柴达木盆地第三系咸水湖相生油岩古沉积环境地球化学特征   总被引：9，自引：0，他引：9  

叶爱娟  朱扬明 《海洋与湖沼》2006,37(5):472-480

在系统分析柴达木盆地西部第三系咸水湖相生油岩样品的微量元素、有机物、粘土矿物组成的基础上,揭示了研究区生油岩的无机元素和有机质组成特征;并结合沉积环境的无机与有机地球化学指标,重建了生油岩沉积时的古沉积环境。生油岩的B、Cl-及伽玛蜡烷含量表明,沉积时的水介质条件是半咸水—咸水环境,并伴随湖盆沉积中心北迁过程各层位地层的盐度发生规律性时空]化;生油岩的Fe2 /Fe3 、S2-、Pr/Ph比值、藿烷碳数分布模式及黄铁矿含量反映其沉积时的沉积环境为强还原性;粘土矿物组合特征及含量揭示这些生油岩的沉积相带介于中心咸湖相和边缘咸湖相之间。  相似文献   

Particulate peptidoglycan in seawater determined by the silkworm larvae plasma (SLP) assay     

Akira Shibata  Kouichi Ohwada  Masakazu Tsuchiya  Kazuhiro Kogure 《Journal of Oceanography》2006,62(1):91-97

Peptidoglycan (PG) is a biopolymer found exclusively in the cell wall of bacteria. Recent chemical analysis of particulate organic matter suggests that a major amount of the muramic acid, an amino sugar present only in PG, could not be accounted for in terms of bacterial cells (Benner and Kaiser, 2003); however, data on particulate PG is quite sparse. In the present study, conducted in 1996, the PG was examined at 5 sampling sites in the northwestern Pacific Ocean, and in natural seawater cultures. Particulate PG, which was concentrated using a 96-well filtration plate equipped with Durapore filters (pore size, 0.22 μm), was measured by the silkworm larvae plasma (SLP) assay. The PG concentration generally decreased with depth and correlated significantly with bacterial abundance throughout the entire water column. However, the ratio of particulate PG to bacterial abundance varied with depth. The average ratio was 0.61 ± 0.53 (average ± SD, n = 40) between 50 and 2000 m, which agreed with the bacterial cellular PG content from 0.63 to 1.1 fg cell⁻¹ obtained in seawater cultures. On the other hand, the ratios of PG to bacteria from the surface to 50 m (3.7 ± 2.6, n = 29) and below 2,000 m (2.1 ± 1.7, n = 7) were significantly higher than that between 50 and 2,000 m. These results may suggest that, in the surface and deep layers, a significant fraction of particulate PG was present in bacterial detritus, whereas this fraction was reduced in the middle layer.  相似文献   

The application of isotopic and biogeochemical markers to the study of the biochemistry of organic matter in a macrotidal estuary, the Loire, France   总被引：1，自引：0，他引：1  

A. Saliot  J. Tronczynski  P. Scribe  R. Letolle 《Estuarine, Coastal and Shelf Science》1988,27(6)

The biogeochemistry of organic matter in a macrotidal estuary, the Loire, France, has been studied for two years during different seasons. Both particulate matter and sediment have been sampled in the riverine zone, in the maximum turbidity zone and in the ocean near the river mouth. Two techniques have been used: carbon isotopic ratio determination and analysis of lipid-marker signatures in the n-alkane, n-alkene and fatty acid series. For the period corresponding to the output of the maximum turbidity zone in the ocean, the complete change of organic matter, continental in nature in the inner estuary, pure marine in the outer estuary is well illustrated by the decrease of δ¹³C values and of carbon preference index of n-alkanes. Input sources of organic matter by continental plants, plankton and micro-organisms are discussed from biogeochemical-marker analyses data along with the processes of accumulation of particles and their evolution with the season. Some criteria for evidencing the nature of various organic-matter pools are assessed and compared in different chemical-marker series as follows: high molecular weight n-alkanes and fatty acids, perylene for continental imprints, polyunsaturated 18-, 20- and 22-carbon fatty acids, n-C₁₇, n-alkenes and squalene for algae imprints, branched iso and anteiso fatty acids, Δ11-C_18:1 for microbial imprints.  相似文献   

Fe(OH)_3胶体与铜离子作用的研究     

张恩仁  田玉红  张正斌  刘莲生 《热带海洋学报》2001,(4)

使用切向流超滤系统得到粒度较均匀的Fe(OH)3胶体,进而对Fe(OH)3胶体粒子与Cu2 的作用进行了研究,并将实验结果与南沙群岛海区表层水中铜与胶体物质结合状况的调查数据进行了比较分析,得到如下结果:(1)在海水介质中,铜在Fe(OH)3胶体上结合的百分率(pH>5)随pH的升高而下降,随着Fe(OH)3胶体浓度的减小而下降?(2)在天然海水介质中,使铜在Fe(OH)3胶体上结合的百分率在50%-70%的有机物浓度为1.0mg·L-1,有机物浓度的增大使铜与无机胶体结合的百分率有下降的趋势?  相似文献   

Sources and hydrothermal alteration of organic matter in Quaternary sediments: A synthesis of studies from the Central Gulf of California     

Bernd R. T. Simoneit 《Marine and Petroleum Geology》1986,3(4)

Deep sea drilling in the Central Gulf of California, a young and active spreading centre, shows that the high heat flow typical of these regions causes extensive alteration of sediment organic matter, especially near sills and above magma chambers where hydrothermal activity is concentrated. Even on the nearby passive margin, where there are no sills, heat flow is moderately high and hydrocarbon generation has begun in immature sequences. Migrating light hydrocarbons are detected especially where hydrothermal activity is concentrated. Thermogenic methane is more widespread, though not in the passive margin bordering the spreading centre. Despite the incidence of hydrocarbon generation and migration, the amounts of hydrocarbons involved are relatively small and apparently do not lead to commercially significant accumulations of petroleum.The organic matter in these sediments is mostly marine because the Gulf of California generally has low runoff from land and highly productive surface waters. Turbidites rich in terrigenous organic material are locally abundant in the mainly pelagic section in the Guaymas Basin. The highest concentrations of organic matter are found in laminated diatomites deposited on the Guaymas passive margin within the oxygen minimum zone.  相似文献   

夏、冬两季长江口及邻近海域悬浮物的分布特征及其沉积量   总被引：11，自引：0，他引：11  

庞重光  王凡  白学志  张明翰 《海洋科学》2003,27(12):31-35

利用2001年7～8月 ,2002年1月两个航次的悬浮物浓度资料 ,并参考其它水文参数 ,简要分析长江口及邻近海域悬浮物的分布特征 :无论夏季还是冬季 ,长江入海悬浮物总是向东南方输运 ;冬季由于再悬浮作用显著 ,悬浮物浓度明显高于夏季 ,且南北分布范围也明显增大 ,垂向分布均匀。同时采用数值模拟的海流流速值和观测的悬浮物浓度值计算悬浮物的断面通量 ,并最终得计算区悬浮物夏、冬两季的沉积量 ,夏、冬季长江口及邻近海域悬浮物的沉积量分别为0.79×108t,1.44×108t。  相似文献   

Quantum yield for the photochemical production of dissolved inorganic carbon in seawater   总被引：2，自引：0，他引：2  

Sophia C. Johannessen  William L. Miller 《Marine Chemistry》2001,76(4):108

The direct photooxidation of coloured dissolved organic matter (CDOM) to dissolved inorganic carbon (DIC) may provide a significant sink for organic carbon in the ocean. To calculate the rate of this reaction on a global scale, it is essential to know its quantum yield, or photochemical efficiency. We have determined quantum yield spectra, φ(λ), (moles DIC/mole photons absorbed) for 14 samples of seawater from environments ranging from a turbid, eutrophic bay to the Gulf Stream. The spectra vary among locations, but can be represented quite well by three pooled spectra for zones defined by location and salinity: inshore φ(λ)=e^{−(6.66+0.0285(λ−290))}; coastal φ(λ)=e^{−(6.36+0.0140(λ−290))}; and open ocean φ(λ)=e^{−(5.53+0.00914(λ−290))}. Production efficiency increases offshore, which suggests that the most highly absorbing and quickly faded terrestrial chromophores are not those directly responsible for DIC photoproduction.  相似文献   

胶州湾悬浮颗粒现场剖面测量与结果分析   总被引：6，自引：0，他引：6  

魏建伟  石学法  方习生  张伟滨  王宗灵 《海洋科学进展》2006,24(1):74-82

应用LISST-100现场激光粒度仪于2003年3月在胶州湾首次进行了悬浮颗粒剖面测量,获得了2个剖面的悬浮颗粒现场粒度分布光衰减资料。2个剖面的悬浮颗粒分布自上而下非常相似,颗粒平均大小多为38~74μm,其中1~20μm细颗粒组分所占的比重高。水柱表层悬浮颗粒略粗于底部悬浮颗粒,而且内湾悬浮颗粒比外湾粗。水柱近底层悬浮颗粒粒径同底质浮泥颗粒粒径大小相近,颗粒组成也非常相似。悬浮颗粒浓度自上而下逐渐增大,接近底部颗粒浓度急剧增高。根据现场测量数据可以马上对悬浮颗粒有效密度、颗粒沉降速率和通量做粗略估算。分析结果表明,光衰减系数同颗粒浓度显著相关,推断光衰减主要是由1~250μm悬浮颗粒的散射作用引起的,而<20μm的悬浮粒子对光衰减作用起着主要控制作用。光衰减系数与颗粒投影面积显著相关,表明颗粒投影面积可以作为遥感离水反射率的替代指标。  相似文献   

Distributions of dissolved and particulate biogenic thiols in the subartic Pacific Ocean     

Christopher L. Dupont  James. W. Moffett  Robert R. Bidigare  Beth A. Ahner 《Deep Sea Research Part I: Oceanographic Research Papers》2006,53(12):1961-1974

Dissolved and particulate concentrations of the biogenic thiols cysteine (Cys), arginine–cysteine (Arg–Cys), glutamine–cysteine (Gln–Cys), γ-glutamate–cysteine (γ-Glu–Cys) and glutathione (GSH) were measured in the subartic Pacific Ocean in the summer of 2003 using high performance liquid chromatography (HPLC) with precolumn derivatization as reported in previous work. In this study, a preconcentration protocol for the derivatized thiols was utilized to extend detection limits of dissolved thiols to picomolar levels. The measured concentrations of particulate and dissolved thiols were uncoupled, with distinctive depth profiles and large differences in the particulate to dissolved ratios between individual compounds. Glutathione was the most abundant particulate thiol whereas the most abundant dissolved thiol was γ-Glu–Cys, with concentrations as high as 15 nM. Given the relatively small pool of intracellular γ-Glu–Cys and the very low dissolved concentrations of GSH, we hypothesize that glutathione released from cells is rapidly converted to the potentially degradation resistant γ-Glu–Cys outside the cell. The relatively high concentrations of other dissolved thiols compared to particulate concentrations implies both biological exudation and slow degradation rates. Some thiols appear to vary with changes in nutrient availability but this effect is difficult to decouple from changes in community structure inferred from pigment analyses. Dissolved thiol concentrations also exceed typical metal concentrations in the subartic Pacific, supporting previous arguments that they may be important in metal speciation.  相似文献   

Complexation of mercury by dissolved organic matter in surface waters of Galveston Bay, Texas   总被引：3，自引：0，他引：3  

Seunghee Han  Gary A. Gill  Ronald D. Lehman  Key-Young Choe 《Marine Chemistry》2006,98(2-4):156-166

The chemical speciation of dissolved mercury in surface waters of Galveston Bay was determined using the concentrations of mercury-complexing ligands and conditional stability constants of mercury-ligand complexes. Two classes of natural ligands associated with dissolved organic matter were determined by a competitive ligand exchange-solvent solvent extraction (CLE-SSE) method: a strong class (L_s), ranging from 19 to 93 pM with an average conditional stability constant (K_HgLs) of 10²⁸, and a weak class (L_w) ranging from 1.4 to 9.8 nM with an average K_HgLs of 10²³. The range of conditional stability constants between mercury and natural ligands suggested that sulfides and thiolates are important binding sites for dissolved mercury in estuarine waters. A positive correlation between the estuarine distribution of dissolved glutathione and that of mercury-complexing ligands supported this suggestion. Thermodynamic equilibrium modeling using stability constants for HgL, HgCl_x, Hg(OH)_x, and HgCl(OH) and concentrations of each ligand demonstrated that almost all of the dissolved mercury (> 99%) in Galveston Bay was complexed by natural ligands associated with dissolved organic matter. The importance of low concentrations of high-affinity ligands that may originate in the biological system (i.e., glutathione and phytochelatin) suggests that the greater portion of bulk dissolved organic matter may not be important for mercury complexation in estuarine surface waters.  相似文献