Thermodynamics of mixing in diopside–jadeite,CaMgSi<Subscript>2</Subscript>O<Subscript>6</Subscript>–NaAlSi<Subscript>2</Subscript>O<Subscript>6</Subscript>, solid solution from static lattice energy calculations     

Victor L. Vinograd  Julian D. Gale  Björn Winkler 《Physics and Chemistry of Minerals》2007,34(10):713-725

Static lattice energy calculations (SLEC), based on empirical interatomic potentials, have been performed for a set of 800 different structures in a 2 × 2 × 4 supercell of C2/c diopside with compositions between diopside and jadeite, and with different states of order of the exchangeable Na/Ca and Mg/Al cations. Excess static energies of these structures have been cluster expanded in a basis set of 37 pair-interaction parameters. These parameters have been used to constrain Monte Carlo simulations of temperature-dependent properties in the range of 273–2,023 K and to calculate a temperature–composition phase diagram. The simulations predict the order–disorder transition in omphacite at 1,150 ± 20°C in good agreement with the experimental data of Carpenter (Mineral Petrol 78:433–440, 1981). The stronger ordering of Mg/Al within the M1 site than of Ca/Na in the M2 site is attributed to the shorter M1–M1 nearest-neighbor distance, and, consequently, the stronger ordering force. The comparison of the simulated relationship between the order parameters corresponding to M1 and M2 sites with the X-ray refinement data on natural omphacites (Boffa Ballaran et al. in Am Mineral 83:419–433, 1998) suggests that the cation ordering becomes kinetically ineffective at about 600°C.  相似文献   

Modelling sensible and latent heat fluxes over sea during unstable,very close to neutral conditions     

Anna Rutgersson  Björn Carlsson  Ann-Sofi Smedman 《Boundary-Layer Meteorology》2007,123(3):395-415

During slightly unstable but still very close to neutral conditions new results from two previous investigations have shown a significant increase of sensible and latent heat fluxes over the sea. The vertical heat transport during these conditions is dominated by detached eddies originating at the top of the boundary layer, bringing relatively cold and dry air to the surface. This effect can be described in numerical models by either enhanced heat transfer coefficients for sensible and latent heat (Stanton and Dalton numbers respectively) or with an additional roughness length, added to the original roughness lengths for heat and humidity. Such new expressions are developed using turbulence measurements from the Baltic Sea valid for wind speeds up to 14 m s⁻¹. The effect of including the increased heat fluxes is investigated using two different numerical models: a regional three-dimensional climate model covering northern Europe, and a process-oriented ocean model for the Baltic Sea. During periods of several days, the latent heat flux can be increased by as much as 100 W m⁻². The increase in sensible heat flux is significantly smaller since the process is only of importance in the very near-neutral regime where the sensible heat flux is very small. The long-term average effect over the Baltic Sea is of the order of several W m⁻².  相似文献   

The expansion of the metagalaxy     

Björn Bonnevier 《Astrophysics and Space Science》1981,79(2):509-513

In the big-bang hypothesis the metagalaxy (or Universe) is considered to have expanded from a state of extremely high density. The observations of distant galaxies are usually interpreted with this picture in mind. As pointed out by Alfvén it is important to see, if these observations do really require the hypothesis of an early extremely high density. It is found that with present available information, it is not possible to conclude that the density has been higher than implied by the Schwarzschild limit.  相似文献   

Factors influencing particulate matter geochemistry in the St. Lawrence estuary turbidity maximum     

Charles Gobeil  Bjørn Sundby  Norman Silverberg 《Marine Chemistry》1981,10(2):123-140

635 samples of suspended particulate matter (SPM), collected in the St. Lawrence river and estuary during periods of high and low river flow from a series of individual and anchor stations on a transect traversing the turbidity maximum zone, as well as two sediment box cores, were analyzed for Al, Si, Ca, Mg, Fe and Mn.An abrupt change in elemental composition occurs when traversing the front at the landward edge of the turbidity maximum. As the SPM concentration increases across the front from 20–200 mg l^?1, the Ca/Al and Mg/Al ratios of the SPM increase and the Si/Al, Fe/Al and Mn/Al ratios decrease. The almost 50% decrease of the Mn/Al ratio is not related to changes in salinity. Within the turbidity maximum the tidal-averaged Si/Al, Ca/Al, Mg/Al and Fe/Al ratios of the SPM do not differ significantly from the landward to the seaward end of the turbidity zone, but on one tidal station the ratios of Si, Ca and Fe to Al are significantly lower at high river flow than at low flow. The Mn/Al ratio is insensitive to the extreme variations of either salinity (0.6–30‰) or SPM concentrations (10–480 mg l^?1) within the turbidity zone. A tendency for higher Mn/Al ratios to be associated with near-bottom SPM, observed in the center of the turbidity zone during the low river flow period, is well developed in the lower reaches of the zone.Diagenetic mobilization within the rare fine-grained bottom sediments of the turbidity maximum is responsible for changes in Mn and Fe content of particulate matter, and early settling of coarse-grained components and size sorting within the zone are responsible for other compositional changes. Local sources, desorption and precipitation are apparently of secondary importance. The depletion of both Mn and Fe in the SPM and sediment of the upper estuary implies a net seaward escape of diagenetically mobilized metal.  相似文献   

Is trophic state or regional location the strongest determinant for Chl-a/TP relationships in lakes?     

Knut L. Seip  Erik Jeppesen  Jens Petter Jensen  Bj?rn Faafeng 《Aquatic Sciences - Research Across Boundaries》2000,62(3):195-204

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Spatial and temporal variation in particle size and particulate organic matter content in suspended particulate matter from peatland‐dominated catchments in Finland          下载免费PDF全文

Hannu Marttila  Bjørn Kløve 《水文研究》2015,29(6):1069-1079

Properties of suspended particulate matter play a vital role in transport processes, but information from boreal lowland river systems with high organic loads is limited. This study analysed data from 2 years of sampling at 30 locations in Finland (204 samples in total) using suspended particulate matter samplers to determine effective and absolute particle size and organic fractions. Mean d₅₀ value was 22 and 49 µm for absolute and effective particle size, respectively. The organic fraction content ranged from 2.1% to 36% (mean 9.6%), highlighting the importance of particle organic matter for suspended particulate matter flux in the region. The results indicated that the suspended particulate matter particle size distribution and load in the study region is dominated by composite particles. There were considerable spatial and temporal variations in transport of organic fractions, effective particle size and degree of aggregation (range 1.5–93%). Headwaters and, in particular, late summer and spring flood conditions with flow peaks produced the largest composite particles, whereas agriculture‐dominated sites produced smaller but more tightly compacted particles. Organic plant fibres appeared to play a vital role in floc formation in peat‐covered catchments, whereas in agriculture‐dominated catchments, land use‐derived aggregates dominated the composition. This study provides empirical evidence of the importance of effective particle size measurement in understanding the dynamics of suspended particulate matters in boreal lowland river systems. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Fennoscandia revisited: a spatially improved tree-ring reconstruction of summer temperatures for the last 900 years   总被引：1，自引：0，他引：1  

Hans W. Linderholm  Jesper Björklund  Kristina Seftigen  Björn E. Gunnarson  Mauricio Fuentes 《Climate Dynamics》2015,45(3-4):933-947

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A statistical downscaling algorithm for thermal comfort applications     

David Rayner  Fredrik Lindberg  Sofia Thorsson  Björn Holmer 《Theoretical and Applied Climatology》2015,122(3-4):729-742

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Modelling the potential impact of global warming on Ips typographus voltinism and reproductive diapause     

Anna Maria Jönsson  Susanne Harding  Paal Krokene  Holger Lange  Åke Lindelöw  Bjørn Økland  Hans Peter Ravn  Leif Martin Schroeder 《Climatic change》2011,109(3-4):695-718

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Meteorological effects on seasonal displacements of the ?knes rockslide, western Norway   总被引：1，自引：1，他引：0  

Guro Gr?neng  Hanne H. Christiansen  Bj?rn Nilsen  Lars Harald Blikra 《Landslides》2011,8(1):1-15

In the alpine topography along one of the long fjords with steep and high mountain sides in western Norway the large ?knes rockslide area is defined by a distinct back scarp rising from 800 to 1,000 m a.s.l. In 2004, an extensive monitoring program started, including establishment of a meteorological station above the upper tension crack, 900 m a.s.l. This paper evaluates the significance of meteorological conditions affecting the displacements recorded by five extensometers and two laser sensors in the tension crack from November 2004 to August 2008. Meteorological factors of importance for the recorded activity in the tension crack are found to be melt water in spring and large temperature fluctuations around the freezing point in spring, autumn, and early winter. The records show less acceleration phases in the measured distance across the tension crack in the second half of the analyzed period even though annual displacements are increasing, indicating that other processes, like disintegration of irregularities along unfilled joints and disintegration of intact rock bridges in the sliding plane have become more important.  相似文献