吉林省下三叠统卢家屯组LA-ICP-MS锆石U-Pb定年及其地质意义     

聂立军  于宏斌  张建泽  王聪  李栋  李阳 《吉林大学学报(地球科学版)》2015,45(2):453-470

卢家屯组按岩性组合自下而上分为影背山砾岩段、漏斗山杂色岩段、杨树河子黑色岩段,前人采集到的Palaeanodonta-Palaeomutela动物群、Pleuroneia? sp.和叶肢介等生物化石组合指示时代为二叠纪。本次对九台市影背山双顶山卢家屯组建组剖面下、中、上段进行了系统的碎屑锆石U-Pb同位素年代学研究,证实卢家屯组由下至上存在3个最小锆石年龄峰值,分别为(283.4±7.9)、(262.4±3.9)、(255.5±5.8) Ma,确定了卢家屯组的上限为晚二叠世。根据卢家屯组中碎屑锆石存在1 800 Ma和2 500 Ma左右的典型华北板块基底年龄,认为华北板块北缘与其北侧地块群最终闭合时间应为P₃-T₁。  相似文献   

Chronology and Geochemistry of Mesozoic Volcanic Rocks in the Linjiang Area,Jilin Province and their Tectonic Implications   总被引：9，自引：1，他引：9  

YU Yang  XU Wenliang  PEI Fuping  YANG Debin  ZHAO Quanguo 《《地质学报》英文版》2009,83(2):245-257

Zircon U-Pb ages and geochemical analytical results are presented for the volcanic rocks of the Naozhigou, Ergulazi, and Sidaogou Formations in the Linjiang area, southeastern Jilin Province to constrain the nature of magma source and their tectonic settings. The Naozhigou Formation is composed mainly of andesite and rhyolite and its weighted mean 206Pb/238U age for 13 zircon grains is 222±1 Ma. The Ergulazi Formation consists of basaltic andesite, basaltic trachyandesite, and andesite, and six grains give a weighted mean 206Pb/238U age of 131±4 Ma. The Sidaogou Formation consists mainly of trachyandesite and rhyolite, and six zircon grains yield a weighted mean 206Pb/238U age of 113±4 Ma. The volcanic rocks have SiO2=60.24%–77.46%, MgO=0.36%–1.29% (Mg#=0.32–0.40) for the Naozhigou Formation, SiO2=51.60%–59.32%, MgO=3.70%–5.54% (Mg#=0.50–0.60) for the Ergulazi Formation, and SiO2=58.28%–76.32%, MgO=0.07%–1.20% (Mg#=0.14–0.46) for the Sidaogou Formation. The trace element analytical results indicate that these volcanic rocks are characterized by enrichment in light rare earth elements (LREEs) and large ion lithophile elements (LILEs), relative depletion in heavy rare earth elements (HREEs) and high field strength elements (HFSEs, Nb, Ta, and Ti), and negative Eu anomalies. Compared with the primitive mantle, the Mesozoic volcanic rocks in the Linjiang area have relatively high initial 87Sr/86Sr ratios (0.7053-0.7083) and low εNd(t) values (?8.38 to ?2.43), and display an EMII trend. The late Triassic magma for the Naozhigou Formation could be derived from partial melting of a newly accretional crust with the minor involvement of the North China Craton basement and formed under an extensional environment after the collision of the Yangtze Craton and the North China Craton. The Early Cretaceous volcanic rocks for the Ergulazi and Sidaogou Formations could be formed under the tectonic setting of an active continental margin related to the westward subduction of the Izanagi plate.  相似文献   

新疆肯登高尔铜钼矿区侵入岩年代学、地球化学及其大地构造意义     

王冠南  顾雪祥  章永梅  李卫东  曹景良  颜家辉 《地质学报》2017,91(11):2473-2492

肯登高尔铜钼矿床是新疆西天山博罗科努成矿带中一处矽卡岩型矿床,矿体赋存于纳林果勒中酸性侵入体与上石炭统东图津河组钙质粉砂岩夹碳酸盐岩的接触带上。纳林果勒岩体主要由花岗闪长岩与二长花岗岩组成。通过LA-ICP-MS锆石U-Pb同位素定年,获得花岗闪长岩和二长花岗岩的加权平均年龄分别为316.3±3.5Ma和298.9±3.3Ma,表明两者侵位时代分别为晚石炭世和早二叠世。地球化学组成上花岗闪长岩具有高硅和高钠的特征,富集Sr、Rb和Th,亏损Nb、Ta、Yb和Y,无Eu异常,岩石具有埃达克岩的特征,是造山晚期加厚下地壳部分熔融的产物。二长花岗岩具有富硅、富钾、低铝的特征,富集Rb、Th、Nb和Hf,亏损Sr、Ta和Ti,具有明显Eu负异常,岩石为高分异I型花岗岩,是岩石圈伸展减薄背景下,下地壳进一步熔融形成的基性岩浆通过分离结晶作用形成的产物。结合成岩年龄和区域构造背景,推测西天山北缘在晚石炭世进入碰撞造山阶段,在早二叠世向造山后伸展阶段过渡。  相似文献   

新疆东天山哈尔里克奥陶纪的构造属性:来自火山岩LA ICP MS锆石U Pb年代学与地球化学的制约     

李江涛  何学锋  刘亮  杨鹏涛  梁斌  苏画 《现代地质》2017,31(3):460

新疆东天山哈尔里克造山带火山岩为一套酸性—基性岩(流纹岩、英安岩、安山岩、玄武岩)夹火山碎屑岩(凝灰岩)的岩石组合。流纹岩样品的LA ICP MS锆石U Pb定年结果显示,时代为中奥陶世大坪期((4688±91) Ma),代表了该套火山岩的形成年龄。岩石地球化学分析结果显示,该套火山岩SiO2含量介于4912%～7824%,TiO2介于012%～100%,Al2O3介于1131%～2086%;铝饱和指数A/CNK值为080～131(均值为099),里特曼指数σ值为019～386(均值为129),Mg#值为887～4929(均值为3120);富集大离子亲石元素(LILE)Ba、Rb以及轻稀土元素(∑LREE)La、Ce,亏损高场强元素(HFSE)Nb、Ta、Ti等。微量元素和稀土元素的相关图解与比值以及发育的捕获锆石反映了俯冲带岛弧钙碱性火山岩特征,且存在大陆地壳混染作用。综合区域地质资料分析,在早古生代期间(中奥陶世—早志留世),哈尔里克造山带存在大面积的与岛弧演化有关的加里东期岩浆活动,此期间哈尔里克造山带的构造背景为洋壳俯冲有关的岛弧环境,其形成可能与东准噶尔南部克拉麦里洋向南俯冲作用有关。  相似文献   

北秦岭西段黄牛铺岩体锆石U Pb年代学、岩石地球化学特征及其地质意义     

姚征  张亚峰  杨涛  易鹏飞  郑淑新 《现代地质》2017,31(6):1157

对北秦岭西段黄牛铺岩体进行了LA ICP MS锆石U Pb年代学与岩石地球化学分析。结果显示,黄牛铺岩体的锆石U Pb年龄为(4493±49) Ma,表明其形成时代为晚奥陶世。黄牛铺岩体属于准铝质高钾钙碱性系列,在成因类型上具有I型花岗岩的岩石矿物学与地球化学特征,其稀土元素配分曲线呈轻稀土元素富集、重稀土元素亏损(LREE/HREE=983~1155)、铕弱负异常(δEu=082~095)的右倾型,微量元素Rb、Th、U、Sm等富集,Ta、Nb、Ti、Hf等明显亏损,表现为岛弧岩浆岩的地球化学特征。结合区域地质资料,认为黄牛铺岩体形成于晚奥陶世商丹洋俯冲过程中的岛弧环境,是壳幔岩浆混合作用的产物,这为进一步研究北秦岭的构造演化过程提供了更加充分准确的岩浆活动证据。  相似文献   

西准噶尔恰达地区哈尔加乌组火山岩锆石U-Pb年代学、地球化学及地质意义     

田陟贤  李永军  田猛  杨高学  向坤鹏  佟丽莉 《吉林大学学报(地球科学版)》2016,46(1):135-145

恰达地区的二叠系哈尔加乌组火山岩分布于唐巴勒蛇绿岩带东侧、准噶尔盆地西南缘,主要岩性为灰绿色-紫红色(气孔)(杏仁)玄武岩-玄武安山岩-安山岩。LA-ICP-MS锆石U-Pb年龄为(296.6±8.1) Ma,MSWD=7.7(93%置信度),时代属早二叠世。地球化学研究表明:该火山岩属亚碱性系列,全碱含量较高(w(Na₂O+K₂O)=3.95%~6.39%)且相对富钠。轻稀土(LREE)相对富集((La/Yb)_N=3.49~14.66)且分馏较好((La/Sm)_N值均大于1.00(1.68~3.51)),重稀土分馏较差((Gd/Yb)_N=1.38~2.56)。仅部分样品有微弱的负铕异常(δEu=0.88~1.15)。微量元素具有大离子亲石元素(LILE)相对富集,高场强元素(HFSE)Nb、Ta相对亏损,Zr、Hf轻微富集的特征。综合火山岩的地球化学特征,结合相关构造判别图解及火山岩所处的区域地质背景,认为哈尔加乌组火山岩的形成背景以板内大陆环境为主,兼有部分弧火山岩的特征,形成于俯冲碰撞造山期后的区域伸展背景下,火山岩的岛弧特征是对碰撞前混染弧组分的继承。  相似文献   

ICP-OES法测定煤样中磷、铜、铅、锌、镉、铬、镍、钴等元素   总被引：1，自引：0，他引：1  

杜白  徐红梅  廖丽荣 《云南地质》2012,(1):128-130

采用硝酸—氢氟酸—高氟酸混合体系,微波消解样品,用ICP-OES法测定煤样中微量元素P、Cu、Pb、Zn、Cr、Dd、Ni、Co,快速简便、准确度高。  相似文献   

In Situ Determination of Au and Cu in Natural Pyrite by Near‐Infrared Femtosecond Laser Ablation‐Inductively Coupled Plasma‐Quadrupole Mass Spectrometry: No Evidence for Matrix Effects     

German Velásquez  Anastassia Y. Borisova  Stefano Salvi  Didier Béziat 《Geostandards and Geoanalytical Research》2012,36(3):315-324

Gold and copper concentrations were determined in natural pyrite by near‐infrared femtosecond LA‐ICP‐QMS, using both sulfide reference materials (pyrrhotite Po‐726 and in‐house natural chalcopyrite Cpy‐RM) and NIST SRM 610 as external calibrators. Firstly, using NIST SRM 610 as the external calibrator, we calculated the Au concentration in Po‐726 and the Cu concentration in Cpy‐RM. The calculated concentration averages for Au and Cu were similar to the values published for Po‐726 and Cpy‐RM, respectively. Secondly, we calculated Au and Cu concentrations taking NIST SRM 610 as an unknown sample and using Po‐726 and Cpy‐RM as external calibrators. Again, the average values obtained closely reflected the preferred concentrations for NIST SRM 610. Finally, we calculated Au and Cu concentrations in natural pyrite using sulfide and silicate reference materials as external calibrators. In both cases, calculated concentrations were very similar, independent of the external calibrator used. The aforementioned data, plus the fact that we obtained very small differences in relative sensitivity values (percentage differences are between 5% and 17% for ⁵⁷Fe, ⁶³Cu and ¹⁹⁷Au) on analyses of silicate and sulfide RMs, indicate that there were no matrix effects related to the differences in material composition. Thus, it is possible to determine Au and Cu in natural sulfides using NIST silicate glasses as an external calibrator.  相似文献   

In Situ Determination of First‐Row Transition Metal,Ga and Ge Abundances in Geological Materials via Medium‐Resolution LA‐ICP‐MS     

Ricardo Arevalo Jr  William F. McDonough  Philip M. Piccoli 《Geostandards and Geoanalytical Research》2011,35(2):253-273

An in situ, medium‐resolution LA‐ICP‐MS method was developed to measure the abundances of the first‐row transition metals, Ga and Ge in a suite of geological materials, namely the MPI‐DING reference glasses. The analytical protocol established here hinged on maximising the ablation rate of the ultraviolet (UV) laser system and the sensitivity of the ICP‐MS, as well minimising the production of diatomic oxides and argides, which serve as the dominant sources of isobaric interferences. Non‐spectral matrix effects were accounted for by using multiple external calibrators, including NIST SRM 610 and the USGS basaltic glasses BHVO‐2G, BIR‐1G and BCR‐2G, and utilising ⁴³Ca as an internal standard. Analyses of the MPI‐DING reference glasses, which represent geological matrices ranging from basaltic to rhyolitic in composition, included measurements of concentrations as low as < 10⁰ μg g^?1 and as high as > 10⁴ μg g^?1. The new data reported here were found to statistically correlate with the ‘preferred’ reference values for these materials at the 95% confidence level, though with significantly better precision, typically on the order of ≤ 3% (2s_m). This analytical method may be extended to any matrix‐matched geological sample, particularly oceanic basalts, silicate minerals and meteoritic materials.  相似文献   

Uranium and Thorium Concentration and Isotopic Composition in Five Glass (BHVO‐2G,BCR‐2G,NKT‐1G,T1‐G,ATHO‐G) and Two Powder (BHVO‐2, BCR‐2) Reference Materials     

Kathryn A. Matthews  Michael T. Murrell  Steven J. Goldstein  Andrew J. Nunn  Deborah E. Norman 《Geostandards and Geoanalytical Research》2011,35(2):227-234

Here we report uranium and thorium isotopic ratios and elemental concentrations measured in solid reference materials from the USGS (BHVO‐2G, BCR‐2G, NKT‐1G), as well as those from the MPI‐DING series (T1‐G, ATHO‐G). Specifically created for microanalysis, these naturally‐sourced glasses were fused from rock powders. They cover a range of compositions, elemental concentrations and expected isotopic ratios. The U‐Th isotopic ratios of two powdered source materials (BCR‐2, BHVO‐2) were also characterised. These new measurements via multi‐collector thermal ionisation mass spectrometry and multi‐collector inductively coupled plasma‐mass spectrometry can now be used to assess the relative performance of techniques and facilitate comparison of U‐Th data amongst laboratories in the geoscience community for in situ and bulk analyses.  相似文献