Precise and Accurate In Situ Determination of Lead Isotope Ratios in NIST,USGS, MPI‐DING and CGSG Glass Reference Materials using Femtosecond Laser Ablation MC‐ICP‐MS     

Chen Kaiyun  Yuan Honglin  Bao Zhian  Zong Chunlei  Dai Mengning 《Geostandards and Geoanalytical Research》2014,38(1):5-21

Lead isotope ratio data were obtained with good precision and accuracy using a 266 nm femtosecond laser ablation (fLA) system connected to a multi‐collector ICP‐MS (MC‐ICP‐MS) and through careful control of analytical procedures. The mass fractionation coefficient induced by 266 nm femtosecond laser ablation was approximately 28% lower than that by 193 nm excimer laser ablation (eLA) with helium carrier gas. The exponential law correction method for Tl normalisation with optimum adjusted Tl ratio was utilised to obtain Pb isotopic data with good precision and accuracy. The Pb isotopic ratios of the glass reference materials NIST SRM 610, 612, 614; USGS BHVO‐2G, BCR‐2G, GSD‐1G, BIR‐1G; and MPI‐DING GOR132‐G, KL2‐G, T1‐G, StHs60/80‐G, ATHO‐G and ML3B‐G were determined using fLA‐MC‐ICP‐MS. The measured Pb isotopic ratios were in good agreement with the reference or published values within 2s measurement uncertainties. We also present the first high‐precision Pb isotopic data for GSE‐1G, GSC‐1G, GSA‐1G and CGSG‐1, CGSG‐2, CGSG‐4 and CGSG‐5 glass reference materials obtained using the femtosecond laser ablation MC‐ICP‐MS analysis technique.  相似文献   

Geochemistry,and zircon U–Pb and molybdenite Re–Os geochronology of Jilongshan Cu–Au deposit,southeastern Hubei Province,China     

A‐Juan Pang  Sheng‐Rong Li  M. Santosh  Qing‐Yu Yang  Bao‐Jian Jia  Cheng‐Dong Yang 《Geological Journal》2014,49(1):52-68

The Jilongshan skarn Cu–Au deposit is located at the Jiurui ore cluster region in the southwestern part of the Middle–Lower Yangtze River valley metallogenic belt. The region is characterized by NW‐, NNW‐ and EW‐trending faults and the mineralization occurs at the contact of lower Triassic carbonate rocks and Jurassic granodiorite porphyry intrusions. The intrusives are characterized by SiO₂, K₂O, and Na₂O concentrations ranging from 61.66 to 67.8 wt.%, 3.29 to 5.65 wt.%, and 2.83 to 3.9 wt.%, respectively. Their A/CNK (A/CNK = n(Al₂O₃)/[n(CaO) + n(Na₂O) + n(K₂O)]) ratio, δEu, and δCe vary from 0.77 to 1.17, 0.86 to 1, and 0.88 to 0.96, respectively. The rocks show enrichment in light rare earth elements ((La/Yb)_N = 7.61–12.94) and large ion lithophile elements (LILE), and depletion in high field strength elements (HFSE), such as Zr, Ti. They also display a peraluminous, high‐K calc‐alkaline signature typical of intrusives associated with skarn and porphyry Cu–Au–Mo polymetallic deposits. Laser ablation inductively coupled plasma spectrometry (LA‐ICP‐MS) zircon U–Pb age indicates that the granodiorite porphyry formed at 151.75 ± 0.70 Ma. A few inherited zircons with older ages (677 ± 10 Ma, 848 ± 11 Ma, 2645 ± 38 Ma, and 3411 ± 36 Ma) suggest the existence of an Archaean basement beneath the Middle–Lower Yangtze River region. The temperature of crystallization of the porphyry estimated from zircon thermometer ranges from 744.3 °C to 751.5 °C, and 634.04 °C to 823.8 °C. Molybdenite Re–Os dating shows that the Jilongshan deposit formed at 150.79 ± 0.82 Ma. The metallogeny and magmatism are correlated to mantle–crust interaction, associated with the subduction of the Pacific Plate from the east. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

2021年滦州M_S4.3地震和2015年昌黎M_S4.2地震震源参数及构造意义研究     

李赫  董一兵  王熠熙 《大地测量与地球动力学》2022,42(12):1281-1287

基于京津冀地震台网观测资料,利用CAP方法反演滦州M_S4.3地震、昌黎M_S4.2地震及其M_S3.3余震的震源机制,并利用近震深度震相获得更为准确的震源深度,结合双差定位法获得2个地震序列的震源分布结果,对发震构造及成因关联开展分析研究。结果显示：1）滦州M_S4.3地震的节面Ⅰ走向、倾角、滑动角分别为211°、85°、168°,节面Ⅱ分别为302°、78°、5°,震源错动类型为走滑型,震源深度为8 km,地震序列的震源分布呈NNE向,短轴剖面显示断层面倾角近垂直,认为其发震断层面为节面Ⅰ;昌黎M_S4.2地震及M_S3.3余震的节面Ⅰ分别为189°、68°、161°及190°、61°、170°,节面Ⅱ分别为286°、72°、23°及285°、81°、29°,震源错动类型同为走滑型,震源深度为10.5 km,地震序列的震源分布呈NNE向,短轴剖面显示断层面倾角近垂直,认为其发震断层面为节面Ⅰ;2）基于滦州M_S4.3地震、昌黎M_S4.2地震及滦州M_S7.1地震的震源参数结果,结合区域地质构造等资料分析认为,3次地震的发震构造不是上地壳先存断裂,而可能与震源区的深部构造背景密切相关,即壳内包体现象是孕育这些地震的共同基础。  相似文献   

Changes in the Chemical Components of Light Crude Off During Simulated Short Term Weathering     

MA Qimin LUO Xia YU Zhigang 《中国海洋大学学报(英文版)》2007,6(3):231-236

To unambiguously identify spilled oils and to link them to the known sources are extremely important in settling questions of environmental impact and legal liability. The fate and behavior of spilled oils in the environment depend on a number of physicochemical and biological factors. This paper presents the results regarding changes in chemical composition of light crude oil during simulated short-term weathering based on natural environmental conditions. The results show that the saturated hydrocarbons of the light crude oil mainly distribute between n-C8 and n-C23 and the most abundant n-alkanes are found in the n-C10 to n-C16. The main chemical components of the light crude oil are n-alkanes and isoprenoids. The aromatic compounds are subordinate chemical components. Under the conditions of the weathering simulation experiment,n-alkanes less than n-C12,toluene and 1,3-dimethyl benzene are lost after 1 d weathering,the n-C13,n-C14,naphthalene and 2-methyl-naphthalene are lost on the fifth day of weathering,and n-C15 alkane components show certain weatherproof capability. The ratios n-C17/pristane and n-C18/phytane are unaltered and can be used to identify the source of the light crude oil during the first 8 d of weathering. After 21 d,the ratio pristine/phytane can not provide much information on the source of the spilled light crude oil. Triterpanes（m/z 191） as biomarker compounds of light crude oil are more valuable.  相似文献   

中祁连地块西段青白口系其它大坂组英安质凝灰岩LA- ICP- MS锆石U- Pb年龄及其地质意义     

张金明  陈光庭  才航加 《地质论评》2023,69(2):747-760

新元古界青白口系其它大坂组是中祁连地块西段基底岩系之一,对研究中祁连地块元古宙地质构造演化具有重要意义。笔者等通过1∶5万区调工作在其它大坂组中发现了英安质晶屑岩屑凝灰岩夹层,并对凝灰岩进行了锆石U-Pb年代学、岩石地球化学研究。测年结果表明样品中锆石年龄主要分3组。结合区域地质资料,笔者等认为第一组锆石(1456～1524 Ma)和第二组锆石(1018～1021 M)为外来锆石或/碎屑锆石,分别为物源区中元古代早期Columbia超大陆裂解事件和Rodinia大陆聚合事件(格林威尔造山作用)在中祁连地块中的响应;第三组锆石(946～964 Ma)的n(²⁰⁶Pb)/n(²³⁸U)加权年龄为958±3 Ma(MSWD=1.4),代表英安质凝灰岩的形成时代。岩石地球化学分析表明,其它大坂组英安质晶屑岩屑凝灰岩样品属于过铝质(A/CNK=1.37～1.75)、高钾(K₂O>Na₂O,K₂O=4.48%～4.86%)、钙碱性(σ=0.89～1.26)火山岩,稀土总量为(149....  相似文献   

基于气枪震源信号的云南漾濞M_S6.4地震前后波速变化     

苏金波  杨微  李孝宾  王伟涛  杨军  陈颐 《地球物理学报》2022,65(2):649-662

本文基于宾川气枪地震信号发射台激发的地震波信号,利用线性叠加和时频域相位加权叠加方法提高信噪比,通过反褶积、插值拟合和波形互相关等方法,获得2021年漾濞M;6.4地震前后气枪震源初至波信号走时变化特征.结果表明两种叠加方法得到的走时变化趋势基本一致,在沿发震断裂带附近的3个台站观测到的初至波走时延迟为7.3~14.4 ms,在射线路径上平均波速降低了0.08%~0.12%,距离震中位置较远的台站走时延迟为2~6 ms.分析认为,观测到的走时变化主要是漾濞M;6.4地震引起强地面运动造成浅层介质疏松、同震破裂导致震源区地下介质裂隙增加和地下流体侵入等共同作用造成,相关研究成果有助于加深和促进对此次地震震源物理过程的认识和了解.  相似文献   

2022年1月8日青海门源6.9级地震的震源区结构特征和b值意义初探     

孙安辉  高原  赵国峰  任超  梁姗姗 《地球物理学报》2022,(3)

2022年1月8日1时45分青海省门源县发生M_S6.9地震.本文基于青藏高原东北缘水平分辨率为0.3°的地震层析成像结果,获取了震源周边区域的地壳浅部构造信息,包括波速、泊松比以及估计的裂隙密度和饱和率的空间分布.结果表明:此次门源M_S6.9地震发生在P波和S波波速剧烈变化的区域,靠近高速体的边缘.泊松比和饱和率同样都显示,门源M_S6.9地震发生在高低值变化的过渡区.地震活动参数分析显示,震前冷龙岭断裂带的震源周边区域显示出了低b值、较低的a值和高a/b值的特征,与龙门山—岷山构造带强震之前的情况类似.裂隙密度在冷龙岭断裂两侧呈现出显著差异,北侧高于南侧,这可能是震后现场科考发现的断裂带地表破裂北侧高于南侧的构造成因.  相似文献   

2020年2月18日长清M_S4.1地震发震构造研究     

戴宗辉  李冬梅  王鹏  郑建常  王志才  李霞 《地震》2022,42(1):111-121

本文利用基于波形互相关的双差定位方法对2020年2月18日长清M_S4.1地震序列进行了精定位计算, 共得到33个地震事件的精定位结果。 结果显示, 地震序列主要沿NW向分布, 在水平方向上具有自NW向SE迁移, 在深度上具有由浅向深迁移的特征; 序列震源深度主要集中在2~7 km, 其中, 主震的震源深度约2.8 km。 由于长清地震序列的地震数量较少, 为了更准确地了解长清地震序列的发震构造、 探索该序列的发生和发展过程, 本文采用CAP方法反演了主震的震源机制解, 其中, 节面Ⅰ走向223°、 倾角42°、 滑动角-160°, 节面Ⅱ走向117.9°、 倾角76.8°、 滑动角-49.8°, 最佳拟合震源矩心深度约2.8 km, 矩震级M_W4.2。 结合区域构造特征分析认为, 长清M_S4.1地震的发震断裂为孝里铺断裂和东阿断裂之间发育的一条浅层次生断裂。 在ENE向区域应力场作用下, 发震断裂产生高角度正断滑动, 并伴有左旋走滑分量, 从而引发长清地震序列。  相似文献   

2022年云南宁蒗M_S 5.5地震前云南地区异常特征分析     

吴艳芳  付虹  胡小静  王赟辉 《地震地磁观测与研究》2022,43(2):188-197

通过对2022年1月2日宁蒗M_S 5.5地震前震中附近地区地震学、地下流体、定点形变等观测资料进行分析,发现本次地震前多学科异常呈现以下特征： ① M_S 5.5地震发生在宁蒗地区M_S ≥ 5.0地震平静近10年背景下,震中附近M_L ≥ 3.0地震于震前1年形成空区,主震发生在空区边缘,空区长轴180 km,按照川滇地区统计公式计算,未来发生地震的震级为5.8±0.5,与宁蒗M_S 5.5地震大小相当; 2015年以来,震中附近50 km范围内M_L ≥ 3.0地震呈平静—活跃—平静—发震的特征; ②地球物理观测异常均于震前7个月内出现,集中分布在滇西北地区距震中300 km范围内,且水温和水位测项异常出现较早; ③定点形变采用NS向与EW向幅值相加来描述同一观测资料的变化,数据曲线幅值增大可作为临震异常3个月短期指标,距震中越近,观测台项异常比例越高;④大部分宏观异常出现在震前3个月内,宏观异常增多可作为时间预测判据。综合上述多学科异常,认为地震学异常出现最早,可用于判定发震区域,用流体和定点形变观测异常追踪时间,宏观异常更多作为短期判定指标,可为宁蒗地区M_S ≥ 5.0地震资料积累提供跟踪思路和方法。  相似文献   

2022年1月8日门源6.9级地震山东地震台网测定面波震级对比分析     

石玉燕  张春鹏  颜启  苗庆杰 《地震地磁观测与研究》2022,43(4):1-7

通过对山东地震台网记录的2022年1月8日门源M_S 6.9地震原始波形进行分析,测算出88个测震台站的M_S、M_S7、M_S(BB)等3种面波震级,并与中国地震台网速报和青海区域地震台网编目测定结果进行对比分析。结果表明：①山东地震台网测定门源M_S6.9地震的面波震级M_S、M_S7、M_S(BB)分别为7.20、7.16、6.96;②M_S(BB)震级的测定方法简单,不同台站之间的偏差较小,一致性较好,适合在地震台网的地震速报中使用。这与震级国家标准GB 17740—2017的规定相一致。  相似文献