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McNearney Lake is an acidic (pH=4.4) lake in the Upper Peninsula of Michigan with low acid neutralizing capacity (ANC=-38 eq L-1) and high SO inf4 sup2- and aluminium concentrations. Oligotrophy is indicated by high Secchi transparency and by low chlorophyll a, total phosphorus, and total nitrogen concentrations. The lake water is currently acidic because base cations are supplied to the lake water at a low rate and because SO inf4 sup2- from atmospheric deposition was not appreciably retained by the lake sediments or watershed and was present in the water column.This interdisciplinary paleolimnological study indicates that McNearney Lake is naturally acidic and has been so since at least 4000 years B.P., as determined from inferred-pH techniques based on contemporary diatom-pH relationships. Predicted pH values ranged from 4.7 to 5.0 over the 4000-year stratigraphy. Considerable shifts in species composition and abundance were observed in diatom stratigraphy, but present-day distributions indicate that all abundant taxa most frequently occur under acidic conditions, suggesting that factors other than pH are responsible for the shifts. The diatom-inferred pH technique as applied to McNearney Lake has too large an uncertainly and is not sensitive enough to determine the subtle recent changes in lakewater pH expected from changes in atmospheric deposition because: (1) McNearney Lake has the lowest pH in the contemporary diatom data set in the region and confidence intervals for pH predictions increase at the extremes of regressions; (2) other factors in addition to pH may be responsible for the diatom species distribution in the lake and in the entire northern Great Lakes region; (3) McNearney Lake has a well-buffered pH as a consequence of its low pH and high aluminium concentrations and is not expected to exhibit a large pH change as a result of changes in atmospheric deposition; and (4) atmospheric deposition in the region is modest and would not cause a pH shift large enough to be discernable in McNearney Lake.Elevated atmospheric deposition is indicated in recent sediments by Pb, V, and polycyclic aromatic hydrocarbon accumulation rates and to a lesser extent by those of Cu and Zn; however, these accumulation rates are substantially lower than those observed for acidified lakes in the northeastern United States. Although atmospheric loadings of materials associated with fossil fuel combustion have recently increased to McNearney Lake and apparently are continuing, the present study of the diatom subfossil record does not indicate a distinct, recent acidification (pH decrease).Order of the first two authors is alphabetical  相似文献   
23.
The mangrove or mud crab, Scylla serrata, is an important component of mangrove fisheries throughout the Indo-Pacific. Understanding crab diets and habitat use should assist in managing these fisheries and could provide additional justification for conservation of the mangrove ecosystem itself. We used multiple chemical tracers to test whether crab movements were restricted to local mangrove forests, or extended to include adjacent seagrass beds and reef flats. We sampled three mangrove forests on the island of Kosrae in the Federated States of Micronesia at Lelu Harbor, Okat River, and Utwe tidal channel. Samples of S. serrata and likely food sources were analyzed for stable carbon (δ13C), nitrogen (δ15N), and sulfur (δ34S) isotopes. Scylla serrata tissues also were analyzed for phosphorus (P), cations (K, Ca, Mg, Na), and trace elements (Mn, Fe, Cu, Zn, and B). Discriminant analysis indicated that at least 87% of the crabs remain in each site as distinct populations. Crab stable isotope values indicated potential differences in habitat use within estuaries. Values for δ13C and δ34S in crabs from Okat and Utwe were low and similar to values expected from animals feeding within mangrove forests, e.g., feeding on infauna that had average δ13C values near −26.5‰. In contrast, crabs from Lelu had higher δ13C and δ34S values, with average values of −21.8 and 7.8‰, respectively. These higher isotope values are consistent with increased crab foraging on reef flats and seagrasses. Given that S. serrata have been observed feeding on adjacent reef and seagrass environments on Kosrae, it is likely that they move in and out of the mangroves for feeding. Isotope mixing model results support these conclusions, with the greatest mangrove ecosystem contribution to S. serrata diet occurring in the largest mangrove forests. Conserving larger island mangrove forests (> 1 km deep) appears to support crab foraging activities.  相似文献   
24.
L.A. Sromovsky  P.M. Fry 《Icarus》2005,179(2):459-484
Near-infrared adaptive optics imaging of Uranus by the Keck 2 telescope during 2003 and 2004 has revealed numerous discrete cloud features, 70 of which were used to extend the zonal wind profile of Uranus up to 60° N. We confirmed the presence of a north-south asymmetry in the circulation [Karkoschka, E., 1998. Science 280, 570-572], and improved its characterization. We found no clear indication of long term change in wind speed between 1986 and 2004, although results of Hammel et al. [Hammel, H.B., Rages, K., Lockwood, G.W., Karkoschka, E., de Pater, I., 2001. Icarus 153, 229-235] based on 2001 HST and Keck observations average ∼10 m/s less westward than earlier and later results, and 2003 observations by Hammel et al. [Hammel, H.B., de Pater, I., Gibbard, S., Lockwood, G.W., Rages, K., 2005. Icarus 175, 534-545] show increased wind speeds near 45° N, which we do not see in our 2003-2004 observations. We observed a wide range of lifetimes for discrete cloud features: some features evolve within ∼1 h, many have persisted at least one month, and one feature near 34° S (termed S34) seems to have persisted for nearly two decades, a conclusion derived with the help of Voyager 2 and HST observations. S34 oscillates in latitude between 32° S and 36.5° S, with a period of ∼1000 days, which may be a result of a non-barotropic Rossby wave. It also varied its longitudinal drift rate between −20°/day and −31°/day in approximate accord with the latitudinal gradient in the zonal wind profile, exhibiting behavior similar to that of the DS2 feature observed on Neptune [Sromovsky, L.A., Limaye, S.S., Fry, P.M., 1993. Icarus 105, 110-141]. S34 also exhibits a superimposed rapid oscillation with an amplitude of 0.57° in latitude and period of 0.7 days, which is approximately consistent with an inertial oscillation.  相似文献   
25.
The Galileo Probe sampled Jupiter's atmosphere at the edge of a 5-μm hot spot, where it found very little cloud opacity above the 700 mb level. Only τ=1-2 at λ=0.5 μm was inferred from Net Flux Radiometer observations (Sromovsky et al. 1998, J. Geophys. Res.103, 22,929-22,977), in seeming conflict with Chanover et al. (1997, Icarus128, 294-305) who inferred τ=6-8 above the 700 mb level (at λ∼0.9 μm) from 893-nm and 953-nm WFPC2 observations of a group of hot spots. Postulating a heterogeneous cloud structure is one way to resolve the conflict. We obtained a more satisfying resolution by reinterpretation of the HST observations with Probe-compatible assumptions about the vertical distribution of cloud particles. Assuming a physically thin upper (putative NH3) cloud with adjustable optical depth and effective pressure (peff<440 mb) and a physically thin midlevel (putative NH4SH) cloud with adjustable optical depth but a fixed pressure of 1.2 bars, we are able to fit WPFC2 observations with probe-consistent opacities in hot spot regions. With the same cloud pressures, but higher middle cloud opacities, we are even able to fit the visibly bright regions. Little variability is seen in the upper cloud. Best fits to October 1995 WFPC2 observations in dark regions (5-μm hot spots) yielded τupper=1.3-1.9 at 0.9 μm and peff=240 mb−270 mb, while in visibly bright regions between hot spots we obtained τupper=1.6-2.2 and peff=250 mb−290 mb. May 1996 observations yielded slightly higher values of τupper (1.8-2.3 and 2.0-2.8) and peff (250 mb−310 mb and 265 mb−320 mb). We found that the most important variable parameter is the opacity of the middle cloud, which ra nged from τ=1, 2 in dark regions, to τ=8-30 in bright regions. From limb darkening characteristics, we inferred a wavelength-dependent haze opacity ranging from 0.2±0.05 at 660 nm to 0.35±0.05 at 953 nm, and an effective haze pressure near 120 mb. We did not find it necessary to use low single scattering albedos that require effective imaginary indices, that are several orders of magnitude larger than the values of the main putative cloud components.  相似文献   
26.
Flooding associated with tropical storms can cause extreme perturbations in riverine and coastal ecosystems. Measuring isotope variability of tropical storm events can help investigate the impacts of flooding. We measured the water isotope composition (δD and δ18O) of rain and associated floodwater collected during two storms and subsequent major and minor flooding events in the subtropical coast of eastern Australia. Compared with baseline regional rainfall isotope values of ?15.0 ± 1.9‰ for δD and ?3.3 ± 0.2‰ for δ18O, floodwater had lower values with ?33.8 ± 2.5‰ δD and ?5.1 ± 0.4‰ δ18O for the major flood and ?29.4 ± 1.0‰ δD and ?4.6 ± 0.1‰ δ18O for the minor flood. The low isotope composition of the floodwater was associated with the transport of large quantities of suspended sediments, with sediment loads 30 to 70 times larger than during base flow conditions. Floods carried up to 35% of the annual phosphorus and up to 208% of the currently calculated average annual nitrogen load of the Brisbane River. The dramatic changes caused by a rapid increase in discharge from 2 to 2015 m3 s?1 over 2 days in the major flood would have major consequences in riverine and coastal ecosystems of the region. These changes could potentially be traced using the isotope composition of the floodwaters. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   
27.
This study tested the feasibility of using 3-D laser imaging to measure the bulk density of iron meteorites. 3-D laser imaging is a technique in which a 3-D model of an object is built after aligning and merging individual detailed images of its surface. Assuming that the mass of the object is known, the volume of the model is calculated by software and an estimate of bulk density can be obtained by dividing mass by volume. The 3-D laser imaging technique was used to determine the density of 46 fragments from 11 different iron meteorites. The technique proved to be robust and was applied successfully to study samples ranging close to four orders of magnitude in mass (8 g to 156 kg) and exhibiting a variety of surface textures (e.g., cracks, regmaglypts), reflectivities (e.g., polished surfaces, fusion crust, rust), and morphologies (e.g., sharp angular edges, shrapnel tendrils). Three metrics were considered to estimate the error associated with density measurements: the range accuracy of the laser camera, image alignment error, and inter-operator variability during model building. Inter-operator variability was the largest source of error and was highest when assembling models of samples which either lacked distinctive features or were very complex in shape. Excluding two anomalous Zagora samples where silicate inclusions might have lowered density, the densities measured using 3-D laser imaging ranged from 6.98 to 7.93 g cm−3, consistent with previous studies. There is overlap between bulk density and iron meteorite class, and therefore bulk density cannot be used in isolation as a classification criterion. It is a good indicator, however, of weathering effects and of the potential presence of low-density inclusions.  相似文献   
28.
A GSFC Super Loki optical ozonesonde instrument was flown as part of the ozone sensor intercomparison balloon campaign at Gap, France, in June 1981. A primary objective was to confirm biases between external absorption techniques, such as the GSFC sonde, and in situ techniques, which include ECC, Mast-Brewer, and DASIBI sondes. Ozone distributions were obtained with the GSFC sonde on three of the four ascent-descent legs of the first flight on 19 June. Ozone densities were measured redundantly over altitudes from 22 to 32 km using filters centered at 303 and 300 nm. The three profiles obtained by averaging the data from the two channels are in close agreement with an average S.E. of 1.4%. However, small but consistent differences were found between the ozone densities measured at the two wavelengths. The average difference is 5% using Vigroux cross sections and 4% using preliminary Bass cross sections. The integral ozone amount above the first ceiling altitude of 32.85 km was determined by the Langley plot method to be 45 D.U. The total ozone derived by integrating the optical ozonesonde and ECC profiles is within 2% of the Chiran Dobson Spectrophotometer observation based on a pre-campaign calibration but is 9% greater than the amount derived using a post-campaign calibration.  相似文献   
29.
For a homogeneously deformed rock composed initially of an isotropic distribution of object shapes, finite strain may be determined from the correlation between the orientations of either two-dimensional or one-dimensional sample cuts and the frequencies with which they intersect marker objects. Mimran previously published an incorrect method for planar samples under the heading ‘density distribution technique’. Methods are described by which the three-dimensional strain may be directly determined from six general samples, either linear or planar. Construction of two-dimensional ellipses as an intermediate step is unnecessary and enforces practical difficulties.These methods may be simplified by use of samples parallel to known principal axes or planes of the finite strain. In this case the same large errors may arise from slight misorientation of samples as with other methods of strain measurement. A new quick method is proposed, combining linear and planar measurements of frequencies of intersected objects, which is thought to be the first method to circumvent a large part of the error from this error source. For example, if true X:Z ratio is 9 : 1, and orientations in the XZ plane are misjudged by 8°, normal methods give 38% error where the new method gives, with care, an error of 1.9%. For methods of strain measurement such as are described here the concept of strain ellipsoid is unnecessarily limiting, and should be abandoned.  相似文献   
30.
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