Igarapé Weir decelerated transport of contaminated sediment in the Paraopeba River after the failure of the B1 tailings dam (Brumadinho)     

《国际泥沙研究》2023,38(5):673-697

The B1 dam of Córrego do Feijão Mine, owned by Vale, S.A. mining company and located on the Ferro-Carvão stream, collapsed and injected 2.8 Mm³ of clayey, silty, and sandy iron- and manganese-rich tailings into the Paraopeba River (Minas Gerais state, Brazil). The accident occurred on 25 January 2019 and the tailings have been co-transported with coarser natural sediment since then, being partly trapped in the Igarapé Weir reservoir located on the Paraopeba River nearly 45 km downstream the injection point. The general purpose of the current study was to model suspended sediment transport in the vicinity of the Igarapé Weir aiming to assess the concomitant barrier effect imposed by this structure. Specifically, the spatial distributions of suspended clay, silt, and very fine-grained sand fractions (CSS) of sediment were mapped around the Igarapé Weir under low-flow (16 m³/s) and high-flow (5 to 10,000 years return period stream discharge; 699–2,699 m³/s) regimes, using RiverFlow2D as the modelling tool. The concentrations of the various grain materials in the upstream and downstream sectors were quantified linking the barrier effect to concentration reductions in the direction of stream flow. It was also a study goal to calculate differences of iron and manganese concentrations in the sediment + tailings mixtures along the Paraopeba River. The study results showed reductions in the CSS between 6.6% and 18%, from upstream to downstream of the Igarapé Weir, related with backwater effects, free and submerged hydraulic jumps, bank sedimentation in periods of high flow, and streambed sedimentation controlled by channel sinuosity and tailings density. These reductions were accompanied by drops in the concentrations of iron and manganese present in the clay and silt fractions, which varied between 6% and 42% under low flows and between 16% and 44% under high flows. Bank sedimentation was viewed as a potential threat to the riparian vegetation in the long-term. Dredging is the potentially most effective mitigation measure to help lead the Paraopeba River to a pre-rupture condition. The retention of sediment + tailings transported in suspension is less effective than the trapping of bedload sediment + tailings behind the Igarapé weir. The efficacy of sediment trapping is expected to be larger for natural sediment because it is much coarser than the tailings. In that context, the simulations revealed for the low-flow period that 33.6% of the sediment deposition comprised suspended transport of natural sediment (thus, was comprised 66.4% of bedload transport), this proportion rose to 86.9% for mixtures of natural sediment + tailings, a result that did not differ much for the high-flow periods.  相似文献