Migration and dispersion of trace elements in the rock–soil–plant system in areas underlain by black shales and slates of the Okchon Zone, Korea     

Jin-Soo Lee  Hyo-Taek Chon  Kyoung-Woong Kim 《Journal of Geochemical Exploration》1998,65(1):61-78

The Okchon black shale in Korea provides a typical example of natural geological materials enriched with potentially toxic elements. The Chung-Joo, Duk-Pyung, Geum-Kwan, I-Won, Bo-Eun and Chu-Bu areas are underlain by these black shales and slates of the Guryongsan Formation or the Changri Formation, which are parts of the Okchon Group in the central part of the southern Korean Peninsula. In order to investigate the enrichment levels and dispersion patterns of potentially toxic elements in the rock–soil–plant system, environmental geochemical surveys were undertaken in the above six study areas in the Okchon Zone. After appropriate preparation, rock and soil samples were analyzed for potentially toxic elements by instrumental neutron activation analysis (INAA) and inductively coupled plasma atomic emission spectrometry (ICP-AES), and plant samples by atomic absorption spectrometry (AAS). In particular, Ba, Cd, Mo, V and U in Okchon black shales are highly enriched, and their mean concentrations are significantly higher than those in black slates. These elements are geochemically associated, and might be enriched simultaneously. The highest mean concentrations of 42.0 μg g⁻¹ As, 2100 μg g⁻¹ Ba, 10.9 μg g⁻¹ Cd, 213 μg g⁻¹ Mo, 83 μg g⁻¹ U, 938 μg g⁻¹ V and 394 μg g⁻¹ Zn are found in black shales from the Duk-Pyung area. Mean concentrations of As, Mo and U in soils overlying black shales occurring in the Duk-Pyung area (30 μg g⁻¹ As, 24 μg g⁻¹ Mo and 50 μg g⁻¹ U) and Chu-Bu area (39 μg g⁻¹ As, 15 μg g⁻¹ Mo and 27 μg g⁻¹ U) are higher than the permissible level. Enrichment index values of the six study areas decrease in the order of Duk-Pyung > Chu-Bu > Bo-Eun > Chung-Joo > Geum-Kwan = I-Won areas. Relationships between trace element concentrations in soils and plants are significantly correlated, and the biological absorption coefficients (BAC) in plants are in the order of Cd > Zn = Cu > Pb, which suggests that Cd is more bioavailable to plants than the other elements. Cadmium concentrations in plant species decrease in the order of chinese cabbage > red pepper > soybean = sesame > rice stalk > corn > rice grain. From the result of sequential extraction analysis of soils, relatively high proportions of Cu, Pb and Zn are present as residual fractions, and that of Cd as non-residual fractions. Cadmium occurs predominantly as exchangeable/water-acid soluble phase in soils, and this is in agreement with the findings of high Cd concentrations in plants.  相似文献   

蓝细菌聚金作用实验研究   总被引：2，自引：0，他引：2       下载免费PDF全文

林丽  朱利东 《地质科学》1998,33(4):483-488

蓝细菌聚金实验研究表明:①不同的生物由于生化组分的差异,其富金能力不同,低等蓝细菌生物比动物细胞富金能力强;②金在细胞中的分布与其各部分生化组成(也就是生物配体)密切相关;③金离子进入细胞不是一种简单的扩散作用,而是通过细胞膜界面两侧物质之间的交换而实现的,蓝细菌活体聚金机理主要是参与生命活动的吸收作用;④在较高温热水环境中微生物对成矿最显着。  相似文献   

西藏玉龙铜矿床次生氧化富集作用机制   总被引：8，自引：0，他引：8  

陈建平  王成善 《地质学报》1998,72(2):153-161

作文阐述了西藏玉龙铜矿床成矿过程中的“沉积初步富集期”和“西藏玉龙铜矿床次生氧化成矿作用模式”,这不仅对指导当前生产具有重要的现实意义,而且为在玉龙铜矿带进一步找矿共作劈了新的方向。  相似文献   

准噶尔含煤盆地构造演化与聚煤作用   总被引：5，自引：1，他引：4  

王俊民 《新疆地质》1998,(1)

准噶尔含煤盆地是新疆主要含煤盆地之一 ,从含煤盆地内各煤田的含煤地层特征 ,构造特征及煤层赋存特征着手 ,分析了盆地内的沉积环境 ,构造演化和聚煤作用 ,论述了两个主要聚煤期所形成的含煤建造的发生、发展过程 ,指出了两个含煤建造中聚煤中心和富煤带的位置  相似文献   

贵金属资源的应用及开发   总被引：1，自引：1，他引：0  

唐杰  张凯 《世界地质》1998,17(4):98-102

将贵金属的应用,资源分布,生产和贵金属的分析化学结合在一起进行了综述,由于贵金属资源的短缺性及考虑可持续发展战略,特别介绍了贵金属资源的二次回收问题,并对其将来的发展作了一定的评价和展望。  相似文献   

重庆玉峡锶矿床中分散元素锶的超常富集机制   总被引：2，自引：0，他引：2  

朱创业 《矿物岩石地球化学通报》1998,(4)

重庆玉峡锶矿床位于华蓥山构造带的南段。含矿岩系为下三叠统嘉陵江组二段一亚段的含藻含膏白云岩,含矿层位自下而上有三个矿层。矿层呈似层状、透镜状赋存于西山背斜北段的背斜转折端及相邻两翼的层间虚脱部位。矿石矿物有天青石、菱锶矿、钡天青石,脉石矿物为白云石、...  相似文献   

Secondary copper enrichment in tailings at the Laver mine, northern Sweden   总被引：3，自引：2，他引：1  

H. Holmström  J. Ljungberg  M. Ekström  B. Öhlander 《Environmental Geology》1999,38(4):327-342

 Field and laboratory studies of the sulphide-bearing tailings at Laver, northern Sweden, show that the present release of metals from the tailings is low, especially with regard to Cu. A large part of the Cu released by sulphide oxidation is enriched in a distinct zone just below the oxidation front. The enrichment zone occurs almost all over the tailings area except in areas with a shallow groundwater table. The Cu enrichment is caused by formation of covellite and adsorption onto mineral surfaces. The transport of Zn, Co, Cd, Ni and S seems to be controlled mainly by adsorption. No secondary zone or secondary minerals containing these metals have been found. Just below the groundwater table, metals are released into solution when the enrichment zone reaches the groundwater due to the low pH. An increased release of metals, especially Cu, can be expected in the future, since the enrichment zone is moving towards the groundwater table. Received: 4 December 1997 · Accepted: 17 December 1998  相似文献   

粉煤灰土壤及所产蔬菜的有害元素含量变化和环境意义   总被引：1，自引：0，他引：1  

谭衢霖  翟建平  周维科  钱琴 《高校地质学报》1999,(3)

利用南京第二热电厂湿排的粉煤灰,进行了改良蔬菜土壤的试验,并对试验用的粉煤灰、不同施灰量的土壤及所产蔬菜共３８ 个样品的有害元素和放射性元素含量进行了系统的测定。结果表明：这些元素在土壤中的含量与粉煤灰施用量无明显相关性;在本次试验范围内施用粉煤灰没有造成土壤的污染;其所产蔬菜的这些元素含量也均低于国家卫生标准限值,食用是安全的。  相似文献   

TBP萃淋树脂微色谱柱分离富集钼的研究及应用   总被引：3，自引：0，他引：3  

宋金如  龚治湘  王玉学 《华东地质学院学报》1999,22(1):51-56

研究了ＴＢＰ萃淋树脂微色谱柱分离富集微量钼的柱性能,确定了分离钼的最佳条件。在减压条件下,运用零空床体积洗脱技术,以３ｍｏｌ／ＬＨＣｌ为上柱介质,０．５ｍｏｌ／ＬＨＣｌ洗脱,可使钼（ＶＩ）与钨（Ⅵ）、铁（Ⅲ）、锡（Ⅳ）等干扰离子快速分离,采用邻氯苯基荧光酮胶束增溶光度法,测定矿石中微量钼,结果满意。  相似文献   

川西高原草原地区的金矿成矿元素的表生地球化学特征   总被引：1，自引：1，他引：0  

赵琦 《物探与化探》1999,23(5):381-387,396

通过对川西高原草原地区的东北寨、马脑壳和哲波山金矿区的研究,总结该区的特殊的弱酸性偏还原的表生地球化学特征.并研究不同组元素的贫化和富集,不同粒级、不同深度的元素变化规律,提出金砷锑汞钨等元素是该区金矿的主成矿元素,总结出该区的表生地球化学特征.  相似文献