Relict olivine grains, chondrule recycling, and implications for the chemical, thermal, and mechanical processing of nebular materials     

Alex Ruzicka  Christine Floss 《Geochimica et cosmochimica acta》2008,72(22):5530-5557

Chondrules and isolated forsterites in five low-subtype ordinary chondrites [NWA 3127 (LL3.1), Sahara 97210 (LL3.2), Wells (LL3.3), Chainpur (LL3.4), and Sahara 98175 (LL3.5)] were studied using petrographic, EMPA, and SIMS techniques to better constrain the origin of chondrules and the olivine grains within them. Our results imply that igneous crystallization, vapor fractionation, redox effects, and open-system behavior were important processes. All olivine grains, including normal, relict, and isolated forsterite grains, show evidence for igneous fractionation under disequilibrium conditions, with olivine crystallizing during rapid cooling (closer to 2000 °C/h than to 100 °C/h). Vapor fractionation is manifested by anti-correlated abundances between refractory elements (Al, Sc, Y, Ti, Ca, V) and volatile elements (Cr, Mn, P, Rb, Fe) in olivine. Redox effects are evidenced in various ways, and imply that Fe, Co, Ni, and P were partitioned more into metal, and V was partitioned more into olivine, under reducing conditions in the most FeO-poor melts. There is no obvious evidence for systematic variations in olivine composition according to meteorite subtype, but shock melting in Sahara 97210 resulted in the injection of glass-derived melt into olivine, resulting in artificially high abundances of Ba, Sr, Na, Ti, and some other incompatible elements in olivine. Terrestrial weathering in a hot desert environment may have mobilized Ba and Sr in some glasses.Our data suggest that chondrules in ordinary chondrites experienced repeated thermal, chemical, and mechanical processing during a “recycling” process over an extended time period, which involved multiple episodes of melting under fluctuating redox and heating conditions, and multiple episodes of chondrule break-up in some cases. Forsterite grains, including normal grains in forsterite-bearing type I chondrules, the cores of isolated forsterites, and relict forsterite in type II chondrules, all crystallized from similar, refractory melts under reducing conditions; relict Mg-olivine and isolated forsterite grains were thus derived from type I chondrules. Olivine in type II chondrules, including normal grains and ferroan overgrowths on relict Mg-olivine, crystallized from more volatile-rich, oxidized, and relatively unfractionated melts. Relict dusty olivine grains in type I chondrules were derived from type II chondrules during incomplete melting episodes involving reduction and some vaporization, with clear (non-dusty) grains in dusty olivine-bearing chondrules crystallizing from the reduced and partly vaporized melts. Melt compositions parental to normal olivine grains in type I and II chondrules are systematically enriched in refractory elements compared to bulk chondrule compositions, implying that chondrules often experienced open-system exchange with more volatile-rich surroundings after some olivine had crystallized, possibly while the chondrules were still partly molten. Type II chondrules could have been derived from type I chondrules by the addition of relatively volatile-rich material, followed by re-melting and little evaporation under oxidizing conditions. In contrast, type I chondrules could have been derived from type II chondrules by re-melting involving more-or-less evaporation under reducing conditions. Chemical, oxygen isotope, and petrographic data are best accommodated by a model in which there were several (>2-3, sometimes ?4-5) melting episodes for most chondrules in ordinary chondrites.  相似文献   

Catch-quota balancing in multispecies individual fishing quotas   总被引：2，自引：1，他引：2  

James N. Sanchirico  Daniel Holland  Kathryn Quigley  Mark Fina   《Marine Policy》2006,30(6):767-785

Individual fishery quotas (IFQs) are an increasingly prevalent form of fishery management around the world, with more than 170 species currently managed with IFQs. Yet, because of the difficulties in matching quota holdings with catches, many argue that IFQs are not appropriate for multispecies fisheries. Using on-the-ground-experience with multispecies IFQ fisheries in Iceland, New Zealand, Australia, and Canada, we assess the design and use of catch-quota balancing mechanisms. Our methodology includes a mix of interviews with fishery managers, industry representatives, and brokers, literature review, and data analysis. We find that a combination of incentives and limits on use rates for the mechanisms provide sufficient flexibility to the quota owner without the fishery manager incurring excessive levels of overexploitation risk. Contrary to some opinions, these programs are evidence that it is possible to implement IFQ programs for multispecies fisheries and that they can be profitable and sustainable.  相似文献   

Intrinsic sample methods for mineral exploration and resource assessment     

DeVerle Harris  Guocheng Pan 《Natural Resources Research》1993,2(2):113-121

We report on an objective methodology, referred to as intrinsic sample methodology, for the delineation of exploration target areas or resource areas for assessment. Important features of the methodology include (1) identification of recognition criteria for critical genetic factors, (2) synthesis of new variables from enhanced geodata, (3) estimation of logit probability models, and (4) cutting of estimated logit probabilities to delineate exploration targets or resource areas. The methodology is demonstrated on the Walker Lake quadrangle of Nevada and California.  相似文献   

Solution thermochemistry of humic substances—I. Acid-base equilibria of humic acid     

E.M. Perdue 《Geochimica et cosmochimica acta》1978,42(9):1351-1358

The technique of titration calorimetry has been used to characterize the acidic functional groups of humic acid. Both the concentrations of acidic functional groups and the thermodynamic parameters (pK_a, ΔH_a, etc.) for ionization of these functional groups were determined. The calculated values confirm the generally accepted opinion that humic acid contains both carboxyl and phenolic hydroxyl groups. Furthermore, at least one-third of the phenolic hydroxyl groups are not ortho to carboxyl groups and thus cannot participate in chelation of metal ions via salicylate-like complexing sites. The nature of the remaining two-thirds of the phenolic hydroxyl groups is still unknown.  相似文献   

Effect of hydrogen limitation and temperature on the fractionation of sulfur isotopes by a deep-sea hydrothermal vent sulfate-reducing bacterium     

Joost Hoek  Anna-Louise Reysenbach  Donald E. Canfield 《Geochimica et cosmochimica acta》2006,70(23):5831-5841

The fractionation of sulfur isotopes by the thermophilic chemolithoautotrophic Thermodesulfatator indicus was explored during sulfate reduction under excess and reduced hydrogen supply, and the full temperature range of growth (40-80 °C). Fractionation of sulfur isotopes measured under reduced H₂ conditions in a fed-batch culture revealed high fractionations (24-37‰) compared to fractionations produced under excess H₂ supply (1-6‰). Higher fractionations correlated with lower sulfate reduction rates. Such high fractionations have never been reported for growth on H₂. For temperature-dependant fractionation experiments cell-specific rates of sulfate reduction increased with increasing temperatures to 70 °C after which sulfate-reduction rates rapidly decreased. Fractionations were relatively high at 40 °C and decreased with increasing temperature from 40-60 °C. Above 60 °C, fractionation trends switched and increased again with increasing temperatures. These temperature-dependant fractionation trends have not previously been reported for growth on H₂ and are not predicted by a generally accepted fractionation model for sulfate reduction, where fractionations are controlled as a function of temperature, by the balance of the exchange of sulfate across the cell membrane, and enzymatic reduction rates of sulfate. Our results are reproduced with a model where fractionation is controlled by differences in the temperature response of enzyme reaction rates and the exchange of sulfate in and out of the cell.  相似文献   

New typologies for estuarine morphology     

David Prandle  Andrew Lane  Andrew J. Manning   《Geomorphology》2006,81(3-4):309-315

New theories to explain how tides and river flow determine estuarine bathymetries have been developed. The range of validity of these theories has been subsequently assessed against a recently available observational data set.Success in reproducing the evolution of estuarine bathymetries that has occurred over the last 10 000 years provides the basis for the translation, here, of these theories into new typologies. These then provide reference frameworks to enhance our perspective on existing morphologies and identify ‘anomalous’ estuaries. Further refinement of these new theories requires analyses of causal factors responsible for such anomalies drawing on classical morphological experience. These frameworks can also be used for calculating likely future bathymetric adjustments for prescribed changes in mean sea level, tidal amplitudes, river flow and sediment supply.  相似文献   

Partial melting to produce high-silica rhyolites of a young bimodal suite: compositional constraints among rhyolites, basalts, and metamorphic xenoliths from the Harney Basin, Oregon   总被引：1，自引：0，他引：1  

Martin J. Streck 《International Journal of Earth Sciences》2002,91(4):583-593

  相似文献   

Optimal placement of dampers and actuators based on stochastic approach     

Franklin Y. Cheng  Hongping Jiang  Xiaozhe Zhang Ph.D. Candidate 《地震工程与工程振动(英文版)》2002,1(2):237-249

A general method is developed for optimal application of dampers and actuators by installing them at optimal location on seismic-resistant structures. The study includes development of a statistical criterion, formulation of a general optimization problem and establishment of a solution procedure. Numerical analysis of the seismic response in time-history of controlled structures is used to verify the proposed method for optimal device application and to demonstrate the effectiveness of seismic response control with optimal device location. This study shows that the proposed method for the optimal device application is simple and general, and that the optimally applied dampers and actuators are very efficient for seismic response reduction.  相似文献   

A Comparison of Benzene and Toluene Plume Lengths for Sites Contaminated with Regular vs. Ethanol-Amended Gasoline   总被引：3，自引：0，他引：3  

G.M.L Ruiz-Aguilar  K. O'Reilly  P.J.J. Alvarez 《Ground Water Monitoring & Remediation》2003,23(1):48-53

This article describes various statistical analyses of plume-length data to evaluate the hypothesis that the presence of ethanol in gasoline may hinder the natural attenuation of hydrocarbon releases. Plume dimensions were determined for gasoline-contaminated sites to evaluate the effect of ethanol on benzene and toluene plume lengths. Data from 217 sites in Iowa (without ethanol; set 1) were compared to data from 29 sites in Kansas that were contaminated by ethanol-amended gasoline (10% ethanol by volume; set 2). The data were log-normally distributed, with mean benzene plume lengths (± standard deviation) of 193 ± 135 feet for set 1 and 263 ± 103 feet for set 2 (36% longer). The median lengths were 156 feet and 263 feet (69% longer), respectively. Mean toluene plume lengths were 185± 131 feet for set 1 and 211 ±99 feet for set 2 (14% longer), and the median lengths were 158 feet and 219 feet (39% longer), respectively. Thus, ethanol-containing BTEX plumes were significantly longer for benzene (p < 0.05), but not for toluene. A Wilcoxon signed rank test showed that toluene plumes were generally shorter than benzene plumes, which suggests that toluene was attenuated to a greater extent than benzene. This trend was more pronounced for set 2 (with ethanol), which may reflect that benzene attenuation is more sensitive to the depletion of electron acceptors caused by ethanol degradation. These results support the hypothesis that the presence of ethanol in gasoline can lead to longer benzene plumes. The importance of this effect, however, is probably site-specific, largely depending on the release scenario and the available electron acceptor pool.  相似文献   

Natural Gradient Tracer Test to Evaluate Natural Attenuation of MTBE Under Anaerobic Conditions   总被引：1，自引：0，他引：1  

Illa Amerson  Richard L. Johnson 《Ground Water Monitoring & Remediation》2003,23(1):54-61

A natural gradient tracer test using perdeuterated MTBE was conducted in an anaerobic aquifer to determine the relative importance of dispersion and degradation in reducing MTBE concentrations in ground water. Preliminary ground water chemistry and hydraulic conductivity data were used to place the tracer within an existing dissolved MTBE plume at Port Hueneme, California. Following one year of transport, the tracer plume was characterized in detail.
Longitudinal dispersion was identified as the dominant mechanism for lowering the perdeuterated MTBE concentrations. The method of moments was used to determine the longitudinal and lateral dispersion coefficients (0.85 m²/day and 0.08 m²/day, respectively). A mass-balance analysis, carried out after one year of transport, accounted for 110% of the injected mass and indicated that no significant mass loss occurred. The plume structure created by zones of higher and lower hydraulic conductivity at the site was complex, consisting of several localized areas of high tracer concentration in a lower concentration plume. This is important because the aquifer has generally been characterized as exhibiting fairly minor heterogeneity. In addition, the tracer plume followed a curved flowpath that deviated from the more macroscopic direction of ground water flow inferred from local ground water elevation measurements and the behavior of the existing plume. Understanding the mass balance, plume structure, curvature of the tracer plume, and consequently natural attenuation behavior required the detailed sampling approach employed in this study. These data imply that a detailed understanding of site hydrogeology and an extensive sampling network may be critical for the correct interpretation of monitored natural attenuation of MTBE.  相似文献