海洋沉积物孔隙水中阴阳离子含量的离子色谱法分析方法   总被引：2，自引：0，他引：2  

葛璐  杨涛  杨競红  蒋少涌 《海洋地质与第四纪地质》2006,26(4):125-130

分别采用Metrosep A Supp4-250型阴离子柱和Metrosep C 2-150型阳离子柱,以1.8 mmol/L Na2CO3 1.7 mmol/L NaHCO3和4 mmol/L酒石酸 0.75 mmol/L吡啶二羧酸为阴阳离子淋洗液,用离子色谱仪来测定海洋沉积物孔隙水中阴离子Cl-、Br-和SO42-浓度和阳离子Na 、NH4 、K 、Ca2 、Mg2 的浓度。特别是针对高Cl-和高Na 背景下Br-和NH4 的测定做了专门分析,得到了较理想的结果,建立了一套离子色谱法测定海洋沉积物孔隙水中常见的阴阳离子含量的实验方法。  相似文献   

锌对虾夷扇贝和刺参幼体的毒性效应   总被引：11，自引：1，他引：11  

朱丽岩  吕建发  唐学玺  高象贤  徐怀恕 《海洋通报》1999,18(4):34-37

以虾夷扇贝和刺参幼体为材料,采用急性毒性试验和亚急性毒性试验的方法,研究了锌对虾夷扇贝稚贝及幼贝和刺参幼虫的毒性效应。结果显示,锌对虾夷扇贝稚贝的２４ｈＬＣ５０ ６．４０ｍｇ／Ｌ,４８ｈＬＣ５０为３．３１ｍｇ／Ｌ,７２ｈＬＣ５０为１．３９ｍｇ／Ｌ,９６ｈＬＣ５０为０．６１ｍｇ／Ｌ;而对幼贝的２４ｈＬＣ５０为３．３２ｍｇ／Ｌ,４８ｈＬＣ５０为２．６４ｍｇ／Ｌ。７２ｈＬＣ５０为１．７６ｍｇ／Ｌ,９６ｈ  相似文献   

Isotopes and Geochronology of the Meixian-type Pb-Zn-(Ag)Deposits,Central Fujian Rift,South China:Implications for Geological Events     

FENG Chengyou  ZHANG Dequan  LI Daxin  SHE Hongquan  DONG Yingjun 《《地质学报》英文版》2008,82(4):826-837

Central Fujian Rift is another new and important volcanogenic massive sulfide Pb-Zn polymetallic metallogenetic belt. In order to find out the material genesis and mineralization period of Meixian-type Pb-Zn-Ag deposits, S and Pb isotope analysis and isotope geochronology of ores and wall rocks for five major deposits are discussed. It is concluded that the composition of sulfur isotope from sulfide ore vary slightly in different deposits and the mean value is close to zero with the 834S ranging from -3.5‰ to ＋5.6‰ averaging at ＋2.0‰, which indicates that the sulfur might originate from magma or possibly erupted directly from volcano or was leached from ore-hosted volcanic rock. The lead from ores in most deposits displays radioactive genesis character （206pb/204pb〉18.140, 207Pb/204pb〉15.584, 208pb/204pb〉38.569） and lead isotope values of ores are higher than those of wall rocks, which indicates that the lead was likely leached from the ore-hosted volcanic rocks. Based on isotope data, two significant Pb-Zn metallogenesis are delineated, which are Mid- and Late-Proterozoic sedimentary exhalative metailogenesis （The single zircon U-Pb, Sm-Nd isochronal and Ar-Ar dating ages of ore- hosted wall rocks are calculated to be among 933-1788 Ma.） and Yanshanian magmatic hydrothermal superimposed and alternated metallogenesis （intrusive SHRIMP zircon U-Pb and Rb-Sr isochronal ages between 127-154 Ma）.  相似文献   

粤东成矿地质背景及银-铜-铅-锌成矿物质来源探讨     

郭锐  曾国光 《矿产与地质》2008,22(3):236-240

通过对粤东地区地层和岩石中成矿元素含量和区域地质背景的分析,认为粤东地区铜铅-锌-银成矿作用与燕山期的构造-岩浆作用关系密切,成矿物质中银-铜-锌以下地壳来源为主,铅则以上地壳及沉积地层来源为主。  相似文献   

国际联合矿业公司在秘鲁发现新的铜、锌矿化带     

刘伟 《国土资源情报》2008,(4):55-55

据国际联合矿业公司（ICMI）称,该公司在秘鲁Pachapaqui多金属矿地钻探发现了新的铜、锌矿化带,该发现有相当大的潜力,增加了该矿地的资源。 该公司说,表面厚厚的角砾岩体似乎与矿脉相接,沿东西延伸至少200米。此外,该公司正评估400-500米角砾岩简的表面含金潜力和靠近该矿地的两个有名的采矿区的岩体。  相似文献   

中国南方离子吸附型稀土矿床成矿类型及其母岩控矿因素探讨     

付伟  赵芹  罗鹏  李佩强  陆济璞  周辉  易泽邦  许成 《地质学报》2022,96(11):3901-3923

传统认为中国南方的离子吸附型稀土矿床可划分为以“足洞式”为代表的重稀土型和以“河岭式”(或“花山式”)为代表的轻稀土型两种矿化类型。然而，近年来发现的许多矿床(如清溪、寨背和馒头山等)的赋矿风化壳中出现了轻稀土矿与重稀土矿并存现象，表现出特殊的“上轻下重”双层矿体结构。这指示了除重稀土型和轻稀土型之外，还存在着轻重稀土共生型的过渡类型。本研究通过对三种不同成矿类型的若干典型矿床系统对比，指出成矿类型的多样性与母岩性质密切相关，尤其是母岩的稀土元素地球化学和稀土载体矿物属性是制约成矿类型变化的关键因素。统计数据表明，从重稀土型→轻重稀土共生型→轻稀土型，成矿母岩的全岩稀土总量变化不大(ΣREY: 200×10-6~450×10-6→200×10-6~500×10-6→200×10-6~800×10-6)，但轻重稀土配分值出现较显著的区间性差异(ΣLREE/ΣHREY: 02~1→1~5→2~10)。与之同时，母岩中能为离子相稀土提供物源且具有重稀土配分属性的稀土副矿物类型和数量明显减少，这与全岩稀土元素地球化学特征中重稀土分量占比的降低趋势也互相匹配。该结果指示，以往认为重稀土配分母岩形成重稀土矿床、轻稀土配分母岩形成轻稀土矿床的传统观点需要外延，即一部分具有低度轻稀土配分属性(1＜ΣLREE/ΣHREY＜5)且含有丰富易风化稀土副矿物的母岩还可能形成轻重稀土共生型矿床，该认识可为今后离子吸附型稀土矿床勘查工作提供新的找矿依据。  相似文献   

贵州南部“半边街式”铅锌矿床地质特征及其成因探讨   总被引：1，自引：0，他引：1  

陈国勇  安琦  王敏 《地球学报》2006,27(6):570-576

贵州省南部地区是全国重要的汞、锑资源分布区。2000年由于产于上泥盆统中铅锌矿的陆续发现,贵州省地矿局启动了以铅锌资源评价和成矿规律研究为主的地质工作,目标是总结铅锌矿产出的地质特征和成矿规律。通过三年的研究认为,该区处扬子准地台、华南褶皱带和右江造山带交汇部位,受晚古生代初期发生的陆内裂谷活动影响,产生了一个与桂中台陷相连的大型沉积凹陷区—黔南台陷沉积区,形成了巨厚碳酸盐和碎屑岩沉积,产生了与裂陷盆地边缘同沉积断层活动有关的低温成矿作用,造成了在晚泥盆纪以前的地层中汞、锑、砷、金、铅锌等矿床沿同沉积断层密集分布。本文通过矿床特征总结和矿床成因探讨,建立了准同生沉积成矿作用模式,旨在为该区寻找这类矿床提供参考和借鉴作用。  相似文献   

Mercury contaminations to the ambient air, soil and water compartments in the zinc smelting area in Weining County, Guizhou, China     

《中国地球化学学报》2006,25(B08):241-241

  相似文献   

Adsorption of Pentachlorophenol onto Oxide and Clay Minerals： Surface Reaction Model and Environmental Implications     

WU Daqing DIAO Guiyi YUAN Peng PENG Jinlian 《《地质学报》英文版》2006,80(2):192-199

The adsorption of pentachlorophenol （PCP） onto quartz, kaolinite, illite, montmorillonite and iron oxides has been investigated by batch equilibrium techniques. The pH-dependent isotherms are curves with peak values, the position of which is at about pH = 5-6 depending on the mineral species. Based on distribution of both speciation of surface hydroxyls on minerals and PCP in solution a surface reaction model involving surface complexation and surface electrostatic attraction is presented to fit the pH-dependent isotherms, and both reaction constants are calculated. The results show that on quartz and phyllosilicate minerals the predominant adsorption reaction is surface complexation, meanwhile both of surface electrostatic attraction and surface complexation are involved on the iron oxide minerals. The reaction constants of surface electrostatic adsorption are usually one to three orders in magnitude, larger than that of surface complexation. The concentration-dependent isotherms can be well fitted by Langmnir equation with the correlation coefficient R〉0.93 for kaolinite and iron oxides. The maximum adsorption is found in the order： hematite 〉 lepidocrocite 〉 goethite 〉 kaolinite 〉 quartz 〉 montmorillonite ≈ illite, which can be interpreted by consideration of both reaction mechanism and surface hydroxyl density. The significant adsorption of PCP onto mineral surfaces suggests that clay and iron oxide minerals will play an important role as HIOCs are adsorbed in laterite or latertoid soil, which is widespread in South China.  相似文献   

新疆绿色电气石颜色成因研究   总被引：5，自引：0，他引：5       下载免费PDF全文

王进军陶晓风  王武军 《岩石矿物学杂志》2005,24(4):319-323

新疆绿色电气石颜色成因比较特殊,为了更好地了解其颜色的形成,主要采用化学分析、吸收光谱、穆斯堡尔谱等测试手段对绿色电气石颜色成因进行研究。化学分析结果显示每个样品中均含有少量不同过渡元素离子,如Fe2 、Ti4 、Cr3 等,影响着绿色的形成;利用吸收光谱测试方法确定了致色离子的吸收带位置及主要离子的种类、价态,并根据化学成分计算出相应的化学式,利用穆斯堡尔谱确定了铁离子在晶体中的占位。综合运用上述测试方法,确定了绿色电气石的颜色成因。  相似文献