Kaidun meteorite: Crystals of oxides in cavities     

A. V. Ivanov  M. E. Zolensky  N. N. Kononkova  S. V. Yang  I. A. Stroganov 《Geochemistry International》2006,44(3):249-257

Cavities in two texturally and genetically distinct clasts of the Kaidun meteorite were found out to contain crystals of distinct morphology, but of a similar composition. Cavities in chondrite breccia #d3A contain thin (<4 μm) elongated (up to 25 μm long) crystals that grew perpendicular to the walls of the cavity. The walls of the cavities in partly fused clast #d(3–5)D are covered with clusters of acicular crystals. In both clasts, the crystals are covered by films of phyllosilicates and always have a composition approximated by the formula (Mg,Fe,Mn)₅Al₂O₈·nH₂O. No mineral phase of this composition has ever been found in nature. The genesis of the mineral phases in the cavities is thought to be related to the crystallization from a fluid of similar composition. The fluid was produced during the cooling of the melt that produced clast #d(3–5)D. The unusual composition of the crystals testifies that this fluid had an unusual composition. This can be explained by the unique nature of clast #d(3–5)D, for which there are good reasons to propose a Martian origin.  相似文献   

Peridotite-gabbro-trondhjemite association of the Mid-Atlantic Ridge between 12°58′ and 14°45′N: Ashadze and Logachev hydrothermal vent fields     

S. A. Silantyev  E. A. Krasnova  M. Cannat  N. S. Bortnikov  N. N. Kononkova  V. E. Beltenev 《Geochemistry International》2011,49(4):323-354

This study aimed at reconstructing the sequence of events in the magmatic and metamorphic evolution of peridotites, gabbroids, and trondhjemites of the oceanic core complexes of the Ashadze and Logachev hydrothermal vent fields. The study object was the collections of plutonic rocks made during cruises 22 and 26 of the R/V Professor Logachev, Cruise 41 of the R/V Akademik Mstislav Keldysh, and the Russian-French expedition Serpentine aboard the R/V Pourquoi pas? The data reported here suggest that the oceanic core complexes of the Ashadze and Logachev fields were formed via the same scenario in the two MAR regions. On the other hand, the analysis of petrological and geochemical characteristics of the rocks indicated that the oceanic core complexes of the MAR axial zone between 12°58′ and 14°45′N show a pronounced petrological and geochemical heterogeneity manifested in variations in the degree of depletion of mantle residues and the Nd isotopic compositions of the rocks of the gabbro-peridotite association. The trondhjemites of the Ashadze hydrothermal field can be considered as partial melting products of gabbroids under the influence of hydrothermal fluid. It was supposed that the presence of trondhjemites in the MAR oceanic core complexes can be used as a marker for the highest temperature deep-rooted hydrothermal systems. Perhaps, the region of the MAR axial zone in which petrologically and geochemically contrasting oceanic core complexes are spatially superimposed served as sites for the development of large hydrothermal clusters with a considerable ore-forming potential.  相似文献   

Mineralogical and geochemical zoning of sediments at the Semenov cluster of hydrothermal fields, 13°31′-13°30′ N, Mid-Atlantic Ridge     

V. Yu. Rusakov  V. V. Shilov  B. N. Ryzhenko  I. F. Gablina  I. A. Roshchina  T. G. Kuz’mina  N. N. Kononkova  I. G. Dobretsova 《Geochemistry International》2013,51(8):646-669

New material from eight columns recovered during Cruise 32 of the R/V Professor Logachev in 2009 was used to explore the lithological facies, biostratigraphy, mineralogy, and geochemistry of sediments from the northwestern (active) and eastern (inactive) hydrothermal vent fields of the Semenov cluster. Mineral types of sediments were distinguished, and a general scheme was proposed for the vertical structure of the hydrothermal-sedimentary sequence overlying massive sulfide ores. It was found that the ore-bearing sediments exhibit a vertical zoning in the distribution of mineral assemblages, which are controlled by oxygen activity. The mechanisms of the formation of atacamite, CuCl₂ · 3Cu(OH)₂, which is a widespread mineral in red iron-oxide bodies replacing sulfides (gossans), were evaluated.  相似文献   

Analytical results for the material of the Chelyabinsk meteorite   总被引：1，自引：0，他引：1  

E. M. Galimov  V. P. Kolotov  M. A. Nazarov  Yu. A. Kostitsyn  I. V. Kubrakova  N. N. Kononkova  I. A. Roshchina  V. A. Alexeev  L. L. Kashkarov  D. D. Badyukov  V. S. Sevast’yanov 《Geochemistry International》2013,51(7):522-539

This paper presents the results of the mineralogical, petrographic, elemental, and isotopic analysis of the Chelyabinsk meteorite and their geochemical interpretation. It was shown that the meteorite can be assigned to LL5-group ordinary chondrites and underwent moderate shock metamorphism (stage S4). The Chelyabinsk meteorite contains a significant fraction (approximately one-third by volume) of shock-melted material similar in composition to the main volume of the meteorite. The results of isotopic analysis suggest that the history of meteorite formation included an impact event approximately 290 Ma ago.  相似文献   

Solution behavior of C-O-H volatiles in FeO-Na2O-Al2O3-SiO2 melts in equilibrium with liquid iron alloy and graphite at 4 GPa and 1550°C     

A. A. Kadik  V. V. Koltashev  E. B. Kryukova  V. G. Plotnichenko  T. I. Tsekhonya  N. N. Kononkova 《Geochemistry International》2014,52(9):707-725

In order to elucidate the solution behavior of carbon and hydrogen in iron-bearing magmatic melts in equilibrium with a metallic iron phase and graphite at oxygen fugacity (fO₂) values 2–5 orders of magnitude below the iron-wustite buffer equilibrium, fO₂ (IW), experiments were carried out at 4 GPa and 1550°C with melts of FeO-Na₂O-SiO₂-Al₂O₃ compositions. Melt reduction in response to an fO₂ decrease was accompanied by a decrease in FeO content. The values of fO₂ in the experiments were determined on the basis of equilibrium between Fe-C-Si alloy and silicate liquid. Infrared and Raman spectroscopy showed that carbon compounds are formed in FeO-Na₂O-SiO₂-Al₂O₃ melts: CH₄ molecules, CH₃ complexes (Si-O-CH₃), and complexes with double C=O bonds. The content of CO₂ molecules and carbonate ions (CO ₃ ^2? ) is very low. In addition to carbon-bearing compounds, dissolved hydrogen occurs in melt as H₂ and H₂O molecules and OH^? groups. The spectral characteristics of FeO-Na₂O-SiO₂-Al₂O₃ glasses indicate the occurrence of redox reactions in the melt, which are accompanied at decreasing fO₂ by a significant decrease in H₂O and OH^?, a slight decrease in H₂, and a significant concomitant increase in CH₄ content. The content of species with the double C=O bond increases considerably at decreasing fO₂ and reaches a maximum at ΔlogfO₂(IW) = ?3. According to the obtained IR spectra, the total water content (OH^? + H₂O) in the glasses is 1.2–5.8 wt % and decreases with decreasing fO₂. The high H₂O contents are due largely to oxygen release related to FeO reduction in the melt. The total carbon content at high H₂O (4.9–5.8 wt %) is approximately 0.4 wt %. The carbon content in liquid iron alloys depends on silicon content and, probably, oxygen solubility and ranges from 0.3 to 3.65 wt %. Low carbon contents were observed at a significant increase in Si content in liquid iron alloy, which may be as high as ～13 wt % at fO₂ values 4–5 orders of magnitude below fO₂(IW).  相似文献   

Mechanisms of formation of barium-rich phlogopite and strontium-rich apatite during the final stages of alkaline magma evolution     

I. P. Solovova  A. V. Girnis  I. D. Ryabchikov  N. N. Kononkova 《Geochemistry International》2009,47(6):578-591

Carbonatite veinlets in fergusite from the Dunkeldyk potassium-rich basaltoid complex (southeastern Pamirs) are composed of clinopyroxene, phlogopite, and apatite phenocrysts embedded in a crystallized calcite-bearing groundmass. The examination of back-scattered electron images revealed areas of significantly different compositions in fluorapatite and fluorphlogopite. The content of BaO in the phlogopite ranges from 0.68 to 10.9 wt %. There are also variations in MgO and F contents. The maximum BaO content corresponds to high mole fractions of the Ba end member kinoshitalite (up to 0.24) in the phlogopite. The zoned fluorapatite phenocrysts are rich in SrO (0.77–25.4 wt %). An increase in SrO content is accompanied by an increase in Ce₂O₃, La₂O₃, and BaO and a distinct decrease in CaO. Most of the apatite grains are rimmed by elongated colorless crystals showing the maximum SrO contents. Based on the experimentally determined Ba and Sr partition coefficients between these minerals, silicate and carbonate melts, and fluid, a model was proposed for the enrichment of phases in these trace elements. It was shown that the mineral-forming media of the Ba-rich phlogopites was a residual melt enriched in volatiles (including F) and fluid-mobile elements. During that stage, the decomposition reactions of early Ba-bearing feldspars with subsequent incorporation of BaO in Ba-rich phlogopites played an important role. The mechanism of formation of Sr-rich apatites is fundamentally different: early apatite grains with moderate Sr contents recrystallized under the influence of Sr-rich fluids released during the late magmatic stage. Thus, despite their close association in a single rock, the Ba-bearing phlogopite and Sr-rich apatite were formed by significantly different mechanisms. Our previous investigations of melt and fluid inclusions in minerals from the rocks of the Dunkeldyk complex and the results obtained in this study allowed us to suggest that the barium, fluorite-carbonatite, and rare metal mineralization occurring in the region developed owing to the prolonged evolution of primary magmas, resulting in the formation of melt-solutions (brines) and hydrothermal systems.  相似文献   

Conditions of the formation and composition of noritic magmas of the Kivakka intrusion,north Karelia: Evidence from melt inclusion study     

O. A. Andreeva  V. B. Naumov  I. A. Andreeva  N. N. Kononkova 《Geochemistry International》2010,48(2):187-193

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U-Pb zircon age of gabbroids of the Ust’-Belaya mafic-ultramafic massif (Chukotka) and its interpretation     

G. V. Ledneva  B. A. Bazylev  V. V. Lebedev  N. N. Kononkova  A. Ishiwatari 《Geochemistry International》2012,50(1):44-53

The Ust’-Belaya mafic-ultramafic massif is assigned to the Western Koryak fold belt and largely composed of residual spinel peridotites, layered spinel and plagioclase peridotites, and gabbros. These rocks are crosscut by occasional plagiogranite and diorite veins and exhibit locally a close spatial association with basalts and carbonate-sedimentary deposits of Late Devonian and Early Carboniferous age. Based on this evidence, the massif was ascribed to the pre-Late Devonian ophiolite association. Our study presents new U-Pb SHPIMP II zircon ages and petrographic and mineralogical data on samples of the layered amphibole gabbro and vein diorite from the Ust’-Belaya massif. The approximate concordant U-Pb age corresponding to a timing of of amphibole gabbro crystallization is 799 ± 15 Ma, and the concordant U-Pb age reflecting a timing of of vein diorite crystallization is 575 ± 10 Ma. These ages coupled with geological studies of the massif, petrological and mineralogical investigations of the dated samples, as well as literature data on the petrology of peridotites and the age of formed plagiogranites suggest that the peridotites and layered gabbros of the Ust’-Belaya massif were formed by the Late Riphean, whereas the vein diorite and plagiogranite were resulted from a later (Vendian-Cambrian) magmatic stage. The peridotites and gabbros of the massif display no genetic relationship with spatially associated basalts and sedimentary rocks and, thus, they cannot be considered as members the pre-Late Devonian ophiolitic association. The results of this study will inevitably lead to a significant revision of geological and geodynamic interpretations of the Ust’-Belaya mafic-ultramafic massif. However, uneven study of the Precambrian complexes of the Koryak and Chukchi areas, their evolution in different structures of the region cannot yet be described by a single geodynamic scenario.  相似文献   

A new occurrence of alkaline magmatism on the Kola Peninsula: An agpaitic dyke in the Kandalaksha region     

M. I. Akimenko  L. N. Kogarko  N. V. Sorokhtina  N. N. Kononkova  V. P. Mamontov 《Doklady Earth Sciences》2014,458(1):1125-1128

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Rubidium mineralization in rare-element granitic pegmatites of the Voron’i tundras,Kola Peninsula,Russia     

I. V. Pekov  N. N. Kononkova 《Geochemistry International》2010,48(7):695-713

Rare-element pegmatites in the Voron’i tundras, Kola Peninsula, Russia, contain late abundant Rb mineralization. Individual Rb minerals are Rb-dominant feldspars and micas that form continuous solid solution series with K analoques. The feldspars contain from 17 to 86 mol % RbAlSi₃O₈ (5.5–25 wt % Rb₂O) and 1–5 mol % CsAlSi₃O₈, and the muscovite contains 2.6–9.4 wt % Rb₂O. The Li micas are members of the lepidolite-polylithionite series and their Rb-dominant analogues. They form a continuous series of solid solutions with the Rb concentrations varying from 0.09 to 0.54 apfu., K concentrations varying from 0.82 to 0.33 apfu, and Cs concentrations varying from 0.02 to 0.18 apfu The maximum Rb₂O concentration in the newly found mineral voloshinite, an Rb analogue of lepidolite, is 12.2 wt %. The Rb-rich feldspars and micas sometimes crystallized directly or were formed via cation exchange with the young fluid. The Rb minerals are spatially and genetically closely associated with pollucite. It is supposed that initially Rb was contained in a high-temperature pollucite solid solution and was released from it at decreasing temperature as a result of a reaction with the aqueous fluid and notably enriched the latter. It is shown that Rb mineralization is generally typical of pollucite-bearing pegmatites.  相似文献