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51.
Gas production from unconventional reservoirs has led to widespread environmental concerns. Despite several excellent reviews of various potential impacts to water resources from unconventional gas production, no study has systematically and quantitatively assessed the potential for these impacts to occur. We use empirical evidence and numerical and analytical models to quantify the likelihood of surface water and groundwater contamination, and shallow aquifer depletion from unconventional gas developments. These likelihoods are not intended to be exact. They provide a starting point for comparing the probabilities of adverse impacts between types of water resources and pathways. This analysis provides much needed insight into what are “probable” rather than simply “possible” impacts. The results suggest that the most likely water resource impacts are surface water and groundwater contamination from spills at the well pad, which can be as high as 1 in 10 and 1 in 100 for each gas well, respectively. For wells that are hydraulically fractured, the likelihood of contamination due to inter-aquifer leakage is 1 in 106 or lower (dependent on the separation distance between the production formation and the aquifer). For gas-bearing formations that were initially over-pressurized, the potential for contamination from inter-aquifer leakage after production ceases could be as high as 1 in 400 where the separation between gas formation and shallow aquifer is 500 m, but will be much lower for greater separation distances (more characteristic of shale gas).  相似文献   
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Beach ridge stratigraphy can provide an important record of both sustained coastal progradation and responses to events such as extreme storms, as well as evidence of earthquake induced sediment pulses. This study is a stratigraphic investigation of the late Holocene mixed sand gravel (MSG) beach ridge plain on the Canterbury coast, New Zealand. The subsurface was imaged along a 370 m shore-normal transect using 100 and 200 MHz ground penetrating radar (GPR) antennae, and cored to sample sediment textures. Results show that, seaward of a back-barrier lagoon, the Pegasus Bay beach ridge plain prograded almost uniformly, under conditions of relatively stable sea level. Nearshore sediment supply appears to have created a sustained sediment surplus, perhaps as a result of post-seismic sediment pulses, resulting in a flat, morphologically featureless beach ridge plain. Evidence of a high magnitude storm provides an exception, with an estimated event return period in excess of 100 years. Evidence from the GPR sequence combined with modern process observations from MSG beaches indicates that a palaeo-storm initially created a washover fan into the back-barrier lagoon, with a large amount of sediment simultaneously moved off the beach face into the nearshore. This erosion event resulted in a topographic depression still evident today. In the subsequent recovery period, sediment was reworked by swash onto the beach as a sequence of berm deposit laminations, creating an elevated beach ridge that also has a modern-day topographic signature. As sediment supply returned to normal, and under conditions of falling sea level, a beach ridge progradation sequence accumulated seaward of the storm feature out to the modern-day beach as a large flat, uniform progradation plain. This study highlights the importance of extreme storm events and earthquake pulses on MSG coastlines in triggering high volume beach ridge formation during the subsequent recovery period. © 2019 John Wiley & Sons, Ltd.  相似文献   
55.
In this contribution an overview of oceanic lithosphere, associated ore deposits (sulphides, Fe and Mn oxides, chromitites) and their final destination in ophiolitic rocks are presented. This is followed by a discussion on massive sulphide mineralisation formed at mid-ocean ridges (MOR) and/or supra-subduction zones (SSZ). The geological characteristics and the genesis of the Cu-rich massive sulphide deposits of Cyprus and of the Oman ophiolite are discussed based on an extensive review of the published literature. This is followed by a synopsis of the ophiolitic terranes and associated mineral system in the Urals. We also present an overview of the ophiolitic belts and sutures of the Tethyan orogens, focussing on the podiform chromite deposits that they typically host, with a special focus on the ophiolitic chromitites of Turkey. A final section deals with possible ophiolites of Proterozoic and Archaean ages and, where applicable, associated chromitites. In the concluding remarks a brief note is made of some specific ancient seafloor hydrothermal constructs that have been interpreted as black chimneys in volcanogenic massive sulphide (VMS) deposits now hosted in ophiolitic sequences.  相似文献   
56.
The Bastar craton in central India, surrounded by cratonic blocks and Paleoproterozoic to Neoproterozoic orogenic belts, is a window to investigate the Archean-Paleoproterozoic crustal evolution and tectonic processes. Here we propose a new tectonic classification of the craton into the Western Bastar Craton (WBC), Eastern Bastar Craton (EBC), and the intervening Central Bastar Orogen (CBO). We present petrologic, geochemical and zircon U-Pb, REE and Lu-Hf data from a suite of rocks from the CBO and along the eastern margin of the WBC Including: (1) volcanic successions comprising meta-andesite and fine-grained amphibolite, representing arc-related volcanics along a convergent margin; (2) ferruginous sandstone, in association with rhyolite, representing a volcano-sedimentary succession, deposited in an active trench; and (3) metamorphosed mafic-ultramafic suite including gabbro, pyroxenite and dunite invaded by trondhjemite representing the section of sub-arc mantle and arc root adjacent to a long-lasting subduction system. Petrologic studies indicate that the mafic-ultramafic suite crystallized from an island arc tholeiitic parental magma in a suprasubduction zone environment. The chondrite-normalized and primitive mantle normalized diagrams of the mafic and ultramafic rocks suggest derivation from MORB magma. The mixed characters from N-MORB to E-MORB of the studied samples are consistent with subduction modification of a MORB related magma, involving partial melting of the metasomatized mantle wedge. Our zircon U-Pb age data suggest that the cratonic nuclei was constructed as early as Paleoarchean. We present evidence for active subduction and arc magmatism through Mesoarchean to Neoarchean and early Paleoproterozoic, with the trench remaining open until at least 2.3 Ga. Two major crust building events are recognized in the Bastar craton: during Mesoarchean (recycled Paleoarchean subduction-related as well as juvenile/depleted mantle components) and Neoarchean (accretion of juvenile oceanic crust, arc magmatism including granite batholiths and related porphyry mineralization). The final cratonization occurred during latest Paleoproterozoic, followed by collisional assembly of the craton and its incorporation within the Peninsular Indian mosaic during Mesoproterozoic. In the global supercontinent context, the craton preserves the history of Ur, the earliest supercontinent, followed by the Paleo-Mesoproterozoic Columbia, as well as minor thermal imprints of the Neoproterozoic Rodinia and associated Grenvillian orogeny.  相似文献   
57.
This study used new and published U-Pb geochronological, chemical, and Sr-Nd-Hf-O isotopic data (n > 2500) from Jurassic granite-granodiorite-diorite-monzonite-gabbro plutons in the southern part of the Korean Peninsula to assess the spatiotemporal evolution of a flare-up magmatism, its tectonic connection, and specific contributions of mantle and crustal reservoirs to the magmas generated. After a ~15 m.y. magmatic gap in the Late Triassic, calc-alkaline granitoids intruded into the outboard Yeongnam Massif, then magmatic activity migrated systematically toward the inboard Gyeonggi Massif. The early phase of the Jurassic magmatism is represented by relatively sodic plutons showing distinctly primitive isotopic signatures. The crustal signature of the plutons became increasingly prominent with decreasing age. Voluminous inboard plutons in the Gyeonggi Massif and the intervening Okcheon Belt are dominated by Middle Jurassic peraluminous granites that show isotopic compositions conspicuously shifted toward old crustal values. The Nd-Hf isotopic compositions of the inboard plutons are distinctly less radiogenic than those of Jurassic plutons in Southwest Japan and southeastern China, which corroborates the North China affinity of the Yeongnam and Gyeonggi massifs. The geochronological and geochemical data compiled in this study suggest a tectonomagmatic model consisting sequentially of (1) an extension-dominated arc system in the margin of the Yeongnam Massif (ca. 200–190 Ma); (2) low-angle subduction and the development of an advancing arc system (ca. 190–180 Ma); (3) continued low-angle subduction, extensive underthrusting of fertile crustal materials to the arc root, and consequent magmatic flare-up (ca. 180–170 Ma); and (4) flat subduction and the development of the Honam Shear Zone (ca. 170–160 Ma). The subsequent magmatic lull and previous dating results for synkinematic rocks and minerals indicate that the compressional arc system was maintained until the Early Cretaceous.  相似文献   
58.
Eurypterids, the so-called sea scorpions, are a group of extinct chelicerates with a diversity of over 250 species. Although the group has a distribution across most of the globe, the majority of taxa are known from the northern Hemisphere. Despite the general palaeontological interest in sea scorpions, Gondwanan—specifically Australian—taxa have received little consideration. To rectify this, we collate data on Australian sea scorpion material from the Gogo, Melbourne and Montys Hut formations, the Humevale and Muttama Creek siltstones and the Wilson Creek Shale. The studied material spans the late Silurian to the late Devonian and highlights a rich Pterygotidae fauna, especially in the state of Victoria. We conclude that presently there is insufficient material to erect new taxa. However, further collecting of material—especially the Wilson Creek Shale and the Montys Hut Formation—will uncover more material to aid in understanding the most southern, Gondwanan eurypterids.  相似文献   
59.
Post-collisional K-rich volcanic rocks (KVRs) can provide an opportunity to constrain the architecture of the lithosphere and the mechanisms of plateau uplift. However, their petrogenesis and geodynamic setting remain in dispute. Lithium concentrations and isotopic compositions of 87 potassic, ultrapotassic and Mg-rich potassic volcanic rocks (PVRs, UPVs, and MPRs, respectively) in SW Tibet, along with new Pb–Sr–Nd isotope data and whole-rock analyses, are used to constrain their mantle source and genesis. These rocks are characterized by very similar δ7Li values: PVRs vary from −4.9‰ to +3.2‰, UPVs from −3.9‰ to +1.7‰, and MPRs from −1.2‰ to +3.5‰. They can be classified into two groups: Group I (19 out of 87 samples) with heavier δ7Li values (+1.0‰ to +3.5‰) similar to those reported for mid-ocean-ridge and ocean-island basalts (MORBs and OIBs, respectively), and Group II (68 out of 87 samples) with lighter values (−4.9‰ to +1.0‰) similar to those of Indian lower crust. These variable isotopic compositions may record the isotopic signature of the early-middle Miocene subcontinental lithospheric mantle (SCLM). This paper demonstrates the existence of isotopically light mantle domains beneath the Lhasa terrane, which were ascribed to the interaction with fluids/melts derived from the subducted Indian lower crust. The modeling curves of Indian lower crust with a metasomatized mantle composition fully account for compositional variations in the PVRs, UPVs, and MPRs. They were generated by the partial melting of SCLM, which was metasomatized by fluids/melts derived from the subducted Indian lower crust (ca. 4–14%, ca. 4–10%, and ca. 6–10% for the PVRs, UPVs, and MPRs, respectively). The Li isotopic data indicate that the Indian lower crust was subducted beneath the central Lhasa subterrane, and this sheds new light on the formation of the Tibet Plateau.  相似文献   
60.
The Lorca and Fortuna basins are two intramontane Neogene basins located in the eastern Betic Cordillera (SE Spain). During the Late Tortonian—Early Messinian, marine and continental evaporites precipitated in these basins as a consequence of increased marine restriction and isolation. Here we show a stratigraphic correlation between the evaporite records of these basins based on geochemical indicators. We use SO4 isotope compositions and Sr isotopic ratios in gypsum, and halite Br contents to characterize these units and to identify the marine or continental source of the waters feeding the evaporite basins. In addition, we review the available chronological information used to date these evaporites in Lorca (La Serrata Fm), including a thick saline deposit, that we correlate with the First Evaporitic Group in Fortuna (Los Baños Fm). This correlation is also supported by micropalaeontological data, giving a Late Tortonian age for this sequence. The Second Evaporitic Group, (Chicamo Fm), and the Third Evaporitic Group (Rambla Salada Fm) developed only in Fortuna during the Messinian. According to the palaeogeographical scheme presented here, the evaporites of the Lorca and Fortuna basins were formed during the Late Tortonian—Early Messinian, close to the Betic Seaway closure. Sulphate isotope compositions and Sr isotopic ratios of the Ribera Gypsum Mb, at the base of the Rambla Salada Fm (Fortuna basin), match those of the Late Messinian selenite gypsum beds in San Miguel de Salinas, in the near Bajo Segura basin (40 km to the East), and other Messinian Salinity Crisis gypsum deposits in the Mediterranean. According to these geochemical indicators and the uncertainty of the chronology of this unit, the assignment of the Rambla Salada Fm to the MSC cannot be ruled out.  相似文献   
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