Weathering of Fruchtschiefer building stones: mineral dissolution or rock disaggregation?     

Cornelius Fischer  Stephan Kaufhold  Wanja Wedekind  Reiner Dohrmann  Volker Karius  Siegfried Siegesmund 《Environmental Earth Sciences》2011,63(7-8):1665-1676

Building stones manufactured from contact metamorphic slates (Fruchtschiefer slate) from Theuma (Sachsen, Germany) were investigated for mineralogical alterations as well as for changes in porosity and surface roughness due to weathering. After weathering periods of several years to decades, the originally dark gray-colored slates show pale spots of several centimeters in size at the surface of building stones. The dark-colored and light-colored sections of the slate show no differences in mineralogy. Surface weathering did not result in newly precipitated minerals. It was also found that the observed differences in color are not caused by variations in sedimentary organic carbon concentration or in sulfide/sulfate concentrations. Obtained results instead indicate that dark surface sections may show a thin cover of recent organic matter (OM), e.g., living OM, soot, dirt, etc. Microscopic investigations suggested that this cover was exfoliated at light-colored surface sections. The observed disaggregation of the upper 2 mm of the building block material results in an increase in porosity. Porosity of black (unweathered) slate is <2 vol.%. Due to weathering, the slate’s pores with diameters >1 μm show a significant increase in frequency compared to the original pore size distribution. Porosity of weathered rock volumes increased to approx. 8 vol.%. Discolored surface sections show a higher surface roughness (root-mean-square roughness, Rq ~ 1 μm) compared to dark-colored slate surfaces (Rq ~ 200 nm), both data are for cleavage planes. Preferentially, the discolored surface sections are located close to the edges of cut stones. This and the alteration in porosity, pore size, and surface roughness indicate that color changes of the slate are largely influenced by rock disaggregation proceeding from the edges into the center rather than by mineral dissolution/precipitation processes.  相似文献   

Nb–Ta fractionation by partial melting at the titanite–rutile transition     

Timm John  Reiner Klemd  Stephan Klemme  Jörg A. Pfänder  J. Elis Hoffmann  Jun Gao 《Contributions to Mineralogy and Petrology》2011,161(1):35-45

During the evolution of the Earth, distinct geochemical reservoirs with different Nb/Ta ratios have developed. Archean granitoids of the tonalite–trondhjemite–granodiorite (TTG) suite, which represent the Earth’s early continental crust, show larger Nb/Ta variations than any other Earth reservoir. This implies that significant Nb–Ta fractionation must have occurred during early crust formation, while the underlying mechanism behind is still unclear. Here, we present a new model on how Nb may be fractionated from Ta during partial melting of subducted oceanic crust. Our data show that Nb/Ta ratios in melts derived from rutile- and titanite-bearing eclogite are largely controlled by the modal relative abundances of rutile and titanite in the source. High modal ratios of titanite over rutile generate melts with very high Nb/Ta (>60), whereas low modal titanite/rutile produces melts with much lower Nb/Ta (≤30). Very low Nb/Ta (<16) occur when all Ti-phases are consumed at very high degrees of melting. As the modal ratio of titanite to rutile is a function of pressure, the Nb/Ta of melts is a function of melting depth. Our new model helps to explain the extreme variation of Nb/Ta observed in many TTGs and thus how Nb and Ta were fractionated during the early evolution of the Earth. Furthermore, the model also indicates that simple one-stage melting models for mafic crust are not sufficient to explain the formation of TTGs.  相似文献   

德国4站点极端降水频数和强度趋势变化分析   总被引：1，自引：0，他引：1  

杨靖文  孙即霖  Reiner Schlitzer 《中国海洋大学学报(自然科学版)》2010,(Z1)

根据不莱梅、波茨坦、卡尔斯鲁厄和楚格峰1901—2007年逐日降水量分析了各站极端降水的频数和强度趋势变化。结果表明:山区(楚格峰)出现的极端降水数量呈上升趋势,且强度显著增强,在冬、夏2季亦如此。这与全球变暖背景下,山区的积雪融化导致对流活动增强以及大气环流影响水汽输送增强有关;在超过绝对阈值的极端降水方面,北方地区(不莱梅和波茨坦)发生频数保持稳定,无显著趋势变化,南方地区(卡尔斯鲁厄)有显著减少的趋势,且不莱梅的频数变化趋势与波茨坦相似,具有强正相关,而此2站与卡尔斯鲁厄的频数变化趋势呈反位相,有较强的负相关;除楚格峰外,极端降水强度变化无显著趋势。低海拔地区在冬季极端降水的频数和强度上,大部分有显著上升的趋势,而夏季,在2方面均出现不同程度的下降;极端降水频数和强度呈强正相关。  相似文献   

On the spectral consistency of the altimetric ocean and geoid surface: a one-dimensional example     

Alberta Albertella  Reiner Rummel 《Journal of Geodesy》2009,83(9):805-815

Geoid models from the new generation of satellite gravity missions, such as GRACE and GOCE, in combination with sea surface from satellite altimetry allow to obtain absolute dynamic ocean topography with rather high spatial resolution and accuracy. However, this implies combination of data with fundamentally different characteristics and different spatial resolutions. Spectral consistency would imply the removal of the short-scale features of the altimetric sea surface height by filtering, to provide altimetric data consistent with the resolution of the geoid field. The goal must be to lose as little as possible from the high precision of the altimetric signal. Using a one-dimensional example we show how the spectrum is changing when a function defined only on a limited domain (ocean in the real case) is extended or not as to cover the complete domain (the whole sphere in the real case). The results depend on the spectral characteristics of the altimetric signal and of the applied filter. Referring to the periodicity condition, as it is requested in the case of Fourier analysis, the action of the two classical filters (Ideal Low Pass and Gauss filter) and of two alternative procedures (wavelets and Slepian) is studied.  相似文献   

Weathering of volcanic tuff rocks caused by moisture expansion   总被引：1，自引：1，他引：0  

Wanja Wedekind  Rubén López-Doncel  Reiner Dohrmann  Mathias Kocher  Siegfried Siegesmund 《Environmental Earth Sciences》2013,69(4):1203-1224

Moisture expansion in natural building stones is considered one of the most important factors affecting their weathering and deterioration. The processes that may be responsible for the expansion under determinate relative humidity (hygric dilatation) and water-saturated conditions (hydric dilatation) are generally attributed to the presence of swellable clay minerals. In contrast to this assumption, our investigations show that moisture expansion also takes place in volcanic tuff building stones almost free from clay minerals. To provide a deeper understanding of the processes, swelling and deterioration were performed on 14 volcanic tuffs used as important building stones of different ages, compositions and weathering stages from Mexico, Germany and Hungary. The investigations undertaken include extensive chemical, petrophysical and fabric analyses. The samples show a wide range of effective porosity, microporosity, capillary water absorption, moisture expansion, and CEC values. High moisture expansion does not seem to depend on clay mineral content alone. We also observed that there is no significant effect on dilatation if clay minerals are present but only form a thin coat on the outer shell of bigger pores. Moreover, we identified a correlation between microporosity, average pore radius and moisture expansion. The investigations highlight the fact that moisture expansion cannot only be attributed to swellable clay minerals, and suggest that the presence and accumulation of micropores and their average radius and distribution play an important role for non-clay associated swelling intensity, which can most probably be attributed to the disjoining pressure.  相似文献   

Transformation of global spherical harmonic models of the gravity field to a local adjusted spherical cap harmonic model     

Ghadi K. A. Younis  Reiner Jäger  Matthias Becker 《Arabian Journal of Geosciences》2013,6(2):375-381

The new global gravity models represented by global spherical harmonics like EGM2008 require a high degree and order in their coefficients to resolve the gravity field in local areas; therefore, there are interests to represent the regional or local field by less parameters and to develop a parameter transformation from the global model to a local kind of spherical harmonic model. The authors use local spherical cap harmonics for the regional gravity potential representation related to a local pole and a local spherical coordinate system. This allows to model regional gravity potential with less parameters and less memory requirements in computation and storage. From different kinds of representations of spherical cap harmonics, we have selected the so-called adjusted spherical cap harmonics (ASCH). This is the most appropriate for the presented mathematical model of deriving its coefficients from global gravity models. In that way, the global gravity models can fully be exploited and mapped to regional ASCH, in particular with respect to the computation of regional geoid models with improved solution.  相似文献   

Mediterranean physical oceanography and biogeochemical cycles: General circulation and climate variability     

Joaquín Tintor  Guest Editors  Alberto Alvarez  Reiner Onken  Guest Editor 《Progress in Oceanography》2005,66(2-4):87

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Transport of South Atlantic water through the passages south of Guadeloupe and across 16°N, 2000–2004   总被引：1，自引：1，他引：1  

Monika Rhein  Kerstin Kirchner  Christian Mertens  Reiner Steinfeldt  Maren Walter  Ulrich Fleischmann-Wischnath 《Deep Sea Research Part I: Oceanographic Research Papers》2005,52(12):2234-2249

CTD, vessel-mounted ADCP and LADCP measurements in the Caribbean passages south of Guadeloupe (three repeats) and along 16°N (five repeats) were carried out between December 2000 and July 2004. The CTD data were used to calculate the contribution of South Atlantic water (SAW) in the upper 1200 m between the isopycnals σ_θ=24.5 and 27.6. Northern and southern source water masses are defined and an isopycnal mixing approach is applied. The SAW fractions are then combined with the ADCP flow field to calculate the transport of SAW into the Caribbean and across 16°N. The SAW inflow into the Caribbean through the passages south of Guadeloupe ranges from 7.6 to 11.6 Sv, which is 50–75% of the total inflow. The mean (9.1±2.2 Sv) is in the range of previous estimates. Ambiguities in the northern and southern source water masses of the salinity maximum water permitted us only to calculate the contribution of SAW from the eastern source in this water mass. We estimated the additional SAW transport by the western source to be of the order of 1.9±0.7 Sv. The calculation of the SAW transport across 16°N was hampered by the presence of several anticyclonic rings from the North Brazil Current (NBC) retroflection region, some of the rings were subsurface intensified. Provided that the rings observed at 16°N are typical rings and that all rings which are annually produced in the NBC retroflection area (6.5–8.5 per year) reach 16°N, the SAW ring transport across 16°N is calculated to 5.3±0.7 Sv. From the 5 repeats at 16°N, only two showed a net northward flow, suggesting that the mean northward SAW transport is dominated by ring advection. The joint SAW transports of the Caribbean inflow (9.1 Sv) and the flow across 16°N (5.3 Sv) sum up to 14.4 Sv. The transport increases to 16.3 Sv if the additional SAW transport from the western source of SMW (1.9±0.7 Sv) is included. These transport estimates and the following implications depend strongly on the assumption that the surface water in the Caribbean inflow is of South Atlantic origin. The transport estimates are, however, in the range of the inverse model calculations for the net cross-hemispheric flow. About 30–40% of this transport is intermediate water from the South Atlantic, presumably supporting studies which found the contributions of intermediate and upper warm water to be of a comparable magnitude. For the upper warm water (σ_θ<27.1), the Caribbean inflow seems to be the major path (7.9±1.6 Sv), the ring induced transport across 16°N is about 30% of that value. The intermediate water transport across 16°N was calculated to be 2.3–3.6 Sv, the inflow into the Caribbean is slightly smaller (1.5–2.4 Sv).  相似文献   

The evolution of stars and gas in starburst galaxies     

Roberto Cid Fernandes  João R. S. Leão  Reiner Rodrigues Lacerda 《Monthly notices of the Royal Astronomical Society》2003,340(1):29-42

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The relation between degree-2160 spectral models of Earth’s gravitational and topographic potential: a guide on global correlation measures and their dependency on approximation effects     

Christian?HirtEmail author  Moritz?Rexer  Sten?Claessens  Reiner?Rummel 《Journal of Geodesy》2017,91(10):1179-1205

Comparisons between high-degree models of the Earth’s topographic and gravitational potential may give insight into the quality and resolution of the source data sets, provide feedback on the modelling techniques and help to better understand the gravity field composition. Degree correlations (cross-correlation coefficients) or reduction rates (quantifying the amount of topographic signal contained in the gravitational potential) are indicators used in a number of contemporary studies. However, depending on the modelling techniques and underlying levels of approximation, the correlation at high degrees may vary significantly, as do the conclusions drawn. The present paper addresses this problem by attempting to provide a guide on global correlation measures with particular emphasis on approximation effects and variants of topographic potential modelling. We investigate and discuss the impact of different effects (e.g., truncation of series expansions of the topographic potential, mass compression, ellipsoidal versus spherical approximation, ellipsoidal harmonic coefficient versus spherical harmonic coefficient (SHC) representation) on correlation measures. Our study demonstrates that the correlation coefficients are realistic only when the model’s harmonic coefficients of a given degree are largely independent of the coefficients of other degrees, permitting degree-wise evaluations. This is the case, e.g., when both models are represented in terms of SHCs and spherical approximation (i.e. spherical arrangement of field-generating masses). Alternatively, a representation in ellipsoidal harmonics can be combined with ellipsoidal approximation. The usual ellipsoidal approximation level (i.e. ellipsoidal mass arrangement) is shown to bias correlation coefficients when SHCs are used. Importantly, gravity models from the International Centre for Global Earth Models (ICGEM) are inherently based on this approximation level. A transformation is presented that enables a transformation of ICGEM geopotential models from ellipsoidal to spherical approximation. The transformation is applied to generate a spherical transform of EGM2008 (sphEGM2008) that can meaningfully be correlated degree-wise with the topographic potential. We exploit this new technique and compare a number of models of topographic potential constituents (e.g., potential implied by land topography, ocean water masses) based on the Earth2014 global relief model and a mass-layer forward modelling technique with sphEGM2008. Different to previous findings, our results show very significant short-scale correlation between Earth’s gravitational potential and the potential generated by Earth’s land topography (correlation +0.92, and 60% of EGM2008 signals are delivered through the forward modelling). Our tests reveal that the potential generated by Earth’s oceans water masses is largely unrelated to the geopotential at short scales, suggesting that altimetry-derived gravity and/or bathymetric data sets are significantly underpowered at 5 arc-min scales. We further decompose the topographic potential into the Bouguer shell and terrain correction and show that they are responsible for about 20 and 25% of EGM2008 short-scale signals, respectively. As a general conclusion, the paper shows the importance of using compatible models in topographic/gravitational potential comparisons and recommends the use of SHCs together with spherical approximation or EHCs with ellipsoidal approximation in order to avoid biases in the correlation measures.  相似文献