Mass fluxes of xenobiotics below cities: challenges in urban hydrogeology     

Mario Schirmer  Frido Reinstorf  Sebastian Leschik  Andreas Musolff  Ronald Krieg  Gerhard Strauch  John W. Molson  Marion Martienssen  Kristin Schirmer 《Environmental Earth Sciences》2011,64(3):607-617

Urban areas are the focus of major ecological, social and economical activity. They are thus also prime locations of increasing conflict with regard to water use and water protection. As a direct and/or indirect consequence of urban land use and human activity, urban water systems are frequently polluted with organic contaminants including waste water-born xenobiotics such as pharmaceuticals, personal care products (collectively known as PPCPs) and endocrine-active substances. This study reviews new integrated methodologies including flux calculations as well as chemical investigations for determining the impact of human activities on urban water systems and on processes within the urban watershed. The use of indicator substances, representing different contaminant sources and pathways, integral pumping tests and mass balance approaches are suitable alternatives within these environments. The issues are explored using contaminant mass balance examples from Halle/Saale and Leipzig, Germany.  相似文献   

Formation of U-depleted rhyolite from a basanite at El Hierro, Canary Islands   总被引：2，自引：0，他引：2  

Olgeir Sigmarsson  Didier Laporte  Marion Carpentier  Bertrand Devouard  Jean-Luc Devidal  Joan Marti 《Contributions to Mineralogy and Petrology》2013,165(3):601-622

Phonolite and trachyte are the felsic magmas of the alkaline magma suites, which characterize the Canary Islands. The October 2011 submarine eruption off El Hierro, the westernmost island, nevertheless, produced a small volume of rhyolitic magma. The rhyolite occurred as highly vesicular, white coloured pumices enveloped in and mingled with darker coloured basanitic pumice. The basanitic pumice is relatively crystal poor with a few euhedral olivines (mostly Fo_77–79), clinopyroxenes and Fe-rich spinels, whereas very rare olivine of same composition is found together with equally rare Fe-sulphide and FeTi-rich oxides in the rhyolite. The Fe–Mg exchange equilibrium in the oxides permits to calculate an equilibrium temperature of 970–890 °C for the rhyolite, in agreement with quartz-melt equilibrium at ca. 930 °C. A striking mineralogical feature of the rhyolite is the presence of rounded to contorted grains of milky quartz, which are xenocrysts incorporated and partly dissolved into the magma. Analyses of residual volatile concentrations in the glasses show that the rhyolite melt was highly degassed, whereas the basanitic glass still has important halogen concentrations. Trace element patterns of the mafic glasses and their elevated incompatible element concentrations are typical of the western Canary Island basanites. In contrast, the trace element composition of the rhyolite shows surprisingly low concentrations for all elements except the most incompatible ones (e.g. Rb, Ba, K and Th). All other measured LILE, HFSE and REE have significantly lower concentration than the basanitic counterpart that can be explained by fractionation of accessory phases (1 % apatite, 1 % sphene and 0.1 % zircon). Surprisingly, low U concentration is presumably related to elevated oxygen fugacity in the rhyolite, causing U to be in a hexavalent state, and fluxing of F-rich gas leading to volatilization of UF₆, known to emanate at low temperature. The results suggest that a gas-rich basanitic melt remobilized a small volume of stagnant rhyolitic melt formed by incorporation of approximately 10 % quartz-rich sediment into a late differentiate of trachytic composition. Sediments at the interface of an old oceanic crust adjacent to a continental shield and younger volcanic island are likely to act as magma traps were sediment assimilation may alter the mantle-derived magma composition. Quartz assimilation thus explains the production of rhyolite magma in a volcanic island characterized by an alkaline magma series from primitive basanites to trachytes.  相似文献   

Carbon Sequestration and Release from Antarctic Lakes: Lake Vida and West Lake Bonney (McMurdo Dry Valleys)     

G. M. Marion  A. E. Murray  B. Wagner  C. H. Fritsen  F. Kenig  P. T. Doran 《Aquatic Geochemistry》2013,19(2):135-145

Perennial ice covers on many Antarctic lakes have resulted in high lake inorganic carbon contents. The objective of this paper was to evaluate and compare the brine and CO₂ chemistries of Lake Vida (Victoria Valley) and West Lake Bonney (Taylor Valley), two lakes of the McMurdo Dry Valleys (East Antarctica), and their potential consequences during global warming. An existing geochemical model (FREZCHEM-15) was used to convert measured molarity into molality needed for the FREZCHEM model, and this model added a new algorithm that converts measured DIC into carbonate alkalinity needed for the FREZCHEM model. While quite extensive geochemical information exists for ice-covered Taylor Valley lakes, such as West Lake Bonney, only limited information exists for the recently sampled brine of >25 m ice-thick Lake Vida. Lake Vida brine had a model-calculated pCO₂ = 0.60 bars at the field pH (6.20); West Lake Bonney had a model-calculated pCO₂ = 5.23 bars at the field pH (5.46). Despite the high degree of atmospheric CO₂ supersaturation in West Lake Bonney, it remains significantly undersaturated with the gas hydrate, CO₂·6H₂O, unless these gas hydrates are deep in the sediment layer or are metastable having formed under colder temperatures or greater pressures. Because of lower temperatures, Lake Vida could start forming CO₂·6H₂O at lower pCO₂ values than West Lake Bonney; but both lakes are significantly undersaturated with the gas hydrate, CO₂·6H₂O. For both lakes, simulation of global warming from current subzero temperatures (?13.4 °C in Lake Vida and ?4.7 °C in West Lake Bonney) to 10 °C has shown that a major loss of solution-phase carbon as CO₂ gases and carbonate minerals occurred when the temperatures rose above 0 °C and perennial ice covers would disappear. How important these Antarctic CO₂ sources will be for future global warming remains to be seen. But a recent paper has shown that methane increased in atmospheric concentration due to deglaciation about 10,000 years ago. So, CO₂ release from ice lakes might contribute to atmospheric gases in the future.  相似文献   

Changes in Nutrient Biogeochemistry in Response to the Regression of Zostera noltii Meadows in the Arcachon Bay (France)     

Marie-Lise Delgard  Bruno Deflandre  Jonathan Deborde  Marion Richard  Céline Charbonnier  Pierre Anschutz 《Aquatic Geochemistry》2013,19(3):241-259

From 1989 to 2007, a severe decline in Zostera noltii meadows was reported in the Arcachon Bay, with an accelerated regression after 2005. We investigated the inter-annual variability of the biogeochemistry of the sediment in an area affected by seagrass decline. In late summer and in winter of the years 2006, 2010, and 2011, sediment cores were collected at low tide on vegetated and adjacent non-vegetated sediments located in the eastern part of the Arcachon Bay. The geochemical analyses of sediment solid-phase organic carbon, reactive P and Fe, and the pore water concentrations of Fe²⁺, DIP, and NH₄ ⁺ are presented. The changes in the chemistry of sediment and pore water between 2006 and 2010 are interpreted as a consequence of the decrease in the Z. noltii biomass between 2006 and 2010. The absence of significant seasonal variations in biomass throughout the growth period (March–September) in 2011 is most likely related to the regression of Z. noltii meadow that strongly affects the study area. In contrast to the healthy meadow in 2006, the declining meadow favored the dissolution of sedimentary particulate phosphorus in winter. In late summer, the low biomass of seagrass resulted in a net release of ammonium in the pore water of the upper 20 cm of sediment. This study clearly shows that seagrass decay may enhance nutrient release in sediments, resulting in a significant supply of phosphorus to the water column of a magnitude comparable to annual inputs to the lagoon from the rivers and the tidal pump.  相似文献   

Fluvial processes and environmental change: A.G. Brown, T.A. Quine (Eds.). Wiley, Chichester, United Kingdom, 1999, 413 pp. Price US$160.00 (hardcover). ISBN 0-471-985481-1     

D. A. Marion 《Geomorphology》2001,36(3-4)

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A review of the LATEX project: mesoscale to submesoscale processes in a coastal environment   总被引：1，自引：1，他引：0  

Anne A. Petrenko  Andrea M. Doglioli  Francesco Nencioli  Marion Kersalé  Ziyuan Hu  Francesco d’Ovidio 《Ocean Dynamics》2017,67(3-4):513-533

The main objective of the LAgrangian Transport EXperiment (LATEX) project was to study the influence of coastal mesoscale and submesoscale physical processes on circulation dynamics, cross-shelf exchanges, and biogeochemistry in the western continental shelf of the Gulf of Lion, Northwestern Mediterranean Sea. LATEX was a five-year multidisciplinary project based on the combined analysis of numerical model simulations and multi-platform field experiments. The model component included a ten-year realistic 3D numerical simulation, with a 1 km horizontal resolution over the gulf, nested in a coarser 3 km resolution model. The in situ component involved four cruises, including a large-scale multidisciplinary campaign with two research vessels in 2010. This review concentrates on the physics results of LATEX, addressing three main subjects: (1) the investigation of the mesoscale to submesoscale processes. The eddies are elliptic, baroclinic, and anticyclonic; the strong thermal and saline front is density compensated. Their generation processes are studied; (2) the development of sampling strategies for their direct observations. LATEX has implemented an adaptive strategy Lagrangian tool, with a reference software available on the web, to perform offshore campaigns in a Lagrangian framework; (3) the quantification of horizontal mixing and cross-shelf exchanges. Lateral diffusivity coefficients, calculated in various ways including a novel technique, are in the range classically encountered for their associated scales. Cross-shelf fluxes have been calculated, after retrieving the near-inertial oscillation contribution. Further perspectives are discussed, especially for the ongoing challenge of studying submesoscale features remotely and from in situ data.  相似文献   

Hydrodynamic time parameters response to meteorological and physical forcings: toward a stagnation risk assessment device in coastal areas     

Drouzy  Marion  Douillet  Pascal  Fernandez  Jean-Michel  Pinazo  Christel 《Ocean Dynamics》2019,69(8):967-987

Ocean Dynamics - Identifying zones of stagnation and deposition of terrigenous matter or contaminants induced by human activity is a key issue in coastal areas. In this paper, circulation processes...  相似文献   

Investigating suspended particulate matter in coastal waters using the fractal theory     

Chapalain  Marion  Verney  Romaric  Fettweis  Michael  Jacquet  Matthias  Le Berre  David  Le Hir  Pierre 《Ocean Dynamics》2019,69(1):59-81

Ocean Dynamics - Suspended particulate matters (SPM) in coastal waters were investigated with an approach combining suspended particulate matter concentrations (SPMCs) measured by an optical...  相似文献   

Late Pleistocene–Holocene environmental and climatic history of a freshwater paramo ecosystem in the northern Andes     

Luisa Patiño  Maria Isabel Velez  Marion Weber  César A. Velásquez-r  Santiago David  Manuela Rueda  Ivonne Castañeda  Diana Arboleda 《第四纪科学杂志》2020,35(8):1046-1056

This study presents the first multi-proxy palaeoenvironmental and palaeoclimatic history for northern South America based on the palaeolimnological reconstruction of a pond located in a dry paramo at 3570 masl. During the Last Glacial Maximum (LGM), the study area was under glacial conditions, then during global events Heinrich Stadial 1 (HS1), Bølling–Allerød (BA), and the Younger Dryas (YD), the pond expanded, accumulation rates and proxies for erosion reached the highest values, indicative of humid conditions, with maxima in humidity during the BA and YD. Dry conditions and pond desiccation occurred in the Greenlandian–Northgrippian and by 6010 cal a bp the area was transformed into the mire of today. Comparisons with records from other sites in South America indicate that changes in humidity are most likely controlled by the Intertropical Convergence Zone, mainly during the glacial and postglacial, and by changes in the Pacific Ocean, more pronounced after the YD.  相似文献   

Calculation of equilibria in CO<Subscript>2</Subscript>–water–salt systems using the Frezchem model     

M. V. Mironenko  V. B. Polyakov  G. M. Marion 《Geochemistry International》2016,54(9):824-828

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