Geochemistry and behavior of REE in stream sediments close to an old Sn-W mine,Ribeira, Northeast Portugal     

《Chemie der Erde / Geochemistry》2014,74(4):545-555

The abandoned Sn-W Ribeira mine, northeast of Portugal, contained quartz veins with cassiterite, wolframite, scheelite, pyrite, arsenopyrite, sphalerite, chalcopyrite, manganocolumbite, bismuthinite, native bismuth, phosphates and carbonates. The exploration took place on the northern slope of the Viveiros stream, which is an affluent of the Sabor River. The waste-rock dumps and tailings were deposited on the hillside, close to the mine and are nowadays exposed to significant weathering and erosion, as they are not vegetated. The eroded material is transported by the Viveiros stream toward the Sabor River. A seasonal stream drains the tailings. The stream sediments samples were collected along the Viveiros stream, in the seasonal stream, in a seasonal spring at the bottom of the tailings, in the Sabor River and in other streams not affected by mine workings, following the mine influence along the Viveiros stream and in the Sabor River (1.2 km away from the mine workings). The data show that the degree of pollution increases along the Viveiros stream, especially in winter. The highest degree of pollution is for As, In, W, Sn and Bi. The sediments from the drainage of the main tailings are particularly polluted during winter, by Bi, In and Sn. The sedimentary precipitate from the spring is polluted in Cu, As, In, Sn, Ta, W, Bi, Zn, Nb, Ag, Sb and Ta. The sediments from the Sabor River are significantly polluted by As, Ag, In, Sn, W and Bi. The sediments from the regional streams, Viveiros stream and Sabor River have similar REE (NASC normalized) patterns (ΣREE = 131.7–185.9 mg/kg, La_N/Lu_N = 1.23–1.42 and Eu/Eu* = 1.02), while those from the seasonal stream, crossing the main tailings, are enriched in REE (ΣREE = 250.3–283.6 mg/kg, La_N/Lu_N = 1.6–2.09 and Eu/Eu* = 0.96). The general decrease in La_N/Lu_N values with increase in total Fe₂O₃ can be explained by the partitioning of HREE to the solid Fe-oxides phase. The sedimentary precipitate and coatings, which are mainly formed by Fe-oxy-hydroxides, but also contain jarosite, are impoverished in all REE. The impoverishment can be explained by the release of REE from the surface of the Fe-oxy-hydroxides, which occurs due to a local lowering of pH, caused by jarosite dissolution. During successive alternate cycles of wet and dry conditions, takes place the formation of Fe-oxy-hydroxides and jarosite in the sedimentary precipitate and coatings. The subsequent dissolution of jarosite releases acidity, thus promoting de-sorption of REE from the Fe-oxy-hydroxides mineral phases.  相似文献   

A 7000-year record of environmental change,including early farming impact,based on lake-sediment geochemistry and pollen data from County Sligo,western Ireland     

Michael O'Connell  Beatrice Ghilardi  Liam Morrison 《Quaternary Research》2014

Detailed, chronologically tightly constrained, lake-sediment-based geochemical and pollen records have enabled local changes in soil erosion, woodland cover and composition, and prehistoric farming impact to be reconstructed in considerable detail. The profile opens shortly after 7800 BC when tall canopy trees were well-established and presumably in equilibrium with their environment. A distinct perturbation that involved an increase in pine and birch, a decrease in oak and a minor opening-up of the woodland is regarded as the local expression of the 8.2 ka climate anomaly. Lack of response in the geochemical erosional indicators is interpreted as evidence for drier conditions. A short-lived, over-compensation in climate recovery followed the 8.2 ka event. Neolithic farming impact is clearly expressed in both the pollen and geochemical data. Both datasets indicate that Neolithic impact was concentrated in the early Neolithic (3715–3440 BC). In the interval 3000–2700 BC there appears to have been a break in farming activity. The pollen data suggest substantially increased farming impact (both arable and pastoral) in the Bronze Age, with maximum farming and woodland clearances taking place in the late Bronze Age (1155–935 BC). These developments are poorly expressed in the geochemical record, possibly due to within-lake changes.  相似文献   

贵州晴隆中二叠统大厂层砾岩成因研究   总被引：1，自引：0，他引：1  

陈军  杨瑞东  郑禄林  高军波  魏怀瑞 《地质论评》2014,60(6):1309-1322

贵州晴隆中二叠统大厂层中—上部产出一套呈囊状、透镜状分布的砾岩层。对大厂层砾岩沉积序列、结构、构造特征和矿物组合进行研究,结果表明:沉积序列为"反粒序",砾岩成分单一,基本为玄武质,是由峨眉山玄武岩直接改造而成,未发育河道相沉积特征;大厂层砾石具特殊的"泥化边"构造,是玄武岩在海水中大量水解的直接证据,填隙物中的青磐岩化矿物组合表明砾岩遭受了低温热液的改造。填隙物具有接近凝灰岩的Zr/Hf(30.7~43.4,均值38.0),揭示玄武岩在改造形成砾石的过程中有火山碎屑(火山灰)参与成岩;砾石和填隙物相对玄武岩贫Na(Na2O)富K(K2O),三者具有相似的稀土配分模式,其中∑REE呈规律性变化(玄武岩最高,砾石次之,填隙物中最低)。沉积背景分析认为,峨眉地幔柱作用使地壳发生了差异抬升,抬升一侧暴露遭受剥蚀形成不整合面,相对沉降一侧继续接受沉积,大厂层正是峨眉山玄武岩前锋带在局限海盆边缘(沉降侧),于茅口灰岩之上继续沉积的产物。大厂层砾岩形成机制是:炽热玄武岩流在海水中急剧爆裂,同时火山碎屑参与沉积,形成的玄武岩前积层(淬碎熔岩角砾)及凝灰岩,沉积在茅口组灰岩之上;在后期的演化过程中,炽热玄武岩冷凝收缩,柱状节理发育,在潮汐流和沿岸流的相互作用下不断磨蚀形成大厂层砾岩。  相似文献   

安徽金寨三仙山地区梅山群碎屑岩成分及其对物源区构造属性和地层时代的意义          下载免费PDF全文

柴广路  李双应  芦艳琳  杨栋栋  稽在飞 《地质科学》2014,(2):668-683

安徽金寨三仙山地区位于大别山北缘,该地梅山群主要为一套轻微变质的碎屑岩系。砂岩碎屑组分统计表明,砂岩类型主要为岩屑石英砂岩、岩屑石英杂砂岩,石英、长石、岩屑的平均含量为87.21%、1.67%、9.64%,杂基含量为15%,石英几乎全为单晶石英（95.79%）,长石以斜长石为主,岩屑主要为沉积岩屑（75.49%）,其次为变质岩屑（24.51%）。碎屑岩地球化学元素平均含量为：SiO₂（75.99%）,Al₂O₃（11.96%）,MgO（0.72%）,CaO（0.10%）,Fe₂O₃（4.02%）,K₂O（1.70%）,Na₂O（0.26%）。ΣREE=170.49×10^-6（74.49×10^-6～309.42×10^-6）,LREE/HREE=11.16（7.89～14.26）,轻稀土略有富集,δEu=0.72（0.59～0.90）,La/Yb=22.08（13.01～31.18）,（La/Yb）_N=14.89（8.77～21.02）,δCe=0.84（0.42～0.97）。碎屑岩地球化学特征指示三仙山地区梅山群母岩主要为古老沉积岩、长英质火山岩和古老变质基底,具有多重物源区。梅山群构造背景较复杂,主要为被动大陆边缘和活动大陆边缘,其次为大陆岛弧。三仙山地区梅山群碎屑岩的源岩成分、构造背景与商城-固始地区石炭系有很大差别,故其地层时代有待于进一步研究。  相似文献   

Distribution of trace metals in stream sediments along the Trans-Amazonian Federal Highway,Pará State,Brazil     

《Journal of South American Earth Sciences》2014

A total of 64 sediment samples were collected along a stretch of about 988 km of the Trans-Amazonian Federal Highway, between Marabá and Itaituba, Pará State, in order to characterize the distribution of metals and trace elements. Due to the lithological and geological diversity along this stretch of the Amazon, the study region was divided in three distinct tracks. Statistical data analysis (Spearman correlation and Principal Factor Analysis) shows strong signature and predominance of regional rocks chemistry, such as mafic-ultramafic-bearing elements (Ni and Cr) and hydrothermalism-bearing elements such as Cu and Pb. Enrichment factors were calculated for three different normalizer agents: 1) Fe and Mn, representing the Fe and Mn (hydr)oxides, 2) Al representing clay minerals, and 3) organic matter (OM). The Fe and Mn (hydr)oxides showed to be the most proficient metal carrier among the geological matrices, likely due to the larger lithological diversity. On the other hand, OM positively correlated to trace element distribution.  相似文献   

Low-pressure evolution of arc magmas in thickened crust: The San Pedro–Linzor volcanic chain,Central Andes,Northern Chile     

《Journal of South American Earth Sciences》2014

Magmatism at Andean Central Volcanic Zone (CVZ), or Central Andes, is strongly influenced by differentiation and assimilation at high pressures that occurred at lower levels of the thick continental crust. This is typically shown by high light to heavy rare earth element ratios (LREE/HREE) of the erupted lavas at this volcanic zone. Increase of these ratios with time is interpreted as a change to magma evolution in the presence of garnet during evolution of Central Andes. Such geochemical signals could be introduced into the magmas be high-pressure fractionation with garnet on the liquidus and/or assimilation from crustal rocks with a garnet-bearing residue. However, lavas erupted at San Pedro–Linzor volcanic chain show no evidence of garnet fractionation in their trace element patterns. This volcanic chain is located in the active volcanic arc, between 22°00^′S and 22°30^′S, over a continental crust ∼70 km thick. Sampled lavas show Sr/Y and Sm/Yb ratios <40 and <4.0, respectively, which is significantly lower than for most other lavas of recent volcanoes in the Central Andes. In addition, ⁸⁷Sr/⁸⁶Sr ratios from San Pedro–Linzor lava flows vary between 0.7063 and 0.7094. This is at the upper range, and even higher than those observed at other recent Central Andean volcanic rocks (<0.708). The area in which the San Pedro–Linzor volcanic chain is located is constituted by a felsic, Proterozoic upper crust, and a thin mafic lower crustal section (<25 km). Also, the NW–SE orientation of the volcanic chain is distinctive with respect to the N–S orientation of Central Andean volcanic front in northern Chile. We relate our geochemical observations to shallow crustal evolution of primitive magmas involving a high degree of assimilation of upper continental crust. We emphasize that low pressure AFC- (Assimilation Fractional Crystallization) type evolution of the San Pedro–Linzor volcanic chain reflects storage, fractionation, and contamination of mantle-derived magmas at the upper felsic crust (<40 km depth). The ascent of mantle-derived magmas to mid-crustal levels is related with the extensional regime that has existed in this zone of arc-front offset since Late-Miocene age, and the relatively thin portion of mafic lower crust observed below the volcanic chain.  相似文献   

柴北缘绿梁山地区早古生代弧后盆地型蛇绿岩的年代学、地球化学及大地构造意义   总被引：12，自引：5，他引：7  

朱小辉  陈丹玲  刘良  赵姣  张乐 《岩石学报》2014,30(3):822-834

岩石学、地球化学、年代学及Lu-Hf同位素综合研究表明在柴北缘西段绿梁山大平沟地区出露一套弧后盆地型蛇绿岩,岩石类型主要包括变质橄榄岩、变火山岩、变辉长岩及斜长花岗岩。其中变火山岩具有LREE亏损,类似N-MORB的稀土配分模式,同时又具有富集大离子亲石元素,亏损Nb、Ta等高场强元素的岛弧火山岩的地球化学特征,应形成在弧后盆地环境。斜长花岗岩为低钾准铝质花岗岩,具有LREE略微富集,HREE平坦的稀土配分型式,显示强烈Eu正异常,其εHf(t)值介于13.7～15.3之间,为变辉长岩部分熔融的产物,熔融温压条件可能为P=0.8～0.9GPa和T=～800℃。年代学研究结果表明变辉长岩的形成时代为535±2Ma,斜长花岗岩的形成时代为493±3Ma,指示本地区弧后盆地拉张时限至少介于493～535Ma之间,而柴北缘地区古大洋俯冲消减作用应早于535Ma。  相似文献   

吉林东部延边地区二长花岗岩年代学、岩石成因学及其构造意义研究   总被引：7，自引：5，他引：2  

张超  郭巍  徐仲元  刘正宏  刘永江  雷聪聪 《岩石学报》2014,30(2):512-526

高岭岩体位于吉林省延边地区和龙市东侧,大地构造位置上位于华北板块北缘东段,岩性主要为似斑状二长花岗岩,基质为中粒-中细粒结构。LA-ICP-MS锆石U-Pb测年结果显示,样品YH04和N-5的加权平均年龄分别为172.25±0.97Ma和170.9±0.68Ma,表明岩体侵位时代为中侏罗世。岩石地球化学特征上,高岭岩体样品具有高硅(69.60%~74.30%)、富铝(13.90%~15.80%)、富钾(3.05%~4.50%)和低镁(0.22%~0.82%)及Mg#(26~37)的特点。样品富集轻稀土元素,相对亏损重稀土元素(LREE/HREE=13~21),具有微弱的负Eu到正Eu异常(δEu=0.78~2.14),其稀土元素配分模式图与埃达克岩稀土元素配分模式图类似。高岭岩体样品富集大离子亲石元素Cs、Rb、Ba、K、Sr和高场强元素Th、U和Zr,同时亏损高场强元素Nb、Ta以及P元素。同时样品具有较低的初始87Sr/86Sr值(0.7039~0.7051)和负的εNd(t)值(-0.6~-0.3),且其t DM1和t DM2模式年龄分别为922~928Ma和984~1011Ma,表明研究区新元古代存在地壳增生事件。Sr-Nd同位素特征及岩石地球化学特征表明高岭岩体母源岩浆来源于加厚下地壳基性岩石部分熔融且受到了新元古代增生物质的影响。结合区域构造演化,中侏罗世高岭岩体侵位构造环境可能受到环太平洋构造体系和华北板块与西伯利亚板块持续碰撞的叠加影响。  相似文献   

内蒙古中部构造混杂带晚古生代-早中生代变质基性岩的地球化学特征及其大地构造意义   总被引：6，自引：4，他引：2  

张晋瑞  初航  魏春景  王康 《岩石学报》2014,30(7):1935-1947

内蒙古中部构造混杂带中的变质基性岩可分为南、北两带:南带位于乌兰沟-图林凯地区,被划分至温都尔庙群下部的桑达来因组,主要为一套变质玄武岩和辉长岩、辉绿岩,局部含有超基性岩和碳酸岩透镜体,其中变质基性火山岩以绿片岩相变质为主,局部保留枕状构造或发育蓝片岩,已有的锆石U-Pb年代学数据表明南带变质基性火山岩形成于晚古生代到早中生代;北带位于芒和特-二道井-红格尔一线,主要呈岩块状保存在由绢云绿泥石英片岩、硅质岩、含铁石英岩和少量的大理岩组成的基质中,岩石类型包括蓝片岩、冻蓝闪石片岩、阳起片岩、绿帘角闪片岩等。地球化学研究显示南、北两带的变质基性岩相对低Al(Al2O3=10.66%~14.97%)、低Ti(TiO2=1.27%~1.96%)、高Na(Na2O=1.02%~4.20%)、贫K(K2O=0.02%~0.71%),具有拉斑玄武岩到碱性玄武岩系列的过渡特征,高的Na2O/K2O比值(6.89~454)暗示这些基性岩在变质作用前发生了细碧角斑岩化。不活动元素Zr与其他高场强元素(HSFE;Th、Nb、Hf、Ti)和稀土元素(REE)显示良好的线性关系,表明在变质过程中,高场强元素和稀土元素基本保持稳定,可以反映原岩的性质。根据稀土、微量元素配分型式和相关比值可以将内蒙中部构造混杂带中的变质基性岩分为两类:一类稀土含量相对较低(∑REE=46.00×10-6~78.08×10-6)、轻重稀土分异不明显((La/Yb)N=0.50~1.04),无明显Eu负异常,Hf/Ta=6.82~15.18,具有正常的大洋中脊玄武岩(NMORB)特征;另一类稀土含量相对较高(∑REE=58.66×10-6~151.3×10-6)、轻重稀土分异明显((La/Yb)N=2.28~4.68),无明显Eu负异常,Hf/Ta=2.06~4.70,与富集型洋中脊玄武岩(E-MORB)相似。部分变质基性岩样品轻微富集大离子亲石元素Rb和Ba,可能暗示原岩在就位过程中遭受了微弱的陆壳混染。以上地球化学特征表明这些变质基性岩的原岩可能形成于一个扩张规模有限的陆内洋盆环境。已有的古生物地理学研究表明古亚洲洋闭合后,到晚古生代早期,内蒙古中部地区成为佳-蒙地块的一部分。石炭纪期间整个内蒙古中部发育稳定的浅海相沉积,局部为造山后隆起环境,发育加里东I型花岗岩和花岗闪长岩。从晚石炭世-早二叠世起,内蒙中部开始处于伸展环境:二连浩特到东乌珠穆沁旗一带发育大量的碱性岩;华北克拉通北缘发育很多高钾钙碱性-碱性的花岗岩;内蒙中部地区广泛发育二叠纪大石寨组双峰式火山岩。到中二叠世开始裂解形成若干近东西向分布的海盆,发育哲斯组、林西组浅海相、泻湖相沉积。持续的伸展形成了有限洋盆,发育以温都尔庙群为代表的含铁硅质岩以及晚古生代-早中生代基性岩。由于早中三叠世华北板块与扬子板块全面碰撞和陆内造山过程的影响,有限洋盆最终在早中生代之后发生被动闭合,形成南、北构造混杂带,并导致该基性岩乃至整个内蒙中部的晚古生代沉积发生广泛绿片岩相变质作用,而局部蓝片岩的形成可能与有限洋盆的俯冲作用有关。  相似文献   

五台杂岩晚太古代花岗质岩石中斜长角闪岩包体的年代学和地球化学研究     

刘超辉  刘福来  施建荣 《岩石学报》2014,30(10):2857-2871

华北克拉通中部造山带被认为是由东西部陆块碰撞而产生的陆陆碰撞带,而恒山-五台-阜平地区位于中部造山带的中部,是该地区最大也是最具代表性的基底岩石剖面。总体上,五台杂岩可以分为变质表壳岩和花岗质岩体两大类,前者又被划分为五台群和滹沱群,而后者可划分为2560~2520Ma侵位的强烈变形的闪长岩-英云闪长岩-奥长花岗岩-花岗闪长岩系列、2176~2084Ma侵位的弱变形的斑状正长-钾质花岗岩以及约1810Ma侵位的未变形的A型花岗岩。在晚太古代花岗岩中普遍发育有斜长角闪岩包体,它们在露头上不连续分布,呈绿色到黑色,强烈拉伸成扁条状或透镜状,直径一般在几米到十几米之间。根据地球化学特征恢复它们的原岩为拉斑玄武岩。锆石U-Pb定年结果表明它们的结晶时代为2.7Ga,变质时代为1.85Ga。全岩εNd(t)值为-3.1~+3.5,亏损地幔模式年龄为2.83~3.65Ga。原始地幔均一化蛛网图解上,斜长角闪岩具有明显的Nb、Ta和Ti的负异常,而在球粒陨石均一化稀土元素配分图解中它们具有轻稀土弱富集[(La/Yb)N=1.36~3.52]以及重稀土平坦[(Gd/Yb)N=0.94~1.38]的特征。地球化学以及同位素特征表明它们很可能来自于受到俯冲板片流体改造的轻度富集地幔中尖晶石二辉橄榄岩的部分熔融。更重要地,这些斜长角闪岩包体的锆石U-Pb年龄与全岩Nd亏损地幔模式年龄相似,都为27~28亿年左右,这说明在华北克拉通中部造山带很可能存在过大量的27亿年左右的新生地壳岩石,它们代表了一期重要的地壳生长事件。  相似文献