2-辛胺吡啶—新的萃取试剂     

N.A.Borsh  O.M.Petrukhin  胡文清 《地球科学与环境学报》1981,(1)

等人曾提出用n—辛苯胺(OA)富集铂族金属时指出,惰性稀释剂中的OA能够在酸性介质中萃取钯和铂,在中性介质中以配位—溶剂化方式萃取铑。3(5)—甲基吡唑由盐酸溶液中萃取钯和铑。在吸着剂上吸着铂族金属,是基于苯乙烯和3(5)—甲基吡唑的共聚合物,同铂族金属形成以M-N键的化合物。显然,芳香胺对铂族金属具有一定的特效性。由脂肪胺转变为苯胺和杂环芳香胺时氮原子得更“软”。铂族金属多与“软”配位体结合。  相似文献   

A review of pollutants in the sea-surface microlayer (SML): a unique habitat for marine organisms     

Wurl O  Obbard JP 《Marine pollution bulletin》2004,48(11-12):1016-1030

Boundary layers between different environmental compartments represent critical interfaces for biological, chemical and physical processes. The sea-surface microlayer (uppermost 1-1000 microm layer) forms the boundary layer interface between the atmosphere and ocean. Environmental processes are controlled by the SML, and it is known to play a key role in the global distribution of anthropogenic pollutants. Due to its unique chemical composition, the upper organic film of the SML represents both a sink and a source for a range of pollutants including chlorinated hydrocarbons, organotin compounds, petroleum hydrocarbons, polycyclic aromatic hydrocarbons (PAH) and heavy metals. These pollutants can be enriched in the SML by up to 500 times relative to concentrations occurring in the underlying bulk water column. The SML is also a unique ecosystem, serving as an important habitat for fish eggs and larvae. Concentration ranges and enrichment factors of pollutants in the SML in different areas of the world's oceans have been critically reviewed, together with available toxicity data for marine biota found within the SML. Overall, the SML is highly contaminated in many urban and industrialized areas of the world, resulting in severe ecotoxicological impacts. Such impacts may lead to drastic effects on the marine food web and to fishery recruitment in coastal waters. Studies of the toxicity of fish eggs and larvae exposed to the SML contaminants have shown that the SML in polluted areas leads to significantly higher rates of mortality and abnormality of fish embryos and larvae.  相似文献   

Influence of small-scale heterogeneities on contaminant transport in fractured crystalline rock     

Mettier R  Kosakowski G  Kolditz O 《Ground water》2006,44(5):687-696

We present a sequence of purely advective transport models that demonstrate the influence of small-scale geometric inhomogeneities on contaminant transport in fractured crystalline rock. Special weight is placed on the role of statistically generated variable fracture apertures. The fracture network geometry and the aperture distribution are based on information from an in situ radionuclide retardation experiment performed at Grimsel test site (Swiss Alps). The obtained breakthrough curves are fitted with the advection dispersion equation and continuous-time random walks (CTRW). CTRW is found to provide superior fits to the late-arrival tailing and is also found to show a good correlation with the velocity distributions obtained from the hydraulic models. The impact of small-scale heterogeneities, both in fracture geometry and aperture, on transport is shown to be considerable.  相似文献   

Distribution of trace organic contaminants and total mercury in sediments from the Bilbao and Urdaibai Estuaries (Bay of Biscay)     

Bartolomé L  Tueros I  Cortazar E  Raposo JC  Sanz J  Zuloaga O  de Diego A  Etxebarria N  Fernández LA  Madariaga JM 《Marine pollution bulletin》2006,52(9):1111-1117

  相似文献   

Atmospheric lead fallout over the last century recorded in Gulf of Lions sediments (Mediterranean Sea)     

Miralles J  Véron AJ  Radakovitch O  Deschamps P  Tremblay T  Hamelin B 《Marine pollution bulletin》2006,52(11):1364-1371

Six marine sediment cores from the Gulf of Lions continental slope (700-1700 m water depth) were analyzed for stable lead isotopes and (210)Pb geochronology in order to reconstruct lead atmospheric fallout pattern during the last century. The detrital lead contribution is 25 microg g(-1) and the mean sediment anthropogenic inventory is 110+/-7 microg cm(-2), a little bit higher than atmospheric deposition estimate. Anthropogenic lead accumulation in sediments peaked in early 1970s (1973+/-2) in agreement with lead emissions features. For the period 1986-1997, the sediment signal also reflect the decrease of atmospheric lead described by independent atmospheric fallout investigations. The anthropogenic Pb deposition in the late 1990s was similar to the 1950s deposition, attesting thus of the output of European environmental policies.  相似文献   

Salinity-induced survival strategy of Vibrio cholerae associated with copepods in Cochin backwaters     

Thomas KU  Joseph N  Raveendran O  Nair S 《Marine pollution bulletin》2006,52(11):1425-1430

The occurrence of Vibrio cholerae in water, sediment and copepods was studied over a wide range of salinity using conventional and polymerase chain reaction (PCR) techniques in the Cochin backwaters. V. cholerae occurred either as culturable or non-culturable form in this tropical estuary. During the pre monsoon period when high salinity prevailed (35.5psu) V. cholerae was associated with copepods only in non-culturable form, but with the onset of monsoon when lower salinity prevailed, copepod-associated-V. cholerae reverted back to culturable form. The optimum salinity range for culturability was found to be 15-20psu. This points to the fact that salinity is a major factor that which influences V. cholerae's culturability and its association with copepods in Cochin backwaters.  相似文献   

The use of the marine biotic index AMBI in the assessment of the ecological status of the Obidos lagoon (Portugal)     

Carvalho S  Gaspar MB  Moura A  Vale C  Antunes P  Gil O  da Fonseca LC  Falcão M 《Marine pollution bulletin》2006,52(11):1414-1424

This study reports the longitudinal distribution of sediment properties, including inorganic and organic contaminants, and the structure of the benthic community in Obidos lagoon, a coastal system permanently connected to the sea and with negligible freshwater sources. Sediments from the upper to central lagoon consist of fine particles (91%) and from the lower lagoon of sands (94%). Chemical composition is strongly correlated to the percentage of fine particles. Contamination is relatively low in those sediments suggesting the effect of diffuse sources. The increase in organic matter content from down- to upstream areas was associated with the dominance of opportunistic species, while sensitive and indifferent species to organic enrichment were mainly associated to the clean sandy downstream area. The marine biotic index (AMBI) was suitable for the discrimination of the biological and environmental gradients in the Obidos lagoon and was highly related with the gradient of organic matter content in this system.  相似文献   

华北西部贺兰山中段黄旗口花岗岩成因及地质意义   总被引：1，自引：0，他引：1       下载免费PDF全文

余淳梅  杨华本  曾佐勋  吴林波 《地球科学》2019,44(4):1266-1277

华北克拉通孔兹岩带内发育类型复杂的各类岩石,是记录和反演华北西部早期块体拼合以及岩浆作用、变质演化的重要对象,而其中段发育的出露面积广阔、岩性复杂的黄旗口花岗岩体的研究还较为薄弱.在野外地质和岩相学研究基础上,主要报道了贺兰山中段黄旗口花岗岩的主、微量元素和Sr-Nd同位素组成,对岩体的源区特征、成因及地质意义进行了探讨.黄旗口复式花岗岩体主要由早期正长花岗岩、二长花岗岩和晚期英云闪长岩组成.两期岩体具有高K₂O（2.97%~6.71%）含量,A/CNK均大于1.1,但晚期侵入单元较早期岩石更贫硅、富铝.两期岩体都表现为轻稀土富集、Eu负异常的特点,且强烈富集K、Rb、Th等大离子亲石元素,亏损Nb、Ta、P、Ti等高场强元素.岩石87Sr/86Sr初始比值变化范围较大,可能是后期改造的结果;ε_Nd（t）变化在+1.81~+4.90,对应的Nd同位素模式年龄T_DM1为2.10~2.37 Ga,T_DM2为2.10~2.35 Ga.这些特征表明黄旗口岩体为S型花岗岩,可能来自该区归属于孔兹岩的赵池沟组岩系的部分熔融,并可能有地幔岩浆的参与.结合区域变质、岩浆事件的综合研究成果,认为黄旗口不同期次的花岗岩具有造山带花岗岩的特征,分别形成于阴山地块和鄂尔多斯地块碰撞拼合以及造山后伸展的不同阶段.   相似文献   

塔里木盆地塔北隆起奥陶系-侏罗系泥岩稀土元素地球化学特征   总被引：12，自引：0，他引：12  

张沛  郑建平  张瑞生  余淳梅 《沉积学报》2005,23(4):740-746

分析了塔里木盆地塔北隆起奥陶系、三叠系和侏罗系泥岩的稀土元素丰度。不同时代泥岩都表现出轻稀土富集、重稀土含量均一和具有Eu负异常特征;但它们∑LREE/∑HREE、LaN/YbN、(La/Yb)UCC、Eu/Eu和Ce/Ce等参数则显示这些泥岩形成时的物源和环境有差别。奥陶纪时,研究区处于相对稳定的沉积环境,物源为成熟度高的大陆上地壳;二叠纪到三叠纪构造-火山活动强烈,部分沉积物来自火山岩的风化;侏罗纪塔北隆起区则进入稳定构造沉降阶段。这一差别对认识塔里木盆地及周边造山带形成演化研究有指示意义。  相似文献   

Field Relationships, Geochemistry, Zircon Ages and Evolution of a Late Archaean to Palaeoproterozoic Lower Crustal Section in the Hengshan Terrain of Northern China   总被引：13，自引：0，他引：13  

A. KRNER  S.A. WILDE  P.J. O’BRIEN  C.W. PASSCHIER  N.P. WALTE 《《地质学报》英文版》2005,79(5):605-632

The Hengshan complex forms part of the central zone of the North China Craton and consists predominantly of ductilely-deformed late Archaean to Palaeoproterozoic high-grade, partly migmatitic, granitoid orthogneisses, intruded by mafic dykes of gabbroic composition. Many highly strained rocks were previously misinterpreted as supracrustal sequences and represent mylonitized granitoids and sheared dykes. Our single zircon dating documents magmatic granitoid emplacement ages between 2.52 Ga and 2.48 Ga, with rare occurrences of 2.7 Ga gneisses, possibly reflecting an older basement. A few granitic gneisses have emplacement ages between 2.35 and 2.1 Ga and show the same structural features as the older rocks, indicating that the main deformation occurred after -2.1 Ga. Intrusion of gabbroic dykes occurred at -1920 Ma, and all Hengshan rocks underwent granulite-facies metamorphism at 1.88-1.85 Ga, followed by retrogression, sheafing and uplift. We interpret the Hengshan and adjacent Fuping granitoid gneisses as the lower, plutonic, part of a late Archaean to early Palaeoproterozoic Japan-type magmatic arc, with the upper, volcanic part represented by the nearby Wutai complex. Components of this arc may have evolved at a continental margin as indicated by the 2.7 Ga zircons. Major deformation and HP metamorphism occurred in the late Palaeoproterozoic during the Luliang orogeny when the Eastern and Western blocks of the North China Craton collided to form the Trans-North China orogen. Shear zones in the Hengshan are interpreted as major lower crustal discontinuities post-dating the peak of HP metamorphism, and we suggest that they formed during orogenic collapse and uplift of the Hengshan complex in the late Palaeoproterozoic （〈1.85 Ga）.  相似文献