南海神狐海域沉积物自生黄铁矿和石膏S同位素特征及对甲烷渗漏强度的示踪   总被引：1，自引：1，他引：0  

张美  陆红锋  管红香  刘丽华  邬黛黛  吴能友 《海洋学报(英文版)》2018,37(7):20-27

The northern slope of the South China Sea is a gas-hydrate-bearing region related to a high deposition rate of organic-rich sediments co-occurring with intense methanogenesis in subseafloor environments.Anaerobic oxidation of methane(AOM) coupled with bacterial sulfate reduction results in the precipitation of solid phase minerals in seepage sediment,including pyrite and gypsum.Abundant aggregates of pyrites and gypsums are observed between the depth of 667 and 850 cm below the seafloor(cmbsf) in the entire core sediment of HS328 from the northern South China Sea.Most pyrites are tubes consisting of framboidal cores and outer crusts.Gypsum aggregates occur as rosettes and spheroids consisting of plates.Some of them grow over pyrite,indicating that gypsum precipitation postdates pyrite formation.The sulfur isotopic values(δ~(34) S) of pyrite vary greatly(from –46.6‰ to –12.3‰ V-CDT) and increase with depth.Thus,the pyrite in the shallow sediments resulted from organoclastic sulfate reduction(OSR) and is influenced by AOM with depth.The relative high abundance and δ~(34) S values of pyrite in sediments at depths from 580 to 810 cmbsf indicate that this interval is the location of a paleo-sulfate methane transition zone(SMTZ).The sulfur isotopic composition of gypsum(from–25‰ to –20.7‰) is much lower than that of the seawater sulfate,indicating the existence of a 34 S-depletion source of sulfur species that most likely are products of the oxidation of pyrites formed in OSR.Pyrite oxidation is controlled by ambient electron acceptors such as MnO_2,iron(Ⅲ) and oxygen driven by the SMTZ location shift to great depths.The δ~(34) S values of gypsum at greater depth are lower than those of the associated pyrite,revealing downward diffusion of 34 S-depleted sulfate from the mixture of oxidation of pyrite derived by OSR and the seawater sulfate.These sulfates also lead to an increase of calcium ions from the dissolution of calcium carbonate mineral,which will be favor to the formation of gypsum.Overall,the mineralogy and sulfur isotopic composition of the pyrite and gypsum suggest variable redox conditions caused by reduced seepage intensities,and the pyrite and gypsum can be a recorder of the intensity evolution of methane seepage.  相似文献   

华南陆缘高热流区的壳幔温度结构与动力学背景          下载免费PDF全文

张健  王蓓羽  唐显春  董淼  艾依飞 《地球物理学报》2018,61(10):3917-3932

华南陆缘是我国重要的矿产、地热资源区.晚中生代以来，在太平洋板块西向俯冲，地幔热对流活动共同作用下，该区出现多期岩浆-热事件和大规模爆发式成矿作用.在前人研究基础上，本文利用地表热流观测资料、地震剪切波资料、重力位球谐系数，计算了壳-幔温度结构，分析了动力学背景.计算结果表明：华南陆缘东南沿海地带，地壳10 km以浅温度达200℃以上，居里点温度475℃，莫霍面平均温度550℃.地壳浅层较热，花岗岩中放射性元素衰变放热是地壳浅层地下水热活动的重要热源，但地壳总体温度不高，为"冷壳热幔"型热结构.地幔中，90 km深度，温度950~1250℃；120 km深度，温度1050~1400℃；150 km深度，温度1200~1450℃；220 km深度，温度1500~1700℃."热"岩石圈底界深度在110~150 km之间，西深东浅.岩石圈内，地幔应力场为挤压-伸展相间格局；岩石圈之下，地幔应力场为一个以南昌为中心、长轴NE-SW向的椭圆.分析认为，晚中生代以来，太平洋板块的西向俯冲，导致华南陆缘在区域性SE向地幔对流背景上叠加局域性不稳定热扰动，在175~85Ma期间，上地幔物质向上流动，形成不同的岩浆活动高峰期.同时，岩石圈地幔受俯冲洋壳流体的影响，含水量高，黏度小，在地幔流切向应力场作用下，岩石圈底界由西向东"波浪"状减薄.现今岩石圈之下仍具备地幔小尺度热对流温度条件，但除地表浅层外，地壳整体温度不高，岩石圈构造稳定.  相似文献   

Spatial and temporal analysis of hillslope–channel coupling and implications for the longitudinal profile in a dryland basin          下载免费PDF全文

Katerina Michaelides  Rory Hollings  Michael Bliss Singer  Mary H. Nichols  Mark A. Nearing 《地球表面变化过程与地形》2018,43(8):1608-1621

The long‐term evolution of channel longitudinal profiles within drainage basins is partly determined by the relative balance of hillslope sediment supply to channels and the evacuation of channel sediment. However, the lack of theoretical understanding of the physical processes of hillslope–channel coupling makes it challenging to determine whether hillslope sediment supply or channel sediment evacuation dominates over different timescales and how this balance affects bed elevation locally along the longitudinal profile. In this paper, we develop a framework for inferring the relative dominance of hillslope sediment supply to the channel versus channel sediment evacuation, over a range of temporal and spatial scales. The framework combines distinct local flow distributions on hillslopes and in the channel with surface grain‐size distributions. We use these to compute local hydraulic stresses at various hillslope‐channel coupling locations within the Walnut Gulch Experimental Watershed (WGEW) in southeast Arizona, USA. These stresses are then assessed as a local net balance of geomorphic work between hillslopes and channel for a range of flow conditions generalizing decadal historical records. Our analysis reveals that, although the magnitude of hydraulic stress in the channel is consistently higher than that on hillslopes, the product of stress magnitude and frequency results in a close balance between hillslope supply and channel evacuation for the most frequent flows. Only at less frequent, high‐magnitude flows do channel hydraulic stresses exceed those on hillslopes, and channel evacuation dominates the net balance. This result suggests that WGEW exists mostly (~50% of the time) in an equilibrium condition of sediment balance between hillslopes and channels, which helps to explain the observed straight longitudinal profile. We illustrate how this balance can be upset by climate changes that differentially affect relative flow regimes on slopes and in channels. Such changes can push the long profile into a convex or concave condition. © 2018 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd.  相似文献   

南海北部东沙海域天然气水合物分解事件及其与海底滑塌的关系     

黄怡  王淑红  颜文  程俊 《热带海洋学报》2018,37(4):61-69

东沙海域是南海北部一个重要的天然气水合物成藏区, 其陆坡广泛发育滑塌构造。文章对采自东沙陆坡中部973-4柱样和下部平坦区973-5柱样开展了沉积学粒度、底栖有孔虫种属特征和稳定同位素等的综合分析。研究结果表明: 两个柱样中底栖有孔虫的δ¹³C在末次冰期均出现明显负偏现象, 同时δ¹⁸O增高, 指示该时期东沙海域存在持续的天然气水合物分解事件; 末次冰消期以来, δ¹³C负偏现象逐渐消失, δ¹⁸O值降低, 可能是由于海平面上升阻止了天然气水合物分解。973-4柱样仅在末次盛冰期对应层位440~600cm段存在明显的滑塌沉积, 且该层段对应的特征底栖有孔虫Uvigerina spp.和Bulimina spp.的数量突增, 推测该区的海底滑塌可能是由于末次盛冰期海平面大幅度下降引起天然气水合物大量分解诱发所致; 973-5柱样同样记录到了海底滑塌现象, 但其滑塌沉积晚于973-4柱样的滑塌时间, 且其规模较小。  相似文献   

Wintertime rates of net primary production and nitrate and ammonium uptake in the southern Benguela upwelling system     

RF Flynn  JM Burger  K Pillay 《African Journal of Marine Science》2018,40(3):253-266

The elevated levels of primary productivity associated with eastern boundary currents are driven by nutrient- rich waters upwelled from depth, such that these regions are typically characterised by high rates of nitrate-fuelled phytoplankton growth. Production studies from the southern Benguela upwelling system (SBUS) tend to be biased towards the summer upwelling season, yet winter data are required to compute annual budgets and understand seasonal variability. Net primary production (NPP) and nitrate and ammonium uptake were measured concurrently at six stations in the SBUS in early winter. While euphotic zone NPP was highest at the stations nearest to the coast and declined with distance from the shore, a greater proportion was potentially exportable from open-ocean surface waters, as indicated by the higher specific nitrate uptake rates and f-ratios (ratio of nitrate uptake to total nitrogen consumption) at the stations located off the continental shelf. Near the coast, phytoplankton growth was predominantly supported by ammonium despite the high ambient nitrate concentrations. Along with ammonium concentrations as high as 3.6 µmol l^–1, this strongly suggests that nitrate uptake in the inshore SBUS, and by extension carbon drawdown, is inhibited by ammonium, at least in winter, although this has also been hypothesised for the summer.  相似文献   

Tectonometamorphic evolution of the Atbashi high‐P units (Kyrgyz CAOB,Tien Shan): Implications for the closure of the Turkestan Ocean and continental subduction–exhumation of the South Kazakh continental margin          下载免费PDF全文

Chloé Loury  Yann Rolland  Stéphane Guillot  Pierre Lanari  Clément Ganino  Raphael Melis  Anthony Jourdon  Carole Petit  Olivier Beyssac  Sylvain Gallet  Patrick Monié 《Journal of Metamorphic Geology》2018,36(8):959-985

The South Tien Shan (STS) belt results from the last collision event in the western Central Asian Orogenic Belt (CAOB). Understanding its formation is of prime importance in the general framework of the CAOB. The Atbashi Range preserves high‐P (HP) rocks along the STS suture, but still, its global metamorphic evolution remains poorly constrained. Several HP units have been identified: (a) a HP tectonic mélange including boudins of mafic eclogites in a sedimentary matrix, (b) a large (>100 km long) high‐P metasedimentary unit (HPMU) and (c) a lower blueschist facies accretionary prism. Raman Spectroscopy on carbonaceous material combined with phengite and chlorite multiequilibria and isochemical phase diagram modelling indicates that the HPMU recorded homogeneous P–T conditions of 23–25 kbar and 560–570°C along the whole unit. ⁴⁰Ar/³⁹Ar dating on phengite from the HPMU ranges between 328 and 319 Ma at regional scale. These ages are interpreted as (re‐) crystallization ages of phengite during T_max conditions at a pressure range of 20–25 kbar. Thermobarometry on samples from the HP tectonic mélange provides similar metamorphic peak conditions. Thermobarometry on the blueschist to lower greenschist facies accretionary prism indicates that it underwent P–T conditions of 5–6 kbar and 290–340°C, highlighting a 17–20 kbar pressure gap between the HPMU‐tectonic mélange units and the accretionary prism. Comparison with available geochronological data suggests a very short time span between the prograde path (340 Ma), HP metamorphic peak (330 Ma), the T_max (328–319 Ma) and the final exhumation of the HPMU (303–295 Ma). Extrusion of the HPMU, accommodated by a basal thrust and an upper detachment, was driven by buoyant forces from 70–75 km up to 60 km depth, which directly followed continental subduction and detachment of the HPMU. At crustal depths, extrusion was controlled by collisional tectonics up to shallow levels. Lithological homogeneity of the HPMU and its continental‐derived character from the North Tien Shan suggest this unit corresponds to the hyper‐extended continental margin of the Kazakh continent, subducted southward below the north continental active margin of the Tarim craton. Integration of the available geological data allows us to propose a general geodynamic scenario for Tien Shan during the Carboniferous with a combination of (a) N‐dipping subduction below the Kazakh margin of Middle Tien Shan until 390–340 Ma and (b) S‐dipping subduction of remaining Turkestan marginal basins between 340 and 320 Ma.  相似文献   

黑河中游夏季昼夜水汽同位素特征及水汽来源分析          下载免费PDF全文

孟鸿飞  张明军  王圣杰  邱雪  杜铭霞  张亚宁  余秀秀  周苏娥 《干旱区地理》2020,43(2):360-370

基于2012年6~8月的实测水汽同位素数据及相关气象数据，对黑河中游夏季昼夜的同位素基本特征、水汽来源方向及潜在蒸发源地进行了研究。结果表明：空气水汽线斜率白天大于夜晚和水汽过量氘值白天大于夜晚，综合说明白天局地蒸发较夜晚强烈；夏季受西风水汽影响显著。其中，6月主要受西风水汽和北冰洋水汽影响，7、8月主要受西风水汽和东南方向水汽影响，且8月受东南方向水汽影响最为明显；水汽运移路径上下垫面地形和气压带移动会影响水汽后向轨迹高度，西北方向上水汽输送通道较顺畅，风速较大，有利于水汽的输送；水汽蒸发源地主要集中在研究区周围及以东、以北部，其次是西北部。绿洲是主要的水汽蒸发源地，其次是城市和河流，白天较夜晚局地蒸发强烈且面积大。  相似文献   

基于 SRP 概念模型的祁连山地区生态脆弱性评价   总被引：1，自引：0，他引：1       下载免费PDF全文

刘佳茹  赵军  沈思民  赵彦军 《干旱区地理》2020,43(6):1573-1582

基于生态敏感性-生态恢复力-生态压力度（SRP）概念模型，从地形、气候、植被和社会经济 因子选取 8 个评价指标，利用遥感和 GIS 技术，采用主成分分析方法求取权重，对祁连山地区启动 水源涵养区生态环境保护和综合治理规划研究前后近 10 a 的生态脆弱性程度进行系统、定量地评 估，旨在揭示生态脆弱性的分布特征、时空演变及动因，为区域生态保护、资源利用和可持续发展 提供参考。结果表明：（1）从研究区生态脆弱性分布来看，祁连山地区主要以轻度和重度脆弱为 主，脆弱性程度从西北向东南地区逐渐减弱，西北地区植被覆盖度小，海拔高，生态环境较为恶劣 是导致脆弱性程度较高的原因；（2）祁连山地区 3 期生态脆弱程度呈逐渐下降趋势，综合指数分别 为 3.307、3.118 和 3.103；2005 年 生 态 脆 弱 性 较 高 ，极 度 脆 弱 面 积 为 28 610 km²，2010 年 下 降 为 11 723 km²，2015 年降低为 6 174 km²，极度脆弱面积逐渐减少；（3）从祁连山地区生态脆弱性演变动 因来看，8 个指标对生态脆弱性影响均较为显著，但在不同的时间影响程度各不相同，2005—2015 年 3 期数据中对生态脆弱性影响最大的均为植被指数，降水次之，地形因子影响最小。总体来看， 近年来祁连山地区生态脆弱性程度有所降低，但仍然需要加强保护力度，促进生态环境可持续 发展。  相似文献   

A modified numerical model for moisture-salt transport in unsaturated sandy soil under evaporation     

Wei Wen  YuanMing Lai  ZheMin You 《寒旱区科学》2020,12(3):125-133

Soil salinization, caused by salt migration and accumulation underneath the soil surface, will corrode structures. To analyze the moisture-salt migration and salt precipitation in soil under evaporation conditions, a mathematical model consisting of a series of theoretical equations is briefly presented. The filling effect of precipitated salts on tortuosity factor and evaporation rate are taken into account in relevant equations. Besides, a transition equation to link the solute transport equation before and after salt precipitation is proposed. Meanwhile, a new relative humidity equation deduced from Pitzer ions model is used to modify the vapor transport flux equation. The results show that the calculated values are in good agreement with the published experimental data, especially for the simulation of volume water content and evaporation rate of Toyoura sand, which confirm the reliability and applicability of the proposed model.  相似文献   

生物土壤结皮铁代谢微生物组成及其功能基因对演替的响应     

王岩松  刘玉冰  王增如  赵丽娜  漆婧华  张雯莉 《中国沙漠》2020,40(3):193-200

采用微生物宏基因组学微阵列GeoChip 5.0技术，选择腾格里沙漠东南缘沙坡头地区不同年代人工固沙植被区的生物土壤结皮（BSC）为对象，分析BSC演替过程中参与铁代谢的功能微生物组成及其功能基因变化特征，研究微生物铁代谢对BSC演替的响应及调控。结果表明：真菌参与铁吸收和转运过程，古菌参与铁转运和贮存过程，细菌则在铁代谢吸收、转运和贮存过程中均起主要调控作用。门水平上，BSC铁代谢功能微生物组成变化对演替的响应不敏感，BSC铁代谢微生物主要为变形菌门（Proteobacteria）。BSC铁代谢功能基因多样性的显著提高和三类铁代谢过程基因信号强度达到最高水平需要经过61 a的演替。调控BSC铁吸收过程的主要功能基因为亚铁氧化酶编码基因iro；调控原核生物铁转运过程的主要功能基因，为羟基苯甲酰丝氨酸铁外膜转运体编码基因cirA和Fe（Ⅱ）转运蛋白编码基因feoB，真菌铁转运过程主要依靠含铁细胞转运体和铁氧化酶高亲和力的作用；调控铁贮存过程的主要功能基因为固定相类核蛋白编码基因dps。在BSC演替阶段末期，上述铁代谢功能基因强度的显著增加促进了微生物的铁代谢潜能。干旱、半干旱荒漠生态系统植被恢复过程中微生物铁代谢潜能的恢复需要较长时间。  相似文献