Hydro-geochemistry of groundwater and surface water in Dschang town(West Cameroon): Alkali and alkaline-earth elements ascertain lithological and anthropogenic constraints          下载免费PDF全文

Yemeli Elida Joelle  Temgoua Emile  Kengni Lucas  Ambrosi Jean-Paul  Momo-nouazi Mathieu  Silatsa-Tedou Francis Brice  Wamba Franck Robean  Tchakam-Kamtchueng Brice 《地下水科学与工程》2021,9(3):212-224

This study focuses on the sources of alkali and alkaline-earth elements based on the geochemistry of groundwater and surface water in Dschang concerning environmental and anthropogenic constraints. A comprehensive set of 50 samples from groundwater and surface water were analyzed by ICPMS and processed by spatial interpolation in a GIS environment. The results highlight a geochemical anomaly at the center of the densely inhabited area subject to a profusion of open dumps discharges. This anomaly with the highest spatial contents of Be(Cs, Rb, Mg) suggests an anthropogenic source that demarcates with the lowest alkali and alkaline-earth elements on the peripheral area of Dschang. Other findings include lithological constraints with volcanic rocks being the main source compared to granitoid.The study points out good correlations between Be, Cs, Rb and Mg spatial distributions and physicochemical parameters of waters(K, EC, TDS), and inversely with the lowest p H. p H is established as the most functioning physico-chemical constraint of alkali and alkaline-earth mobility in Dschang. The p H lowest values within the geochemical anomaly also highlight the impact of human activities on water acidity, which later enhance elements mobility and enrichment. Despite low elements contents relative to WHO standards, our findings point out an example of anthropogenic impact on water geochemistry linked to solid waste pollution; it also demonstrates significant anthropogenic changes of environmental physicochemical parameters of prime importance in the mobility and distribution of elements in the study area.Similar assessments should be extended in major towns in Cameroon.  相似文献   

柴达木盆地那棱格勒河及其尾闾盐湖锂成矿物源：来自水化学和锶、硫同位素证据   总被引：2，自引：0，他引：2  

李庆宽  王建萍  吴蝉  樊启顺  秦占杰  陈亮  魏海成  都永生  袁秦  李建森  山发寿 《地质学报》2021,95(7):2169-2182

柴达木盆地那棱格勒河尾闾盐湖（一里坪干盐滩、东台吉乃尔盐湖、西台吉乃尔盐湖和察尔汗盐湖别勒滩区段）赋存了我国目前最大的卤水锂矿床。那棱格勒河及其尾闾盐湖锂的物源仍存在一定争议,主要有围岩风化、古湖残留、含盐系地层淋滤、油田水、深部水等,目前缺乏有力的地球化学证据。本文系统采集了那棱格勒河流域及其尾闾盐湖不同水体样品16件,分析了其主、微量元素含量及锶、硫同位素组成。结合前人的研究成果,对区域水体中锂的来源进行了探讨,得出结论如下：那棱格勒河水锂含量（0. 45~0. 79 mg/L）比楚拉克阿拉干河支流（0. 00~0. 05 mg/L）高出一个数量级,其高锂含量主要受洪水河支流的补给;洪水河高锂含量与其上游热泉水的补给有关,该热泉水锂、锶含量高、 87 Sr/ 86 Sr比值偏高, δ 34 S值偏低,与青藏高原典型热泉水地球化学特征（锂含量0. 4~34. 8 mg/L,锶含量0. 07~4. 24 mg/L, 87 Sr/ 86 Sr比值0. 71224~0. 71259, δ 34 S值- 10. 6‰~7. 6‰）较一致。那棱格勒河水（0. 71170）和尾闾盐湖卤水（0. 71143~0. 71156）相似的 87 Sr/ 86 Sr比值,以及研究区河、湖水硫同位素组成符合主要蒸发浓缩过程 δ 34 S值逐渐下降的变化趋势,均证明研究区尾闾盐湖卤水锂资源主要受那棱格勒河的补给;而古湖残留水、盆地西部含盐系地层淋滤水或油田水具有明显不同的水化学特征和锶、硫同位素组成,这些水体对研究区尾闾盐湖锂补给的贡献较小,可忽略不计。  相似文献   

陕西八卦庙金矿床NE向黄铁矿-石英成矿期成矿物质来源和成矿机制探讨:原位硫同位素证据     

蔡光耀  安芳  袁轶  刘芳  刘炜  张京渤 《地质学报》2021,95(5):1561-1572

八卦庙金矿床位于秦岭造山带凤太铅锌多金属矿田北部,是陕西省规模较大的金矿床之一,已探明金储量约106 t.赋矿围岩是上泥盆统星红铺组浅变质泥质碎屑岩和碳酸盐岩,其成矿过程可划分为3期,分别是①顺层磁黄铁矿-石英成矿期;②NE向黄铁矿-石英成矿期;③裂隙硫化物-方解石成矿期.目前关于NE向黄铁矿-石英成矿期成矿物质来源和成矿机制仍存在争议.本文通过矿相学观察,将NE向黄铁矿-石英成矿期划分为自形磁黄铁矿-黄铁矿-粗粒石英阶段(Ⅰ)、他形黄铁矿-银金矿-细粒石英阶段(Ⅱ)、他形磁黄铁矿-自然金-方解石阶段(Ⅲ)和黑云母阶段(IV),并在此基础上采用激光剥蚀-多接收等离子体质谱(LA-MC-ICP-MS)分析方法对千枚岩围岩中以及不同阶段形成的硫化物进行了原位S同位素测试,结果显示围岩中原生磁黄铁矿的δ34 S值集中于11.6‰～13.0‰之间,介于前人报道的原生黄铁矿δ34 S值变化范围(3.3‰～16.0‰);阶段I形成的黄铁矿的δ34 S值为8.4‰～10.1‰,磁黄铁矿为7.6‰～8.0‰;阶段II黄铁矿的δ34 S值相对较高,为14.0‰～15.9‰;阶段Ⅲ磁黄铁矿的δ34 S值介于6.4‰～8.3‰之间.八卦庙金矿NE向黄铁矿-石英成矿期总体相对富集重硫同位素、离散程度较大,各阶段硫化物的硫同位素值介于矿集区花岗岩和围岩硫之间,显示其具有岩浆硫与地层硫混合的特征.结合阶段I到阶段Ⅲ矿物组合的变化(黄铁矿+磁黄铁矿→黄铁矿→磁黄铁矿),推断阶段IIδ34 S值增高是水岩反应引起的硫化作用所致,而阶段Ⅲ硫同位素值降低可能与岩浆水的加入密切相关.结合成矿物理化学条件,推断该成矿期成矿热液中金主要以Au(HS)2-的形式迁移,阶段I到阶段Ⅱ由水岩反应引起的硫化作用是导致他形黄铁矿-银金矿-细粒石英阶段(Ⅱ)金矿化的主要原因,而岩浆水的混入可能是导致他形磁黄铁矿-自然金-方解石阶段(Ⅲ)金沉淀的主要机理.  相似文献   

扬子西缘东川落雪地区元古宙地层中3890 Ma锆石的发现   总被引：1，自引：0，他引：1  

刘军平  熊波  李静  王小虎  胡绍斌  俞赛赢  张虎  杨爱平  吴清华 《地质学报》2021,95(5):1606-1613

利用LA-ICP-MS U-Pb同位素测定技术,在扬子西缘滇中东川地区古元古界阿不都组流纹质玻屑熔结凝灰岩中发现了1颗冥古宙锆石,锆石具有明显的核-幔-边结构,其核部的207 Pb/206 Pb年龄为3890±47 Ma,此年龄被解释为岩浆结晶,Th/U比值为0.34;变质边的207 Pb/206 Pb年龄为3561±45～3616±55 Ma,Th/U比值为0.07～0.19.锆石的原位Hf同位素测定给出了176 Hf/177 Hf=0.280317～0.280451,εHf(t)=-4.6～0.6(平均值为-2.5),TDM1=3861～3980 Ma,TDM2=4036～4106 Ma(平均值为4059 Ma).这颗锆石为扬子陆块目前发现的最老锆石,其Hf同位素及微量元素特征说明扬子陆块存在4.0 Ga的地壳增生作用及古老陆壳的再循环;结合前人同位素研究资料,说明扬子西缘东川落雪地区元古宙时同华北陆块可能具有亲缘性;本次的发现,为扬子陆块寻找冥古宙和始太古代物质实体提供重要依据,也为认识地球早期大陆演化过程提供了重要新信息.  相似文献   

Early Eocene leucocratic sill/dike swarms in the Gangdese belt,southern Tibet: Tectonic implications for Indo-Asian collision     

《China Geology》2021,4(1):56-66

The timing of the initial Indo-Asian collision is a subject of debate for a long time. Besides, the magmatic trace of the collisional process is also unclear. In the present study, the authors report Early Eocene leucocratic sill/dike swarms in the northern edge of the Nymo intrusive complex of the Gangdese belt, southern Tibet. The Nymo intrusive complex was emplaced at ca. 50 –47 Ma and surrounded by the metamorphosed Jurassic-aged Bima Formation volcano-sedimentary sequence along its northern side. At outcrops, the leucocratic sills/dikes intruded along or truncated the deformed foliations of the host Bima Formation, which has been subject to high-temperature amphibolite-facies metamorphism at ca. 50 –47 Ma. Detailed cathodoluminescence image analyses reveal that the zircon grains of the leucocratic sills/dikes have core-mantle textures. The cores yield the Jurassic ages comparable to the protolith ages of the Bima Formation. In contrast, the mantles of zircon grains yield weighted mean ages of ca. 49–47 Ma, representing the crystallization timing of these leucocratic sills/dikes. The coeval ages for the Nymo intrusive complex, the high-temperature metamorphism, and the leucocratic sills/dikes indicate that a close relationship exists among them. The authors tentatively suggest that these leucocratic sills/dikes were generated from partial melting of the Jurassic-aged Bima Formation volcanic rocks, triggered by the high heat from the magma chamber of the Nymo intrusive complex. This Early Eocene tectono-thermal event of coeval magmatism, metamorphism and partial melting was most likely formed during the Indo-Asian collisional setting.©2021 China Geology Editorial Office.  相似文献   

94/220 GHz星载雷达双波长比对非球形冰晶云参数敏感性分析          下载免费PDF全文

吴举秀  窦芳丽  安大伟  顾瑜  周青  刘伟 《气象学报》2019,77(3):529-540

利用不同形状冰晶的散射特性,获得了非球形冰晶云的94/220 GHz测云雷达双波长比,探讨了非球形冰晶云的双波长比与云内微物理参数的关系,分析了衰减前后的星载雷达反射率因子及双波长比的垂直廓线。结果表明:（1）双波长比可以反映小到0.1 mm中值尺度的冰粒子,对粒子总数、谱的形状参数不敏感,对粒子大小、形状、云衰减较敏感。（2）雷达灵敏度一定时,星载雷达可测云厚与雷达波长、冰含水量（IWC）的垂直分布、云厚及衰减有关;没有进行衰减订正时,双波长比和衰减有关,冰含水量越大,波长越短,衰减越大,双波长比最大值与可探测云厚有关。两部雷达可探测冰含水量为0.001—0.1 g/m3、厚2 km的冰云;当云厚5 km、冰含水量垂直分布在0.001—0.2 g/m3时,云厚的94%基本可以被220 GHz云雷达探测到。（3）如果两部雷达气象方程中用水的介电因子,测量回波强度应进行介电因子的订正后再计算双波长比。   相似文献   

华南地区春季平流层入侵对对流层低层臭氧影响的模拟研究     

赵恺辉  包云轩  黄建平  张潇艳  刘诚  戚慧雯  许玮 《大气科学》2019,43(1):75-86

利用中尺度大气化学模式WRF/Chem对2013年3月6日华南地区一次平流层入侵事件及其对对流层低层臭氧的影响进行模拟研究。通过加入UBC（Upper Boundary Condition）上边界处理方案,弥补WRF/Chem模式未考虑平流层臭氧化学反应的不足。结合臭氧探空廓线资料、地面O₃、CO、NO_x、相对湿度、温度和风速等观测资料以及再分析资料对模拟结果进行定量评估,结果表明模式能较为真实地模拟本次平流层入侵过程。模拟分析进一步揭示:（1）副热带高空急流是本次平流层入侵的主要原因。当华南地区处在副热带急流入口区左侧下沉区域时,平流层入侵将富含臭氧的干燥空气输送到对流层中低层。（2）本次平流层入侵对对流层低层臭氧收支有重要影响,导致香港地区近地层臭氧体积混合比浓度明显上升,如塔门站夜间臭氧浓度升高21.3 ppb（1 ppb=1×10-9）。地面气象场和化学物种的分析进一步确认了平流层入侵的贡献。（3）采用动力学对流层顶高度时零维箱式模型和Wei公式计算得到的平流层入侵通量相当,分别为-1.42×10-3 kg m-2 s-1和-1.59×10-3 kg m-2 s-1,这一结果与前人研究相吻合,且与采用热力学对流层顶高度计算所得到的结果具有可比性。  相似文献   

Sub-seasonal to Seasonal Hindcasts of Stratospheric Sudden Warming by BCC_CSM1.1(m):A Comparison with ECMWF     

Jian RAO  Rongcai REN  Haishan CHEN  Xiangwen LIU  Yueyue YU  Yang YANG 《大气科学进展》2019,36(5):479-494

This study focuses on model predictive skill with respect to stratospheric sudden warming(SSW) events by comparing the hindcast results of BCC_CSM1.1(m) with those of the ECMWF's model under the sub-seasonal to seasonal prediction project of the World Weather Research Program and World Climate Research Program. When the hindcasts are initiated less than two weeks before SSW onset, BCC_CSM and ECMWF show comparable predictive skill in terms of the temporal evolution of the stratospheric circumpolar westerlies and polar temperature up to 30 days after SSW onset. However, with earlier hindcast initialization, the predictive skill of BCC_CSM gradually decreases, and the reproduced maximum circulation anomalies in the hindcasts initiated four weeks before SSW onset replicate only 10% of the circulation anomaly intensities in observations. The earliest successful prediction of the breakdown of the stratospheric polar vortex accompanying SSW onset for BCC_CSM(ECMWF) is the hindcast initiated two(three) weeks earlier. The predictive skills of both models during SSW winters are always higher than that during non-SSW winters, in relation to the successfully captured tropospheric precursors and the associated upward propagation of planetary waves by the model initializations. To narrow the gap in SSW predictive skill between BCC_CSM and ECMWF, ensemble forecasts and error corrections are performed with BCC_CSM. The SSW predictive skill in the ensemble hindcasts and the error corrections are improved compared with the previous control forecasts.  相似文献   

CINRAD-SA双偏振雷达资料在降水估测中的应用初探   总被引：2，自引：0，他引：2       下载免费PDF全文

陈超  胡志群  胡胜  张扬  李珊珊 《气象》2019,45(1):113-125

对基于水平反射率ZH和差分传播相移率K_(DP)的降水估测综合法R(C)进行了改进,并对广州S波段双偏振雷达2016年2次飑线和2次台风降水过程的Φ_(DP)使用小波分析进行滤波处理,在此基础上使用变距最小二乘法拟合得到K_(DP)的值。分别使用R(C)和R(Z_H)法对2次飑线和2次台风降水过程进行降水估算,将估算结果和雨量计小时雨量进行了对比,并将两种方法的评估结果进行了对比。结果表明:(1)对于飑线类型降水,R(C)法对5 mm·h~(-1)以上的降水估测精度要好于R(Z_H)法,且降水率越大,R(C)法优势越明显,当降水率≥20 mm·h~(-1)时,两次过程R(C)法比R(Z_H)法的平均相对误差(RE)降低了17. 2%,平均绝对误差(AE)减少了1.89 mm,平均均方根误差(RMSE)减少了1.66 mm;(2)对于台风类型降水,R(C)法对5 mm·h~(-1)以上的降水估测精度也好于R(Z_H)法,当降水率≥20 mm·h~(-1)时,两次过程R(C)法比R(Z_H)法的平均RE降低了33. 19%,平均AE减少了3. 95 mm,平均RMSE减少了4.05 mm;(3)对于飑线和台风两种类型降水R(C)法都明显改善了降水率较大时的R(Z_H)法低估问题,但R(C)法在降水率10 mm·h~(-1)时也存在低估,可能是由雨滴谱资料观测误差导致拟合的系数偏小或雷达硬件造成的观测偏差等造成的。  相似文献   

Tectono-magmatic evolution from accretion to collision in the southern margin of the Central Asian Orogenic BeltSCIEI北大核心CSCD     

李舢  王涛  肖文交  侯泉林 《岩石学报》2023,(5):1261-1275

造山带演化及增生到碰撞的转变是板块构造与大陆动力学研究中的前沿科学问题。中亚造山带被认为是古亚洲洋长期俯冲-增生演化形成的显生宙最大的增生造山带,以发育巨量的面状展布的俯冲-增生相关的弧岩浆岩为特征。并且,由于中亚增生型造山带在潘吉亚最后聚合过程中发生弧弧(陆)碰撞,因此缺乏大规模且跨构造单元的碰撞相关的构造和变质等物质标志。显然,能否识别出大洋闭合期间碰撞作用的岩浆标志成为确定增生造山带增生过程终止的关键之一。本文系统研究确定:中亚造山带东南缘二叠纪到三叠纪钙碱性-碱钙性岩浆在空间分布上显示出由北西向南东迁移演化的特征;在岩浆性质上具有从二叠纪新生地壳来源的弧岩浆向早-中三叠世碰撞挤压背景下古老陆壳组分逐渐增多的高Sr/Y岩浆以及晚三叠世后造山伸展相关的A型花岗岩演化的特征。这些特征提供了俯冲-增生向碰撞造山演变的关键岩浆岩证据。结合区域资料,厘定出增生造山带最后碰撞相关的标志性岩浆为沿缝合带呈零星线性展布的增厚下地壳源区的高Sr/Y花岗岩类,构建了中亚造山带南缘从双向俯冲-增生到增生楔-增生楔碰撞及后造山伸展的三阶段构造-岩浆演化模型。系统对比研究,揭示出增生-碰撞相关的岩浆记录沿横向展布在中亚造山带南缘甘肃北山到吉林中部一带,表明碰撞挤压相关的岩浆作用在中亚造山带南缘具有一定的普适性。中亚造山带南缘从增生到碰撞的岩浆演化记录的厘定,证实显生宙最大的巨型增生造山带演化末期经历了碰撞造山作用,对进一步深入探索增生造山演化末期碰撞相关的标志性岩浆具有重要意义。  相似文献