高级变质岩中Zr、Hf、Nb、Ta的ICP-MS准确分析   总被引：15，自引：0，他引：15  

刘勇胜  柳小明等 《地球科学》2003,28(2):151-156

采用高压密闭溶样ICP－MS研究了片麻岩、榴辉岩等高级变质岩中Nb、Ta、Zr、Hf准确分析方法。实验表明：在温度为190℃时,溶样时间大于36h,Nb、Ta、Zr、Hf可完全溶解,而获得准确的分析结果。但Nb、Ta在稀硝酸介质中的不稳定性会导致分析结果的误差,采用0．1％HF介质的“F^-基体”匹配,可保持Nb、Ta长时间的稳定性。所建立的高压密闭溶样ICP－MS分析方法用于苏鲁－大别地区片麻岩、榴辉岩等高级变质岩的分析,经与XRF及碱熔融ICP－MS方法对比,分析结果具有良好的一致性。  相似文献   

等离子体发射光谱法同时测定岩石中微量锆、铪、铌和钽等元素     

郑永凤  张晨 《铀矿地质》1991,(5)

本文介绍了一种快速离子交换分离—ICP-AES法同时测定岩石中微量锆、铪、铌和钽等元素的新方法。样品经碱熔、浸取、过滤,其沉淀连同滤纸放回原烧杯,加入H~+型阳离子交换树脂和少量酒石酸溶液。基体元素(Fe~(3+),Al~(3+),Ca~(2+),Mg~(2+)等)被树脂吸附,锆、铪、铌和钽与酒石酸形成稳定络合物存留在溶液中,经干过滤后,用ICP-AES方法直接测定。欲测元素的样品分析实际检出限分别为:Zr0.2ppm。Hf、Nb、Ta均为0.4ppm。实践证明,本方法不仅步骤简单,分析速度快,而且分析结果或靠,精密度和准确度良好。  相似文献   

Determination of Zr, Hf, Th and U by Isotope Dilution and Inductively Coupled Plasma-Quadrupole Mass Spectrometry After Concomitant Separation Using Extraction Chromatography     

Brieuc Le Fèvre  Christian Pin 《Geostandards and Geoanalytical Research》2002,26(2):161-170

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板块汇聚边缘玄武岩大地构造环境的Th、Nb、Zr判别   总被引：5，自引：0，他引：5  

孙书勤  张成江  黄润秋 《地球科学进展》2006,21(6):593-598

根据Th、Nb、Zr的地球化学性质和判别机理，利用世界上典型大地构造环境区玄武岩类的Th、Nb、Zr数据，研究了Th、Nb、Zr判别玄武岩大地构造环境的地球化学机理，发现不同构造环境区玄武岩系的Th、Nb、Zr特征具有显著差异，其比值特征能将玄武岩形成的大地构造位置很好地划分出来。提出了板块汇聚边缘玄武岩大地构造环境的Nb/Zr Th/Zr判别图，该图不但能较好地区分出板块汇聚边缘中的洋—洋俯冲带、洋—陆俯冲带及陆—陆碰撞带，同时还能反映出岛弧区大地构造环境演化的趋势。  相似文献   

大洋中脊热水探测与新型传感器   总被引：3，自引：0，他引：3  

张雪彤张荣华  胡书敏王勇 《地质论评》2006,52(6):843-847

对大洋中脊的探测带来了大量科学发现。在大洋中脊热水喷口的极端条件下，在大的温度梯度范围内，一方面在喷口（黑烟囱）周围形成巨量金属硫化物快速堆积；另一方面在喷口周围由内向外形成一个生物晕。为了研究洋中脊极端条件下的水热过程，模拟洋中脊水-岩相互作用条件下生命过程，需要在高温高压环境中原位获取数据，必须利用先进、灵敏的化学传感器。由于新材料技术的发展，美国和西方国家深海探测时广泛使用YSZ电化学传感器（氧化钇稳定的氧化锆陶瓷，YSZ：Yttria Stabilized Zirconia），这种传感器的优点是在温度大于200℃的高温时性能良好，在低于200℃条件下灵敏度降低，而且在国际市场上没有这些高温高压化学传感器出售。“十五”期间，科技部863计划，首次将发展深海高温高压传感器的海底多参数检测技术之一列入我国计划。根据863计划，中国科学家通过努力研制成功一系列具有中国自主知识产权的高温高压化学传感器，在自主研制了YSZ传感器的同时，发明了国际上首次可以在大温度范围、在海上实用的Zr／ZrO2高温化学传感器，可部分替代YSZ传感器。这两类集成式化学传感器可以探测大洋中脊400℃／40MPa热水的pH、H2、H2S、Eh等，并在2004年的南海的海试中取得成功。  相似文献   

Zircon Trace Element Constraints on U-Pb Dating: A Case Study of the Huayuangong A-type Granite in the Lower Yangtze Region,Eastern China     

QI Fei  YAN Jun 《《地质学报》英文版》2021,95(4):1171-1182

For magmatic rocks, it is often found that zircon 206 Pb/238 U and 207 Pb/235 U ratios continuously plot on the concordia line with a relatively large age span for the same sample, which gives rise to large dating errors or even unrealistic dating results. As the trace element concentrations of zircon can reflect its equilibrated magma characteristics, they can be used to determine whether all the analytical spots on the zircons selected to calculate the weighted mean age are cogenetic and formed in a single magma chamber. This work utilizes the results of zircon trace element concentrations and U-Pb isotopic analyses to explore the screening of reasonable U-Pb ages, which can be used to determine a more accurate intrusion crystallization age. The late Mesozoic Huayuangong granitic pluton complex, which is located in the Lower Yangtze region, eastern China, was selected for a case study. The Huayuangong pluton comprises the central intrusion and the marginal intrusion. Two samples from the marginal intrusion yielded consistent zircon weighted mean 206 Pb/238 U ages of 124.6 ± 2.0 Ma and 125.9 ± 1.6 Ma. These analytical spots also exhibit Zr/Hf and Th/U ratios concordant with the evolution of a single magma, from which the dated zircons crystallized. However, for the central intrusion, the analytical spots on zircons from two samples all show a continuous distribution on the concordia line with a relatively large age span. For each sample from the central intrusion, the zircon Zr/Hf ratios do not conform to a single magma evolutionary trend, but rather can be divided into two groups. We propose that zircon Zr/Hf ratios can provide a new constraint on U-Pb zircon dating and zircon Th/U ratios can also be used as a supplementary indicator to constrain zircon dating and determine the origins of the zircons and whether magma mixing has occurred. By screening zircon analytical spots using these two indicators, the two samples from the central intrusion of the Huayuangong pluton produce results of 122.8 ± 4.3 Ma and 122.9 ± 2.2 Ma, which are consistent with the field observations that the central intrusion is slightly younger than the marginal intrusion.  相似文献   

Rare eclogite‐mafic granulite in felsic granulite in Blanský les: precursor of intermediate granulite in the Bohemian Massif?     

P. Štípská  R. Powell  M. Racek 《Journal of Metamorphic Geology》2014,32(4):325-345

Mafic granulite, generated from eclogite, occurs in felsic granulite at Kle?, Blanský les, in the Bohemian Massif. This is significant because such eclogite is very rare within the felsic granulite massifs. Moreover, at this locality, strong interaction has occurred between the mafic granulite and the adjacent felsic granulite producing intermediate granulite, such intermediate granulite being of enigmatic origin elsewhere. The mafic granulite involves garnet from the original eclogite, containing large idiomorphic inclusions of omphacite, plagioclase and quartz, as well as rutile. The edge of the garnet is replaced by a plagioclase corona, with the garnet zoned towards the corona and also the inclusions. The original omphacite–quartz–?plagioclase matrix has recrystallized to coarse‐grained polygonal (‘equilibrium’‐textured) plagioclase‐diopsidic clinopyroxene–orthopyroxene also with brown amphibole commonly in the vicinity of garnet. Somewhat larger quartz grains are embedded in this matrix, along with minor ilmenite, rutile and zircon. Combining the core garnet composition with core inclusion compositions gives a pressure of the order of 18 kbar from assemblage and isopleths on a P?T pseudosection, with temperature poorly constrained, but most likely >900 °C. From this P?T pseudosection, the recrystallization of the matrix took place at ~12 kbar, and from Zr‐in‐rutile thermometry, at relatively hot conditions of 900–950 °C. It is largely at these conditions that the eclogite/mafic granulite interacted with the felsic granulite to make intermediate granulite (see next paper).  相似文献   

Meteoritic zircon – Occurrence and chemical characteristics     

《Chemie der Erde / Geochemistry》2014,74(3):453-469

In common with the remarkable variation in the bulk rock Zr content of distinct meteorite groups, ranging from <1 ppm to >800 ppm, the occurrence and abundance of accessory zircon is also highly diverse and limited to certain meteorite classes. A detailed literature study on the occurrence of meteoritic zircon, along with other Zr-bearing phases reveals that lunar rocks, eucrites and mesosiderites are the prime sources of meteoritic zircon. Rare zircon grains occur in chondrites, silicate-bearing iron meteorites and Martian meteorites, with grain sizes of >5 μm allowing chemical and chronological studies at high spatial resolution using secondary ion mass spectrometry (SIMS) technique. Grain sizes, crystal habits, structural and chemical characteristics of zircon grains derived from various meteorite types, including their REE abundances, minor element concentrations, and Zr/Hf values is diverse. Superchondritic Zr/Hf values (47 ± 8; s.d. with n = 97), i.e., typical for zircon in eucrites and mesosiderites, indicate crystallization from a fractionated, incompatible-element-rich (residual) melt. Differences in REE abundances, occurrence or absence of Ce- and Eu-anomalies, and overall REE patterns that are often fractionated with a depletion in LREE, might be primarily controlled by variable formation conditions of individual grains and/or differences in the residual melt compositions on a small, local scale within single samples. Subsequent fractionation/modification of the chemical fingerprint of meteoritic zircon can involve high-temperature annealing processes during thermal metamorphic reactions and/or impact events along with mixing of lithic fragments since many samples are breccias.  相似文献   

Voltammetric Determination of High Field‐Strength Elements (Ti,Zr, Hf,Nb, Ta) in Geological Matrices          下载免费PDF全文

Marc Biver  Montserrat Filella 《Geostandards and Geoanalytical Research》2018,42(3):395-401

A voltammetric method for the determination of the high field‐strength elements Ti, Zr, Hf, Nb and Ta by adsorptive stripping of their tartrate complexes is presented. The applicability of the method to geological and metallurgical samples is illustrated by the analysis of certified reference materials (USGS BCR‐2 basalt, BCS‐CRM 388 zircon and Euronorm CRM 579‐1 ferroniobium). Suitable sample preparation techniques, involving fusion with LiBO₂ and acidic and basic fluxes, followed by preliminary separation by anion chromatography are described. The method is rapid, affordable and environmentally friendly as it does not require problematic compounds such as hydrofluoric acid or toxic solvents and represents an alternative to more commonly used methods (AAS, ICP‐OES, ICP‐MS).  相似文献   

Late Cenozoic Chemical Weathering and Environmental Changes Recorded in the Co Ngoin Sediments,Central Qinghai-Tibet Plateau   总被引：1，自引：2，他引：1  

CHEN Shiyue  JIN Zhangdong  WANG Sumin  SHEN Ji Nanjing Institute of Geography  Limnology  Chinese Academy of Sciences  Nanjing  Jiangsu  School of Environment  Planning  Liaocheng University  Liaocheng  Shandong Institute of Earth Environment  Chinese Academy of Sciences  Xi’an  Shaanxi 《《地质学报》英文版》2005,79(3):384-391

A series of faulted inland basins were developed in the central Qinghai-Tibet Plateau, among which the Co Ngoin Basin containing thick lacustrine sediments is located in the peripheral area of the Indian monsoon. In this paper, we present the weathering history and paleoclimatic changes in the last 2.8 Ma based on studies of high-resolution temporal distributions of Sr, Rb and Zr concentrations, Rb/Sr and Zr/Rb ratios and δ ^13C and TOC for the Co Ngoin sediments, in combination with the sediment properties, grain size distribution and clay mineralogy. The sedimentary records indicate three environmental stages in the last 2.8Ma. At the core depth of 197-170m (about 2.8-2.5Ma), low-intensity chemical weathering in the Co Ngoin catchment was experienced under warm-dry to cool-wet climate conditions with relatively low Sr concentration and high Rb/Sr and Zr/Rb ratios. The sudden occurrence of both subalpine coniferous forest and coarses and and gravel sediments in the Co Ngoin core reflects a strong tectonic uplift. The high Sr concentrations and low Rb/Sr and Zr/Rb ratios reflect a relatively strong chemical weathering between 2.5Ma and 0.8Ma (at the core depth of 170-38.5m) under a temperate/cool and wet climate, characterized by mud and silt with fine sand, probably indicating a stable process of denudation and planation of the plateau. Above the depth of 38.5m (about 0.8-0Ma), the coarsening of sediments indicates a strong tectonic uplift and a relatively low intensity of chemical weathering as supported by the record of sediments having relatively low Sr concentrations and high Rb/Sr and Zr/Rb ratios. Since then, the plateau has taken the shape of the modern topographic pattern above 4000m a.s.l.  相似文献