富钴结壳中矿物组成对稀土元素分布的制约     

张平萍  初凤友  李小虎 《海洋学报》2015,37(5):136-147

为探讨富钴结壳中矿物组成对稀土元素分布的制约,对约翰斯顿岛富钴结壳中矿物组成及稀土元素特征进行了研究。依据主要矿物组成,富钴结壳可以分为3种类型,分别命名为A、B、C。由A到C,水羟锰矿含量逐渐降低,B类中磷灰石含量最高,C类中水钠锰矿和钙锰矿含量最高。A类结壳中富集REE3+、Ce,B类结壳中富集Ce和Y。A类富钴结壳中,REE3+、Y以专属吸附的方式富集在铁氧化物上,Ce3+氧化成Ce4+与其他REE分离,吸附在锰矿物上。B类结壳中,稀土元素主要以独立矿物的形式存在,另有部分Ce、LREE3+吸附于铁相中,部分Y存在于磷灰石中。C类结壳中,稀土元素主要赋存在锰矿物中,部分Y存在于磷灰石中。  相似文献   

西沙群岛生物碳酸盐的成因和沉积:来自活体仙掌藻的证据   总被引：1，自引：0，他引：1  

许红  赵新伟  Gregor P. Eberli  LIU Xinyu  朱玉瑞  蔡瑛  LUO Wei  闫桂京  张柏林  魏凯  施剑 《海洋学报(英文版)》2015,34(4):62-73

A recent island survey reveals that the Xuande Atoll and the Yongle Atoll in the Xisha Islands can be classified into one of two systems: the depleted atoll system and growth atoll system; the survey also indicates that the decreased area of several shoals is an unbearable burden for the Xisha Islands, of which the largest island area is 2.13 km2 and the minimum elevation is 1.4 m. According to a survey on the ecological characteristics of Halimeda in the Laolongtou breaker zone of Shidao Island in the Xisha Islands, the green and white living Halimeda are collected,the isotopic ages of 14 C contained in the Halimeda are shown to be 27 years and 55 years, respectively, and carbonate mainly occurs in five types, i.e., luster, segment, sand, sand grain, and marl in the formation. The Halimeda segments mainly provide the carbonate sediments of long-term biogenic deposits in the reef environment and the annual productivity per area is 60–100 g/m2; the characteristics of the microstructure of the Halimeda are analyzed, the aragonite raphide carbonate is deposited and enriched in the cortexes, medullas and cysts, and the Halimeda generally contain major elements such as C, O, Ca, Cl, Mg, K, Na, S and Al, and are rich in trace elements such as tellurium(Te), rhodium(Rh) and strontium. It is believed that the Halimeda grow slowly,including the biotic community of reef corals in the reef areas, thus they possess an environmental remediation capacity, but it takes much time to remedy the environment, and it is necessary to make the law to protect the diversity and vulnerability of the Xisha marine ecology, the ecology of the reef community and the island environment in a scientific way. As indicated in the survey, under the background of global warming and sea-level rise, the discovery of large amounts of Halimeda in the Laolongtou sea area is significant for the natural increase of the depleted atoll system of the Xuande Atoll, while the Halimeda segments represent the primary form of the fossil Halimeda, of which the species can be identified and preserved in great numbers under geological conditions. The Miocene was discovered in large amounts in the Xichen-1 well, therefore the study on the characteristics and mechanism of Halimeda carbonate sediments plays a pivotal role in the formation and construction of organic reefs in the South China Sea as well as oil and gas exploration.  相似文献   

数字相机在类似棋盘检校场中的检校方法研究     

张阳阳  门林杰  周桂初  杨娟 《测绘工程》2015,(2):55-59,64

针对众多非量测单相机的检校方法,通过分析数码相机的误差来源,并考虑相机的内、外方位元素和物镜光学畸变等因素引起的误差,提出一种基于类似棋盘检校场的数字相机检校方法。利用共线方程和二维DLT之间的关系导出了由二维DLT的9个参数表达的主纵线方程,构建同形矩阵,通过不同摄站拍摄目标的多幅影像,求得内、外方位元素的初始值,并由多张影像的空间后方交会求出相机需要检校参数,再由假设检验来检验相机系统参数的显著性。经实例分析表明,利用改进后的方法求解参数的精度满足实际需求,且效率更高。  相似文献   

大视场面阵数字航摄仪检测关键技术探讨     

肖海红  王成龙  韩菲 《测绘科学》2015,(9):129-133

针对常规室内检校场无法满足大视场面阵数字航摄仪检测的问题,文章提出了一种适合此类航摄仪检校的野外检校场的建立方法,通过对检校场控制点布设方案设计、适合影像识别的地标形状设计和地标点三维坐标的精确测定方案研究,实现了检测场内控制点的高精度测量:建立适合大面阵数字航空摄影仪几何误差改正的数学模型,并通过多摄站拍摄足够数量的检校场影像,自动识别并测定每幅影像上全部地标点的影像坐标,用最小二乘平差计算间接求出相机的内方位元素和各项畸变参数,最后通过多组检测参数对比,验证了数学模型及其参数的可靠性与稳定性。  相似文献   

天地图·福建数据融合技术与方法     

翟梦 《测绘与空间地理信息》2015,(10):184-186

通过对福建省1∶10 000核心要素与天地图国家主节点数据研究,分析天地图国家主节点与福建省基础地理信息数据现状,结合天地图数据融合的技术要求,充分考虑融合与共享,设计了福建省1∶10 000核心要素与国家天地图数据融合的总体流程,并分要素阐述处理要求,有效解决了多源多尺度异构数据的融合问题,该技术已经在天地图·福建数据融合项目中得到了应用,为省级基础地理信息数据参与国家天地图数据融合提供了参考。  相似文献   

基于地球化学组合求异的津巴布韦奇马尼马尼地区成矿预测          下载免费PDF全文

张素荣  赵更新  杨俊泉  贺福清  张燕  俞礽安 《地质找矿论丛》2015,30(S1):172-180

如何有效地解释评价异常是化探找矿取得成功的关键,传统的地球化学异常处理方法一般是以单一元素的含量值与背景值的差异来圈定异常,因子-泛克立格求异模型则建立在矿床主成矿期元素共生组合与地球化学异常之间的对应关系。采用因子-泛克立格模型对津巴布韦东部奇马尼马尼地区进行成矿预测,结果表明:奇马尼马尼地区存在7种元素组合,分别对应于不同的岩性组合,F4和F6元素组合异常可作为区内热液成矿指示标志,与东部塔卡金矿套合程度高。利用该模型圈定了5处找矿远景区,Ⅰ号远景区为铜镍金钛铁矿成矿有利区,Ⅱ号远景区具有与塔卡金矿相似的地球化学组合背景,Ⅲ号、Ⅳ号和Ⅴ号远景区则具寻找热液型金铜矿及多金属矿的潜力。  相似文献   

Characterization of Galena and Vein Paragenesis in the Penjom Gold Mine, Malaysia: Trace Elements, Lead Isotope Study and Relationship to Gold Mineralization Episodes     

Zakaria ENDUT  NG Tham Fatt  Jasmi Hafiz ABDUL AZIZ  Sebastien MEFFRE  Charles MAKOUNDI 《《地质学报》英文版》2015,89(6):1914-1925

The Penjom Gold Mine is located 30 km from the Bentong-Raub Suture at the western boundary of the Central Belt in Peninsular Malaysia. Gold mineralization hosted within the vein system is associated with pyrite, arsenopyrite, and minor base metals including galena. Trace element and lead isotope analysis was undertaken on nine samples that represent two stages of galena formed during two tectonic events. Both the Pb isotopes and the trace elements show that the first stage galena within the mineralized areas at the footwall has different geochemical characteristics compared with galena in non mineralized areas in the hanging wall, suggesting that galena crystallized from two different ore fluids and probably at two different times. Higher Te, Se and Bi in the galena from the mineralized area may indicate hydrothermal fluids that migrate through the structural conduit and leached out the metal along the pathway that consist of dominant carbonaceous unit. The Pb isotopic ratio composition are transitional between the bulk crustal growth and an upper crustal growth curve, indicating that derivation was from arc rocks associated with continental crust or a crustal source that includes arc volcanic and old continental sedimentary rocks.  相似文献   

南海北部沉积物常量元素变化、碳酸盐旋回及其古环境意义   总被引：1，自引：0，他引：1  

李小洁  梁莲姬  吴枫  孙有斌 《第四纪研究》2015,35(2)

通过对南海北部ODP1145站沉积物的常量元素和碳酸盐分析,探讨了早更新世南海北部沉积物常量元素和碳酸盐含量变化特征及其古环境意义.结果表明,南海北部沉积物中主量元素CaO、Fe2O3、K2O、Na2O、MnO和P2O5受碳酸盐含量影响相对较小,而SiO2、MgO、Al2O3和TiO2受到碳酸盐含量影响相对较大.碳酸盐校正后的常量元素变化可以划分为3种类型,即PC1、PC2和PC3,它们的主要特点有:PC1元素组合包括了SiO2、CaO、Na2O、P2O5、Fe2O3和K2O,主要反映了与季风强度有关的生源物质产率变化,指示了距今2.5～1.5Ma时段生产力的逐渐降低;PC2元素组合(Al2O3、TiO2)代表了陆源物质的输入,指示了在约2Ma开始陆源物质输入的明显增加;PC3元素组合(MgO、MnO)可能与海洋自生作用有关,反映了海底氧化/还原环境的相对变化.早更新世南海北部CaCO3含量呈阶段性降低,一方面受陆源物质稀释作用的影响,另一方面可能更与生物生产力逐渐降低有关.主量元素组合及碳酸盐含量在约2Ma和1.7Ma左右均发生显著变化,可能指示了早更新世时期东亚冬季风的两次增强.  相似文献   

黔西南中晚二叠世大厂层火山热水沉积成矿作用     

杜丽娟  陈军  杨瑞东  黄智龙  郑禄林  高军波  魏怀瑞 《地质论评》2020,66(2):439-456

贵州晴隆大厂锑矿区赋矿地层大厂层为一套以硅化为主的火山碎屑岩沉积建造,因其别具特色的岩石组合、特殊的构造位置,以及含有金、锑、萤石、硫铁矿等矿产资源而备受地学界关注。晴隆大厂锑矿床90%以上的锑矿体和金矿化体均位于大厂层之中,因此,研究大厂层的形成和演化过程及其对锑、金成矿的控制作用或影响机理显得尤为重要。沉积岩相学研究表明,大厂层主要包括火山岩相(火山溢流相、淬碎角砾岩相、沉凝灰岩相、空落集块岩相和熔结凝灰岩相)和热液沉积岩相(热水沉积相、热水喷流相和热水交代相)。中—晚二叠世(约260 Ma)的溢流玄武岩、基性火山喷发和海底热水喷流活动是大厂层的主要物源供给者。元素地球化学研究表明,大厂层在沉积过程的热水喷流沉积作用提供了Sb、As、Au、Ag、Pb等成矿元素,并形成成矿元素的初始"富集体"。综合研究认为,中—晚二叠世的热水喷流沉积活动在时间上与右江盆地印支期低温热液成矿事件(200～250 Ma)在时空上基本一致,为印支期成矿事件在右江盆地北缘的响应。  相似文献   

Cathodoluminescence and Trace Element Composition of Scheelite from the Middle-Lower Yangtze River Metallogenic Belt (MLYB): Implications for Mineralization and Exploration     

NIE Liqing  ZHOU Taof  CHEN Xuefeng  WANG Fangyue  XIAO Xin 《《地质学报》英文版》2020,94(6):1977-1996

The Middle–Lower Yangtze River Metallogenic Belt (MLYB) is known to contain abundant copper and iron porphyry-skarn deposits, with an increasing number of tungsten deposits and scheelite in Fe–Cu deposits being discovered in the MLYB during recent decades. The ore genesis of the newly-discovered tungsten mineralization in the MLYB is poorly understood. We investigate four sets of scheelite samples from tungsten, iron and copper deposits, using CL imaging and LA–ICP–MS techniques to reveal internal zonation patterns and trace element compositions. The REE distribution patterns of four studied deposits show varying degrees of LREE enrichment with negative Eu anomalies. The oxygen fugacity of ore-forming fluid increased in Donggushan, while the oxygen fugacity of ore-forming fluid decreased in Ruanjiawan, Guilinzheng and Gaojiabang. The scheelites from the Donggushan, Ruanjiawan, Guilinzheng and Gaojiabang deposits show enrichment in LREEs and HFSE, with Nb/La ratios ranging from 1.217 to 52.455, indicating that the four tungsten deposits are enriched in the volatile fluorine. A plot of (La/Lu)N versus Mo/δEu can be used to distinguish quartz vein type, porphyry and skarn tungsten deposits. This study demonstrates that scheelite grains can be used to infer tungsten mineralization and are effective in identifying magmatic types of tungsten deposits in prospective mining sites.  相似文献