Whole-rock geochemical,U-Pb and Sm-Nd isotope characteristics of the Dongueni Mont nepheline syenite intrusion,Mozambique     

Vicente Albino Manjate 《地学前缘(英文版)》2017,8(5):1063-1071

The Dongueni Mont nepheline syenite intrudes migmatitic paragneisses and siliciclastic metasediments of the Barue Complex, Mozambique. This study reports the whole-rock geochemical, U-Pb and Nd isotopic data of the nepheline syenite. The ferroan and alkalic geochemical characteristics are typical of alkaline rocks formed in a within-plate setting. The strong depletion in high field strength elements(HFSEs)(e.g. Ba, Nb, P,and Ti) and enrichment in large ion lithophile elements(LILEs)(e.g. Rb, Th, K, and Pb) are consistent with magmatism in a continental alkaline magmatic province associated with intracontinental rifting. Zircon U-Pb data yielded crystallization ages from 498 ± 19 to 562± 14 Ma,consistent with the Pan-African Orogeny and the inherited zircons yield an age of 1040 Ma, which supports the presence of a Mesoproterozoic crust. Theε_(Nd)(t) values from the nepheline syenite samples range from-15.1 to-16.1 and the T_(DM)values from 1.77 to 1.67 Ga, which indicate that the initial nepheline syenite magma formed from a tholeiitic or mantle source in a within-plate setting with crustal assimilation.  相似文献   

皖南逍遥岩体的年代学、地球化学特征及其成因分析   总被引：3，自引：0，他引：3  

施珂  张达玉  丁宁  王德恩  陈雪锋 《吉林大学学报(地球科学版)》2017,(6):1746-1762

皖南绩溪县逍遥岩体侵位于新元古界南华系、震旦系和下古生界海相沉积盖层中,岩性为花岗闪长岩。测得该岩体LA-ICP-MS锆石U-Pb同位素加权平均值年龄为(149.3±2.3)和(148.6±1.9)Ma,表明:岩体侵位于晚侏罗世。逍遥花岗闪长岩体的电子探针分析显示其黑云母为镁质黑云母。岩石地球化学研究表明:其为高钾钙碱性系列,准铝质—过铝质,属于I型花岗岩;微量元素特征显示其富集轻稀土而亏损重稀土元素,富集Ba、Sr等大离子亲石元素。综合地质、年代学、电子探针和岩石主微量元素分析,逍遥岩体形成于晚侏罗世,其岩浆来源于有幔源物质加入的下地壳,在形成过程中经历了较强的部分熔融作用,该岩体具有火山弧花岗岩特点。  相似文献   

An approach for optimizing in situ cosmogenic 10Be sample preparation     

《Quaternary Geochronology》2016

Optimizing sample preparation for the isotopic measurement of ¹⁰Be extracted from quartz mineral separates has a direct positive effect on the accuracy and precision of isotopic analysis. Here, we demonstrate the value of tracing Be throughout the extraction process (both after dissolution and after processing), producing pure Be (by optimizing ion exchange chromatography methods and quantifying quartz mineral separate and final Be fraction purity), and minimizing backgrounds (through reducing both laboratory process blanks and ¹⁰B isobaric interference). These optimization strategies increase the amount of ¹⁰Be available for analysis during accelerator mass spectrometry (AMS), while simultaneously decreasing interference and contamination, and ensuring that sample performance matches standard performance during analysis. After optimization of our laboratory's extraction methodology, ⁹Be³⁺ ion beam currents measured during AMS analysis, a metric for sample purity and Be yield through the extraction process, matched the ⁹Be³⁺ beam currents of AMS standards analyzed at the same time considering nearly 800 samples. Optimization of laboratory procedures leads to purer samples that perform better, more consistently, and more similarly to standards during AMS analysis, allowing for improved precision and accuracy of measurements used for dating and quantification of Earth surface processes.  相似文献   

义敦岛弧措交玛岩体岩浆混合成因:镁铁质微粒包体的证据   总被引：2，自引：0，他引：2  

王鹏  董国臣  董美玲  李永平  徐一鸣  潘彦宁  陈薇  吴宗昌 《岩石学报》2017,33(8):2535-2547

义敦岛弧北部的措交玛岩基岩体主要由黑云母二长花岗岩和边部的花岗闪长岩组成。在黑云母二长花岗岩中存在有少量镁铁质微粒包体,其成分为闪长质,与寄主岩石接触关系从渐变到截然。在包体周围的寄主岩石中存在黑云母、角闪石自身的包含结构,角闪石包含黑云母,斜长石发育明显的溶蚀结构,核部斜长石被溶蚀成筛状,边部环带状斜长石溶蚀不明显,是基性岩浆注入到酸性岩浆中导致岩浆混合的结果。黑云母二长花岗岩具有更高的轻重稀土分异系数,闪长质包体轻重稀土分异系数较低,黑云母二长花岗岩和暗色闪长质微粒包体具有明显相似性的微量元素特征。寄主岩黑云母二长花岗岩锆石U-Pb年龄为236±1.9Ma,闪长质包体为235±3.9Ma,二者形成年代在误差范围内基本一致,可能为甘孜-理塘洋向西俯冲过程中,俯冲洋壳部分熔融形成的玄武质岩浆上涌底侵于壳-幔边界导致地壳的部分熔融形成酸性的黑云母二长花岗岩岩基。  相似文献   

藏南错那洞淡色花岗岩年代学研究及其对藏南拆离系活动时间的限定   总被引：6，自引：3，他引：3  

董汉文  许志琴  孟元库  易治宇 《岩石学报》2017,33(12):3741-3752

北喜马拉雅片麻岩穹窿带(NHGD)内保存了大陆碰撞后青藏高原中下地壳的构造变形、高级变质、陆壳深熔作用等重要信息,是研究喜马拉雅造山带的深部岩浆作用和构造变形之间的耦合关系、深部岩浆活动乃至青藏高原隆升历史等大陆动力学过程的关键部位。本文对藏南错那洞穹窿内淡色花岗岩进行锆石LA MC-ICP-MS U-Pb、白云母~(40)Ar/~(39)Ar年代学和岩石地球化学分析。锆石U-Pb定年和白云母~(40)Ar/~(39)Ar测年结果表明错那洞淡色花岗岩形成于19.5±0.3Ma~19.7±0.7Ma,冷却年龄为15Ma。岩石地球化学特征显示该花岗岩具有明显的Eu负异常,稀土配分模式和微量元素蛛网图与以Manaslu为代表的高喜马拉雅淡色花岗岩一致,而不同于具有加厚地壳的埃达克岩的特征的北喜马拉雅淡色花岗岩,其形成于与南北向拆离相关的伸展环境。  相似文献   

Characterization of a mud deposit offshore of the Patos Lagoon,southern Brazil     

Allen H. Reed  Richard W. Faas  Mead A. Allison  Lauro J. Calliari  K.T. Holland  S.E. O’Reilly  W.C. Vaughan  A. Alves 《Continental Shelf Research》2009

Rapid deposition of mud on the beach along the shoreface of Rio Grande do Sul, Brazil dramatically influences the normal operations in the littoral zone. In the surf zone, fluid and suspended mud opposes water-wave movement and dissipates water-wave energy; on the beach, mud limits trafficability. As part of a multinational, multidisciplinary program to evaluate the influence of mud strength, density and viscosity on water-wave attenuation, sediments were evaluated in situ or collected for evaluation from an area offshore of Cassino Beach, slightly south of the Patos Lagoon mouth. Shear strength of deposited sediments ranged from 0.6 kPa at the seafloor to 3.4 kPa at ∼1 m below the seafloor. Mud sediments were also collected to simulate the in situ response of fluid mud to shear stresses. For this determination, rheological evaluations were made using a strain-controlled Couette viscometer on numerous remixed samples that ranged in density from 1.05 to 1.30 g/cm³. It was determined that this mud is a non-ideal Bingham material in that it has a true initial yield stress as well as a upper Bingham yield stress. Initial yield stress ranged from 0.59 to 2.62 Pa, upper Bingham yield stress ranged from 1.05 to 7.6 Pa. Apparent viscosity ranged from 0.02 to 4.7 Pa s with the highest viscosities occurring between the two yield stresses. Sediment strength in the remixed samples is 2 to 3 orders of magnitude lower than the horizontal shear strength of the sediment bed as determined by shear vane or predicted from penetrometer measurements. This difference is partially due to the fact that rheological evaluations are made on fully remixed sediments, whereas horizontal shear strength is determined within relatively undisturbed sediments. Similar values of viscosity and shear strength are comparable to those determined for mud in other coastal areas where fluid mud deposits occur.  相似文献   

The isotopic composition of atmospheric argon and 40Ar/39Ar geochronology: Time for a change?   总被引：1，自引：0，他引：1  

Paul R. Renne  William S. Cassata  Leah E. Morgan 《Quaternary Geochronology》2009,4(4):288-298

A redetermination of the isotopic composition of atmospheric argon by Lee, J.-Y., Marti, K., Severinghaus, J.P., Kawamura, K., Yoo, H.-S., Lee, J.B., Kim, J.S. [2006. A redetermination of the isotopic abundances of atmospheric Ar. Geochimica et Cosmochimica Acta 70, 4507–4512] represents the first refinement since the work of Nier [1950. A redetermination of the relative abundances of the isotopes of carbon, nitrogen, oxygen, argon, and potassium. Physical Reviews 77, 789–793]. The new ⁴⁰Ar:³⁸Ar:³⁶Ar proportions imply <1% adjustments to ⁴⁰Ar/³⁹Ar ages in all but exceptional cases of very young and/or K-poor and/or Ca-rich samples, or cases in which samples are grossly under- or over-irradiated. Analytical protocols employing atmospheric argon to determine mass discrimination corrections are insensitive to the effects of revision on the air correction, but are subject to non-negligible adjustments arising from expanded heavy to light isotope ratios attending the increased mass discrimination correction. The competing effects of increased ⁴⁰Ar/³⁹Ar and ⁴⁰Ar/³⁷Ar ratios render the adjustments a function of sample chemistry and neutron irradiation parameters. The improved precision of atmospheric ⁴⁰Ar/³⁶Ar and ³⁸Ar/³⁶Ar permits increasingly sensitive detection of departures from atmospheric values. Non-atmospheric initial ⁴⁰Ar/³⁶Ar values are increasingly well-documented in volcanic materials, including subatmospheric values correlated with ³⁸Ar/³⁶Ar in a trend consistent with kinetic mass fractionation whereby incomplete equilibration between magma and atmosphere favors light isotope enrichment in the magma. The detailed mechanism(s) of such fractionation are unclear and must be clarified by further study. A detectable increase in atmospheric ⁴⁰Ar/³⁶Ar in the past 800 ka [Bender, M.L., Barnett, B., Dreyfus, G., Jouzel, J., Porcelli, D., 2008. The contemporary degassing rate of ⁴⁰Ar from the Earth. Proceedings of the National Academy of Sciences 105, 8232–8237] suggests that ages of late Quaternary (e.g., <100 ka) materials incorporating large amounts of atmospheric argon such as biotite may be underestimated by as much as 100% if a modern atmospheric ⁴⁰Ar/³⁶Ar value is erroneously assumed, unless air argon is used to determine mass discrimination. Further evaluation of the evolution of paleoatmospheric ⁴⁰Ar/³⁶Ar, and the fidelity with which argon trapped in igneous materials reflects this, would be very productive. The use of isochrons rather than model (e.g., plateau) ages mitigates the vagaries associated with uncertain trapped argon isotope ratios, and the importance of strategies to derive statistically valid isochrons is underscored.  相似文献   

Using microcomputed tomography (μCT) to count varves in lake sediment sequences: Application to Lake Sagtjernet,Eastern Norway     

《Quaternary Geochronology》2023

Varved lake sediments are one of the most important natural archives that allow annual resolution paleoclimate reconstructions. Conventional varve counting techniques use thin sections to manually identify lamina. However, this technique is destructive, labour intensive and limited to a 2D representation of complex 3D features which may lead to misidentification of varve boundaries. This study presents the use of microcomputed tomography (μCT) scans in constructing varve chronologies, utilizing scanning resolutions of ∼50 μm (binned to ∼200 μm) for core sections up to 150 cm long. To evaluate this method, we cored and analysed Lake Sagtjernet in Eastern Norway — revealing a 593 cm-long sediment record of the past 10274 (⁺²²⁰/_-329) years, with continuous laminations from 84 to 533 cm depth (75% of the sediments). Through limnological monitoring and microfacies analyses we demonstrate that the laminations are rare ferrogenic varves, with an annual deposition pattern comprised of seasonal changes in biogenic production superimposed on seasonal precipitates of iron and manganese hydroxides. The floating μCT-counted varve chronology presented here is the first non-glacial varve chronology in Norway and covers 4023 ⁺¹¹³/_-185 years. We find that μCT scans allow for a very fast and non-destructive way of counting varves with sufficient detail of varve boundaries. In the few sections where varve boundaries are too vague to resolve, we recommend using complimentary techniques such as thin sections in parallel. The varve chronology is in good agreement with the 95% confidence interval of the independent radiocarbon chronology based on 16 ¹⁴C dates, and ²¹⁰Pb and ¹³⁷Cs activity peaks, indicating that the varve chronology can be equated to calendar age.  相似文献   

Paleomagnetism and geochronology of the Gwalior Sills,Bundelkhand craton,Northern India Block: New constraints on Greater India assembly     

《Gondwana Research》2024

We present an updated paleomagnetic pole from the Gwalior Sills in the Bundelkhand craton within the Northern India Block (NIB). Geochronological results from baddeleyite grains from one of the sills yielded an age of 1719 ± 7 Ma which together with a previously published age indicates the emplacement of sills between 1712 and 1756 Ma (∼1730 Ma). The paleomagnetic pole calculated from additional sites in this study, combined with previous studies, falls at 13.5°N, 173.7°E (A95 = 3.6°, K = 98) indicating near equatorial latitudes for northern India. Limestone sampled a few meters above the contact with the sill exhibits similar directions consistent with having been baked by the sill. The pole does not resemble any younger poles from Peninsular India and receives a reliability score of R = 5. Dykes in the Singhbhum craton are slightly older (1765 Ma) and indicate low paleolatitudes for the Southern Indian Block (SIB). Although the Gwalior and Singhbhum poles data indicate low latitudes for both the NIB and SIB, they are statistically different and indicate that a rotation of at least 65° is required to bring the poles into accord. We propose that the NIB and SIB were in proximity but were separated by an ocean basin. We propose the name Gotosindhu (‘Ancient Sea’) for the body of water separating the NIB and SIB. We also review previous models for the assembly of the Columbia supercontinent during this time and critically examine the position of the NIB/SIB in those reconstructions.  相似文献   

ESRfrag: A new suite of open access programs for the efficient handling of Electron Spin Resonance spectra of enamel fragments     

《Quaternary Geochronology》2022

Accurate decomposition of Electron Spin Resonance (ESR) spectrum is a crucial task to extract compound signal intensities of enamel fragments at different irradiation time, in particular for dose recovery accuracy. While it can be achieved manually, the task is laborious and repetitive. In this paper, we present a new freely available program “ESRfrag” that allows the alignment, merging, and computation of complex angular ESR spectra. This program is an open access web-based code, designed to specifically alleviate the daunting task of working with large amounts of ESR spectra for enamel fragment dating. ESRfrag provides an increased reliability and precision on the results compared to manual calculation by removing operators bias. The program can be freely access through the Geoarchaeology and Archaeometry Research Group website (https://www.garg.org.au/projects).  相似文献