Granitoid Types Related to Cretaceous Plutonic Au-Quartz Vein and Cu-Fe Skarn Deposits, Kitakami Mountains, Japan   总被引：1，自引：0，他引：1  

Shunso Ishihara  Hiroyasu Murakami 《Resource Geology》2004,54(3):281-298

Abstract. Early Cretaceous granitic intrusions are associated with Au‐quartz veins and Cu‐Fe skarns in the the Kitakami Mountains, which are underlain by the late Paleozoic of continental margin‐type sedimentary rocks and Mesozoic accretionary complexes. The plutonic rocks are divided into potassic, high‐Sr/Y calc‐alkaline and low‐Sr/Y calc‐alkaline series. All the metallic mineral deposits are spatially associated with small stocks and plugs; they show no consistent association with the larger plutonic bodies. The plutonic rocks generally belong to the magnetite series but less oxidized in the southwestern part of the Kitakami Mountains where Au‐quartz veins occur. The gold deposits are classified into high and low sulfide types. The high sulfide type contains a high volume of sulfide minerals mostly of chalcopyrite, arsenopyrite and pyrrhotite with low bulk Au/Ag ratios. This type occurs almost exclusively in and surrounding the Orikabe pluton, including two most important gold deposits (Oya and Kohoku) of the Kitakami Mountains. The pluton is composed of potassic gabbroids, potassic granitoids of the shoshonite ‐ high‐K calc‐alkaline series (Orikabe type), and less potassic Sasamori‐type granodiorite. All these rocks belong to a moderately oxidized magnetite series. The Orikabe pluton has one of the lowest initial Sr ratio (0.70392) in the Kitakami Mountains, and the Au‐Cu‐dominant ore components of the high sulfide type Au deposits are considered magmatic in origin carried by the juvenile magmas from the upper mantle. The low sulfide type is generally plain quartz vein with a low volume of sulfides and a high bulk Au/Ag ratio. The associated minerals are often scheelite and/or arsenopyrite and pyrrhotite. The ore deposits include historically famed Au‐quartz veins at Shishiori and Ogayu. They are widespread in the southwestern Kitakami Mountains and may be later than the high sulfide type in age, and are hosted most commonly in the sedimentary rocks, which surround small weakly oxidized magnetite‐series plutons of low to intermediate Sr/Y series. These less differentiated intrusions typically include quartz dior‐ite and granodiorite. Some ore components of this type may have derived from the host sedimentary rocks. Among other mineral deposit types in the region, the largest ore deposit is Kamaishi Cu‐Fe skarn (magnetite ores of 58 MT, Fe 50–64 %; Cu 143 KT). It is related to the high‐Sr/Y series Ganidake granodiorite stock, which is a strongly oxidized magnetite‐series body. In contrast, the second largest deposit in the mountains, Akagane deposit, is a similar‐type skarn but associated with an intrusion classified as less oxidized, ilmenite to intermediate series, and that is intermediate in Sr/Y of calc‐alkaline series granodiorite. Degree of magmatic differentiation appears to be not critical factor in the formation of Au‐quartz vein and Cu‐Fe skarn deposits in the region, but is definitely significant for controlling the distribution of the Mo‐mineralization to the east.  相似文献   

Evolution and Genesis of Magmas from Vico Volcano, Central Italy: Multiple Differentiation Pathways and Variable Parental Magmas   总被引：4，自引：0，他引：4  

PERINI  GIULIA; FRANCALANCI  LORELLA; DAVIDSON  JON P.; CONTICELLI  SANDRO 《Journal of Petrology》2004,45(1):139-182

Vico volcano has erupted potassic and ultrapotassic magmas,ranging from silica-saturated to silica-undersaturated types,in three distinct volcanic periods over the past 0·5Myr. During Period I magma compositions changed from latiteto trachyte and rhyolite, with minor phono-tephrite; duringPeriods II and III the erupted magmas were primarly phono-tephriteto tephri-phonolite and phonolite; however, magmatic episodesinvolving leucite-free eruptives with latitic, trachytic andolivine latitic compositions also occurred. In Period II, leucite-bearingmagmas (⁸⁷Sr/⁸⁶Sr_initial = 0·71037–0·71115)were derived from a primitive tephrite parental magma. Modellingof phonolites with different modal plagioclase and Sr contentsindicates that low-Sr phonolitic lavas differentiated from tephri-phonoliteby fractional crystallization of 7% olivine + 27% clinopyroxene+ 54% plagioclase + 10% Fe–Ti oxides + 4% apatite at lowpressure, whereas high-Sr phonolitic lavas were generated byfractional crystallization at higher pressure. More differentiatedphonolites were generated from the parental magma of the high-Srphonolitic tephra by fractional crystallization of 10–29%clinopyroxene + 12–15% plagioclase + 44–67% sanidine+ 2–4% phlogopite + 1–3% apatite + 7–10% Fe–Tioxides. In contrast, leucite-bearing rocks of Period III (⁸⁷Sr/⁸⁶Sr_initial= 0·70812–0·70948) were derived from a potassictrachybasalt by assimilation–fractional crystallizationwith 20–40% of solid removed and r = 0·4–0·5(where r is assimilation rate/crystallization rate) at differentpressures. Silica-saturated magmas of Period II (⁸⁷Sr/⁸⁶Sr_initial= 0·71044–0·71052) appear to have been generatedfrom an olivine latite similar to some of the youngest eruptedproducts. A primitive tephrite, a potassic trachybasalt andan olivine latite are inferred to be the parental magmas atVico. These magmas were generated by partial melting of a veinedlithospheric mantle sources with different vein–peridotite/wall-rockproportions, amount of residual apatite and distinct isolationtimes for the veins. KEY WORDS: isotope and trace element geochemistry; polybaric differentiation; veined mantle; potassic and ultrapotassic rocks; Vico volcano; central Italy  相似文献   

大型花岗岩基形成和演化的深部动力学过程：滴水构造、钾质火山作用与地表地质过程   总被引：2，自引：0，他引：2  

曾令森  刘静Jason B Saleeby 《地质通报》2006,25(11):1257-1273

以美国内华达山脉复合岩基为例,系统评述了与大型花岗岩基的形成、演化相关的深部地球动力学过程及构造地貌学响应.在大陆岛弧环境下,基性岩浆的底侵作用促使下地壳发生角闪岩脱水部分熔融,在岩基根部形成高密度的石榴辉石岩,岩基根部最终发生重力失稳,形成滴水构造;在地貌上反映为滴水构造对应区域的沉降和相应的张性构造,在岩浆作用上则表现为软流圈地幔上涌和残余富集岩石圈地幔的低程度部分熔融,形成钾质火山岩.这种高度动态的深部动力学过程是维持大型花岗岩基地区较高高程或促使这些区域高程骤然增加的重要因素.  相似文献   

中国东部中生代钾质火成岩研究中的几个问题   总被引：1，自引：1，他引：1       下载免费PDF全文

汪洋 《地质论评》2007,53(2):198-206,I0008

本文探讨当前中国东部中生代钾质火成岩研究中存在的几个问题，即：“C型埃达克岩”的成因、无负Eu异常粗面岩—正长岩的成因、火成岩组合的K60值推算造山带地壳厚度的可信度，和玄武岩构造环境判别图解对中国东部中生代钾质基性岩的适用性。本文认为：①中国东部中生代“C型埃达克岩”有多种成岩过程，并非仅仅源于下地壳物质的部分熔融。②加厚下地壳部分熔融不能形成无负Eu异常的粗面岩—正长岩，同时“C型埃达克岩”与玄武质岩石高压条件下部分熔融产物在钾含量方面具有显著的差别。③火成岩组合的K60值不能用于估算中国东部中生代造山带地壳厚度。④一些常用的玄武岩构造环境地球化学判别图解并不适用于中国东部中生代钾质基性岩。  相似文献   

Potassic Magmatism in Western Sichuan and Yunnan Provinces, SE Tibet, China: Petrological and Geochemical Constraints on Petrogenesis   总被引：31，自引：1，他引：30  

GUO  ZHENGFU; HERTOGEN  JAN; LIU  JIAQI; PASTEELS  PAUL; BOVEN  ARIEL; PUNZALAN  LEA; HE  HUAIYU; LUO  XIANGJUN; ZHANG  WENHUA 《Journal of Petrology》2005,46(1):33-78

Potassic volcanism in the western Sichuan and Yunnan Provinces,SE Tibet, forms part of an extensive magmatic province in theeastern Indo-Asian collision zone during the Paleogene (40–24Ma). The dominant rock types are phlogopite-, clinopyroxene-and olivine-phyric calc-alkaline (shoshonitic) lamprophyres.They are relatively depleted in Na₂O, Fe₂O₃, and Al₂O₃ comparedwith the late Permian–early Triassic Emeishan continentalflood basalts in the western part of the Yangtze craton, andhave very high and variable abundances of incompatible traceelements. Primitive mantle-normalized incompatible element patternshave marked negative Nb, Ta and Ti anomalies similar to thoseof K-rich subduction-related magmas, although the geodynamicsetting is clearly post-collisional. Spatially, some incompatibletrace element abundances, together with inferred depths of meltsegregation based on the Mg-15 normalized compositions of thesamples, display progressive zonation trends from SW to NE withincreasing distance from the western boundary of the Yangtzecraton. Systematic variations in major and trace element abundancesand Sr–Nd–Pb isotope compositions appear to havepetrogenetic significance. The systematic increases in incompatibletrace element abundances from the western margin to the interiorof the Yangtze craton can be explained by progressively decreasingextents of partial melting, whereas steady changes in some incompatibletrace element ratios can be attributed to changes in the amountof subduction-derived fluid added to the lithospheric mantleof the Yangtze craton. The mantle source region of the lamprophyresis considered to be a relatively refractory phlogopite-bearingspinel peridotite, heterogeneously enriched by fluids derivedfrom earlier phases of late Proterozoic and Palaeozoic subductionbeneath the western part of the Yangtze craton. Calculationsbased on a non-modal batch melting model show that the degreeof partial melting ranges from 0·6% to 15% and the proportionof subduction-derived fluid added from0·1% to 0·7%(higher-Ba fluid) or from 5% to 25% (lower-Ba fluid) from theinterior to the western margin of the Yangtze craton. Some pre-existinglithospheric faults might have been reactivated in the areaneighbouring the Ailao Shan–Red River (ASRR) strike-slipbelt, accompanying collision-induced extrusion of the Indo-Chinablock and left-lateral strike-slip along the ASRR shear zone.This, in turn, could have triggered decompression melting ofthe previously enriched mantle lithosphere, resulting in calc-alkalinelamprophyric magmatism in the western part of the Yangtze craton. KEY WORDS: Tibet; potassic magmatism; lithospheric mantle; metasomatism  相似文献   

Geochemical element mobility during alteration/mineralization in the Sungun porphyry copper deposit,Azerbaijan–Iran     

《International Geology Review》2012,54(8):980-1002

The Sungun porphyry copper deposit of northwestern Iran is associated with Miocene diorite/granodiorite to quartz-monzonite intrusive into Eocene volcanic–sedimentary and Cretaceous carbonate rocks. Three main mineralization-related alteration episodes (I, potassic; II, transition; and III, phyllic alterations) were studied in terms of mass transfer during hydrothermal evolution of the Sungun deposit. Isocon plots (Grant, J.A. 1986 Grant, J.A. 1986. The isocon diagram – a simple solution to Gresens’ equation for metasomatic alteration. Economic Geology, 81: 1976–1982. [Crossref], [Web of Science ®] , [Google Scholar], The isocon diagram – a simple solution to Gresens’ equation for metasomatic alteration: Economic Geology, v. 81, p. 1976–1982) were employed to illustrate these changes quantitatively. These plots illustrate that Al, Ti, and Ga were relatively immobile during alteration, and that the alteration was essentially mass-conservative. At all stages in the evolution of the hydrothermal system, computed volume changes were close to zero. In the potassic alteration zone, an obvious enrichment of K and depletions of Na, Ca, Mn, and Fe took place. These changes were due to replacement of plagioclase and amphibole by K-feldspar and biotite, respectively. Potassic alteration was associated with significant addition of Cu, as might be expected from the occurrence of disseminated chalcopyrite and bornite in this zone. In the transition alteration zone, Ca was added, Na, Fe, and Mg were relatively unchanged, and K, Ba, and Cu were depleted. The loss of K and Ba relative to Na reflects replacement of K-feldspar by albite. Phyllic alteration was accompanied by the depletion of Na, K, Fe, and Ba and enrichment of Si and Cu. The losses of Na, K, and Fe reflect the sericitization of alkali feldspar and destruction of ferromagnesian minerals. The addition of Si is consistent with the widespread silicification, which is a major feature of phyllic alteration and the addition of Cu with mobilization from the transition zone, which is depleted in this element.  相似文献   

珂吾拉勒山西段下二叠统钾质基性火山岩的地球化学特征     

罗勇  单强  曾乔松  李宁波  姜玉航  曾令君 《地球化学》2013,(6):544-556

阿吾拉勒山位于中国新疆伊犁地区,是中亚造山带的重要组成部分。本文对阿吾拉勒山西段琼布拉克、卡查可让和托巴斯萨依等地出露的下二叠统基性火山岩的主元素、微量元素和同位素地球化学特征进行了研究。阿吾拉勒山西段琼布拉克、卡查可让、托巴斯萨依等地出露的基性火山岩为钾质基性火山岩（属橄榄玄粗岩系的橄辉玄粗岩）,其镁铁指数从23．3变化到64．1,表明它们经历了相当程度的分异演化;微量元素地球化学特征显示,该类钾质基性火山岩形成于后碰撞弧环境,暗示该地区在早二叠世地球动力学性质由挤压转换为伸展。La／Yb和Nb／Y比值显示,由于源区受到与俯冲有关的流体交代影响,岩石明显富集大离子亲石元素并亏损Nb、Ta和Ti等高场强元素。微量元素地球化学特征还显示,该类钾质基性火山岩的源区除了含有尖晶石、辉石、橄榄石和少量的石榴子石外,还含有一定数量的角闪石或金云母等含水矿物,该类岩石原始岩浆形成于深度大于70km的尖晶石橄榄岩与石榴子石橄榄岩的过渡区;微量元素地球化学特征显示,阿吾拉勒山西段南北两地钾质基性火山岩的源区组成有明显差异：南部的托巴斯萨依钾质基性火山岩较北部的卡查可让和琼布拉克钾质基性火山岩的源区更加富水,受到俯冲物质的影响更强烈,但源区石榴子石含量相对较少;同位素地球化学特征也显示,琼布拉克和卡查可让等地的钾质基性火山岩sNd（f）值比托巴斯萨依的钾质基性火山岩更低,（87Sr／86Sr）i比值比托巴斯萨依的钾质基性火山岩略高,暗示它们源区的富集程度更高,也表明托巴斯萨依的钾质基性火山岩受软流圈的影响更为强烈。  相似文献   

沂沭断裂带中南段钾质火山岩的元素地球化学与Sr-Nd-Hf同位素组成及其对岩石成因的制约   总被引：2，自引：0，他引：2  

邱检生  李友连  刘亮  赵姣龙 《地质学报》2013,87(9):1193-1210

本文以沂沭断裂带中南段莒南-大店一带的钾质火山岩为对象,系统研究了它们的岩石学、元素地球化学和Sr-Nd-Hf同位素组成特征,据此探讨了源区地幔富集机制及岩石成因。莒南钾质火山岩主要为一套安粗质火山-潜火山岩组合,大店多发育粗面质火山岩,二者的锆石LA-ICP-MS U-Pb年龄基本一致,均约为118Ma。在化学组成上,这套火山岩均偏碱性,里特曼指数(σ)介于4.10~5.07,且富钾(K_2O=4.21%~5.77%),在SiO_2-K_2O和K_2O-Na_2O关系图上,均投影在钾玄岩系区。安粗质和粗面质火山岩均富大离子亲石元素(Cs,Rb,Th,U,Pb)和轻稀土元素,贫高场强元素(Nb,Ta,P,Ti),但粗面质火山岩具较显著的Ba、Eu负异常,且轻重稀土比值较低。二类火山岩均具有富集且较均一的Sr-Nd同位素组成(I_(Sr)=0.7086~0.7091,ε_(Nd)(t)=-16.9~-18.2),锆石ε_(Hf)(t)值均为显著的负值(安粗质岩:-22.3~-24.3,粗面岩:-19.7~-23.6)。元素和同位素组成的综合分析表明,区内钾质火山岩的源区地幔极可能遭受了因扬子板块深俯冲和华北克拉通岩石圈拆沉等多次富集事件的影响。至早白垩世,随着郯庐断裂引张的加剧,诱发了软流圈地幔上涌,同时在断裂减压作用的影响下,促使了这一经叠次改造的富集地幔的部分熔融,由此产生的岩浆经进一步分异演化,导致了区内钾质火山岩的形成。  相似文献   

Post-collisional, Potassic and Ultrapotassic Magmatism of the Northern Tibetan Plateau: Constraints on Characteristics of the Mantle Source, Geodynamic Setting and Uplift Mechanisms   总被引：27，自引：1，他引：26  

GUO  ZHENGFU; WILSON  MARJORIE; LIU  JIAQI; MAO  QIAN 《Journal of Petrology》2006,47(6):1177-1220

Cenozoic, post-collisional, potassic and ultrapotassic igneousrocks in the North Qiangtang, Songpan–Ganzi and NorthKunlun terranes of the northern Tibetan Plateau are distributedalong a semi-continuous, east–west-trending, volcanicbelt, which is over 1200 km in length. Spatially, there is aclose association with major strike-slip faults, thrust faultsand pull-apart basins. The ages of these magmatic rocks rangefrom 45 Ma to the present (the youngest known eruption occurredin 1951); they are shoshonitic, compositionally similar to K-richsubduction-related magmas, and range in SiO₂ from 44 to 66 wt%. There is a relative enrichment of large ion lithophile elements(LILE) and light rare earth elements (LREE) in the most primitivemagmatic rocks (MgO >6 wt %) in the North Qiangtang terranecompared with those in the Songpan–Ganzi and North Kunlunterranes; correspondingly, the primitive magmas have higher⁸⁷Sr/⁸⁶Sr and ²⁰⁶Pb/²⁰⁴Pb, and lower ¹⁴³Nd/¹⁴⁴Nd ratios in theNorth Qiangtang terrane than in the Songpan–Ganzi andNorth Kunlun terranes. The dominant factors that control thegeochemical characteristics of the magmas are an enriched asthenosphericmantle source composition, the degree of partial melting ofthis source, and the combined processes of crustal assimilationand fractional crystallization (AFC). Enrichment of the asthenosphereis considered to have occurred by incorporation of subductedsediments into the mantle wedge above a subducted slab of Indianlithosphere during India–Asia convergence. Continentallithospheric mantle, metasomatically enriched during earlierepisodes of subduction, may have also contributed a source componentto the magmas. Trace element modelling indicates that the mantlesource of the most primitive magmas in the North Qiangtang terranecontained higher amounts of subducted sediment (0·5–10%)compared with those in the Songpan–Ganzi and North Kunlunterranes (<2%). The degrees of partial melting required togenerate the primitive potassic and ultrapotassic magmas fromthe enriched mantle sources range from <0·1% to 15%in the three major basement terranes. Energy-constrained AFCmodel calculations show that the more evolved magmatic rocks(MgO <6 wt %) are the results of AFC processes in the middlecrust in the North Qiangtang terrane and the upper crust inthe Songpan–Ganzi and North Kunlun terranes. We proposethat the ultimate driving force for the generation of the post-collisionalpotassium-rich magmatism in north Tibet is the continuous northwardunderthrusting of the Indian continental lithosphere followingIndia–Asia collision. This underthrusting resulted inupwelling of hot asthenosphere beneath north Tibet, squeezedup between the advancing Indian lithosphere and the backstopof the rigid Asian continental lithosphere. Asthenospheric upwellingmay have also contributed to uplift of the northern TibetanPlateau. KEY WORDS: Tibetan Plateau; potassic and ultrapotassic magmatism; enriched asthenospheric mantle source; EC-AFC modelling; geodynamics  相似文献   

甘肃西秦岭两类新生代钾质火山岩:岩石地球化学与成因   总被引：5，自引：2，他引：3       下载免费PDF全文

喻学惠  莫宣学  赵志丹  黄行凯  李勇  陈延芳  韦玉芳 《地学前缘》2009,16(2):79

甘肃西秦岭地区存在钾霞橄黄长岩和钾质粗面玄武岩(钾玄岩)两类钾质火山岩,出露在甘肃西秦岭礼县、宕昌县等,地理坐标大致相当于104°20′～104°50′E,33°30′～34°10′N。钾霞橄黄长岩是一种不含斜长石,但普遍含有高钛金云母、黄长石、白榴石、霞石的岩石,全岩化学成分具低SiO2和Al2O3,富TiO2、CaO、MgO和高K/Na、高Mg#值的特征;钾质粗面玄武岩(钾玄岩)含有大量斜长石但是缺乏高钛金云母、黄长石、白榴石和霞石,全岩化学中SiO2、Al2O3明显高于前者,而TiO2、CaO、MgO、K/Na和Mg#值要比钾霞橄黄长岩低。钾霞橄黄长岩的全岩K/Ar和金云母单矿物的39Ar/40Ar同位素定年落在7.1～23Ma,而钾玄岩的全岩39Ar/40Ar同位素定年落在9Ma左右,因此它们同为中新世产物。两类钾质火山岩具有相似的富集不相容元素和轻稀土的特征。两类钾质火山岩的初始87Sr/86Sr分别在0.70403～0.70749和0.70412～0.70522;143Nd/144Nd分别在0.51274～0.51294和0.51265～0.51276;εNd分别在1.12～5.95和0.3～2.3。206Pb/204Pb、207Pb/204Pb和208Pb/204Pb分别落到18.3746～18.9986、15.529～15.6693和38.4971～39.4144。在火山岩源区示踪的143Nd/144Nd-87Sr/86Sr,207Pb/204Pb-206Pb/204Pb,208Pb/204Pb-206Pb/204Pb,143Nd/144Nd-206Pb/204Pb,87Sr/86Sr-206Pb/204Pb和Ba/Nb-La/Nb图解中,一致显示两类钾质火山岩具有与OIB相似的地球化学特征,源区可能与地幔柱有关,并具有EM1、DMM和HIMU端员混合特征。结合前人对该区深部地球物理和断裂构造的研究,论证了火山岩的起源与成因,指出作为对印度—欧亚大陆强烈碰撞的吸收与调节,高原下软流圈地幔流沿400km界面向北东方向的侧向流动以及西秦岭周边克拉通块体的阻挡,是形成西秦岭断裂系左行走滑特征和巨大拉分盆地的主要原因,也是导致西秦岭新生代两类钾质火山岩和碳酸岩起源与成因的动力学机制,较好地解释了西秦岭新生代岩浆作用起源深度大,具有地幔柱源的地球化学特征,岩石组合与地球化学有别于高原内部及其周边地区新生代钾质火山岩的原因。  相似文献