辽北太古宙块状硫化物矿床     

方如恒 《国土资源》1992,(1)

辽北太古宙由花岗岩-绿岩带组成。绿岩生成于岛弧构造环境,时间在3.0—2.8Ga,火山岩属拉斑玄武质及钙碱性火山岩。花岗岩在绿岩之后侵入,具多旋回特点。块状硫化物矿床与长英质火山岩有关,具有2—3含矿层位,透镜状矿体数目较多,未发现管状细脉带。矿石中Cu>Zn>>Pb,具有明显贫铅的特点,Cu×100/Cu+Zn为88—25。矿床类型属活火山型火山热液矿床。成矿温度为350—250℃,压力为9.5—4.0MPa,fo_2为10~(-30)-10~(-44)Pa,fs_2为2.57×10~(-9)-8.13×10~(-14)Pa,pH值为4.5—5。共生有阿尔戈马型铁矿与火山成因金矿。块状硫化物矿床遭受变质、变形、伟晶岩的改造,并在主褶皱幕期迭生与基性岩有关的热液多金属矿化。  相似文献   

Identification and investigation of sulphur plumes along the Namibian coast using the MERIS sensor     

Thomas Ohde  Herbert SiegelJan Reißmann  Monika Gerth 《Continental Shelf Research》2007

In the upwelling area along the Namibian coast of SW-Africa sulphur discolorations were investigated to study the impact of hydrogen sulphide on the ecosystem using satellite imagery. The formation of colloidal sulphur in the upper water layer results from the oxidation of hydrogen sulphide. The occurrence of sulphur plumes as well as their temporal and spatial development was investigated in relation to the driving meteorological and oceanographic conditions. Because of the sporadic occurrence of sulphur events and the limited number of ship-borne investigations in that area remote sensing of ocean colour is the only method to follow these phenomena continuously and synoptically. In the past the sulphur plumes were studied by true colour images derived from ocean colour satellite data like sea-viewing wide field of view sensor or moderate resolution imaging spectroradiometer and identified by their typical milky turquoise discoloration.  相似文献   

再论大陆地壳断裂拗陷带中的华南型块状硫化物矿床   总被引：16，自引：0，他引：16  

顾连兴  胡文瑄  倪培  何金祥  徐跃通  陆建军  林春明  李伟强 《高校地质学报》2003,9(4):592-608

华南海西-印支断裂拗陷带中的块状硫化物矿床(MSD)主要产于晚古生代海侵岩系底部附近碎屑岩向碳酸盐地层的过渡部位，含矿岩系中伴有少量双峰式火山岩和大量喷流岩，矿床中最基本的矿物共生关系是变质反应关系，金属元素和矿物相的分布往往显示地层学垂直分带和侧向分带，这种分带是同生沉积-成岩、活化转移和后期改造叠加等因素综合作用的产物。层状矿体下盘可以存在着代表海底热液通道的脉状、角砾状和浸染状矿化，与之伴生的硅化、绢云母化和钾长石化等蚀变反映了大陆地壳及其沉积物的富硅、富钾特征。与块状硫化物呈相变关系的层状铁锰矿床下方可存在脉状铅锌和金矿床。南岭地区的断裂拗陷带形成于后加里东大陆内部，而长江中下游则处于向被动陆缘演化的环境。两个地区晚古生代MSD在成分和成矿特征等方面的一系列差异，反映了成矿时基底陆壳成熟度的差异，而钨和锡则是成熟陆壳上MSD的特征元素。与国外苏利文型明显不同的是，华南地区矿床除了与确定无疑的火山岩伴生外，所含有用金属更加丰富多彩，并且往往受到后期花岗岩类岩浆及其热液的改造和叠加，因此可称之为华南型矿床。并以此代表大陆地壳上MSD的成矿特征。  相似文献   

Apparent magnetic polarity reversals due to remagnetization resulting from late diagenetic growth of greigite from siderite     

Leonardo Sagnotti  rew P. Roberts  Richard Weaver  Kenneth L. Verosub  Fabio Florindo  Christopher R. Pike  Trevor Clayton  Gary S. Wilson 《Geophysical Journal International》2005,160(1):89-100

  相似文献   

Geological and geochemical characteristics of the Baimazhai Ni-Cu-（PGE） sulphide deposit in Yunnan, China     

PU Chuanjie QIN Dexian NIAN Hong ZHANG Xueshu Franco PIRAJNO FAN Zhuguo 《中国地球化学学报》2007,26(4):374-383

The sulphide ores of the Baimazhai deposit, although typically orthomagmatic, locally exhibit peculiar textural features and are intimately associated with hydrothermal minerals, such as biotite, amphibole and chlorite. This association suggests that the magmatic sulphide ores were subjected to hydrothermal alteration and subsequent redistribution, resulting in the observed textural features. Geochemically, the Baimazhai sulphide ores are enriched in Cu, Pd and Au, which,according to previous studies, reflects the action of hydrothermal fluids. Interestingly, Ar-Ar dating yielded the plateau ages of about 160–170 Ma, which are at odds with the established Permian age of the Emeishan large igneous province. We interpreted these younger ages as due to thermal resetting during post-Permian tectonothermal events. We have proposed a model in which tectonic movements and hydrothermal fluids related to these events modified the pre-existing magmatic sulphides. Given the degree of overprint, we suggested two possible scenarios: 1) the sulphide disseminations that surround the massive magmatic ores are the result of deformation and hydrothermal alteration; and 2) there were both magmatic massive and disseminated sulphides, in which case the scale and relocation of remobilization would have been smaller, but still detectable.  相似文献   

中国北方造山带岩浆铜镍硫化物矿床及其地球动力学背景——以吉林红旗岭矿床为例   总被引：2，自引：0，他引：2  

郗爱华  顾连兴  李绪俊  郑远川 《地质学报》2006,80(11):1721-1729

中国北方兴蒙造山带东段吉林省中南部产有一系列铜镍硫化物矿床,红旗岭矿床代表的是早三叠纪同造山期与超镁铁质-镁铁质岩浆作用相关的矿床类型.含矿母岩主要是由辉长岩-二辉岩-橄榄辉石岩-辉石橄榄岩等构成的杂岩体和顽火辉石岩超基性岩脉,构成星点状—稀疏浸染状、稠密浸染状、斑杂状、致密块状四种矿石类型.硅酸盐岩石的矿物组合为橄榄石+斜方辉石+单斜辉石+角闪石+斜长石,为钙碱性系列岩石组合类型.岩石化学显示其微量元素富集轻稀土元素和大离子亲石元素Rb、Ba,亏损高场强元素Ti、Nb,相似于俯冲带拉斑玄武岩,可能为幔源岩浆混染地壳物质的结果.同位素年代学证实岩体就位时间约为250Ma左右的早三叠纪,与区域变质和中国北方大面积的同造山花岗岩年龄相似.暗示了含矿岩体的形成和华北板块与西伯利亚板块碰撞造山作用有关,是造山挤压过渡期伸展体制下岩浆作用的产物.  相似文献   

Interactive effects of the type of milling media and copper sulphate addition on the flotation performance of sulphide minerals from Merensky ore Part I: Pulp chemistry     

D.J. Bradshaw  A.M. Buswell  P.J. Harris  Z. Ekmekci 《International Journal of Mineral Processing》2006

It is well known that the chemical environment determines the success of the flotation process, however its characterisation and control is difficult to achieve. This paper, as two parts, Part I and Part II, evaluates the use of various measurements and their interpretation to gain an understanding of the influence of varying parameters such as the type of milling media and copper sulphate addition on the flotation performance of sulphide minerals from a platinum group mineral (PGM) bearing Merensky ore. It shows the complexity of interpretation and the importance of analysing flotation performance holistically. Part I focuses on the pulp chemistry and mineral potential measurements have been used to show the differences in the response of the various mineral electrodes to different conditions. The final flotation recoveries of the sulphide minerals in the ore followed the same trend as the decrease in mineral potential due to collector addition viz. chalcopyrite > pentlandite > pyrrhotite. Type of milling media and copper sulphate addition slightly affected the mineral electrode potential and flotation recovery of chalcopyrite. Addition of copper sulphate increased the recovery of pentlandite and particularly pyrrhotite due to activation by copper (II) ions. The copper activation mechanism was likely to be in the form of initial adsorption of copper hydroxide followed by reduction to Cu⁺ at the surface. However, the changes in flotation performance of the different minerals in the ore could not be completely described by the electrochemical changes, demonstrating the limitations of these measurements. Part II addresses the effect of froth stability as demonstrated by the variations in the mass and water recovery data resulting from the different milling conditions and addition of copper sulphate which emphasised the importance of considering the froth phase in the evaluation of flotation data.  相似文献   

Lewis Ponds, a hybrid carbonate and volcanic-hosted polymetallic massive sulphide deposit, New South Wales, Australia     

Michael W. Agnew  Ross R. Large  Stuart W. Bull 《Mineralium Deposita》2005,39(8):822-844

The Lewis Ponds Zn–Pb–Cu–Ag–Au deposit, located in the eastern Lachlan Fold Belt, central western New South Wales, exhibits the characteristics of both volcanic-hosted massive sulphide and carbonate-hosted replacement deposits. Two stratabound massive to disseminated sulphide zones, Main and Toms, occur in a tightly folded Upper Silurian sequence of marine felsic volcanic and sedimentary rocks. They have a combined indicated resource of 5.7 Mt grading 3.5% Zn, 2.0% Pb, 0.19% Cu, 97 g/t Ag and 1.9 g/t Au. Main Zone is hosted by a thick unit of poorly sorted mixed provenance breccia, limestone-clast breccia and quartz crystal-rich sandstone, whereas Toms Zone occurs in the overlying siltstone. Pretectonic carbonate–chalcopyrite–pyrite and quartz–pyrite stringer veins occur in the footwall porphyritic dacite, south of Toms Zone. Strongly sheared dolomite–chalcopyrite–pyrrhotite veins directly underlie the Toms massive sulphide lens. The mineralized zones consist predominantly of pyrite, sphalerite and galena. Paragenetically early framboidal, dendritic and botryoidal pyrite aggregates and tabular pyrrhotite pseudomorphs of sulphate occur throughout the breccia and sandstone beds that host Main Zone, but are rarely preserved in the annealed massive sulphide in Toms Zone. Main and Toms zones are associated with a semi-conformable hydrothermal alteration envelope, characterized by texturally destructive chlorite-, dolomite- and quartz-rich assemblages. Dolomite, chlorite, quartz, calcite and sulphides have selectively replaced breccia and sandstone beds in the Main Zone host sequence, whereas the underlying porphyritic dacite is weakly sericite altered. Vuggy and botryoidal textures resulted from partial dissolution of the dolomite-altered sedimentary rocks and unimpeded growth of base metal sulphides, carbonate and quartz into open cavities. The intense chlorite-rich alteration assemblage, underlying Toms Zone, grades outward into a weak pervasive sericite–quartz assemblage with distance from the massive sulphide lens. Limestone clasts and hydrothermal dolomite at Lewis Ponds are enriched in light carbon and oxygen isotopes. The dolomite yielded ¹³C_VPDB values of –11 to +1 and ¹⁸O_VSMOW values of 6 to 16. Liquid–vapour fluid inclusions in the dolomite have low salinities (1.4–7.7 equiv. wt% NaCl) and homogenization temperatures (166–232°C for 1,000 m water depth). Dolomitization probably involved fluid mixing or fluid–rock interactions between evolved heated seawater and the limestone-bearing facies, prior to and during mineralization. ³⁴S_VCDT values range from 2.0 to 5.0 in the massive sulphide and 3.9 to 7.4 in the footwall carbonate–chalcopyrite–pyrite stringer veins, indicating that the hydrothermal fluid may have contained mamgatic sulphur and a component of partially reduced seawater. The sulphide mineral assemblages at Lewis Ponds are consistent with moderate to strongly reduced conditions during diagenesis and mineralization. Low temperature dolomitization of limestone-bearing facies in the Main Zone host sequence created secondary porosity and provided a reactive host for fluid-rock interactions. Main Zone formed by lateral fluid flow and sub-seafloor replacement of the poorly sorted breccia and sandstone beds. Base metal sulphide deposition probably resulted from dissolution of dolomite, fluid mixing and increased fluid pH. Pyrite, sphalerite and galena precipitated from a relatively low temperature, 150–250°C hydrothermal fluid. In contrast, Toms Zone was emplaced into fine-grained sediment at or near the seafloor, above a zone of focused up-flowing hydrothermal fluids. Copper-rich assemblages were deposited in the Toms Zone footwall and massive sulphide lenses in Main and Toms zones as the hydrothermal system intensified. During the D₁ deformation, fracture-controlled fluids within the Lewis Ponds fault zone and adjacent footwall volcanic succession remobilized sulphides into syntectonic quartz veins. Lewis Ponds is a rare example of a synvolcanic sub-seafloor hydrothermal system developed within fossiliferous limestone-bearing facies. The close spatial association between limestone, hydrothermal dolomite, massive sulphide and dacite provides a basis for new exploration targets elsewhere in New South Wales.Editorial handling: D. Lentz  相似文献   

锍镍试金富集-电感耦合等离子体质谱法测定黑色页岩中的铂族元素   总被引：5，自引：3，他引：2  

赵素利  张欣  温宏利  李超  屈文俊 《岩矿测试》2011,30(6):723-726

黑色页岩中碳、硫、镍等元素的含量很高,按照常规的锍镍试金熔剂配方不能形成较好的锍扣,影响铂族元素准确定值。本文通过调整试剂配方、优化操作流程等方式建立了黑色页岩中铂族元素的锍镍试金-电感耦合等离子体质谱(ICP-MS)测定方法。结果表明,加入适量硝酸钾可以将铂族元素回收率提高了大约10%。用盐酸溶解锍扣之后,溶液中仍然存在大量黑色沉淀,不易过滤和溶解,趁热在不断搅拌下加入2～3 mL三氯化铁溶液可以在很大程度上减少沉淀量,降低实验操作的难度和不确定性。方法检出限Ru为0.054 ng/g,Rh为0.040 ng/g,Pd为0.40 ng/g,Ir为0.032 ng/g,Pt为0.27 ng/g,Os为0.026 ng/g。精密度和准确度试验表明,该方法稳定可靠,可用于黑色页岩中铂族元素的准确测定。  相似文献   

新桥硫铁矿伴生金银赋存状态及分布规律     

吴大敏 《矿产与地质》2002,16(1):25-27

系统阐述了新桥矿伴生金银的赋存状态和分布规律 ,对综合利用矿产资源 ,提高金银的回收率 ,以及深部资源预测、外围找矿均具有一定的指导意义  相似文献