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21.
金刚石及其寄主岩石是人类认识地球深部物质组成和性质、壳幔和核幔物质循环重要研究对象。本文总结了中国不同金刚石类型的分布,着重对比了博茨瓦纳和中国含金刚石金伯利岩的地质特征,取得如下认识:(1)博茨瓦纳含矿原生岩石仅为金伯利岩,而中国含矿岩石成分复杂,金伯利岩主要出露在华北克拉通,展布于郯庐、华北中央和华北北缘金伯利岩带,具有工业价值的蒙阴和瓦房店矿床分布于郯庐金伯利岩带中;钾镁煌斑岩主要出露在华南克拉通,重点分布在江南和华南北缘钾镁煌斑岩带中;(2)钙钛矿原位U-Pb年龄和Sr、Nd同位素显示,86~97 Ma奥拉帕金伯利岩群和456~470 Ma蒙阴和瓦房店金伯利岩均具有低87Sr/86Sr(0.703~0.705)和中等εNd(t)(-0.09~+5)特征,指示金伯利岩浆源自弱亏损地幔或初始地幔源区;(3)博茨瓦纳金伯利岩体绝大多数以岩筒产出,而中国以脉状为主岩筒次之;博茨瓦纳岩筒绝大部分为火山口相,中国均为根部相,岩筒地表面积普遍小于前者;(4)奥拉帕A/K1和朱瓦能金伯利岩体是世界上为数不多的主要产出榴辉岩捕虏体和E型金刚石的岩筒之一,而同位于奥拉帕岩群的莱特拉卡内、丹姆沙和卡罗韦岩体与我国郯庐带的金伯利岩体类似,均主要产出地幔橄榄岩捕虏体以及P型和E型金刚石;(5)寻找含矿金伯利岩重点注意以下几点:克拉通内部和周缘深大断裂带是重要的控岩构造;镁铝榴石、镁钛铁矿、铬透辉石、铬尖晶石和铬金红石等是寻找含金刚石金伯利岩重要的指示矿物;航磁等地球物理测量需与土壤取样找矿方法相结合才能取得更好效果;(6)郯庐金伯利岩带、江南钾镁煌斑岩带和塔里木地块是中国重要含矿岩石的找矿靶区,冲积型金刚石成矿潜力巨大。 相似文献
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金刚石矿是辽宁省的重要矿产之一,辽宁瓦房店地区已探明的原生金刚石矿资源/储量占中国金刚石资源量的一半以上。通过开展三维建模工作,对该区金伯利岩管的形态、深部找矿方向等提出了一些新的认识。研究认为,三维模型可以更好地展示金伯利岩型金刚石矿体的空间展布形态,并可为勘查工作提出指导性意见。 相似文献
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Conventional diamond exploration seldom searches directly for diamonds in rock and soil samples. Instead, it focuses on the search for indicator minerals like chrome spinel, which can be used to evaluate diamond potential. Chrome spinels are preserved as pristine minerals in the early Paleozoic (∼465 Ma), hydrothermally altered, Group I No. 30 pipe kimberlite that intruded the Neoproterozoic Qingbaikou strata in Wafangdian, North China Craton (NCC). The characteristics of the chrome spinels were investigated by petrographic observation (BSE imaging), quantitative chemical analysis (EPMA), and Raman spectral analysis. The results show that the chrome spinels are mostly sub-rounded with extremely few grains being subhedral, and these spinels are macrocrystic, more than 500 µm in size. The chrome spinels also have compositional zones: the cores are classified as magnesiochromite as they have distinctly chromium-rich (Cr2O3 up to 66.56 wt%) and titanium-poor (TiO2 < 1 wt%) compositions; and the rims are classified as magnetite as they have chromium-poor and iron-rich composition. In the cores of chrome spinels, compositional variations are controlled by Al3+-Cr3+ isomorphism, which results in a strong Raman spectra peak (A1g mode) varying from 690 cm−1 to 702.9 cm−1. In the rims of chrome spinel, compositional variations result in the A1g peak varying from 660 cm−1 to 672 cm−1. The morphology and chemical compositions indicate that the chrome spinels are mantle xenocrysts. The cores of the spinel are remnants of primary mantle xenocrysts that have been resorbed, and the rims were formed during kimberlite magmatism. The compositions of the cores are used to evaluate the diamond potential of this kimberlite through comparison with the compositions of chrome spinels from the Changmazhuang and No. 50 pipe kimberlites in the NCC. In MgO, Al2O3 and TiO2 versus Cr2O3 plots, the chrome spinels from the Changmazhuang and No. 50 pipe kimberlites are mostly located in the diamond stability field. However, only a small proportion of chrome spinels from No. 30 pipe kimberlite have same behavior, which indicates that the diamond potential of the former two kimberlites is greater than that of the No. 30 pipe kimberlite. This is also supported by compositional zones in the spinel grains: there is with an increase in Fe3+ in the rims, which suggests that the chrome spinels experienced highly oxidizing conditions. Oxidizing conditions may have been imparted by fluids/melts that have a great influence on diamond destruction. Here, we suggest that chrome spinel compositions can be a useful tool for identifying the target for diamond potential in the North China Craton. 相似文献
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Picroilmenite samples from five kimberlite pipes of the Yakutian kimberlite province have been studied. Point microprobe analyses of two mutually perpendicular profiles of each sample were carried out to study the compositional inhomogeneity of picroilmenite. Thermomagnetic curves were also recorded for each sample. A model for the processing of thermomagnetic curves is proposed on the basis of the relationship between the Curie point of picroilmenite and the content of the hematite end-member. The compositions determined by the thermomagnetic curves and microprobe analysis are rather similar. The conclusion has been drawn that thermomagnetic analysis can be used for the rapid determination of the picroilmenite composition. The possibilities and restrictions of this method are shown. 相似文献
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辽宁南部瓦房店金刚石矿是国内最大的金刚石矿产区,现已发现4处金刚石成矿带、120个岩体。其中金伯利岩岩管24个、岩脉89个、可疑岩体7个,累计提交1221万克拉储量,占全国金刚石储量52%。本文主要对该矿床的金刚石母岩—金伯利岩的岩石地球化学特征进行了全面系统分析,发现金伯利岩中MgO、NiO、Cr 2O 3的含量与TiO 2、Al 2O 3、Na 2O、K 2O、CaO、P 2O 5等偏碱性组分呈正相关关系;Ni、Cr、Co含量与金刚石含量呈正相关,而Ti、Zr、Ba元素含量与金刚石含量呈负相关。通过对瓦房店矿区金刚石中石榴石及单斜辉石包裹体、橄榄石- 石榴石矿物对、石榴石微量元素、尖晶石- 橄榄石等多种地质温、压计归纳得出金刚石矿的来源深度为150~210 km,压力5~7 GPa,温度1083~1261℃,在上述温、压条件下,结合岩浆化学组成,估算金伯利岩具有低氧逸度(fO 2=2. 913×1. 01325×10-6Pa)的特点。结合野外勘查工作,总结了该矿床的地质特征、控矿构造、矿体空间分布规律等要素,认为NEE向和NE向断裂控制着金伯利岩体的展布方向和矿体形态。脉状金伯利岩体一般呈NEE 70°~80°方向展布,严格受NEE至近EW向的密集节理或裂隙控制。提出了金刚石母岩—金伯利岩是由源于上地幔岩浆,在一定的封闭条件下,受构造与岩性双重控制,多期性的爆发与侵入交替作用所形成,并建立了具有较高氧逸度和较高密度的流变性软流圈,通过渗滤熔体浸蚀岩石圈形成金刚石的理想成因模式,希望为下一步找矿工作提供参考。 相似文献
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以辽宁瓦房店金刚石矿床50号岩管为例,系统分析了该矿床的地质特征。通过对斑状富金云母金伯利岩、含围岩角砾斑状金伯利岩和金伯利凝灰角砾岩进行岩石地球化学分析发现: 碳酸盐化金伯利凝灰角砾岩超基性成分较少,滑石化、蛇纹石化及碳酸盐化混合金伯利凝灰角砾岩超基性成分较多; 铬、镍、钛在金伯利凝灰角砾岩中的含量较低,在含围岩角砾斑状金云母金伯利岩中的含量略高,在斑状富金云母金伯利岩和斑状金伯利岩中的含量最高。该矿床主要为含围岩角砾斑状金伯利岩和斑状富金云母金伯利岩,其次为金伯利凝灰角砾岩、含围岩角砾斑状金云母金伯利岩和含金伯利物质角砾岩。含铬镁铝榴石、铬铁矿和碳硅石是金刚石的伴生矿物。水平方向上,金伯利岩含矿品位西部较富,东部较贫; 垂直方向上,金伯利岩含矿品位变化较小。通过三维建模,推测50号岩管不是根部相,而是受EW向推覆构造作用影响发生的断层错位,在其东侧600 m深处存在50-1号金伯利岩体。 相似文献