北京地区臭氧垂直分布的演变趋势与特征的研究——卫星SBUV资料与地面遥感对比分析          下载免费PDF全文

魏鼎文  陈辉 《地球物理学报》1991,34(4):415-425

利用地面遥感O₃垂直分布的逆转方法〈C〉测量出的北京上空O₃剖面资料,对雨云7号卫星的SBUV系统测量的同地区的O₃垂直分布数据进行了订正.对订正后的长达8年（1979-1986年）的完整的SBUV资料进行了较为仔细的分析,得出了这一时期内的O₃垂直分布长期演变呈下降趋势.并在上层O₃含量的季节变化特征和周期振荡等方面,有新的发现,得出一些有意义的结果.  相似文献   

The role of clouds in tropospheric photochemistry     

J. Lelieveld  P. J. Crutzen 《Journal of Atmospheric Chemistry》1991,12(3):229-267

We show that photochemical processes in the lower half of the troposphere are strongly affected by the presence of liquid water clouds. Especially CH₂O, an important intermediate of CH₄ (and of other hydrocarbon) oxidation, is subject to enhanced breakdown in the aqueous phase. This reduces the formation of HO _x -radicals via photodissociation of CH₂O in the gas phase. In the droplets, the hydrated form of CH₂O, its oxidation product HCO₂ ^–, and H₂O₂ recycle O₂ ^– radicals which, in turn, react with ozone. We show that the latter reaction is a significant sink for O₃. Further O₃ concentrations are reduced as a result of decreased formation of O₃ during periods with clouds. Additionally, NO _x , which acts as a catalyst in the photochemical formation of O₃, is depleted by clouds during the night via scavenging of N₂O₅. This significantly reduces NO _x -concentrations during subsequent daylight hours, so that less NO _x is available for O₃ production. Clouds thus directly reduce the concentrations of O₃, CH₂O, NO _x , and HO _x . Indirectly, this also affects the budgets of other trace gases, such as H₂O₂, CO, and H₂.  相似文献   

Extremely low temperatures in the stratosphore and very low total ozone amount above northern and central Europe during winter 1989     

Klaus Wege 《Journal of Atmospheric Chemistry》1991,12(4):381-390

On 1 February 1989, -83.5°C was recorded in 27.8 hPa over Hohenpeißenberg, the lowest temperature in the 22-year series. This was measured together with a very low total ozone amount of 266 DU. This may be compared with nearly twice this amount on 27 February 1989. The situation was very unusual: following an extremely cold winter in the Arctic stratosphere, the stratospheric cold pole was located over southern Scandinavia on 1 February in a very southerly position. The analyzed temperatures of -92 °C in 30 hPa were also unusual. Even though the low ozone amounts over Hohenpeißenberg were probably dynamically caused, an additional very small ozone decrease due to heterogeneous reactions in altitudes from 23–28 km, where the temperatures lie below -80 °C, cannot be ruled out. Extinction measurements by the orbitting SAGE II instrument indeed show polar stratospheric clouds over Europe near 50° N during the period 31 January–2 February. Also, polar stratospheric clouds were previously observed over Kiruna at similarly low temperatures and signs of a corresponding small ozone decrease were noted there.  相似文献   

北半球臭氧总量与平流层环流关系的分析   总被引：2，自引：7，他引：2  

郑光  吴统文 《高原气象》1991,10(3):277-286

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臭氧和平流层动力学的相互作用   总被引：1，自引：0，他引：1  

Jonathan S.Kinnersley  朱乾根  孙照渤  何金海 《南京气象学院学报》1993,(1)

讨论了给定的南极春季臭氧洞(取自1979—1985年臭氧减少的观测结果)对二维平流层—对流层模式中温度和环流的影响。11月份,南极上空约17km处,温度最多可降低6℃。这种温度变化引起的平均经向环流对臭氧洞起填塞作用,不过,这种影响很小,每年仅产生14DU的变化。观测事实表明,近年来10月份,南半球波活动减弱。为此,我们作了南半球波作用全年都减少一半,并考虑了臭氧洞的数值试验。结果表明,臭氧柱在11月份76°S减少了44DU,在赤道却增加了12DU。  相似文献   

Nonlinear chemical couplings in the tropospheric NO x -HO x gas phase chemistry     

J. Zimmermann  D. Poppe 《Journal of Atmospheric Chemistry》1993,17(2):141-155

A bifurcation phenomenon with relevance to atmospheric chemistry is discussed. The gasphase reactions in the troposphere exhibit two types of temporal evolution which are controlled by the strength of the source,Q, of nitric oxide, NO, via the nonlinear chemical coupling between the hydrogen oxides and nitrogen oxides chemistry. IfQ remains below a threshold value, all short-lived species, including NO, approach steady-state concentrations, while above the threshold bifurcation to another state with increasing (nonstationary) NO concentrations accompanied by a depletion of the OH and HO₂ abundances takes place.  相似文献   

NO2 total column evolution during the 1989 spring at Antarctica Peninsula     

Manuel Gil  Javier Cacho 《Journal of Atmospheric Chemistry》1992,15(2):187-200

Ground-based visible differential absorption spectrometry during twilight has been used for NO₂ total column observations at the Antarctica Peninsula, Marambio Base (64S, 56W), during the austral spring of 1989 (9 September to 25 November).Results show moderate NO₂ vertical column levels of 1.5 to 2.5×10¹⁵ molec cm^-2 in the morning and 2 to 3×10¹⁵ molec cm^-2 in the evening until middle October, highly modulated by planetary wave activity. From that date until the end of the period, a steady increase occurs which is associated with the rising of lower stratosphere temperature as the vortex weakens, reaching values of 5×10¹⁵ molec cm^-2 in late November, with small a.m.-p.m. differences. NO₂ is found to be positively correlated to both total ozone and 50 hPa temperature during the entire spring. However, when analyzing the departures from linear trends, a highly negative correlation has been observed from day 301 onwards.  相似文献   

A Eulerian air pollution model for Europe with nonlinear chemistry   总被引：1，自引：0，他引：1  

Z. Zlatev  J. Christensen  Ø. Hov 《Journal of Atmospheric Chemistry》1992,15(1):1-37

A long-range transport model with nonlinear chemical reactions is described. The model contains 35 pollutants and 70 chemical reactions. This is a Eulerian model defined on a space domain containing the whole of Europe. The spherical space domain (corresponding to the Earth's surface covered by the model) is mapped into a square plane domain and discretized by using a 32×32 grid. The grid increments are equidistant (both along the Ox axis and along the Oy axis). The choice of values of the physical parameters involved in the model and the numerical treatment of the model are shortly discussed. The model is tested with meteorological data for 1985 and 1989. The numerical results are compared with measurements at stations located in different European countries. Extensive comparisons of ozone concentrations for July 1985 with measurements taken at 24 European stations are also carried out. Results concerning three episodes in July 1985 as well as results obtained in the study of the sensitivity of the ozone concentrations to variations of NO _x and/or anthropogenic VOC emissions are presented. The advantages and the limitations of such a model are discussed. The model is continuously improved by adding new modules to it. The plans for improvements in the near future are outlined.  相似文献   

Performance of the electrochemical ozone sonde OSR     

U. Feister  K. H. Grasnick  G. Peters 《Pure and Applied Geophysics》1985,123(3):422-440

Summary The accuracy of the electrochemical ozone sonde, type OSR, has been estimated by analysing tandem ozone soundings of the balloon-borne electrochemical ozone sonde OSR at the Lindenberg Observatory from May to November 1982. A negative bias, though not significant, has been observed above about 28 km for soundings having high single correction factors. Random errors are at their minimum just above the level of the maximum of ozone partial pressure, and reach their maximum in the troposphere. Except at heights above about 28 km the random error of ozone sondes is a factor 2 to 3 times less than the error of the short Umkehr method. Provided that soundings with too high correction factors are neglected, the ozone sonde OSR has an accuracy comparable to that of other Brewer type sondes.The maximum amount of information on the vertical ozone distribution can be drawn from sonde measurements in the lower stratosphere. A study is underway to improve the sensitivity of the sonde OSR and thus to further enhance its reliability.  相似文献   

NUMERICAL SIMULATION OF OZONE DISTRIBUTIONS AND ITS VARIATION MECHANISM_*     

Ren Chuansen  Zhou Xiuji  Li Weiliang  Qin Yu 《Acta Meteorologica Sinica》1997,11(2):129-142

A 2-D global chemistry-transport model is set up in this paper.The model simulates the atmospheric ozone distributions well with specified dynamical conditions.The analysis of ozone variation mechanism shows that ozone is chemically in quasi-equilibrium except for the polar night region where the variation of ozone concentration is under the control of dynamical processes,that the oxygen atoms which produce ozone are mainly provided by the photolysis of O₂ in the upper stratosphere and by the photolysis of NO₂ in the lower stratosphere and the troposphere.and that the ozone is destroyed mainly by NO_x:the reactions between NO_x and O₃ and the odd oxygen cycle contribute 80% to more than 90% of the ozone destruction.  相似文献