华北平原夜间对流性天气对地面O₃混合比的抬升效应          下载免费PDF全文

贾诗卉  徐晓斌  林伟立  王瑛  何心河  张华龙 《应用气象学报》2015,26(3):280-290

2013年6—9月在河北省固城站观测到多次夜间对流性天气伴随地面O₃混合比快速抬升的过程,并引起次日清晨到中午O₃混合比升高。大多数对流过程中,O₃混合比在半小时内升高至60×10-9～80×10-9,同时NO_x等反应性气体混合比下降,θ_se值降低,说明下沉气流将高空气团带到地面,造成了O₃混合比的升高。通过再分析资料得到下沉气团基本来源于对流层中下层,这一结论与当地进行的一次飞机观测结果吻合。多数对流过程中固城站和北京城区地面O₃混合比和θ_se值有相同的变化趋势和程度。根据观测结果,推测华北地区在夏季和初秋时,对流层中下层存在O₃高值区,混合比约为60×10-9～80×10-9。对流性天气对地面O₃抬升的影响区域与对流系统的影响范围有关,可达到中尺度范围。华北地区光化学污染严重,对流性天气引起的地面O₃混合比抬升程度比较强,对环境的影响值得关注。  相似文献   

Observational study of surface ozone at an urban site in East China   总被引：4，自引：1，他引：3  

Wenpo Shan  Yongquan Yin  Jianda Zhang  Yuping Ding 《Atmospheric Research》2008,89(3):252-261

In this study, we present the observational data of near surface ozone and some meteorological parameters during 2004, at an urban site (36°42′ N, 117°08′ E, 34.5 m a.s.l.) of Jinan, China. Hourly ozone concentrations exceeding the standard value of China, 100 ppbv, were observed for 65 h (in 23 days) from April to October, and values exceeding US NAAQS (National Ambient Air Quality Standard) for 1 h ozone, 120 ppbv, were observed for 15 h (in 7 days) from late May to early July. Ozone formation presented the phenomenon of “weekend effect”, especially in summer. Monthly variation of ozone coincided with temperature except for July and August. The low ozone levels in July and August may be due to the short sunshine duration and much rainfall during this period. Among these meteorological parameters, daily averaged ozone shows a significant correlation with temperature (r = 0.66) in the year and with relative humidity (r = − 0.75) in summer. Throughout the year, high ozone concentrations were mainly associated with the wind from 180 to 247.5°, while high ozone concentration seemed to have no obvious correlation with a given wind direction in summer. An anomalous nocturnal high ozone episode during 23–25 May 2004 was investigated. Growth fractions of ozone during the nighttime episode were 62.2% and 71.1% for 23 and 24 May, respectively. Synoptic analysis shows that favorable synoptic condition had presumably elevated the background ozone level in this region. Backward trajectory analysis shows that the increase of ozone concentration and the relatively constant high ozone concentrations during the night of May 23 might originate from the transport of ozone rich air mass above boundary layer. Transport of ozone from Yangtze Delta and East Central China might be a significant process for the high ozone level during night May 24 at Jinan.  相似文献   

平流层臭氧对地表有机氯排放的多耦合响应     

施春华  郑彬  陈月娟 《南京气象学院学报》2009,32(4):522-529

采用一个包含平流层化学、辐射、动力相互作用的二维模式,对地表有机氯排放变化影响平流层的具体过程作出评估,从而确定平流层臭氧对于地表有机氯排放的多耦合响应,也检验了“蒙特利尔议定书”的减排效果。结果表明,以议定书框架协议达成的20世纪90年代地表有机氯排放减少按30％计算,通过输送、扩散和一系列化学反应,导致平流层中上层的各活性化学族的浓度发生变化,稳定后平流层40km到48km经向平均的相对变化率,ClOx减少20％,HOx和NOx增加2％左右,O3恢复5％左右。此外,这些成分变化导致平流层中上层辐射加热率增加,平流层变冷趋势减缓0．6K。  相似文献   

北极平流层冬季早期变暖的GCM模拟研究     

胡永云  姜天宇 《大气科学》2009,33(5):1058-1070

观测表明北极平流层自20世纪70年代末以来在冬季早期 (11～12月) 存在变暖的趋势。为了验证该趋势是否是由于海面温度 (SST) 升高造成的, 我们使用观测的全球SST强迫一个全球大气环流模式 (AGCM)。集合模拟的结果表明, 在SST强迫下, 北极平流层呈现统计显著的变暖趋势, 极地对流层也有相对较弱的变暖趋势, 但统计显著性较低。通过对模拟的位势高度进行经验正交函数 (EOF) 分析, 我们发现北半球位势高度第一模态 (EOF1) 的空间结构非常类似于北极涛动 (AO) 或北半球环状模 (NAM), 其平流层主分量时间序列在冬季早期呈现统计显著的负趋势。与负的AO趋势相对应的是, 对流层高纬度和平流层中高纬度波动增强, 说明极区变暖是由于波动增强产生的极区绝热加热增强造成的。另外, 模拟的结果还表明北极平流层不仅在冬季早期出现变暖的趋势, 在冬季晚期 (2～3月) 北极平流层低层也出现弱的变暖趋势。SST强迫导致北极平流层冬季变暖不利于异相臭氧化学反应的发生, 这对极地平流层臭氧恢复有着重要意义。  相似文献   

中国4个地点地基与卫星臭氧总量长期观测比较   总被引：1，自引：0，他引：1       下载免费PDF全文

郑向东  韦小丽 《应用气象学报》2010,21(1):1-10

对我国河北香河、云南昆明、青海瓦里关及黑龙江龙凤山地基观测臭氧总量与不同时期、不同卫星反演的产品差别特点进行比较,评估地基和卫星观测臭氧总量数据的质量信息以及近30年来我国不同区域臭氧总量的变化趋势特征。结果表明:4个站点的地基与卫星观测臭氧总量的绝对和相对差别分别为-5~10 DU和-5%~4%;日平均相对差别基本上呈现随机分布特征。TOMS算法反演的卫星臭氧总量与地基差别总体上要优于与DOAS算法反演的同期产品。地基与卫星臭氧总量差别呈明显的区域特点,可能反映了卫星反演计算中所需的臭氧、温度垂直分布等初始条件的纬度分布差异对卫星产品精度的影响。在过去30年,4个站点的臭氧总量在经历1993年前的显著降低后于1995—1996年逐渐回升,而瓦里关站在2001年前后的回升更为明显。  相似文献   

Model analysis of seasonal variations in tropospheric ozone and carbon monoxide over East Asia   总被引：1，自引：0，他引：1  

高丽洁  张美根  韩志伟 《大气科学进展》2009,26(2):312-318

Temporal-spatial variations in tropospheric ozone concentrations over East Asia in the period from 1 January 2000 to 31 December 2004 were simulated by using the Models-3 Community Multi-scale Air Quality (CMAQ) modeling system with meteorological fields calculated by the Regional Atmospheric Modeling System (RAMS). The simulated concentrations of ozone and carbon monoxide were compared with ground level observations at two remote sites, Ryori (39.03°N, 141.82°E) and Yonagunijima (24.47°N, 123.02°E). The co...  相似文献   

Reduction of a Model Describing Ozone Oscillations in the Troposphere: Example of an Algorithmic Approach to Model Reduction in Atmospheric Chemistry     

Leonid V. Kalachev  Richard J. Field 《Journal of Atmospheric Chemistry》2001,39(1):65-93

We consider a simplified reaction mechanism from tropospheric chemistryconsisting ofsix chemical species involved in ten dynamic processes. The concentrations of all six speciesundergo temporal oscillation for some parameter values. An asymptoticapproach to reduction of the original six-variable model to a four-variable version is considered together with detailed explanation of the procedure as well as discussion of conditions under whichthe reduction is possible. The reduced system nearly quantitatively represents the oscillating behavior of thefull model and allows elucidation of its basic dynamical features. This approach also can be used to compare various small models of atmospheric chemistry, and to determine their underlying dynamic structure. The method can be systematically appliedto larger atmospheric models.  相似文献   

Air Quality,Climate, and Policy: A Case Study of Ozone Pollution in Tucson,Arizona     

Jeremy E. Diem  Andrew C. Comrie 《The Professional geographer》2001,53(4):469-491

This article addresses the need to better understand the complex interactions between climate, human activities, vegetation responses, and surface ozone so that more informed air‐quality policy recommendations can be made. The impacts of intraseasonal climate variations on ozone levels in Tucson, Arizona from April through September of 1995 to 1998 are determined by relating variations in ozone levels to variations in atmospheric conditions and emissions of ozone's precursor chemicals, volatile organic compounds (VOCs) and nitrogen oxides (NO_x), and by determining month‐specific atmospheric conditions that are conducive to elevated ozone levels. Results show that the transport of ozone and its precursor chemicals within the Tucson area causes the highest ozone levels to be measured at a downwind monitor. The highest ozone levels occur in August, due in part to the presence of the North American monsoon. Atmospheric conditions conducive to elevated ozone concentrations differ substantially between the arid foresummer (May and June) and the core monsoon months ( July and August). Transport of pollution from Phoenix may have a substantial impact on elevated ozone concentrations during April, May, and June, while El Paso/Ciudad Juarez –derived pollution may contribute significantly to elevated ozone concentrations in August and September. Two broad policy implications derive from this work. Regional pollutant transport, both within the U.S. and between the U.S. and Mexico, is a potential issue that needs to be examined more intensively in future studies. In addition, spatiotemporal variations in sensitivities of ozone production require the adoption of both NO_x and VOC control measures to reduce ozone levels in the Tucson area.  相似文献   

Methyl halide hydrolysis rates in natural waters     

Scott Elliott  F. Sherwood Rowland 《Journal of Atmospheric Chemistry》1995,20(3):229-236

International regulations are under consideration for methyl bromide because of its high time dependent ozone depletion potential. Geocycling of the species is not well understood, and removal may occur in several types of natural water incuding the oceanic and those in soils. The hydrolysis reaction is a dominant loss pathway in environmental aqueous systems, but rate constants have generally been reported only in distilled water and at greater than room temperature. Here we present measurements in sodium chloride solutions and in seawater in addition to pure water, and at temperatures across the oceanographic range. The reaction could be followed even in solutions near the freezing point because product methanol was monitored in the method of initial rates. Time constants for methyl bromide hydrolysis fall between 10 and 1000 days over the temperatures of the sea, and are always within an order of magnitude of the fastest abiotic destruction mode, chlorination. Activation energies for the two processes are similar so that the ratio of their time scales does not vary with oceanic location. Hydrolysis rate constants are also listed for the closely related compounds methyls iodide and chloride. Solvolysis of the methyl halides in natural waters acts as a source of methanol to the ocean and atmosphere.  相似文献   

用太阳及天光光度计进行大气臭氧探测          下载免费PDF全文

薛庆渝  郭松 《应用气象学报》1993,4(2):138-144

在紫外光谱区，大气臭氧有较丰富的吸收带结构。作者用自制的太阳及天光光度计测量直射阳光、直射月光和曙暮光的紫外吸收光谱，并用带吸收法计算臭氧垂直柱总量及斜程含量。文中介绍了观测和计算方法，并给出北京地区晴朗天气条件下观测的初步结果。  相似文献