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21.
Guangyou?ZhuEmail author Shuichang?Zhang Yingbo?Liang Jinxing?Dai Jian?Li 《中国科学D辑(英文版)》2005,48(11):1960-1971
The northeastern area of Sichuan Basin, southwestern China, is the area with the maximal reserve of natural gas containing
higher hydrogen sulphide (H2S) that has been found among the petroliferous basins of China, with the proven and controlled gas reserve of more than 200
billion cubic meters. These gas pools, with higher H2S contents averaging 9%, some 17%, are mainly distributed on structural belts of Dukouhe, Tieshanpo, Luojiazhai, Puguang,
etc., while the oolitic-shoal dolomite of the Triassic Feixianguan Fm. (T1f) is the reservoir. Although many scholars regard the plentiful accumulation of H2S within the deep carbonate reservoir as the result of Thermochemical Sulfate Reduction (TSR), however, the process of TSR
as well as its residual geological and geochemical evidence is still not quite clear. Based on the carbon isotopic analysis
of carbonate strata and secondary calcite, etc., together with the analysis of sulfur isotopes within H2S, sulphur, gypsum, iron pyrites, etc., as well as other aspects including the natural gas composition, carbon isotopes of
hydrocarbons reservoir petrology, etc., it has been proved that the above natural gas is a product of TSR. The H2S, sulphur and calcite result from the participation of TSR reactions by hydrocarbon gas. During the process for hydrocarbons
being consumed due to TSR, the carbons within the hydrocarbon gas participate in the reactions and finally are transferred
into the secondary calcite, and become the carbon source of secondary calcite, consequently causing the carbon isotopes of
the secondary calcite to be lower (−18.2‰). As for both the intermediate product of TSR, i.e. sulfur, and its final products,
i.e. H2S and iron pyrites, their sulfur elements are all sourced from the sulfate within the Feixianguan Fm. During the fractional
processes of sulfur isotopes, the bond energy leads to the 32S being released firstly, and the earlier it is released, the lower δ 34S values for the generated sulphide (H2S) or sulfur will be. However, for the anhydrite that participates in reactions, the higher the reaction degree, the more
32S is released, while the less 32S remains and the more δ 34S is increased. The testing results have proved the process of the dynamic fractionation of sulfur isotopes. 相似文献
22.
23.
Massive Sulphide Deposits Related to the Volcano-Passive Continental Margin in the Altay Region 总被引:3,自引:0,他引:3
WANG Jingbin DENG Jiniu ZHANG Jinhong QIN KezhangBeijing Institute of Geology for Mineral Resources State Bureauof Nonferrous Metal Industry Andingmenwai Beijing Zhu Xiling 《《地质学报》英文版》1999,73(3):253-263
The Devonian volcano-passive continental margin in southern Altay is a significant volcanogenic massive sulphide metallogenic belt. Acidic volcanism has been dominant on the inner side of the volcano-passive continental margin, i.e., near the old land, resulting in a Pb-Zn metallogenic sub-belt, in which the ore deposits are hosted by sedimentary rocks in volcanic series, as represented by the large Koktal Pb-Zn deposits. In the central part of the margin far away from the old land, bimodal volcanic formations are well developed, forming volcanics-hosted Cu-Zn metallogenic sub-belts, e.g., the large-scale Ashele Cu-Zn deposit. The Qiaoxiahala sub-belt on the outer side of the margin near the ocean ridge is located at the spreading central trough, where ophiolite suites are developed. This type of deposits is rich in gold and copper, similar to the Cyprus-type Fe-Cu-Au metallogenic sub-belt in metallogenic environment (represented by the Qiaoxiahala medium-scale Fe-Cu-Au deposit). From the old land to th 相似文献
24.
This paper describes simulation experiments in which glucose and cellulose were reacted with polysulphide and hydrogen sulphide at ambient temperatures in an aqueous environment. Organic sulphur containing compounds were formed that yield several thiophenes upon pyrolysis/evaporation. The experiments show that interaction of carbohydrates with hydrogen sulphide or polysulphides is a possible way for carbohydrates to react in very recent sediments. From the results of this study it can be concluded that carbohydrate carbon can be preserved in sediments in a form that is resistant to microbial attack and that will have a greater potential for survival during diagenesis than the carbohydrate precursor. 相似文献
25.
硫化物作为一类重要的常见矿物,目前国内外对其表面矿物学特征研究有限。具体到硫化物固-液界面处的行为机理,前人的研究程度就更低了。笔者自行设计了一个Fe1-xS-Cr^6 原电池,通过实测电动势(E),t-E关系曲线,溶液可见光吸收谱及其λ-A关系曲线,阐明硫化物与Cr^6+溶液间的界面行为机理。认为其界面行为过程为;硫化物溶解→离子反应(氧化还原)→吸附Cr^3 。该原电池与一般原电池结构不同,其主要差别在于将反应电极和测量电极分开,从而解决电极反应过程中的浓度极化问题,提高了电化学实验的精度。该研究成果有助于揭示矿物-液体相互作用机理,完善和丰富表面矿物学研究内容,深化化界面成矿理论,并对环境治理,矿物材料应用等开发领域具有重要的参考价值。 相似文献
26.
块状硫化物矿石中硫化物的压溶和增生及成矿意义——以加拿大西部矿床为例 总被引:7,自引:0,他引:7
加拿大西部块状硫化物矿石普遍地发生过硫化物的压溶和增生。增生作用根据增生体的成分可以分为同质增生和异质增生,根据动力环境可以分为静态增生和动态增生。三晶嵌接结构可以是静态增生的产物。压溶和增生是块状硫化物矿床成岩和变质过程中的重要作用。脉石矿物的压溶可使原生矿石就地加富,硫化物的压溶可使成矿物质发生再活化。增生可促进矿质沉淀。富含硫化物的地层之所以能成为地球化学障而有利于后期热液叠加和层控矿床的形成,硫化物晶芽的增生是一种重要机制。 相似文献
27.
Pressure solution is a common phenomenon in massive sulphide zinc-lead deposits of western Canada and may have been an important factor leading to the mobilization of ore-forming materials during diagenesis, deformation and metamorphism of sedimentary ores.The control of ductile shear zones over gold mineralization could be explained in view of pressure solution of gold-bearing miner-als under shearing stress and the tesultant mobilization of this metal. 相似文献
28.
在陆相古火山角砾岩筒中由火山热液蚀变产生的含黄铁矿次生石英岩中的硫化物,在特别干旱的条件下生成了以毛矾石及黄钾铁钒为主的13种钒类矿物组成的硫化矿床氧化带,并在其中聚集了毛矾石矿体。毛钒石矿是由反复进行的氧化-渗透淋滤作用而富集形成的。 相似文献
29.
30.
Liangyi Meng 《中国科学D辑(英文版)》1997,40(3):225-231
The copper deposits in the mid-lower reaches of the Changjiang River consist mainly of porphyry, skarn and massive sulphide
deposits. According to the geological background, the types of ore deposits and the mineralization, the metallogenic model
of the copper deposits is discussed. It is pointed out that the ore-forming hydrothermal fluids came mainly from magmatic
water and were related to the intermediate-acid intrusions, and that the formation of skarn arid massive sulphide deposits
coincided with the mineralization of porphyry deposits.
Project supported by Doctorate Foundation of the State Education Commission of China. 相似文献