Trace element partitioning between amphibole and hydrous silicate glasses at 0.6–2.6 GPa     

Bo Zhang  Xianxu Hu  Peng Li  Qizhe Tang  Wenge Zhou 《Acta Geochimica》2019,(3):414-429

Partitioning behavior between amphibole and silicate glass of thirty-three minor and trace elements(Sc,Ti, V, Cr, Co, Rb, Sr, P, Y, Zr, Nb, Cs, Ba, K, La, Ce, Pr,Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Hf, Ta, Pb,Th, and U) have been determined experimentally. Products of crystallization of hydrous basalt melts from 0.6 GPa/860 °C up to 2.6 GPa/970 °C were obtained in a multianvil apparatus. Major and trace element compositions of amphibole and glass were determined with a combination of electron microprobe and laser ablation inductively coupled plasma mass spectrometry. The main mineral phase is calcic amphibole, and the coexisting glass compositions are tonalite, granodiorite, and granite. The compatibility of rare earth elements increase at 915 °C and then decrease at 970 °C, but the compatibility of most of these elements shows a continued, significant increase with increasing pressure. For high-field strength elements, large ion lithophile elements, actinide compatibility decrease with increasing temperature or pressure, but transition metals show a continued increase in compatibility within the temperature–pressure conditions. From mathematical and graphical fitting, we determined best-fit values for the ideal ionic radius(r_0, 1.01–1.04 ?), the strain-free partitioncoefficient(D_0, 1.18–1.58), and apparent Young's modulus(E, 142–370 GPa) for the M4 site in amphibole according to the lattice strain model. The D_0^M4 for rare earth elements rises at 915 °C and then drops at 970 °C at 0.6 GPa.However, the D_0^M4 values are positively proportional to the pressure for rare earth elements in the amphibole-glass pairs at 0.6–2.6 GPa and 970 °C. Furthermore, the derived best-fit values for r_0^M4 and E^M4 are almost constant and trend to increase with rising temperature and pressure,respectively. The partition coefficient is distinctly different for different melt compositions. The rare earth elements become more enriched in amphibole if the quenched glass is granodiorite or granite compared to the tonalitic glasses.  相似文献   

用格子玻尔兹曼方法模拟非均匀介质中的电场响应   总被引：2，自引：0，他引：2       下载免费PDF全文

李学民  曹俊兴  何晓燕  王兴建 《地球物理学报》2004,47(2):349-353

介绍了用格子玻尔兹曼方法模拟非均匀介质中的电场响应的数值模拟方法. 格子玻尔兹曼方法是从微观领域出发进行数值计算的一种全新的正演模拟方法;从玻尔兹曼碰撞模型出发,利用泰勒展开和Chapman Enskog展开,在基本力学守恒条件和约束条件的限制下,导出了电场响应的扩散方程,得到了局部平衡分布函数的表达式,给出了若干正演模拟的结果;其结果表明,利用这种方法进行非均匀介质中的电场响应正演模拟具有灵活、方便和简单等优点.  相似文献   

A lattice Boltzmann-finite element model for two-dimensional fluid–structure interaction problems involving shallow waters     

《Advances in water resources》2014

In this paper, a numerical method for the modeling of shallow waters interacting with slender elastic structures is presented. The fluid domain is modeled through the lattice Boltzmann method, while the solid domain is idealized by corotational beam finite elements undergoing large displacements. Structure dynamics is predicted by using the time discontinuous Galerkin method and the fluid–structure interface conditions are handled by the Immersed Boundary method. An explicit coupling strategy to combine the adopted numerical methods is proposed and its effectiveness is tested by computing the error in terms of the energy that is artificially introduced at the fluid–solid interface.  相似文献   

Mesoscale modeling of water penetration into concrete by capillary absorption   总被引：3，自引：0，他引：3  

Licheng Wang  Tamon Ueda 《Ocean Engineering》2011,38(4):519-528

Water penetration into concrete by capillary absorption plays a very important role in the ingress of contaminative substances when the structures are built in aggressive environments. In the present paper the lattice network model is proposed based on the unsaturated flow theory to predict the water penetration into concrete. On the mesocale level, concrete is treated as a three-phase composite. By means of the Voronoi diagram meshing strategy, the lattice network model of concrete with different types of lattice elements is developed. The corresponding transport properties are assigned to the lattice elements in the network falling in different phases. As a result, the lattice elements are idealized as conductive “pipes” in which uni-directional flow can be realized between the two nodes of the elements. Parameters in the lattice network model, such as the sorptivity and porosity of the mortar and the ITZs are quantitatively determined. With help of the approach, the water content distribution within a concrete sample after any elapsed time, especially the penetration depth of water frontier, can be easily predicted. The cumulative water absorption calculated by the lattice network model is shown to be well agreed with the experimental results.  相似文献   

格子玻耳兹曼方法计算混合物整体电导率   总被引：6，自引：0，他引：6       下载免费PDF全文

岳文正  李征  朱克勤  陶果 《地球物理学报》2005,48(2):434-438

本文采用格子玻耳兹曼方法计算混合物的整体电导率．整体电导率与各组分的电导率、体积分数和混合物结构有关．数值计算方法的有效性通过两相混合物并联或串联模型的解析解加以验证．对随机分布模型的计算发现格子玻耳兹曼方法得到的电导率落在H S理论边界内．对Al Bi合金整体电导率的数值模拟结果和实验结果非常相近．对饱和水岩石的介电常数的计算与实验结果相比误差较小．格子玻耳兹曼方法为混合物的整体电导率的计算提供了一个有效的途径.  相似文献   

Viscous flow in three‐dimensional reconstructed porous media     

Marco Pilotti 《国际地质力学数值与分析法杂志》2003,27(8):633-649

  相似文献   

图形软件中矢量汉字的生成与应用     

赵其华  彭社琴 《地质灾害与环境保护》1997,8(2):59-64

在研制岩土工程制图软件时，摸索出两种矢量汉字的生成技术，现作一介绍，以便为有同样问题的读者提供参考，避免不必要的重要工作。  相似文献   

Systematic distribution of incompatible elements in mantle peridotite: importance of intra- and inter-granular melt-like components     

T. Hiraga  D. L. Kohlstedt 《Contributions to Mineralogy and Petrology》2009,158(2):149-167

In this paper, we examine the distribution of incompatible elements in Earth’s mantle based on data reported for 20 mantle xenoliths collected from 5 localities worldwide. A structural model combined with an element partitioning model forms the basis for our analyses. The former separates a bulk peridotite into mineral crystal lattices, interfaces (grain and interphase boundaries), and intra- and inter-granular inclusions as sites for incompatible elements. The latter relates the distribution of elements among these sites based on lattice strain theory. By treating both intra- and inter-granular inclusions as a melt-like phase, the combined models successfully reproduce the relative concentrations of incompatible elements among minerals, clean rock (reconstituted from mineral compositions and mineral mode), and whole rock. The analyses reveal common signatures in the rocks: (1) incompatible elements in the crystal lattices of olivine, orthopyroxene and clinopyroxene achieved chemical equilibrium. (2) Olivine, orthopyroxene and clinopyroxene grains contain similar amounts of an intra-granular, melt-like component possibly in the form of sub-micron inclusions with weight (≈volume) fractions between 5 × 10⁻⁵ and 1 × 10⁻². (3) All rocks contain an inter-granular melt-like component with a fraction between 10⁻⁴ and 10⁻², well above the amount expected to be stored along interfaces. (4) Fractions of the inter- and intra-granular components are positively correlated, indicating that they were originated from the same process. (5) The inter- and intra-granular melt-like phases are chemically equilibrated with other structural components. Based on plausible upwelling rates for mantle xenoliths, it is unlikely that the melt-like component formed during ascent. Instead, its ubiquitous appearance, its invisibility to optical microscopy, and its absorption of the incompatible elements in a manner similar to a melt phase even at sub-solidus condition, all might be explained by the presence of amorphous silica precipitates such as those observed previously in naturally occurring and experimentally annealed mantle composites. From the mineral mode, grain size, and mineral plus whole rock concentrations of incompatible elements, we can ascribe the chemical signatures of xenoliths to achievement of chemical equilibrium at mantle conditions rather than to a consequence of some disequilibrium (metasomatic) effect as has been done previously. Although it should be tested by additional analytical studies, our model will make it possible to determine whether or not a rock is chemically equilibrated in terms of the distribution of incompatible elements or if a metasomatic (disequilibrium) event is required.  相似文献   

饱和多相流体岩石电性的格子气模拟   总被引：16，自引：3，他引：13       下载免费PDF全文

岳文正  陶果  朱克勤 《地球物理学报》2004,47(5):905-910

利用计算机建立具有不同骨架颗粒形状和不同孔隙度的孔隙介质模型,采用格子气自动机方法模拟孔隙介质在油水饱和度不同的情况下电的传输特性,揭示了流体饱和度与介质电阻率之间呈现非阿尔奇现象的本质原因. 本文发现饱和度指数是饱和度和孔隙度的函数,反映了孔隙介质导电路径的复杂程度随饱和度变化而变化的情况,而不是传统地认为饱和度指数是流体分布状态的反映. 并得到新的饱和度计算公式. 以某油田为例,将计算的饱和度结果与实际岩芯实验的结果作对比,说明新公式的有效性.  相似文献   

Seismic properties of the upper mantle beneath Lanzarote (Canary Islands): Model predictions based on texture measurements by EBSD   总被引：1，自引：0，他引：1  

Pierre Vonlanthen  Karsten Kunze  Luigi Burlini  Bernard Grobety 《Tectonophysics》2006,428(1-4):65-85

We present a petrophysical analysis of upper mantle xenoliths, collected in the Quaternary alkali basalt fields (Series III and IV) from the island of Lanzarote. The samples consist of eight harzburgite and four dunite nodules, 5 to 15 cm in size, and exhibit a typical protogranular to porphyroclastic texture. An anomalous foliation resulting from strong recovery processes is observed in half of the specimens. The lattice preferred orientations (LPO) of olivine, orthopyroxene and clinopyroxene were measured using electron backscatter diffraction (EBSD). In most samples, olivine exhibits LPOs intermediate between the typical single crystal texture and the [100] fiber texture. Occasionally, the [010] fiber texture was also observed. Simultaneous occurrence of both types of fiber textures suggests the existence of more than one deformation regime, probably dominated by a simple shear component under low strain rate and moderate to high temperature. Orthopyroxene and clinopyroxene display a weaker but significant texture. The LPO data were used to calculate the seismic properties of the xenoliths at PT conditions obtained from geothermobarometry, and were compared to field geophysical data reported from the literature. The velocity of P-waves (7.9 km/s) obtained for a direction corresponding to the existing seismic transect is in good agreement with the most recent geophysical interpretation. Our results are consistent with a roughly W–E oriented fastest P-wave propagation direction in the uppermost mantle beneath the Canary Islands, and with the lithosphere structure proposed by previous authors involving a crust–mantle boundary at around 18 km in depth, overlaid by intermediate material between 11 and 18 km.  相似文献