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81.
82.
The hydrolysis of silicic acid, Si(OH)4, was studied in a simplified seawater medium (0.6 M Na(Cl)) at 25°C. The measurements were performed as potentiometric titrations (hydrogen electrode) in which OH was generated coulometrically. The total concentration of Si(OH)4, B, and log[H+] were varied within the limits 0.00075 B 0.008 M and 2.5 -log[H+] 11.7, respectively. Within these ranges the formation of SiO(OH)3 and SiO2(OH)22− with formation constants log β−11(Si(OH)4 SiO(OH)3 + H+) = −9.472 ±0.002 and log β−21(Si(OH)4 SiO2(OH)22− + 2H+) = −22.07 ± 0.01 was established. With B > 0.003 M polysilicate complexes are formed, however, with -log[H+] 10.7 their formation does not significantly affect the evaluated formation constants. Data were analyzed with the least squares computer program LETAGROPVRID.  相似文献   
83.
The combination of high strain modulus from conventional light weight deflectometer (LWD) analysis and low strain modulus from LWD-induced seismic analysis would move the pavement community towards field characterization of non-linear soil stiffness for use in mechanistic-empirical pavement design. This paper explores the experimental and numerical analysis of surface seismic waves during conventional light weight deflectometer testing. Field experiments were conducted on clay, silt and gravel soils to characterize the nature of LWD-induced surface waves and to determine both low and high strain moduli. The usable high frequency limit was found to be 300 Hz for LWD-induced surface waves, enabling the low strain modulus characterization of the top 0.3–0.5-m-thick soil layer. A numerical investigation revealed that modal interference is a significant contributor to near field effects, and that a distance of one wavelength between the LWD center and receiver array center is required to minimize these effects. The LWD-induced surface wave strain levels at a 1 m offset from the LWD were found to be on the order of 10−2 to 10−3% compared to the 10−3 to 10−4% strain levels associated with conventional small hammer-induced surface waves. The measured low and high strain modulus compares well with published modulus reduction functions.  相似文献   
84.
A number of Norwegian glaciers were selected in the 1960s for long-term mass-balance measurements, to produce necessary hydrological information for hydropower exploitation. Special large-scale glacier maps were produced for field work and data processing, and some glaciers have been mapped more than once. Thus, comparison of glacier maps can be used to calculate changes in glacier volume for some of the glaciers, provided they are of sufficient accuracy.
Conventional mass-balance measurements were carried out on all the selected glaciers. A cumulative calculation of net balances for a series of years is used to indicate the change in a glacier's volume during that period. However, various errors originate in the field, some of which are systematic, particularly on glaciers with large winter accumulation.
The present study indicates that certain errors are difficult to define and determine, For the maritime glacier Ålfotbreen, a cumulative mass-balance calculation gives a positive total balance (+3.4 m water equivalent in the period 1968–88), whereas the map comparison indicates a total negative balance (−5.8 m water equivalent). This indicates a discrepancy between the methods, which must be accounted for.
Determination of errors in mass-balance measurements is difficult. Sinking of stakes in the accumulation area and the use of sounding sticks (steel probes) in heavy snowlayers cause problems.  相似文献   
85.
The C -response connects the magnetic vertical component and the horizontal gradient of the horizontal components of electromagnetic variations and forms the basis for deriving the conductivitydepth profile of the Earth. Time-series of daily mean values at 42 observatories typically with 50 years of data are used to estimate C -responses for periods between 1 month and 1  yr. The Z : Y method is applied, which means that the vertical component is taken locally whereas the horizontal components are used globally by expansion in a series of spherical harmonics.
In combination with results from previous analyses, the method yields consistent results for European observatories in the entire period range from a few hours to 1  yr, corresponding to penetration depths between 300 and 1800  km.
1-D conductivity models derived from these results show an increase in conductivity with depth z to about 2  S  m-1 at z =800  km, and almost constant conductivity between z =800 and z =2000  km with values of 310  S  m-1, in good agreement with laboratory measurements of mantle material. Below 2000  km the conductivity is poorly resolved. However, the best-fitting models indicate a further increase in conductivity to values between 50 and 150  S  m-1.  相似文献   
86.
The Amazon Macrotidal Mangrove Coast (AMMC) is a large (~7500 km2) contiguous mangrove fringe eastwards from the Amazon River mouth. It encompasses dozens of interconnected bays intercalated with mangrove peninsulas. Mud accumulates on the mangrove flats, whereas the bed of the bays and channels is generally sandy. In this study we investigated the circulation, sediment transport and deposition in a central site at one of these mangrove peninsulas. The study was undertaken during the dry period, when there is no influence of the Amazon River plume and minimum local freshwater inflow. Current and suspended-sediment concentration were monitored in a feeder channel on the mangrove flat along a ~1000 m section oriented along the peninsula axis. Sediment deposition was also measured on the flat. Our results show there was a strong exchange between the neighboring bays. Channel currents were flood dominant, reaching up to >1 m s−1, with residual water and sediment transport westwards. Suspended sediment concentration (SSC) in the channel was directly related to velocity magnitude, ranging between 50 and 350 mg L−1. The flat was flooded in a way that indicated the tidal wave evolves westwards, nearly parallel to the AMMC shoreline. Currents on the flats were much slower than those in the channel and showed slight ebb dominance. However, SSC was higher during the flood than ebb, clearly indicating settling during the current deceleration and limited erosion during the following ebb–flow acceleration. The net sediment transport across the section was 60 tons westwards for the period of the experiment (~4 days). The mean deposition rate was 0.006 kg m−2 s−1 (or 1.4 kg m−2 per tide), which was higher than rates from other reported assessments in mangroves. The set of results indicate very large internal sediment reworking in the AMMC. © 2019 John Wiley & Sons, Ltd.  相似文献   
87.
In recent decades, eutrophication has increased the extent of hypoxic and anoxic conditions in many coastal marine environments. In such conditions, the nutrient flux across the sediment?Cwater interface is a key process controlling the biogeochemical dynamics, and thereby the level and character of biological production. In some areas, management attempts to drive the ecosystem towards phosphorus (P) limitation, which calls for reliable knowledge on the mechanisms controlling P-cycling. We report a well-controlled laboratory experiment on benthic fluxes of P, when shifting from a state of hypoxic and azoic sediments to oxic and zoic bottom conditions. Adding any of three types of macrobenthic fauna (mysid shrimp, pontoporeid amphipod and tellinid clam) to oxygenated aquarium sections resulted in benthic P fluxes that differed consistently from the azoic control sections. All species caused liberation of dissolved organically bound P (DOP) from the sediment, in contrast to the azoic systems. The shrimp and the amphipod also resuspended the sediment, which resulted in a release of P bound to particles (>0.45???m). Dissolved inorganic phosphate (DIP) was released during hypoxic conditions, but was taken up after oxygenation, irrespective of the presence or absence of bottom fauna. In the presence of fauna, the uptake of DIP roughly equalled the release of DOP, suggesting that the benthic efflux of DOP following oxygenation and bottom fauna (re)colonisation might be considerable. This is an hitherto overlooked animal-controlled nutrient flux, which is missing from coastal marine P budgets.  相似文献   
88.
During the late Saalian Drenthe glaciation ice-damming of the Upper Weser Valley led to the formation of glacial Lake Weser. The lake drained catastrophically into the Münsterland Embayment as the western ice dam failed, releasing up to 110 km3 of water with a calculated peak discharge of 2.5 × 105 m3/s to 1.3 × 106 m3/s. Geographic information systems (GIS) and high-resolution digital elevation models (DEM) were used to map streamlined landforms and channel systems in front of lake overspills. Geological maps, 2450 boreholes and the DEM were integrated into the 3D modeling program GOCAD to reconstruct the distribution of flood-related deposits, palaeotopographic surfaces and the internal facies architecture of streamlined hills. The drainage pathways are characterized by the occurrence of deep plunge pools, channels, streamlined hills and 4 km long and 12 m deep V-shaped megaflutes. Plunge pools are deeply incised into Mesozoic basement rocks and occur in front of three major overspill channels. The plunge pools are up to 780 m long, 400 m wide and 35 m deep. Approximately 1–10.5 km downslope of the overspill channels fan shaped arrays of streamlined hills are developed, each covering an area of 60–130 km2, indicating rapid flow expansion. The hills commonly have quadrilateral to elongated shapes and formed under submerged to partly submerged flow conditions, when the outburst flood entered a shallow lake in the Münsterland Embayment. Hills are up to 4300 m long, 1200 m wide, 11 m high and have characteristic average aspect ratios of 1:3.3. They are separated by shallow, anabranching channels in the outer zones and up to 30 m deep channels in the central zones. Hills partly display V-shaped chevron-like bedforms that have apices facing upslope, are 1.6–2.5 km long, 3–10 m high, 0.8–1.2 m from limb to limb, with limb separation angels of 20–35°. These bedforms are interpreted as mixed erosional depositional features. It is hypothesized that the post-Saalian landscape evolution of the Münsterland Embayment has considerably been influenced by catastrophic floods of glacial Lake Weser, creating large and deep valleys, which subsequently became the new site of river systems. The outburst floods probably followed the east-west-trending Saalian Rhine-Meuse river system eventually flowing into the North Sea, the Strait of Dover and the Bay of Biscay. It is speculated that the Hondsrug ice stream may have been enhanced or even triggered by the formation and outburst of glacial lakes in the study area.  相似文献   
89.
Groundwater is the principal water resource in semi‐arid and arid environments. Therefore, quantitative estimates of its replenishment rate are important for managing groundwater systems. In dry regions, karst outcrops often show enhanced recharge rates compared with other surface and sub‐surface conditions. Areas with exposed karst features like sinkholes or open shafts allow point recharge, even from single rainfall events. Using the example of the As Sulb plateau in Saudi Arabia, this study introduces a cost‐effective and robust method for recharge monitoring and modelling in karst outcrops. The measurement of discharge of a representative small catchment (4.0 · 104 m2) into a sinkhole, and hence the direct recharge into the aquifer, was carried out with a time‐lapse camera. During the monitoring period of two rainy seasons (autumn 2012 to spring 2014), four recharge events were recorded. Afterwards, recharge data as well as proxy data about the drying of the sediment cover are used to set up a conceptual water balance model. The model was run for 17 years (1971 to 1986 and 2012 to 2014). Simulation results show highly variable seasonal recharge–precipitation ratios between 0 and 0.27. In addition to the amount of seasonal precipitation, this ratio is influenced by the interannual distribution of rainfall events. Overall, an average annual groundwater recharge for the doline (sinkhole) catchment on As Sulb plateau of 5.1 mm has estimated for the simulation period. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   
90.
The best method to evaluate the seismic site response is by means of borehole vertical arrays that use earthquake records from different depths. In this paper we introduce the implementation of a single borehole sensor system (synchronized to a sensor on the surface) that is fixed at variable depths within a single well. This system is used for recording small amplitude earthquake signals at variable stiffness conditions in depth to compute empirical borehole transfer functions. The computed average empirical borehole transfer functions allow the estimation of an S-wave velocity model that is constrained using the frequency peak observed in the H/V ratio curve.Pairs of surface and borehole earthquake records were obtained with the borehole sensor placed at − 10, −20, −50, and − 100 m depth in a test site in Managua, Nicaragua. The average velocity of the final model down to − 100 m appeared to be in good agreement with the average velocity computed via cross-correlation using the surface and borehole signals. Likewise, an inverted MASW profile and H/V ratio at the same site agree with the S-wave velocity model obtained.  相似文献   
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