Fluid sources for the La Guitarra epithermal deposit (Temascaltepec district, Mexico): Volatile and helium isotope analyses in fluid inclusions   总被引：1，自引：0，他引：1  

Antoni Camprubí  Beverly A. Chomiak  Ruth E. Villanueva-Estrada  David I. Norman  Martin Stute 《Chemical Geology》2006,231(3):252-284

The La Guitarra deposit (Temascaltepec district, South-Central Mexico), belongs to the low/intermediate sulfidation epithermal type, has a polymetallic character although it is currently being mined for Ag and Au. The mineralization shows a polyphasic character and formed through several stages and sub-stages (named I, IIA, IIB, IIC, IID, and III). The previous structural, mineralogical, fluid inclusion and stable isotope studies were used to constrain the selection of samples for volatile and helium isotope analyses portrayed in this study. The N₂/Ar overall range obtained from analytical runs on fluid inclusion volatiles, by means of Quadrupole Mass Spectrometry (QMS), is 0 to 2526, and it ranges 0 to 2526 for stage I, 0 to 1264 for stage IIA, 0 to 1369 for stage IIB, 11 to 2401 for stage IIC, 19 to 324 for stage IID, and 0 to 2526 for stage III. These values, combined with the CO₂/CH₄ ratios, and N₂-He-Ar and N₂-CH₄-Ar relationships, suggest the occurrence of fluids from magmatic, crustal, and shallow meteoric sources in the forming epithermal vein deposit. The helium isotope analyses, obtained by means of Noble Gas Mass Spectrometry, display R/Ra average values between 0.5 and 2, pointing to the occurrence of mantle-derived helium that was relatively diluted or “contaminated” by crustal helium. These volatile analyses, when correlated with the stable isotope data from previous works and He isotope data, show the same distribution of data concerning sources for mineralizing fluids, especially those corresponding to magmatic and crustal sources. Thus, the overall geochemical data from mineralizing fluids are revealed as intrinsically consistent when compared to each other.The three main sources for mineralizing fluids (magmatic, and both deep and shallow meteoric fluids) are accountable at any scale, from stages of mineralization down to specific mineral associations. The volatile and helium isotope data obtained in this paper suggest that the precious metal-bearing mineral associations formed after hydrothermal pulses of predominantly oxidized magmatic fluids, and thus it is likely that precious metals were carried by fluids with such origin. Minerals from base-metal sulfide associations record both crustal and magmatic sources for mineralizing fluids, thus suggesting that base metals could be derived from deep leaching of crustal rocks. At the La Guitarra epithermal deposit there is no evidence for an evolution of mineralizing fluids towards any dominant source. Rather than that, volatile analyses in fluid inclusions suggest that this deposit formed as a pulsing hydrothermal system where each pulse or set of pulses accounts for different compositions of mineralizing fluids.The positive correlation between the relative content of magmatic fluids (high N₂/Ar ratios) and H₂S suggests that the necessary sulfur to carry mostly gold as bisulfide complexes came essentially from magmatic sources. Chlorine necessary to carry silver and base metals was found to be abundant in inclusion fluids and although there is no evidence about its source, it is plausible that it may come from magmatic sources as well.  相似文献   

大陆科学钻探先导孔（CCSD—P1）橄榄岩地幔属性及动力学意义     

郑建平汤华云  张志海余淳梅张瑞生  路凤香杨经绥 李天福 《现代地质》2007,21(2):275-285

早中生代的扬子大陆向华北大陆的深俯冲碰撞作用以及中、新生代的华北东部岩石圈减薄作用是国际大陆动力学问题研究的两个热点。然而，把它们有机联系起来，探讨深部岩石圈演化动力学过程的研究还很少。报道了中国大陆科学钻探先导孔（CCSD-PP1）橄榄岩的矿物岩石化学分析结果。这些橄榄岩亏损玄武质组分（如低w（CaO＋Al2O3）、高Mg^#等），并经历了中元古代来自软流圈的碳酸岩熔体的交代作用和早中生代的超高压再平衡过程。结合已发表的华北捕虏体橄榄岩资料，对这一橄榄岩的原始地幔属性进行了分析。发现CCSD-PP1橄榄岩与华北古老岩石圈地幔组成相似，是早中生代来自华北岩石圈的构造侵入体。早中生代华北岩石圈的伸展减薄与苏鲁超高压变质岩石的折返提供了早期软流圈物质上涌的构造体制。  相似文献   

天然气中甲烷和CO2的二元同位素特征     

唐茂  赵辉  刘耘 《矿物学报》2007,27(3):396-399

不同成因的天然气由于形成温度不同，往往会有不同的稳定同位素特征。但是，由于经常不能同时获得天然气以及它的生成母体的同位素成分，很难用单独的C或H同位素成分来确定它的形成温度。在形成天然气时，不同的温度会形成不同的二元同位素的浓度，温度越低，二元同位素的比例越大，因此只需要知道天然气本身的二元同位素的浓度，就可以确定形成温度，从而避免了需要知道天然气生成母体的同位素成分这一难题。本文利用高级量子化学计算，预测了不同温度下天然气中甲烷和CO2气体的二元同位索（Clumped isotope）的特征，提供用于天然气成因分析的新方法。  相似文献   

乌尔逊凹陷含片钠铝石砂岩分布     

刘群  刘立  高玉巧 《世界地质》2007,26(4):403-408

海拉尔盆地乌尔逊凹陷发现含片钠铝石砂岩，片钠铝石为一种成岩自生矿物。将含片钠铝石砂岩和CO2气的井位综合对比，结合该区构造断裂带分布与γ5花岗岩分布特征以及含片钠铝石砂岩与CO2气纵深分布数据的研究，确定含片钠铝石砂岩的分布与断裂带以及γ5花岗岩的分布具有耦合关系，同时含片钠铝石砂岩与CO2气的分布也具有区域相关性。从而可以确定片钠铝石可以作为CO2气的示踪矿物。  相似文献   

C02-CH4流体与金成矿作用：以阿尔泰山南缘和穆龙套金矿为例     

徐九华谢玉玲  丁汝福阴元军单立华  张国瑞 《岩石学报》2007,23(8):2026-2032

造山型金矿的成矿作用与H20-CO2流体有着密切的联系。然而对阿尔泰山南缘和穆龙套金矿的流体包裹体研究表明，无水的CO2-CH4流体在中亚成矿域中一些金矿床中具有同样重要意义。阿尔泰山南缘萨热阔布金矿包裹体的Xch4达0.20～0.23，穆龙套金矿的XCH4为0.07～0.23。CH4扩大了流体不混溶的范围，有利于对Au的富集沉淀。CO2流体在Au成矿中的重要作用至少包括了三方面的意义，即：缓冲流体PH值范围、提高流体中的Au含量并使其维持与还原硫的络合作用进行迁移；扩大超临界流体的温度范围；增加流体不混溶的区域。CH4的加入扩大了流体不混溶的范围，有利于对Au的富集沉淀。  相似文献   

Geochemical characteristics of crude oils from Well Zheng-1 in the Junggar Basin, Xinjiang, China     

李志明  张长江  秦建中  张渠  范明  刘文斌  张志荣 《中国地球化学学报》2007,26(2):163-169

Well Zheng-1 is located in the combined area of the central uplift and the north Tianshan piedmont depression in the Junggar Basin. Two oil-bearing beds are recognized at 4788–4797 m of the Lower Cretaceous Tugulu Formation (K1tg) and 4808.5–4812.5 m of the Lower Jurassic Sangonghe Formation (J1s). The geochemical characteristics of family composition, carbon isotopic composition, saturated hydrocarbons, sterane and terpane biomarkers and carotane of two crude oils are described in this paper. The results show that the geochemical characteristics of the two crude oils are basically similar to each other, indicating they were all derived mainly from the high mature, brine, algae-rich lake facies sediments. Oil-source correlation revealed that crude oils of the two beds were derived mainly from the source rocks of Permian and mixed by the oil derived from the source rocks of Jurassic and Triassic. This is consistent with the geological background with several sets of source rocks in the area studied.  相似文献   

2-D Crustal thermal structure along Thuadara-Sindad DSS profile across Narmada-Son lineament,central India   总被引：1，自引：0，他引：1  

S. N. Rai  S. Thiagarajan 《Journal of Earth System Science》2007,116(4):347-355

Central India is traversed by a WSW-ENE trending Narmada-Son lineament (NSL) which is characterized by the presence of numerous hot springs, feeder dykes for Deccan Traps and seismicity all along its length. It is divided in two parts by the Barwani-Sukta Fault (BSF). To the west of this fault a graben exists, whereas to the east the basement is uplifted between Narmada North Fault (NNF) and Narmada South Fault (NSF). The present work deals with the 2-D thermal modeling to delineate the crustal thermal structure of the western part of NSL region along the Thuadara-Sindad Deep Seismic Sounding (DSS) profile which runs almost in the N-S direction across the NSL. Numerical results of the model reveal that the conductive surface heat flow value in the region under consideration varies between 45 and 47mW/m². Out of which 23mW/m² is the contribution from the mantle heat flow and the remaining from within the crust. The Curie depth is found to vary between 46 and 47 km and is in close agreement with the earlier reported Curie depth estimated from the analysis of MAGSAT data. The Moho temperature varies between 470 and 500°C. This study suggests that this western part of central Indian region is characterized by low mantle heat flow which in turn makes the lower crust brittle and amenable to the occurrence of deep focused earthquakes such as Satpura (1938) earthquake.  相似文献   

楚雄龙岗地区超级不整合与金成矿     

郑明秋  谢先柏  李才先 《云南地质》2007,26(4):397-403

龙岗地区陇川运动-华力西运动间造成整个古生代地层缺失，中上三叠统直接覆于下元古界哀牢山岩群、大红山岩群等基底岩系之上，本文称为“超级不整合”。华力西期-喜马拉雅期历次地壳事件在“超级不整合”接触带形成“矿质”的“浪淘砂”式、叠次‘堆积’作用，对该区金成矿有决定性作用，先后发现小水井与大龙潭两个典型金矿床。前者为“地下水热卤水溶滤中低温热液蚀变角砾岩微粒浸染型金矿床”，可类比为“卡林型”；后者为“原生沉积地下热水溶滤中低温热液蚀变砂砾岩微粒-粗粒型金矿床”，为该区首次发现的新类型。  相似文献   

南海北部莺歌海盆地壳源型非生物CO2运聚成藏特征与资源潜力          下载免费PDF全文

何家雄姚永坚  刘海龄施小斌 万志峰 《中国地质》2007,34(5):887-893

南海北部莺歌海盆地壳源型非生物(无机)成因CO2运聚成藏机制独特、分布规律复杂、资源规模及潜力巨大,根据目前勘探及研究程度,其CO2资源量逾万亿立方米,勘探所获地质储量超过2000亿m3,居中国探明CO2地质储量之首,在世界范围亦是罕见的,故具有颇大的资源潜力与综合开发利用前景。CO2具明显的多重性,其不仅能广泛应用于国民经济及工农业生产中,而且是导致"厄尔尼诺"现象,严重影响生态环境的主要温室气体,因此,如何综合开发利用这种储量规模巨大的CO2资源,充分发挥其市场经济价值,促进国家经济建设,这是目前该区天然气勘探开发面临的重大科技攻关课题。  相似文献   

堤坝管涌的室内试验与颗粒流细观模拟研究   总被引：3，自引：0，他引：3  

张刚  周健  姚志雄 《水文地质工程地质》2007,34(6):83-86

本文对水流垂直方向的堤坝管涌现象分别进行了室内模型模拟和颗粒流模拟实验。在室内模型试验模拟中采用先进的数码成像跟踪设备在细观的尺度上对土样在管涌发生发展的全过程进行了观察和记录,为颗粒流细观模拟提供了必要的细观参数及宏观依据。提出的二维孔隙率与三维孔隙率转换的关系公式很好的将室内模型试验的孔隙率同颗粒流数值模拟结合,运用颗粒流程序采用固液耦合的分析模型对管涌现象作进一步的数值模拟分析。根据模拟结果,分析了管涌产生、发展在颗粒细观尺度的原因,对管涌产生发展中的试样细观变化规律及流速的变化规律进行了分析。这些结果为PFC2D在渗流和渗透破坏等方面的深入研究应用提供了一定的实用依据,同时也为在细观尺度上解释和分析管涌现象提供了一条新的途径。  相似文献