Relocation effects of dredged marine sediments on mercury geochemistry: Venice lagoon,Italy     

Seunghee Han  Joris Gieskes  Anna Obraztsova  Dimitri D. Deheyn  Bradley M. Tebo 《Estuarine, Coastal and Shelf Science》2011

Understanding the biogeochemical process of Hg is critical in the overall evaluation of the ecological impacts resulting from the reuse of Hg-contaminated dredged sediment. Sediment banks (V1 and V2) were constructed with freshly dredged sediments from a navigational channel in Venice Lagoon, Italy, with the goal of clarifying potential differences in the biogeochemistry of Hg between the reused dredged sediments and those from surrounding sites (SS1 and S2). Toward this purpose, Hg and monomethylmercury (MMHg) concentrations, and Hg methylation rates (MMRs) in the surface 2.5 cm sediments were monitored, along with ammonium, iron, sulfate and sulfide concentrations in the pore waters of banks and surrounding sites from November 2005 to February 2007. Pore water analyses indicate that the bank sediments are characterized by lower levels of sulfate and iron, and by higher levels of ammonium and sulfide compared to the surrounding sediments. With respect to Hg speciation, the fractions of MMHg in total Hg (%MMHg/Hg) and the MMRs were significantly lower in the bank V1 compared to those in the reference site SS1, whereas the %MMHg/Hg and the MMRs were similar between V2 and S2. A negative correlation is found between the logarithm of the particle-water partition coefficient of Hg and the MMR, indicating that the reduced MMRs in V1 are caused by the limited concentrations of dissolved Hg. Organic matter appears to play a key role in the control of MMR via the control of Hg solubility.  相似文献   

More than just access to fish: The pros and cons of fisher participation in a customary marine tenure (Padu) system under pressure     

Sarah Coulthard 《Marine Policy》2011

The Padu system of South Asia has received growing attention as an example of customary marine tenure that has survived despite rapid development and change throughout the region’s fisheries. This paper describes the Padu system as it functions at Pulicat lagoon, India, where it has enjoyed decades of legitimacy amongst its members, and has contributed to sustainable fishing. Recently, however, the Padu system has become unstable, driven by pressures of an expanding fishing population, reduced access to fishing grounds and a growing ‘shared poverty’. In spite of this, fisher loyalty to uphold the Padu system remains strong. This raises questions about the broader social, political and cultural meanings of Padu, which extend beyond access to a lucrative fishery. The paper highlights a trade-off between the benefits received through Padu membership at a societal level through collective action, and the individual costs of partaking in ‘shared poverty’, which is inherently distributed unequally amongst fishing families. The paper concludes with a discussion on the future of the Padu system in Pulicat, drawing from evolutionary pathways of other Padu systems in the region. It is suggested that, in the Pulicat case, the high social values attributed to the Padu system, alongside complex power structures, may hinder institutional adaptation.  相似文献   

Distribution and partitioning of major and trace elements in pyrite-bearing sediments of a Mediterranean coastal lagoon     

《Chemie der Erde / Geochemistry》2015,75(2):219-236

The formation of iron sulphide minerals exerts significant control on the behaviour of trace elements in sediments. In this study, three short sediment cores, retrieved from the remote Antinioti lagoon (N. Kerkyra Island, NW Greece), are investigated concerning the solid phase composition, distribution, and partitioning of major (Al, Fe) and trace elements (Cd, Cu, Mn, Pb, and Zn). According to ²¹⁰Pb, the sediments sampled correspond to depositions of the last 120 years. The high amounts of organic carbon (4.1–27.5%) result in the formation of Fe sulphides, predominantly pyrite, already at the surface sediment layers. Pyrite morphologies include monocrystals, polyframboids, and complex FeS–FeS₂ aggregates. According to synchrotron-generated micro X-ray fluorescence and X-ray absorption near-edge structure spectra, authigenically formed, Mn-containing, Fe(III) oxyhydroxides (goethite type) co-exist with pyrite in the sediments studied. Microscopic techniques evidence the formation of galena, sphalerite and CuS, whereas sequential extractions show that carbonates are important hosts for Mn, Cd, and Zn. However, significant percentages of non-lattice held elements are bound to Fe/Mn oxyhydroxides that resist reductive dissolution (on average 60% of Pb, 46% of Cd, 43% of Zn and 9% of Cu). The partitioning pattern changes drastically in the deeper part of the core that is influenced by freshwater inputs. In these sediments, the post-depositional pyritization mechanism, illustrated by overgrowths of Fe monosulphides on pre-existing pyrite grains, results in relatively high degree of pyritization that reaches 49% for Cd, 66% for Cu, 32% for Zn and 7% for Pb.  相似文献   

An Experimental Test of the Capacity of Food Web Interactions (Fish–Epiphytes–Seagrasses) to Offset the Negative Consequences of Eutrophication on Seagrass Communities     

E. Gacia  M. M. Littler  D. S. Littler   《Estuarine, Coastal and Shelf Science》1999,48(6):757

A mechanism of competition between epiphytes and seagrasses potentially modulated by grazers was studied in a high-nutrient Thalassia testudinum meadow in the Indian River Lagoon (Florida, U.S.A.). The effects of fish grazing on epiphytes, and likely enhancing T. testudinum growth, was tested through an exclusion experiment. Twelve (2×2m) independent experimental plots were selected within a shallow monospecific bed to which three randomized treatments (exclusion fences, open fences and controls) with four replicates each were assigned. The epiphyte load was monitored on T. testudinum leaves inside the plots from January 1995 to March 1996. Treatment effects occurred during a chlorophyte bloom in March 1995, when the epiphyte biomass was significantly higher inside the exclusion cages than in either of the controls. The composition of the epiphytic community in March 1995 was dominated by sheet-like Enteromorpha and filamentous algae such as Cladophora , which are less resistant to herbivory than the coarsely-branched forms of red algae (e.g. Hypnea , Chondria and Acanthophora) that bloomed subsequently. These results suggest that herbivory change seasonally depending on the availability of different prey species to fish-grazers, which preferentially utilize the fleshy green algae typical of bloom conditions over the thicker coarsely-branched red algae. In the nutrient-rich lagoon the role of top-down interactions in enhancing T. testudinum growth is limited to the reduction of shading by green macroalgae.  相似文献   

Changes in Venice Lagoon dynamics due to construction of mobile barriers     

Michol Ghezzo  Stefano Guerzoni  Andrea Cucco  Georg Umgiesser 《Coastal Engineering》2010

The MoSE project (construction of mobile barrier to safeguard the Lagoon of Venice) entails changes to the structure of the lagoon's inlets. This could have consequences for the areas near the inlets and for the dynamics of the lagoon ecosystem as a whole. In order to predict the effects of the proposed alterations on the hydrodynamics of the lagoon, a well-tested hydrodynamic-dispersion model was applied. Simulations were carried out considering both idealised and realistic tide and wind scenarios.  相似文献   

Spatial and temporal variations of sedimented organic matter in Xiaohai Lagoon, Hainan Island   总被引：1，自引：1，他引：0  

LIU Xingjian  GE Chendong 《海洋学报(英文版)》2012,31(3):74-86

The characteristics of grain-size,total organic carbon(TOC) and total nitrogen(TN) contents,TOC/TN ratios,stable carbon isotope(δ13C) and 210 Pb dating were measured in six sediment cores from the Xiaohai Lagoon.The results show distinct spatial and temporal variations in sedimentation patterns.The sediments are dominated by clayey silt,sandy silt and by silty sand in the southern,middle lagoon and the northern lagoon,respectively.TOC and TN contents decline from south to north.Sedimentation rates,determined by 210 Pb dating,tend to decrease from south to middle.However,the determination of sedimentation rate in the north is difficult.These spatial variations are related to the variations in sediment sources and hydrodynamic conditions in the Xiaohai Lagoon.The variations of organic matter signatures can be divided into two stages in the cores from the southern and middle lagoon.Before 1988,the organic matter signatures are relatively stable.The contribution of terrestrial organic carbon sources varies between 60% and 85%.After 1988,the organic matter signatures demonstrate significant variations.TOC and TN contents increase rapidly,TOC/TN ratios decrease,δ13C values shift to higher and the contribution of terrestrial organic carbon sources decreases to 40%-50%.The contributions of phytoplankton organic matter have increased in the sediment since 1988.Increasing aquaculture activities have had a significant impact on organic matter signatures since 1988.The sedimentation rates have increased rapidly in the southern and middle lagoon since 1988 due to the anthropogenic activities which include aquaculture,mining and deforestation.These activities have caused eutrophication and increased siltation in the southern and middle lagoon.  相似文献   

Isotopic and geochemical characterization of salinization in the shallow aquifers of a reclaimed subsiding zone: The southern Venice Lagoon coastland   总被引：3，自引：0，他引：3  

Julie C. Gattacceca  Christine Vallet-Coulomb  Adriano Mayer  Christelle Claude  Olivier Radakovitch  Enrico Conchetto  Bruno Hamelin   《Journal of Hydrology》2009,378(1-2):46-61

The coastal plain bordering the southern Venice Lagoon is a reclaimed lowland characterized by high subsidence rate, and ground level and water-table depth below sea level. In this agricultural region, where the surface hydrologic network is entirely artificially controlled by irrigation/drainage canals, salinization problems have long been encountered in soils and groundwaters. Here we use isotopic and geochemical tracers to improve our understanding of the origin of salinization and mineralization of the semi-confined aquifer (0–40 m), and the freshwater inputs to this hydrological system. Water samples have been collected at different seasons in the coastal Adriatic Sea, lagoon, rivers and irrigation canals, as well as in the semi-confined aquifer at depths between 12 and 35 m (14 boreholes), and in the first confined aquifer (three boreholes drilled between 40 and 80 m depth). Stable isotopes (δ¹⁸O and δD) and conductivity profiles show that direct saline intrusion from the sea or the lagoon is observed only in a restricted coastal strip, while brackish groundwaters are found over the entire topographic and piezometric depression in the centre of the study area. Fresh groundwaters are found only in the most western zone. The sharp isotopic contrast between the western and central regions suggests disconnected hydrological circulations between these two parts of the shallow aquifer. The border between these two regions also corresponds to the limits of the most strongly subsiding zone.Our results can be interpreted in terms of a four end-member mixing scheme, involving (1) marine water from the lagoon or the open sea, (2) alpine and pre-alpine regional recharge waters carried either by the main rivers Adige, Bacchiglione and Brenta (irrigation waters) or by the regional groundwater circulation, (3) local precipitation, and (4) evaporated waters infiltrated from the surface. Infiltration from the surface is also revealed by the stratification of the electrical conductivity profiles, showing that the brackish groundwaters are overlain by a shallow layer of less saline water all over the central depression. In the first confined aquifer, the groundwaters have isotopic compositions similar to the deep groundwaters of the Venetian confined aquifers (40–400 m depth). The isotopic data and the Br/Cl ratio show that the origin of the salinization of the phreatic aquifer can be ascribed to seawater intrusion alone, with no indication of the involvement of deep brines (identified at 450 m depth) in the process.The chemical composition of the saline and brackish groundwaters is characterized by an excess of sodium and a deficit of calcium compared to conservative mixing between fresh groundwaters and seawater. This suggests that the phreatic aquifer is progressively freshening, as a consequence of the beneficial influence of the extensive irrigation/drainage network, including raised canals acting as a hydraulic barrier along the coast. This freshening tendency may have been lasting since the reclamation in the mid-twentieth century, and has probably been accelerated by the ban on groundwater abstraction since the 1970s.  相似文献   

天津七里海古泻湖湿地环境演变研究   总被引：3，自引：0，他引：3  

秦磊 《湿地科学》2012,10(2):181-187

七里海古泻湖湿地位于天津市宁河县西南部,是全新世以来海退过程在天津平原留下的众多古泻湖湿地之一。分析了七里海古泻湖湿地形成、演变的区域地质背景,指出七里海古泻湖至少经历了3次大规模萎缩,其西南部萎缩较快,东北部萎缩相对较慢。利用历史资料研究了近5000a七里海古泻湖湿地的形成、演变过程,并以1950年航空照片和1976年、1981年、1987年、2000年、2005年的MSS、TM和ETM+影像数据为主要数据源,用遥感和地理信息系统技术研究了近百年七里海古泻湖湿地的环境变化。结果表明,距今5000a,七里海地区为海相沉积环境,海岸线穿越宁河的潘庄镇、大海北、小海北一带;距今3800～3000a,海岸线退至造甲城、七里海镇一带;到清朝乾隆年间,七里海湿地逐渐被分割成前海、后海、曲里海3部分,湖底不断淤积,水面不断萎缩,逐渐演变为湖泊、沼泽湿地;1926～2005年间,七里海湿地大致经历了3个变化阶段:1926～1950年为自然变化阶段,七里海湿地的变化主要受自然因素的影响,该阶段七里海湿地仍由前海、后海、曲里海3部分组成;1951～1981年为改造治理阶段,七里海被潮白河拦腰截断,分为东、西七里海,后海被改造为农田;1982～2005年为围垦和水产养殖阶段,东、西七里海的大面积水域以及湿地周围的大片农田都被改建为养殖池,自然湿地在减少,人工湿地在不断增加,导致七里海湿地景观类型日趋单一,生物多样性明显减少。  相似文献   

Sediments Quality Assessment of Jacarepaguá Lagoon: The Venue of the 2011 Rock in Rio     

José Tavares Araruna Júnior  Paula Elias Benedetti  Patrício José Moreira Pires  Ricardo Froitzheim Rinelli de Almeida 《洁净——土壤、空气、水》2012,40(9):906-910

In order to aid in the efforts of the 2016 Olympic Games, the organizers of 2011 Rock in Rio decided to build a permanent venue next to the Olympic Park. The area is problematic from the geotechnical point of view since it presents soils with low shear strength, low permeability, and high plasticity, so major soil improvement works were carried out. Bored soil–cement columns were placed to increase soil shear strength and reduce compressibility. A meter thick fill composed of gneiss residual soil was placed and trenches were digged to drain rainwater. However, earlier studies conducted on Jacarepaguá Lagoon have detected the presence of heavy metals in these sediments. In this study, an environmental survey on the Jacarepaguá Lagoon sediments took place in order to choose a place where its sediments could be dredged to be later used in the drainage facilities. The results indicated areas where the threshold level 1 (low probability of adverse effects) issued by the general procedures for sediments quality assessments for dredging purposes, Resolution no 344 of the Brazilian Federal Government, was surpassed. Levels above the limits established for cadmium (Cd), lead (Pb), copper (Cu), nickel (Ni), and zinc (Zn) were detected. Based on this consideration the State Environmental Agency issued a permit allowing the organizers of 2011 Rock in Rio to dredge an area close to City of Rock in order to obtain coarse sediments for the drainage facilities. In addition, it was found that those sediments were ideal for this application since their hydraulic conductivity is on the order of 10^?2 cm/s.  相似文献   

History of human activity in coastal southern Brazil from sediment     

《Marine pollution bulletin》2014,78(1-2):209-212

This study reports results of analysis of sediment cores collected from the Patos Lagoon estuary. This estuary receives materials from land runoff into Patos and Mirim lagoons and from exchange with the adjacent South Atlantic Ocean through a narrow inlet. Sediment from these sources is mostly natural, but additional contributions associated with source/activities related to the port of Rio Grande. The aim of this study was to estimate rates of accumulation of the sediments and to assess the significance of metal inputs from these activities relative to natural inputs. Our results indicate an average sedimentation rate of 0.3 cm/yr and that the transport of suspended solids from offshore sources into the estuary was enhanced after the deepening of the channel and construction of the breakwaters (in the early 1900). Results for metal accumulation in these sediments suggest that there have been only minor enrichments which can be attributed to anthropogenic sources.  相似文献