西台吉乃尔盐湖原卤水历年来钾硼锂镁等元素品位变化及未来变化趋势预测          下载免费PDF全文

余明祥  李陇岗  陈元军  秦佳政  刘贺 《盐湖研究》2021,29(3):98-103

研究统计了西台吉乃尔盐湖(以下简称西台)自开发以来原卤水中钾硼锂镁各元素品位变化,利用K~+,Na~+,Mg~(2+)/Cl~-,SO_4~(2-)-H_2O五元体系298K介稳相图研究了主要元素之间相对含量的变化关系。根据西台开发现状建立数学模型,预测了未来10年钾硼锂元素品位变化趋势,为西台盐湖钾硼锂镁等资源的开发和综合利用提供依据。  相似文献   

过硫酸氢钾复合物对对虾养殖底泥硝化作用、氨氧化微生物丰度和群落结构的影响     

赵珍  王宝杰  刘梅  蒋克勇  王雷 《海洋科学》2021,45(11):54-61

采用在模拟池塘中投放过硫酸氢钾复合物（KMPS）进行对比实验的方法,探究KMPS对养殖底质硝化作用的影响。通过对氨氮和亚硝态氮含量的检测,探究对不同时期氮素转化的影响,低频率高剂量投放组中的氨氮和亚硝态氮含量显著降低,而高频率低剂量组中氨氮和亚硝态氮的含量显著上升。高频率低剂量KMPS的投放使氨氧化古菌（AOA）和氨氧化细菌（AOB）丰度降低,而低频率高剂量KMPS的投放不会造成丰度降低,而且还表现出部分时期AOB丰度的上升。进一步对群落结构进行分析发现KMPS的投放使AOA群落中Nitrosopumilu属相对丰度降低,Nitrososphaera属的相对丰度上升,这种相对丰度的变化与KMPS的投放方式无关;但AOB群落受到KMPS投放方式的影响,低频率高剂量的KMPS投放下AOB群落优势属相对丰度显著提高。以上结果均说明低频率高剂量KMPS的投放起到了促进底质硝化作用的效果。同时,可为KMPS用于对虾养殖池塘底质改良开辟一个新的途径。  相似文献   

柴达木盆地宗马海湖地区钾盐矿床成矿规律与成矿预测研究          下载免费PDF全文

崔庆岗  侯新星  来永伟  赵淑芳  魏斌 《山东国土资源》2019,35(10)

研究区位于柴达木盆地北部边缘,属柴达木盆地中—新生代盐类成矿区。该次研究了浅部、中深部及深层储层特征、卤水钾盐的赋存规律及构造控矿理论。浅部卤水钾盐依据KCl含量,分为工业品位区、边界品位区、有浅层卤水区及无浅层卤水区。中深部卤水钾盐分布于山间古冲洪积平原(Ⅰ■)和马海湖次级洼陷(Ⅰ■)中,矿层厚度较大的区域在马海湖次级洼陷(Ⅰ■)北部,主要分布于全新统—更新统含盐系中,计算深度297.22m。深部卤水钾盐,厚度较薄者分布于冷湖六号、冷湖七号构造以北地区的一层至数层的砂岩及砂砾岩层中,自南东向北西由深变浅,分布于上新统,含卤水层段厚约50～250m。厚度较大者分布在赛什腾山山前冲洪积带,北至驼南断裂,南大致至ZK4012孔一线,孔隙卤水层累计深度达1265.14m,分布于全新统—上新统,是今后寻找深层卤水钾盐矿最重要的找矿区域。  相似文献   

青海省柴达木地区钾肥生产企业粉尘、噪声主要职业病危害的调查分析     

萨如丽 《盐湖研究》2018,26(3):64-69

青海是我国资源较为丰富的省份,钾盐资源的开发及钾肥生产在国内占有重要地位。随着青海高原地区盐湖钾肥产业的迅速发展,相关部门对该行业职业卫生、职业病防治工作日渐重视。通过大量的现场数据收集、整理,对青海高原地区盐湖钾肥行业作业人员面临的职业病危害因素、健康安全等相关问题进行了总结和分析,提出了有针对性的防范措施。  相似文献   

Effects of potassium sulfide content in marine diesel fuel oil on emission characteristics of marine furnaces under varying humidity of inlet air   总被引：1，自引：0，他引：1  

Cherng-Yuan Lin  Wei-Cheng Chen 《Ocean Engineering》2006,33(8-9):1260-1270

Degraded fuel oils are generally used in marine power plants for economic purposes, so as to reduce operating expenses. These marine fuel oils commonly contain various oxides or sulfide compounds of metallic elements in the fuel ash, and affect the combustion and emission characteristics of marine power plants to different extents. Moreover, marine power plants are more often operated in a highly humid environment. As a result the emission and burning process may also be altered by the various humidity level of the inlet air. The effects of potassium sulfide in marine diesel on the combustion and emission characteristics of marine furnaces under varying levels of relative humidity of inlet air were experimentally investigated in this study. A cylindrical industrial furnace made of AISI 316 stainless steel, and an automatic oil-fired burner were used for the emission characteristics measurements and observation. A mechanically homogenizing machine was used to stir potassium sulfide (K₂SO₄) powder and marine diesel with a preset K₂SO₄ concentration. The relative humidity of the inlet air and temperature were adjusted to their assigned values by a large-size air conditioner before being pumped into the burner. The marine diesel oil mixture was atomized by the inlet air consequently ignited by an electrode and then burned within the horizontal furnace. There were eight rectangular slots cut in the upper portion of the furnace wall so that the probes of a gas analyzer and a thermocouple could be inserted into radial positions in the cylindrical furnace. The concentrations of gas emission and burning gas temperature and the combustion efficiency were analyzed. The experimental results show that the burning gas temperature, carbon dioxide emission and combustion efficiency decreased when the concentrations of excess air and oxygen emission increased with the addition of potassium sulfide in the marine diesel fuel. This is primarily attributed to the fact that the sulfide of an alkali compound such as K₂SO₄ may suppress the oxidation reaction process, leading to inferior combustion characteristics.  相似文献   

KCl+KHCO_3水溶液中氯化钾的平均活度系数和KHCO_3~0的缔合常数     

陈国华  季荣  薛小平  陈颖 《中国海洋大学学报(自然科学版)》1993,(3)

用钾离子选择电极和银—氯化银电极构成的无液界电池测量了KCl+KHCO_3混合水溶液中KCl的平均活度系数,发现其活度系数的对数与混合溶液中KHCO_3的浓度m_2服从哈奈特关系式。用最小二乘法计算机处理求得了各离子强度条件下相应的哈奈特系数。还用适用于混合电解质溶液的皮茨公式计算了该体系电解质的平均活度系数和溶液的超额自由能,计算出活度系数与实验值之间的平均标准偏差为±0.006。溶液的超额自由能随溶液组成变化表明,对于有相同阳离子(K~+)的该混合溶液中离子间短程作用力主要受Cl~-作用的影响。用累代逼近法用微机计算,求得了KHCO_3~0的化学计量缔合常数经验公式及其热力学缔合常数。  相似文献   

细胞外钙和钾离子对调节离体鲤脑垂体促性腺激素分泌的影响     

林信伟  李英文  林浩然 《海洋与湖沼》1995,26(3):295-301

作者于１９９０年９月－１９９１年１月采用离体灌流培育方法对鲤鱼脑垂体促性激素的分泌调节进行研究。结果表明，脑垂体基础促性腺激素（ＧｔＨ）分泌不依赖于细胞外钙离子（Ｃａ＾２＋）；但脉冲式鲑鱼促性腺激素释放激素（ｓＧｎＲＨ）刺激的ＧｔＨ分泌，则依赖于细胞外Ｃａ＾２＋且细胞外Ｃａ＾２＋的作用至少部分通过电位敏感性Ｃａ＾２＋通道。５０ｍｍｏｌ／Ｌ高浓度钾离子（Ｋ＾＋）显著刺激脑垂体基础ＧｔＨ分泌，Ｋ＾＋的  相似文献   

On the dose dependency of the bleachable and non-bleachable components of IRSL from K-feldspar: Improved procedures for luminescence dating of Quaternary sediments     

《Quaternary Geochronology》2013

The infrared (IR) stimulated luminescence (IRSL) and post-IR IRSL (pIRIR) signals from K-feldspar can, for convenience, be divided into two components, bleachable and ‘non-bleachable’, where the latter corresponds to the ‘residual’ signal observed in sunlight-bleached samples. In this paper, we examine the non-bleachable component of IRSL of K-feldspar for several sedimentary samples from across Eurasia. We observed a large variability in the residual doses among these samples after prolonged exposure to sunlight. By employing multiple elevated temperature (MET) IR stimulations at 50–300 °C, we show that the residual dose increases systematically with stimulation temperature, attaining values as high as ∼50 Gy at 300 °C, even after several hours to tens of hours of exposure to unfiltered sunlight. We examined two samples in detail and found that the bleachable and non-bleachable components produced different dose response curves. Pulse annealing studies showed that the non-bleachable component is more stable than the bleachable component, suggesting that a preheat procedure cannot eliminate the non-bleachable component. Additional experiments revealed that the non-bleachable component is dose dependent. Owing to this dose dependency, we demonstrate mathematically and empirically that the simple subtraction of a residual dose from the measured equivalent dose (D_e) – which is the most common approach employed (if any residual dose is subtracted at all) – will result in underestimation of the actual D_e. We present a method to correct for the dose dependency of the residual dose, which can improve the accuracy of either MET-pIRIR or pIRIR age estimates for samples in which the non-bleachable component represents a significant fraction of the measured signals.  相似文献   

Isotopic and hydrochemical studies of groundwater flow and salinity in the Southern Upper Rhine Graben     

Michael Bauer  Lorenz Eichinger  Philippe Elsass  Wolfram Kloppmann  Gunther Wirsing 《International Journal of Earth Sciences》2005,94(4):565-579

In order to determine the origin and the propagation mechanisms of highly concentrated chloride brines within the Quaternary aquifer system in the southern part of the Upper Rhine Graben, a combined isotope (H, O, C) and hydrochemical analysis was carried out. Groundwater recharge in this area is a complex system, consisting of local precipitation, river bank filtration, lateral flow from the Graben borders and, to a minor extent, an old Pleistocene component. In some areas, groundwater consists of up to 90% of recent bank filtrate, reaching depths down to at least 100 m. The isotopic and hydrochemical results show, that the elevated chloride concentrations in the Quaternary aquifer mainly result from leaky settling basins charged by the French potash mines until the mid 1970s. Input of natural brines coming from tertiary salt diapirs is of only minor importance. While infiltrating, the anthropogenic brines were strongly diluted by local river bank filtrate of the Rhine. Nevertheless, maximum chloride concentrations nowadays still reach some 10,000 mg/l at the base of the aquifer at a depth of more than 100 m below surface. The main volume of the brines is stored in the less permeable lower part of the quaternary sediments (Breisgau-Formation) whereas only a minor part is transported northwards with the rapid convective groundwater flow. Brines undergoing only dilution preserve their hydrochemical characteristics (NaCl-type). In contrast, brines recirculated from the Breisgau-Formation show a northwards increasing alteration through ion exchange processes. Potassium and sodium may be fixed in the fine grained aquifer material while calcium is set free into the groundwater. After a flow distance of about 12 km, complex hydraulic interactions between groundwater and surface waters lead to the rise of strongly diluted and hydrochemically altered brines with chloride contents up to maximum 700 mg/l. The presented case study is an example for a detailed analysis of a multi-component groundwater mixing system using combined isotope and hydrochemical methods. Furthermore, cation exchange is shown as a major process affecting the hydrochemical evolution of the young groundwater in the southern Upper Rhine Graben which is locally strongly polluted by chloride as a consequence of former potash mining.  相似文献   

反浮选-冷结晶法生产氯化钾浮选法除钙研究   总被引：5，自引：1，他引：5       下载免费PDF全文

牛桂然  唐宏学 《盐湖研究》2006,14(1):14-16

研究了青海察尔汗盐湖水采光卤石矿生产氯化钾工艺中浮选除钙的方法。实验结果表明,分级浮选法除钙率平均达88.16%,接近原矿的理论可除钙离子量91.58%。  相似文献