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针对第三类反应体系的反应器网络综合问题,提出将串联反应以反应物到目的产物的反应步数为依据的新分段策略。通过比较不分段目的产物、不分段目的产物和中间产品、分段副产物和分段目的产物这四种不同的瞬时选择性,提出以分段副产物瞬时选择性为参数,以其对关键组分浓度或转化率的导数为依据选择各阶段最合适的反应器,以目的产物总选择性最大为目标采用遗传算法优化反应器网络。通过三个实例验证了本文所建立方法在解决复杂反应反应器网络综合问题的有效性,且本方法同样适用于简单反应体系。 相似文献
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传统的伪谱(PS)方法,采用傅里叶变换(FT)计算空间导数具有很高的精度,每个波长仅需要两个采样点,而时间导数采用有限差分(FD)近似因而精度较低.当采用大时间步长时,由于时空精度不平衡,PS法存在不稳定性问题.原始的k-space方法可以有效地克服这些问题但是却无法适用于非均匀介质.为了提高原始k-space方法模拟非均匀介质波动方程的精度,我们提出了一种新的k-space算子族.它是用非均匀介质的变速度代替原k-space算子中的常数补偿速度构造得到,引入低秩近似可以高效求解.我们将构造的新的k-space算子应用于耦合的二阶位移波动方程,而不是交错网格一阶速度应力波动方程,使模拟弹性波的计算存储量减少.我们从数学上证明了基于二阶波动方程的k-space方法与基于一阶波动方程的k-space方法是等价的.数值模拟实验表明,与传统的PS、交错网格PS和原始的k-space方法相比,我们的新方法可以在时间和空间步长较大的均匀和非均匀介质中,为弹性波的传播提供更精确的数值解.在保持稳定性和精度的同时,采用较大的时空采样间隔,可以大大降低数值模拟的计算成本. 相似文献
4.
The compositional variability of the lithospheric mantle at extensional settings is largely caused by the reactive percolation of uprising melts in the thermal boundary layer and in lithospheric environments.The Alpine-Apennine(A-A)ophiolites are predominantly constituted by mantle peridotites and are widely thought to represent analogs of the oceanic lithosphere formed at ocean/continent transition and slow-to ultraslow-spreading settings.Structural and geochemical studies on the A-A mantle peridotites have revealed that they preserve significant compositional and isotopic heterogeneity at variable scale,reflecting a long-lived multi-stage melt migration,intrusion and melt-rock interaction history,occurred at different lithospheric depths during progressive uplift.The A-A mantle peridotites thus constitute a unique window on mantle dynamics and lithosphere-asthenosphere interactions in very slow spreading environments.In this work,we review field,microstructural and chemical-isotopic evidence on the major stages of melt percolation and melt-rock interaction recorded by the A-A peridotites and discuss their consequences in creating chemical-isotopic heterogeneities at variable scales and enhancing weakening and deformation of the extending mantle.Focus will be on three most important stages:(i)old(pre-Jurassic)pyroxenite emplacement,and the significant isotopic modification induced in the host mantle by pyroxenite-derived melts,(ii)melt-peridotite interactions during Jurassic mantle exhumation,i.e.the open-system reactive porous flow at spinel facies depths causing bulk depletion(origin of reactive harzburgites and dunites),and the shallower melt impregnation which originated plagioclase-rich peridotites and an overall mantle refertilization.We infer that migrating melts largely originated as shallow,variably depleted,melt fractions,and acquired Si-rich composition by reactive dissolution of mantle pyroxenes during upward migration.Such melt-rock reaction processes share significant similarities with those documented in modern oceanic peridotites from slow-to ultraslow-spreading environments and track the progressive exhumation of large mantle sectors at shallow depths in oceanic settings where a thicker thermal boundary layer exists,as a consequence of slow-spreading rate. 相似文献
5.
This paper proposes a numerical approach to the hyperstatic reaction method (HRM) for the analysis of segmental tunnel linings. The influence of segmental joints has been considered directly using a fixity ratio that is determined on the basis of the rotational stiffness. The parameters necessary for the calculation are presented. A specific implementation has been developed using a FEM framework. This code is able to consider the three‐dimensional (3D) effect of segment joints in successive rings on the tunnel lining behaviour. The present HRM allows one to take an arbitrary distribution of segment joints along the tunnel boundary into consideration. In addition, the rotational stiffness of segment joints has been simulated using nonlinear behaviour, as it is closer to the true behaviour of a joint than linear or bilinear behaviour. The numerical results of three hypotheses on ring interaction, which allow the 3D effect of a segmental tunnel lining to be taken into account, have been compared with data obtained from the shield‐driven tunnel of the Bologna–Florence high‐speed railway line project. The numerical results presented in the paper show that the proposed HRM can be used to effectively estimate the behaviour of a segmental tunnel lining. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
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The size effect of copper wire radius (0.04–0.82 mm) on the diffusion-limited current density of an oxygen reduction reaction in stagnant simulated seawater (naturally aerated 0.5 mol/L NaCl) is investigated by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) and compared with the results obtained in 0.5 mol/L H2SO4. In the oxygen diffusion-limited range, size effect is found to occur independent of electrolytes, which is attributed to non-linear diffusion. Additionally, to sati... 相似文献
8.
凹凸棒石与Zn^2+的长期作用研究 总被引:1,自引:0,他引:1
以凹凸棒石与Zn2+为例研究粘土矿物与重金属离子长期作用过程,并运用高分辨透射电镜和X射线衍射分析粘土矿物与重金属离子长期作用的次生物相。结果表明:Zn2+与凹凸棒石的长期作用是一个二阶段的过程,初始阶段为快速吸附作用,其后表现为慢速沉淀反应。高分辨透射电镜和X射线衍射分析表明,凹凸棒石与Zn2+的长期作用过程中,具有纳米矿物特性的凹凸棒石表面快速水化,提高了悬浮液的pH值,诱导Zn2+水解沉淀。而后,凹凸棒石缓慢溶解释放Al3+和SiO44-与Zn(OH)2沉淀反应,形成Zn-A1双氢氧化物和异极矿。这一结果对认识土壤环境中重金属与粘土矿物的作用及重金属的归宿具有重要意义。 相似文献
9.
Compaction induced by pore‐pressure decrease inside a reservoir can be monitored by measuring traveltime shifts of reflection events on time‐lapse seismic data. Recently we introduced a perturbation‐based formalism to describe traveltime shifts caused by the 3D stress‐induced velocity field around a compacting reservoir. Application of this method to homogeneous background models showed that the offset variation of traveltime shifts is controlled primarily by the anisotropic velocity perturbations and can provide valuable information about the shear and deviatoric stresses. Here, we model and analyse traveltime shifts for compacting reservoirs whose elastic properties are different from those of the surrounding medium. For such models, the excess stress is influenced primarily by the contrast in the rigidity modulus μ across the reservoir boundaries. Synthetic examples demonstrate that a significant (25% or more) contrast in μ enhances the isotropic velocity perturbations outside the reservoir. Nevertheless, the influence of background heterogeneity is mostly confined to the reservoir and its immediate vicinity and the anisotropic velocity changes are still largely responsible for the offset dependence of traveltime shifts. If the reservoir is stiffer than the host rock, the background heterogeneity reduces anisotropic velocity perturbations inside the reservoir but increases them in the overburden. As a result, in this case, the magnitude of the offset variation of traveltime shifts is generally higher for reflections from interfaces above the reservoir. We also study compaction‐induced stress/strain and traveltime shifts for a stiff reservoir embedded in a softer layered model based on velocity profiles from the Valhall Field in the North Sea. Despite producing discontinuities in strain across medium interfaces, horizontal layering does not substantially alter the overall behaviour of traveltime shifts. The most pronounced offset variation of traveltime shifts is observed for overburden events recorded at common midpoints close to the reservoir edges. On the whole, prestack analysis of traveltime shifts should help better constrain compaction‐induced velocity perturbations in the presence of realistic background heterogeneity. 相似文献
10.
F.A. Radu N. Suciu J. HoffmannA. Vogel O. Kolditz C.-H. ParkS. Attinger 《Advances in water resources》2011,34(1):47-61
This work deals with a comparison of different numerical schemes for the simulation of contaminant transport in heterogeneous porous media. The numerical methods under consideration are Galerkin finite element (GFE), finite volume (FV), and mixed hybrid finite element (MHFE). Concerning the GFE we use linear and quadratic finite elements with and without upwind stabilization. Besides the classical MHFE a new and an upwind scheme are tested. We consider higher order finite volume schemes as well as two time discretization methods: backward Euler (BE) and the second order backward differentiation formula BDF (2). It is well known that numerical (or artificial) diffusion may cause large errors. Moreover, when the Péclet number is large, a numerical code without some stabilising techniques produces oscillating solutions. Upwind schemes increase the stability but show more numerical diffusion. In this paper we quantify the numerical diffusion for the different discretization schemes and its dependency on the Péclet number. We consider an academic example and a realistic simulation of solute transport in heterogeneous aquifer. In the latter case, the stochastic estimates used as reference were obtained with global random walk (GRW) simulations, free of numerical diffusion. The results presented can be used by researchers to test their numerical schemes and stabilization techniques for simulation of contaminant transport in groundwater. 相似文献